对苯二腈在MAF-5中的孔限制三聚化

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-10-01 DOI:10.1039/d5cc04880j

Xiong-Hai Chen, Lu Jiang, Xue-Wen Zhang, Xing-Tian Qiu, Dong-Dong Zhou, Hao-Long Zhou, Rui-Biao Lin, Xiao-Chun Huang, Jie-Peng Zhang

{"title":"对苯二腈在MAF-5中的孔限制三聚化","authors":"Xiong-Hai Chen, Lu Jiang, Xue-Wen Zhang, Xing-Tian Qiu, Dong-Dong Zhou, Hao-Long Zhou, Rui-Biao Lin, Xiao-Chun Huang, Jie-Peng Zhang","doi":"10.1039/d5cc04880j","DOIUrl":null,"url":null,"abstract":"The nitrile trimerization reaction of terephthalonitrile requires catalysts and temperature above 400 o C, and yields polymers. Being confined in a metal-organic framework MAF-5, the reaction temperature lowers to 240 o C without using catalysts, and the product becomes a unitary trimer.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"18 1","pages":""},"PeriodicalIF":4.2000,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Pore confined trimerization of terephthalonitrile in MAF-5\",\"authors\":\"Xiong-Hai Chen, Lu Jiang, Xue-Wen Zhang, Xing-Tian Qiu, Dong-Dong Zhou, Hao-Long Zhou, Rui-Biao Lin, Xiao-Chun Huang, Jie-Peng Zhang\",\"doi\":\"10.1039/d5cc04880j\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The nitrile trimerization reaction of terephthalonitrile requires catalysts and temperature above 400 o C, and yields polymers. Being confined in a metal-organic framework MAF-5, the reaction temperature lowers to 240 o C without using catalysts, and the product becomes a unitary trimer.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"18 1\",\"pages\":\"\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5cc04880j\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc04880j","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

对苯二甲腈的腈三聚反应需要催化剂和400℃以上的温度，并产生聚合物。在金属-有机骨架MAF-5中，不使用催化剂，反应温度降至240℃，产物为单一三聚体。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Pore confined trimerization of terephthalonitrile in MAF-5

The nitrile trimerization reaction of terephthalonitrile requires catalysts and temperature above 400 o C, and yields polymers. Being confined in a metal-organic framework MAF-5, the reaction temperature lowers to 240 o C without using catalysts, and the product becomes a unitary trimer.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.