多金属氧酸盐催化芳基肼与亚硫酸盐的可见光氧化偶联合成芳基砜

IF 4.3 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-04-24 DOI:10.1039/d4cc06571a

Ahmed Th Abdulghaffar, Chengze Zhang, Jianghao Yu, Guan Wang, Yanrong Ren, ZhongYan Cao, Yuanqing Xu, Wei Chen, Hao Xu, Jingyang Niu

{"title":"多金属氧酸盐催化芳基肼与亚硫酸盐的可见光氧化偶联合成芳基砜","authors":"Ahmed Th Abdulghaffar, Chengze Zhang, Jianghao Yu, Guan Wang, Yanrong Ren, ZhongYan Cao, Yuanqing Xu, Wei Chen, Hao Xu, Jingyang Niu","doi":"10.1039/d4cc06571a","DOIUrl":null,"url":null,"abstract":"This study reports a polyoxometalate-catalyzed visible-light-driven synthesis of aryl sulfones from arylhydrazines and sodium sulfinates using O2 as an oxidant. The method provides excellent stability, broad functional-group compatibility, and notably enhanced reactivity for electron-rich arylhydrazines, offering a sustainable alternative to traditional halogenated aromatic precursors.","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"42 1","pages":""},"PeriodicalIF":4.3000,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Visible-Light-Driven Oxidative Coupling of Arylhydrazines with Sulfinates Catalyzed by Polyoxometalates for Aryl Sulfone Synthesis\",\"authors\":\"Ahmed Th Abdulghaffar, Chengze Zhang, Jianghao Yu, Guan Wang, Yanrong Ren, ZhongYan Cao, Yuanqing Xu, Wei Chen, Hao Xu, Jingyang Niu\",\"doi\":\"10.1039/d4cc06571a\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"This study reports a polyoxometalate-catalyzed visible-light-driven synthesis of aryl sulfones from arylhydrazines and sodium sulfinates using O2 as an oxidant. The method provides excellent stability, broad functional-group compatibility, and notably enhanced reactivity for electron-rich arylhydrazines, offering a sustainable alternative to traditional halogenated aromatic precursors.\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"42 1\",\"pages\":\"\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-04-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d4cc06571a\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4cc06571a","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

本研究报道了一种以氧为氧化剂，由芳酰肼和亚硫酸钠在多金属氧酸盐催化下的可见光合成芳基砜的方法。该方法具有良好的稳定性，广泛的官能团相容性，并显著提高了富电子芳基肼的反应性，为传统的卤化芳香前体提供了可持续的替代品。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Visible-Light-Driven Oxidative Coupling of Arylhydrazines with Sulfinates Catalyzed by Polyoxometalates for Aryl Sulfone Synthesis

This study reports a polyoxometalate-catalyzed visible-light-driven synthesis of aryl sulfones from arylhydrazines and sodium sulfinates using O₂ as an oxidant. The method provides excellent stability, broad functional-group compatibility, and notably enhanced reactivity for electron-rich arylhydrazines, offering a sustainable alternative to traditional halogenated aromatic precursors.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.