Hai Lu, Yanyan Zhao, Jinhaochong Wang, Meng Liu, Shiqiang Yang, Yihang Su, Yan Yuan
{"title":"2,4-二氟苯异硫氰酸酯在动力学有利的锂硫电池电解质中的氧化还原介质","authors":"Hai Lu, Yanyan Zhao, Jinhaochong Wang, Meng Liu, Shiqiang Yang, Yihang Su, Yan Yuan","doi":"10.1039/d5cc00693g","DOIUrl":null,"url":null,"abstract":"2,4-difluorophenyl isothiocyanate (DPIC) was served as a redox mediator for kinetically favorable electrolyte, which can boost the activation of insulating sulfur and sulfide, accelerate the bidirectional conversion reaction kinetics as well as restrict the undesirable shuttle effect, consequently ensuring high sulfur utilization and extended cycle lifespan of Li-S batteries.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"1 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"2,4-difluorophenyl isothiocyanate as a redox mediator in the electrolyte for kinetically favorable Li-S batteries\",\"authors\":\"Hai Lu, Yanyan Zhao, Jinhaochong Wang, Meng Liu, Shiqiang Yang, Yihang Su, Yan Yuan\",\"doi\":\"10.1039/d5cc00693g\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"2,4-difluorophenyl isothiocyanate (DPIC) was served as a redox mediator for kinetically favorable electrolyte, which can boost the activation of insulating sulfur and sulfide, accelerate the bidirectional conversion reaction kinetics as well as restrict the undesirable shuttle effect, consequently ensuring high sulfur utilization and extended cycle lifespan of Li-S batteries.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-04-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5cc00693g\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5cc00693g","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
2,4-difluorophenyl isothiocyanate as a redox mediator in the electrolyte for kinetically favorable Li-S batteries
2,4-difluorophenyl isothiocyanate (DPIC) was served as a redox mediator for kinetically favorable electrolyte, which can boost the activation of insulating sulfur and sulfide, accelerate the bidirectional conversion reaction kinetics as well as restrict the undesirable shuttle effect, consequently ensuring high sulfur utilization and extended cycle lifespan of Li-S batteries.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.