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Supramolecular chemistry-based materials on SO2 capture: Recent Advances 基于超分子化学的SO2捕集材料研究进展
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-09-30 DOI: 10.1039/d5cc04442a
Antonio Hernández-Monsalvo, Pablo Marín-Rosas, Víctor M. Trejos, Nancy Elizabeth Dávila Guzmán, J. de los Reyes, Diego Solis-Ibarra, Enrique Lima, Ricardo A. Peralta, Ilich A. Ibarra
{"title":"Supramolecular chemistry-based materials on SO2 capture: Recent Advances","authors":"Antonio Hernández-Monsalvo, Pablo Marín-Rosas, Víctor M. Trejos, Nancy Elizabeth Dávila Guzmán, J. de los Reyes, Diego Solis-Ibarra, Enrique Lima, Ricardo A. Peralta, Ilich A. Ibarra","doi":"10.1039/d5cc04442a","DOIUrl":"https://doi.org/10.1039/d5cc04442a","url":null,"abstract":"The urgent need for efficient methods to detect, monitor, and capture toxic and hazardous sulfur dioxide (SO2) has driven the development of new devices for this purpose. Due to its significant corrosiveness and highly toxicity, a key requirement for adsorbent materials is their ability to withstand deterioration, alongside possessing high gas sensitivity and selectivity. Within this domain, supramolecular chemistry has made substantial inroads through the development of innovative porous materials formed by the self-assembly of molecular building blocks, driven by diverse interactions. The complex architectures that result can be categorised as either extended networks, such as metal-organic frameworks (MOFs) and covalent organic frameworks (COFs); or as molecular cages, including metal-organic cages (MOCs) and porous organic cages (POCs). These materials have demonstrated high capture capacities, extremely sensitive detection limits, and even active sites for the catalytic transformation of adsorbed molecules. This review aims to highlight the primary contributions of these supramolecular materials to the experimental adsorption of SO2, along with their most remarkable results.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"5 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145189364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ru(II)-Catalysed, Inherent-Directing Group Enabled Site-selective C-H Vinyl trifluoromethylation of Isoquinolones and Benzamides Ru（II）催化的、内在导向基团激活的位点选择性C-H乙烯基异喹诺酮类和苯甲酰胺的三氟甲基化
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-09-30 DOI: 10.1039/d5cc04761g
Sachin ., Tamanna Sharma, Shourabh Rav, Upendra Sharma
{"title":"Ru(II)-Catalysed, Inherent-Directing Group Enabled Site-selective C-H Vinyl trifluoromethylation of Isoquinolones and Benzamides","authors":"Sachin ., Tamanna Sharma, Shourabh Rav, Upendra Sharma","doi":"10.1039/d5cc04761g","DOIUrl":"https://doi.org/10.1039/d5cc04761g","url":null,"abstract":"Herein, we unveil Ru(II)-catalysed an efficient and site-selective route for synthesising vinyltrifluoromethylated arenes by utilising amide carbonyl as an inherent directing group. 2-bromo-3,3,3-trifluoropropene has been utilised as a sustainable surrogate of vinyltrifluoromethylation to provide diversely decorated isoquinolones and benzamides. Mechanistic studies have been performed to articulate the plausible mechanism. A vast array of substrates is amenable to this transformation, and post-synthetic modification of products features the importance of the developed approach.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"2 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145188982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elucidating host–guest interactions between phosphine-based porous aromatic frameworks and platinum for enhanced HER 阐明磷基多孔芳香框架与铂之间的主客体相互作用以增强HER
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-09-30 DOI: 10.1039/d5cc03929k
Yang Xiao, Zelin Shi, Han Yan, Jiahui Li, Shuo Han, Yuting Yang, Xiaofei Jing
{"title":"Elucidating host–guest interactions between phosphine-based porous aromatic frameworks and platinum for enhanced HER","authors":"Yang Xiao, Zelin Shi, Han Yan, Jiahui Li, Shuo Han, Yuting Yang, Xiaofei Jing","doi":"10.1039/d5cc03929k","DOIUrl":"https://doi.org/10.1039/d5cc03929k","url":null,"abstract":"Host–guest interactions between porous materials and metal species play an important role in boosting the catalytic activities of supported catalysts. Here, we utilized phosphine-based porous aromatic frameworks (PAFs) as effective hosts, and elucidated how the interactions between PAFs and Pt nanoparticles affected their catalytic performances for the hydrogen evolution reaction.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"11 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145189366","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Direct palladium-catalyzed C-H arylation of bioactive triazolyl-C-nucleosides on a key position of the heterocyclic base. 在杂环碱的关键位置上直接钯催化生物活性三唑-c -核苷的C-H基化。
IF 4.2 2区 化学
Chemical Communications Pub Date : 2025-09-30 DOI: 10.1039/d5cc04215a
Bartosz Godlewski, Nina Bozinovic, Quentin Joachim, Olivier Monasson, Nadège Lubin-Germain, Angélique Ferry
{"title":"Direct palladium-catalyzed C-H arylation of bioactive triazolyl-<i>C</i>-nucleosides on a key position of the heterocyclic base.","authors":"Bartosz Godlewski, Nina Bozinovic, Quentin Joachim, Olivier Monasson, Nadège Lubin-Germain, Angélique Ferry","doi":"10.1039/d5cc04215a","DOIUrl":"https://doi.org/10.1039/d5cc04215a","url":null,"abstract":"<p><p>Regarding the potential of nucleosides in therapeutics, especially as antiviral and anticancer drugs, the expansion of the chemical space of such molecules appears urgent. Herein, a direct palladium-catalyzed C-H arylation of the triazolyl pseudonucleobase of bioactive <i>C</i>-nucleosides is described with 14 examples bearing different aryl moieties and decorations on the nucleoside core.</p>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":" ","pages":""},"PeriodicalIF":4.2,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145190386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multistage control of near-infrared and magnetic properties via π-dimer modulation in TCNQ radical anion salts 通过π-二聚体调制TCNQ自由基阴离子盐的近红外和磁性能的多级控制
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-09-30 DOI: 10.1039/d5cc04915f
Ruifeng Shu, Takeshi Naota, Daisuke Shiomi, Shuichi Suzuki
{"title":"Multistage control of near-infrared and magnetic properties via π-dimer modulation in TCNQ radical anion salts","authors":"Ruifeng Shu, Takeshi Naota, Daisuke Shiomi, Shuichi Suzuki","doi":"10.1039/d5cc04915f","DOIUrl":"https://doi.org/10.1039/d5cc04915f","url":null,"abstract":"We report a liquescent 7,7,8,8-tetracyanoquinodimethane radical anion (TCNQ•–) salt with N,N'-di-n-octylimidazolium ion that exhibits unprecedented three-stage switching of magnetic and NIR-II absorption properties upon thermal stimulation. This behavior originates from stepwise transformations between co-facial and slipped-stacking π-dimers and monomeric TCNQ•– species.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"6 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145189061","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Soft Carbon-Coated FeNCN Anodes for Enhanced Potassium Ion Storage 用于增强钾离子储存的软碳涂层FeNCN阳极
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-09-30 DOI: 10.1039/d5cc04901f
Erjin Zhang, Kelei Wu, Zhentao Luo, Yuanning Luo, Peng Wang, Bing Hua, Li Xu, Xuejiao Wang, Henan Li
{"title":"Soft Carbon-Coated FeNCN Anodes for Enhanced Potassium Ion Storage","authors":"Erjin Zhang, Kelei Wu, Zhentao Luo, Yuanning Luo, Peng Wang, Bing Hua, Li Xu, Xuejiao Wang, Henan Li","doi":"10.1039/d5cc04901f","DOIUrl":"https://doi.org/10.1039/d5cc04901f","url":null,"abstract":"A novel iron carbodiimide composite with soft carbon coating was synthesized as a high-performance anode for PIBs. An optimized soft carbon coating enhances electronic conductivity and mitigates structural stress, delivering a high initial capacity (500.3 mAh g-1) and exceptional cycling stability (267.6 mAh g-1 after 590 cycles).","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"26 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145189363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photo-Induced Ruthenium-Catalyzed Alkene C–H-Arylation at Room Temperature 室温下光诱导钌催化烯烃c - h -芳基化
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-09-30 DOI: 10.1039/d5cc04527d
Tanumoy Mandal, Stéphane Golling, Sven Trienes, Lutz Ackermann
{"title":"Photo-Induced Ruthenium-Catalyzed Alkene C–H-Arylation at Room Temperature","authors":"Tanumoy Mandal, Stéphane Golling, Sven Trienes, Lutz Ackermann","doi":"10.1039/d5cc04527d","DOIUrl":"https://doi.org/10.1039/d5cc04527d","url":null,"abstract":"C–H arylation has surfaced as a powerful tool for molecular sciences, with alkene C–H arylation thus far requiring either high reaction temperatures of 120 °C or stoichiometric amounts of RMgX. In sharp contrast, we herein report on room-temperature C–H arlyations of alkenes by means of ruthenium(II) catalysis with ample scope. This strategy also enabled late-stage diversification of structurally complex molecules and mechanistic studies provided strong evidence for photo-excitation of a ruthenacycle intermediate.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"39 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145188980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stepwise selective crystallization of Fe and Dy complexes from a Fe/Nd/Dy mixture: separation despite charge and solubility similarity Fe/Nd/Dy混合物中Fe和Dy配合物的逐步选择性结晶：尽管电荷和溶解度相似，但分离
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-09-30 DOI: 10.1039/d5cc03074a
Natsuki Hasegawa, Akiho Yanai, Hinako Masaki, Akira Kirishima, Ryo Tsunashima, Atsuko Masuya-Suzuki
{"title":"Stepwise selective crystallization of Fe and Dy complexes from a Fe/Nd/Dy mixture: separation despite charge and solubility similarity","authors":"Natsuki Hasegawa, Akiho Yanai, Hinako Masaki, Akira Kirishima, Ryo Tsunashima, Atsuko Masuya-Suzuki","doi":"10.1039/d5cc03074a","DOIUrl":"https://doi.org/10.1039/d5cc03074a","url":null,"abstract":"Selective crystallization of charge-identical trenSal complexes enabled stepwise separation of Fe, Nd, and Dy. Remarkably, high selectivity emerged under controlled-base conditions, allowing separation even between species with similar solubilities. This study demonstrates a new approach for f/f and f/d metal separation based on controlled crystallization behavior.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"201 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145188981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient Sb2S3 solar cells via thioacetamide-based hydrothermal deposition 基于硫代乙酰胺的高效Sb2S3太阳能电池
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-09-30 DOI: 10.1039/d5cc05163k
Yanlei Li, Yongtai Yin, Ruilin Deng, Feng Lin, Zhen Yu, Yuqian Huang, Gang Wang
{"title":"Efficient Sb2S3 solar cells via thioacetamide-based hydrothermal deposition","authors":"Yanlei Li, Yongtai Yin, Ruilin Deng, Feng Lin, Zhen Yu, Yuqian Huang, Gang Wang","doi":"10.1039/d5cc05163k","DOIUrl":"https://doi.org/10.1039/d5cc05163k","url":null,"abstract":"We found that the compactness of CdS films is the key factor limiting the device performance of thioacetamide (TAA)-based Sb2S3 solar cells. By accurately controlling the thickness of the CdS films, a power conversion efficiency of up to 6.54% was achieved, which represents the highest reported efficiency for TAA-based Sb2S3 solar cells.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"101 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145188989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Regulating thermal expansion in iron sulfide anode for stable sodium storage 调节硫化铁阳极的热膨胀以实现钠的稳定储存
IF 4.9 2区 化学
Chemical Communications Pub Date : 2025-09-30 DOI: 10.1039/d5cc03710g
Shulian Lei, Yuancheng He, Gaobo Chang, Zhong Li, Hanqing Zhao
{"title":"Regulating thermal expansion in iron sulfide anode for stable sodium storage","authors":"Shulian Lei, Yuancheng He, Gaobo Chang, Zhong Li, Hanqing Zhao","doi":"10.1039/d5cc03710g","DOIUrl":"https://doi.org/10.1039/d5cc03710g","url":null,"abstract":"A Ho2Fe17 alloy, with thermal volume contraction and excellent electronic/thermal conductivity, is introduced into Fe7S8 based anode material. The decreased internal temperature and improved structural stability of the battery, contribute an enhanced sodium storage capacity and long cycling stability.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"18 1","pages":""},"PeriodicalIF":4.9,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145189065","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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