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Electrocatalytic hydrogen evolution performance of RuO2 nanorods grown on top of WO3 nanotube arrays 在WO3纳米管阵列上生长的RuO2纳米棒的电催化析氢性能
IF 2.6 4区 化学
Ionics Pub Date : 2025-05-30 DOI: 10.1007/s11581-025-06395-x
Man Zhang, Jingxiao Ren, Kefeng Wang, Yong-hua Li, Heng Jiang, Wei Wei
{"title":"Electrocatalytic hydrogen evolution performance of RuO2 nanorods grown on top of WO3 nanotube arrays","authors":"Man Zhang,&nbsp;Jingxiao Ren,&nbsp;Kefeng Wang,&nbsp;Yong-hua Li,&nbsp;Heng Jiang,&nbsp;Wei Wei","doi":"10.1007/s11581-025-06395-x","DOIUrl":"10.1007/s11581-025-06395-x","url":null,"abstract":"<div><p>Water electrolysis has been deemed as a simple, safe, and clean way to realize sustainable hydrogen production. However, efficacious water electrolysis for hydrogen production is highly dependent on efficient and stable electrocatalysts. Traditional powder catalysts have defects such as severe particle aggregation, poor conductivity, and weak substrate adhesion. Self-supporting electrodes grown in situ on conductive substrates as electrocatalysts could avoid these problems and therefore exhibit high catalytic activity and stability. Herein, one-dimensional RuO<sub>2</sub> nanorods (NRs) were grown on top of WO<sub>3</sub> nanotube arrays (NTA) through a facile solution impregnation method followed by a high-temperature calcination. The obtained self-supported RuO<sub>2</sub> NRs/WO<sub>3</sub> NTA electrode demonstrates a superb electrocatalytic activity toward hydrogen evolution reaction (HER) in both basic and acidic media. To achieve a current density of 10 mA cm<sup>−2</sup>, the required overpotentials are 33 mV in 1 M KOH and 62 mV in 0.5 M H<sub>2</sub>SO<sub>4</sub>, respectively. Furthermore, RuO<sub>2</sub> NRs/WO<sub>3</sub> NTA also shows excellent long-term electrochemical stability for continuous hydrogen generation over 50 h in both basic and acidic electrolytes. The superb HER activity of RuO<sub>2</sub> NRs/WO<sub>3</sub> NTA could be attributed to the structural merits including large surface area of RuO<sub>2</sub> with abundant catalytically active sites, specific charge transport channel ensuring enhanced reaction kinetics, and abundant open space between RuO<sub>2</sub> nanorods favorable for fast mass transfer and electrolyte accessibility. The present work sheds new light on designing novel one-dimensional composite structures as highly efficient electrocatalyst for sustainable hydrogen generation. Simultaneously, the designed nanorod/nanotube array composite structure in this work is also expected to be applied in other energy conversion devices.</p></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 7","pages":"7205 - 7216"},"PeriodicalIF":2.6,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Weibull Distribution-Informed Neural Networks (WDINNs): a probabilistic framework for enhanced degradation prediction in LIBs 威布尔分布信息神经网络(wdinn):一种用于增强LIBs降解预测的概率框架
IF 2.6 4区 化学
Ionics Pub Date : 2025-05-30 DOI: 10.1007/s11581-025-06431-w
Sahar Qaadan, Aiman Alshare, Alexander Popp, Rami Alazrai, Mohammad I. Daoud, Mostafa Z. Ali, Benedikt Schmuelling
{"title":"Weibull Distribution-Informed Neural Networks (WDINNs): a probabilistic framework for enhanced degradation prediction in LIBs","authors":"Sahar Qaadan,&nbsp;Aiman Alshare,&nbsp;Alexander Popp,&nbsp;Rami Alazrai,&nbsp;Mohammad I. Daoud,&nbsp;Mostafa Z. Ali,&nbsp;Benedikt Schmuelling","doi":"10.1007/s11581-025-06431-w","DOIUrl":"10.1007/s11581-025-06431-w","url":null,"abstract":"<div><p>Lithium-ion batteries (LIBs) are widely used in modern energy systems due to their high energy density and long service life. Accurate estimation of their remaining useful life (RUL) is essential for enhancing system reliability, optimizing maintenance strategies, and minimizing costs. In this work, battery degradation is inferred from voltage signal behavior, which serves as a reliable non-invasive indicator of aging. We propose a novel model called Weibull Distribution-Informed Neural Network (WDINN), which integrates the probabilistic characteristics of the Weibull distribution into a physics-informed deep learning framework. This approach addresses both the non-linear and stochastic nature of battery degradation. To train and validate the model, degradation profiles were extracted from aging datasets and reference performance testing (RPT) data. The WDINN model demonstrated superior performance compared to several state-of-the-art models, including Bi-LSTM, GRU, and ANN. It achieved an RMSE of 0.00027 ± 0.00003 on the aging dataset. Cluster-based evaluation further revealed that WDINN performs particularly well in scenarios of slow, long-term degradation (e.g., Cluster 0), achieving a test loss of 0.00018 ± 0.00001, while maintaining robustness across more variable short-term degradation patterns in the RPT data. This research introduces a robust and interpretable framework that enhances predictive accuracy, enables uncertainty modeling, and advances practical battery health estimation for reliable energy storage systems.</p></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 8","pages":"7803 - 7820"},"PeriodicalIF":2.6,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Malabar spinach–derived hierarchical porous carbon for robust supercapacitors by an activation-pickling-carbonization method 用活化-酸洗-炭化法制备坚固超级电容器用马拉巴菠菜衍生的分层多孔碳
IF 2.6 4区 化学
Ionics Pub Date : 2025-05-30 DOI: 10.1007/s11581-025-06407-w
Zhichao Xie, Linghui Tang, Tingting Ma, Yue Wang
{"title":"Malabar spinach–derived hierarchical porous carbon for robust supercapacitors by an activation-pickling-carbonization method","authors":"Zhichao Xie,&nbsp;Linghui Tang,&nbsp;Tingting Ma,&nbsp;Yue Wang","doi":"10.1007/s11581-025-06407-w","DOIUrl":"10.1007/s11581-025-06407-w","url":null,"abstract":"<div><p>Supercapacitors have attracted considerable interests owing to their elevated power density, swift charge–discharge capabilities, and extended cycle life. The pivotal element in augmenting supercapacitor performance lies in the synthesis of porous carbon materials characterized by high specific surface area and well-developed pore architectures. This work introduces an innovative approach integrating activation, pickling, and carbonization, utilizing Malabar spinach as the carbon precursor and KOH as the activating agent for biochar-based supercapacitors. The activation process enhances the material porosity, while pickling removes the majority of non-carbon elements. Subsequent re-carbonization increases the specific surface area and porosity of carbons, resulting in a higher specific capacitance. The optimized carbons exhibit a high specific surface area (1195.37 m<sup>2</sup> g<sup>−1</sup>), hierarchical porous structure, and remarkable specific capacitance (427.5 F g<sup>−1</sup> at 0.5 A g<sup>−1</sup>). After 10,000 galvanostatic charge/discharge cycles at 10 A g<sup>−1</sup>, the capacitance retention rate remains at 98.71% with a high Coulombic efficiency of 99.67%. Under two-electrode system testing conditions, the energy density measured 6.9 Wh kg<sup>−1</sup> while the power density reached 125.3W kg<sup>−1</sup>. This work demonstrates a promising potential of combining activation, pickling, and carbonization for biomass-derived carbons, which have great potential in the application of electrochemical energy storage and conversion devices.</p></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 7","pages":"7233 - 7243"},"PeriodicalIF":2.6,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Safe and fast charging control strategy for lithium-ion batteries based on deep reinforcement learning 基于深度强化学习的锂离子电池安全快速充电控制策略
IF 2.6 4区 化学
Ionics Pub Date : 2025-05-29 DOI: 10.1007/s11581-025-06411-0
Hengwei Xie, Shengzhe Liu, Ruifeng An, Xiaojun Tan
{"title":"Safe and fast charging control strategy for lithium-ion batteries based on deep reinforcement learning","authors":"Hengwei Xie,&nbsp;Shengzhe Liu,&nbsp;Ruifeng An,&nbsp;Xiaojun Tan","doi":"10.1007/s11581-025-06411-0","DOIUrl":"10.1007/s11581-025-06411-0","url":null,"abstract":"<div><p>With increasing concerns about charging and range anxiety in electric vehicles (EVs), developing safe and fast charging control strategies is particularly important for ensuring the safety of EVs and improving user’s charging experience. This paper proposes a novel safe and fast charging control strategy for lithium-ion batteries based on deep reinforcement learning, capable of adapting to dynamic changes in the charging environment. Firstly, a unilateral sampling soft actor-critic (USSAC) algorithm is proposed and integrated with an electrochemical-thermal coupling model to train an agent capable of optimizing charging speeds while adhering to multiphysical constraints. The trained agent can then provide a safe and fast charging control strategy and be updated online. Secondly, an adaptive negative pulse regulation method that autonomously adds negative pulses base on multiphysical constraints is proposed to further enhance the safety of the charging process. Finally, the proposed charging strategy is simulated and experimentally verified under different environment conditions. The experimental results show that, compared to the commonly used fast charging strategies, the proposed USSAC-based charging strategy can dynamically provide the optimal charging current in real-time according to the battery environment and its own status, effectively mitigating the risks of overcharge, lithium plating, and thermal hazards.</p></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 7","pages":"6865 - 6888"},"PeriodicalIF":2.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Interface engineering of micro-Nb16W5O55for enhanced electron transport and ion diffusion toward ultra-high-rate lithium-ion batteries 微晶nb16w5o55向超高速锂离子电池增强电子传递和离子扩散的界面工程
IF 2.6 4区 化学
Ionics Pub Date : 2025-05-29 DOI: 10.1007/s11581-025-06422-x
Haixia Liu, Wei Dong, Jingyi Hao, Feng Yu, Qigao Han, Chi Guo
{"title":"Interface engineering of micro-Nb16W5O55for enhanced electron transport and ion diffusion toward ultra-high-rate lithium-ion batteries","authors":"Haixia Liu,&nbsp;Wei Dong,&nbsp;Jingyi Hao,&nbsp;Feng Yu,&nbsp;Qigao Han,&nbsp;Chi Guo","doi":"10.1007/s11581-025-06422-x","DOIUrl":"10.1007/s11581-025-06422-x","url":null,"abstract":"<div><p>The performance of lithium-ion batteries, including their maximum output power and minimum charging time, is fundamentally constrained by the efficiency of ion and electron transport. These processes are governed by the electron conductivity and ion diffusion within active electrode materials, and the ionic mobility within the electrolyte. In this work, micron-sized Nb<sub>16</sub>W<sub>5</sub>O<sub>55</sub> particles were coated with reduced graphene oxide (rGO). Simultaneously, the electrolyte was carefully engineered to further support high-rate performance. These modifications significantly improve the material’s electronic conductivity while optimizing interfacial ion diffusion. Hence, the micron-sized rGO/Nb<sub>16</sub>W<sub>5</sub>O<sub>55</sub> exhibits a high reversible capacity (&gt; 250 mAh g<sup>−1</sup> at 0.2 C) with ultra-high rate performance (≈114 mAh g<sup>−1</sup> at 80 C). In addition, the capacity of Li||rGO/Nb<sub>16</sub>W<sub>5</sub>O<sub>55</sub> pouch cell maintains 99.2% after 100 cycles at 10 C. The series-connected pouch cells can charge mobile phones through wireless charging technology. This work offers valuable insights into the interfacial engineering of electrodes, paving the way for fast-charging battery applications.</p></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 7","pages":"6829 - 6837"},"PeriodicalIF":2.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145170372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A brief review: transition metal oxides with carbon composite materials for high-performance supercapacitor, applications, fabrication methods, and future perspective 综述了过渡金属氧化物与碳复合材料在高性能超级电容器中的应用、制备方法及未来展望
IF 2.6 4区 化学
Ionics Pub Date : 2025-05-29 DOI: 10.1007/s11581-025-06393-z
Preeti Yadav, Chetna Tyagi, Norshahirah Mohamad Saidi
{"title":"A brief review: transition metal oxides with carbon composite materials for high-performance supercapacitor, applications, fabrication methods, and future perspective","authors":"Preeti Yadav,&nbsp;Chetna Tyagi,&nbsp;Norshahirah Mohamad Saidi","doi":"10.1007/s11581-025-06393-z","DOIUrl":"10.1007/s11581-025-06393-z","url":null,"abstract":"<div><p>Energy is essential for human enhancement and is used 24 h a day. Nonrenewable and renewable energy sources meet global demands and reduce economic challenges. Supercapacitors offer higher power density, high capacitance value, temperature tolerance, and long-term durability than other energy storage devices. Supercapacitors are used in various applications, including transportation (hybrid vehicles, electric vehicles), automotive, and renewable energy. Electrode materials play a crucial role in supercapacitors’ performance, with transition metal-based materials like transition metal oxides (TMOs), transition metal sulfides (TMS), and transition metal nitrides (TMN) being popular due to their high specific energy output and chemical stability. This review highlights hybridization and performance enhancement of TMO-carbon composites for supercapacitor applications. Emphasis is placed on synergistic interactions that improve charge storage mechanisms, energy density, and cycling stability. Additionally, we discuss applications like hybrid energy storage (HES) systems to improve travel range by integrating batteries with supercapacitors to create a hybrid energy storage system, which is another possibility for providing high current, increasing battery life in electric vehicles, challenges, other promising materials for electrodes, fabrication methods, and future perspectives toward scalability.</p></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 7","pages":"6695 - 6718"},"PeriodicalIF":2.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11581-025-06393-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171308","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ionic liquid–assisted synthesis of N/B/F co-doped biomass-derived hard carbon for sodium-ion batteries 离子液体辅助合成钠离子电池用N/B/F共掺杂生物质衍生硬碳
IF 2.6 4区 化学
Ionics Pub Date : 2025-05-29 DOI: 10.1007/s11581-025-06421-y
Fanming Meng, Fengning Bai, Tingting Wu, Wenxu Qi, Yichen Mou, Nianrun Li, Peng Dong, Xiaoyuan Zeng, Chengxu Zhang, Yingjie Zhang, Jue Hu
{"title":"Ionic liquid–assisted synthesis of N/B/F co-doped biomass-derived hard carbon for sodium-ion batteries","authors":"Fanming Meng,&nbsp;Fengning Bai,&nbsp;Tingting Wu,&nbsp;Wenxu Qi,&nbsp;Yichen Mou,&nbsp;Nianrun Li,&nbsp;Peng Dong,&nbsp;Xiaoyuan Zeng,&nbsp;Chengxu Zhang,&nbsp;Yingjie Zhang,&nbsp;Jue Hu","doi":"10.1007/s11581-025-06421-y","DOIUrl":"10.1007/s11581-025-06421-y","url":null,"abstract":"<div><p>Biomass-derived hard carbon is currently a promising anode material for commercial sodium-ion batteries. The incorporation of heteroatoms into hard carbon materials brings about remarkable improvements in their electrochemical performance. Nevertheless, the variety of biomass precursors and the constraints of traditional doping techniques present formidable hurdles for their practical application. In this study, a simple impregnation doping and two-step carbonization process was employed to prepare N/B/F co-doped hard carbon using <i>Metaplexis japonica</i> tomentum as a precursor and 1-butyl-3-methylimidazole tetrafluoroborate ionic liquid as the dopant source. The doping effect was confirmed by TEM and XPS. Furthermore, Raman spectroscopy results demonstrate that pseudo-graphitic structures, with large interlayer spacing, provide sufficient diffusion channels for Na<sup>+</sup> ion intercalation and pore-filling. When evaluated for sodium-ion batteries, the as-prepared NBF co-doped hard carbon exhibits a discharge capacity of 140.3 mAh g<sup>−1</sup> at 0.1 Ag<sup>−1</sup> and 84.6 mAh g<sup>−1</sup> at 1.5 Ag<sup>−1</sup>, which shows a better performance than commercial hard carbon products. Furthermore, EIS and DFT results demonstrate that co-doping could provide the highest electrical conductivity and synergistic effects, which can significantly alter the adsorption properties of carbon hosts. This method leverages biomass resources and ionic liquids to achieve controlled carbonization at relatively low temperatures, thereby optimizing the pore structure and graphitization degree of the material, which opens a feasible pathway for the preparation of heteroatom-doped biomass-derived hard carbon.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 7","pages":"6949 - 6961"},"PeriodicalIF":2.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11581-025-06421-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancement the discharge capacity of NiCl2-xBrx thermal battery by inhibition overflow of electrolyte 抑制电解液溢出提高NiCl2-xBrx热电池的放电容量
IF 2.6 4区 化学
Ionics Pub Date : 2025-05-29 DOI: 10.1007/s11581-025-06410-1
Jun Tang, Yuhong Nong, Ling Ran, Xinyu Zhang, Licheng Tang, Zhiqiang Zhan, Yusha Deng, Licai Fu
{"title":"Enhancement the discharge capacity of NiCl2-xBrx thermal battery by inhibition overflow of electrolyte","authors":"Jun Tang,&nbsp;Yuhong Nong,&nbsp;Ling Ran,&nbsp;Xinyu Zhang,&nbsp;Licheng Tang,&nbsp;Zhiqiang Zhan,&nbsp;Yusha Deng,&nbsp;Licai Fu","doi":"10.1007/s11581-025-06410-1","DOIUrl":"10.1007/s11581-025-06410-1","url":null,"abstract":"<div><p>Nickel chloride is a promising cathode material for high-power thermal batteries due to its high theoretical capacity, high discharge current density, and high electrode potential. Nevertheless, its substandard electrical conductivity, elevated-temperature melting properties, and electrolyte interface instability considerably constrain its practical applications. In this paper, NiCl<sub>1.6</sub>Br<sub>0.4</sub> with high electrical conductivity and high specific capacity was prepared through comparative experiments, and the merits of BN over MgO for LiB/NiCl<sub>1.6</sub>Br<sub>0.4</sub> thermal battery system were demonstrated by analyzing the difference between electrochemical performance and melting leaching phenomenon. The LiB/BN-E/NiCl<sub>2-x</sub>Br<sub>x</sub> thermal battery system demonstrates optimal discharge performance at 500 °C, achieving a specific capacity of 319 mAh g<sup>−1</sup>, a specific energy of 744 Wh kg<sup>−1</sup>, and a specific power of 7.0 kW kg<sup>−1</sup> under a discharge condition of 0.2 A cm<sup>−2</sup>. The LiB/BN-E/NiCl<sub>2-x</sub>Br<sub>x</sub> thermal battery system has application prospects in high-energy thermal batteries. </p></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 7","pages":"7057 - 7067"},"PeriodicalIF":2.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Diffusive enriched electron beam evaporated ZnSe thin film: electrochemical supercapacitive energy storage application 扩散富集电子束蒸发ZnSe薄膜:电化学超电容储能应用
IF 2.6 4区 化学
Ionics Pub Date : 2025-05-29 DOI: 10.1007/s11581-025-06403-0
Mayank Tiwari, Deepak Jangir, T. Kedara Shivasharma, G. Hema Chandra, Babasaheb R. Sankapal
{"title":"Diffusive enriched electron beam evaporated ZnSe thin film: electrochemical supercapacitive energy storage application","authors":"Mayank Tiwari,&nbsp;Deepak Jangir,&nbsp;T. Kedara Shivasharma,&nbsp;G. Hema Chandra,&nbsp;Babasaheb R. Sankapal","doi":"10.1007/s11581-025-06403-0","DOIUrl":"10.1007/s11581-025-06403-0","url":null,"abstract":"<div><p>Present investigation emphasizes first report on electron beam–evaporated polycrystalline ZnSe thin film towards electrochemical supercapacitive energy storage application. Cubic crystal phase with a preferred orientation along (1 1 1) direction is established along with characteristic remarks at 206 and 252 cm<sup>−1</sup> originated by an excitation wavelength of 532 nm supported by Raman measurements and 2.65 eV as bandgap by using UV–visible spectroscopy. Uniform grains with average size of ~ 120 nm is established through FE-SEM studies. At 10 mV/s, electrochemical investigation of ZnSe electrode unveils 34.82 F/g (9.0 mF/cm<sup>2</sup>) specific capacitance with the voltage window of 0.05 to − 0.75 V in 0.5 M NaCl aqueous electrolyte with 95.49% cyclic stability at 1500 CV cycles. Diffusion-controlled mechanism and surface capacitive processes reveal diffusive enriched pseudocapacitive nature with 96.02% of charge storage.</p></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 7","pages":"7245 - 7256"},"PeriodicalIF":2.6,"publicationDate":"2025-05-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145171417","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Lignin and its composites for supercapacitor applications 木质素及其复合材料在超级电容器中的应用
IF 2.6 4区 化学
Ionics Pub Date : 2025-05-28 DOI: 10.1007/s11581-025-06426-7
Huseyin Uşan, S. Esra Bolsu Kariper, I. Afşin Kariper, Dilek İmren Koç
{"title":"Lignin and its composites for supercapacitor applications","authors":"Huseyin Uşan,&nbsp;S. Esra Bolsu Kariper,&nbsp;I. Afşin Kariper,&nbsp;Dilek İmren Koç","doi":"10.1007/s11581-025-06426-7","DOIUrl":"10.1007/s11581-025-06426-7","url":null,"abstract":"<div><p>This study examines how lignin has been used in supercapacitor and battery applications. The review highlights the synthesifs of lignin and lignin-based composite materials, their structural properties and electrochemical performances, and recent developments in supercapacitor and battery applications. The review initially reviews the fundamentals of supercapacitors and outlines the properties of lignin while providing a detailed review of their applications in various energy storage systems. The focus is on lignin-derived porous structures, conductive polymer composites, and hybrid materials, particularly in energy storage and supercapacitors. The literature review concludes that lignin-based materials offer significant advantages such as high charge storage capacity, cost-effectiveness, and environmental sustainability. Although there are few studies on lignin, this study will contribute to the field by consolidating the findings, filling the knowledge gaps, and guiding future research to accelerate the practical use of lignin in energy storage technologies.</p></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 7","pages":"6679 - 6694"},"PeriodicalIF":2.6,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145170478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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