三维钴腐蚀基Zr-MOF选择性吸附一氧化碳

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-10-01 DOI:10.1039/d5cc04145g

Ken Rapady, Jian Yang, Stéphane Brandès, Nicolas Desbois, Laurie ANDRE, Claude P Gros

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引用次数: 0

摘要

本文介绍了两种基于三苯基苯酚及其金属钴化类似物（CoCorr-MOF）的三维mof。它们具有六角形形貌，颗粒尺寸均匀，微孔比表面积分别为390和304 m²g-1。CoCorr-MOF对CO的亲和力优于其他干扰物（N2、CO2和O2）。其CO吸附量为7.2 cm3 g-1，具有较高的选择性。

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3D Cobalt Corrole-based Zr-MOF for the Selective Adsorption of Carbon Monoxide

Two 3D MOFs based on a triphenylcorrole and their cobalt-metalated analogs (CoCorr-MOF) are presented. They show a hexagonal morphology, homogeneous particles size, and a microporosity with a specific area of 390 and 304 m² g-1, respectively. The CoCorr-MOF presents a better affinity for CO than for other interferents (N2, CO2 and O2). It demonstrates a CO sorption capacity of 7.2 cm3 g-1 with high selectivity.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.