含亮氨酸基二胺单元的对称定向不同手性π堆叠苯并噻二唑组合的种子控制

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-10-01 DOI:10.1039/d5cc05008a

Saeko Yamada, Naoto Inai, Soichiro Ogi, Takeshi Yanai, Shigehiro Yamaguchi

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引用次数: 0

摘要

对称和不对称结合的亮氨酸衍生二胺具有相同的手性苯并噻二唑-含芳炔乙炔可以种子控制三个不同的手性π堆叠组装。理论研究表明，苯并噻二唑单位的取向有助于这种多样性，突出了取代模式和动力学控制程序如何在π共轭超分子体系中结构有序的复杂性。

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Seeded Control of Symmetry-Directed Diverse Chiral π-Stacked Benzothiadiazole Assemblies with Leucine-based Diamide Units

Symmetrical and unsymmetrical incorporation of leucine-derived diamides with identical chirality into a benzothiadiazole-containing aryleneethynylene enables seeded control of three distinct chiral π-stacked assemblies. Theoretical studies indicate that the orientation of benzothiadiazole units contributes to this diversity, highlighting how substitution patterns and kinetic control program structurally ordered complexity in π-conjugated supramolecular systems.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.