{"title":"苯乙烯-马来酸酐辅助葡萄糖-聚乙烯醇碳包覆制备高导电性LiMn0.6Fe0.4PO4","authors":"Quanchen Li, Hao Yang, Xinran Li, Tianyi Zhang, Zijun Liu, Guangchuan Liang","doi":"10.1007/s11581-025-06452-5","DOIUrl":null,"url":null,"abstract":"<div><p>The low conductivity and Li<sup>+</sup> diffusion coefficient of lithium manganese iron phosphate (LMFP) hinder its practical applications. In this study, polyvinyl alcohol (PVA) to partially replace glucose in the LMFP coating, with styrene-maleic anhydride copolymer (SMA) auxiliary carbon source, was added for the coating. Following the addition of SMA, the alternating distribution of hydrophilic and hydrophobic groups within the molecular structure of SMA effectively prevents the aggregation between particles. The agglomeration of primary particles in the sample has been significantly minimized, and the viscosity of the slurry has been effectively decreased. Under the synergistic effect of PVA and SMA, the resulting carbon layer has a high degree of graphitization, the compaction density of the material is improved, and the diffusion coefficient of Li<sup>+</sup> is improved due to the uniform and moderate thickness of the carbon layer. The properties of the modified samples exhibit varying degrees of enhancement. The discharge specific capacity of LPS-4 was 156.8 mA h g<sup>−1</sup> at 0.2 C, and the capacity retention rate was 96.4% after 100 cycles at 1 C. In addition to the improvement of these properties, the powder conductivity of the material has also significantly increased. At a pressure of 350 MPa, the conductivity can attain a value of 3.25 × 10<sup>−2</sup> S cm<sup>−1</sup>.</p></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 8","pages":"7731 - 7743"},"PeriodicalIF":2.6000,"publicationDate":"2025-06-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Highly conductive LiMn0.6Fe0.4PO4 synthesized with styrene maleic anhydride-assisted glucose and polyvinyl alcohol carbon coating\",\"authors\":\"Quanchen Li, Hao Yang, Xinran Li, Tianyi Zhang, Zijun Liu, Guangchuan Liang\",\"doi\":\"10.1007/s11581-025-06452-5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The low conductivity and Li<sup>+</sup> diffusion coefficient of lithium manganese iron phosphate (LMFP) hinder its practical applications. In this study, polyvinyl alcohol (PVA) to partially replace glucose in the LMFP coating, with styrene-maleic anhydride copolymer (SMA) auxiliary carbon source, was added for the coating. Following the addition of SMA, the alternating distribution of hydrophilic and hydrophobic groups within the molecular structure of SMA effectively prevents the aggregation between particles. The agglomeration of primary particles in the sample has been significantly minimized, and the viscosity of the slurry has been effectively decreased. Under the synergistic effect of PVA and SMA, the resulting carbon layer has a high degree of graphitization, the compaction density of the material is improved, and the diffusion coefficient of Li<sup>+</sup> is improved due to the uniform and moderate thickness of the carbon layer. The properties of the modified samples exhibit varying degrees of enhancement. The discharge specific capacity of LPS-4 was 156.8 mA h g<sup>−1</sup> at 0.2 C, and the capacity retention rate was 96.4% after 100 cycles at 1 C. In addition to the improvement of these properties, the powder conductivity of the material has also significantly increased. At a pressure of 350 MPa, the conductivity can attain a value of 3.25 × 10<sup>−2</sup> S cm<sup>−1</sup>.</p></div>\",\"PeriodicalId\":599,\"journal\":{\"name\":\"Ionics\",\"volume\":\"31 8\",\"pages\":\"7731 - 7743\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2025-06-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ionics\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11581-025-06452-5\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ionics","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11581-025-06452-5","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
磷酸锰铁锂(LMFP)电导率低、Li+扩散系数低,阻碍了其实际应用。在本研究中,聚乙烯醇(PVA)部分取代了LMFP涂层中的葡萄糖,并用苯乙烯-马来酸酐共聚物(SMA)辅助碳源作为涂层。加入SMA后,SMA分子结构内亲疏水基团的交替分布有效地阻止了颗粒间的聚集。样品中初生颗粒的团聚明显减少,浆料的粘度有效降低。在PVA和SMA的协同作用下,得到的碳层石墨化程度高,材料的压实密度提高,且由于碳层厚度均匀适中,提高了Li+的扩散系数。改性后样品的性能表现出不同程度的增强。在0.2 C下,LPS-4的放电比容量为156.8 mA h g−1,在1 C下循环100次后的容量保持率为96.4%。除了这些性能的改善外,材料的粉末电导率也显著提高。在350mpa压力下,电导率可达3.25 × 10−2 S cm−1。
Highly conductive LiMn0.6Fe0.4PO4 synthesized with styrene maleic anhydride-assisted glucose and polyvinyl alcohol carbon coating
The low conductivity and Li+ diffusion coefficient of lithium manganese iron phosphate (LMFP) hinder its practical applications. In this study, polyvinyl alcohol (PVA) to partially replace glucose in the LMFP coating, with styrene-maleic anhydride copolymer (SMA) auxiliary carbon source, was added for the coating. Following the addition of SMA, the alternating distribution of hydrophilic and hydrophobic groups within the molecular structure of SMA effectively prevents the aggregation between particles. The agglomeration of primary particles in the sample has been significantly minimized, and the viscosity of the slurry has been effectively decreased. Under the synergistic effect of PVA and SMA, the resulting carbon layer has a high degree of graphitization, the compaction density of the material is improved, and the diffusion coefficient of Li+ is improved due to the uniform and moderate thickness of the carbon layer. The properties of the modified samples exhibit varying degrees of enhancement. The discharge specific capacity of LPS-4 was 156.8 mA h g−1 at 0.2 C, and the capacity retention rate was 96.4% after 100 cycles at 1 C. In addition to the improvement of these properties, the powder conductivity of the material has also significantly increased. At a pressure of 350 MPa, the conductivity can attain a value of 3.25 × 10−2 S cm−1.
期刊介绍:
Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.