镁盐掺入PVA聚合物电解质的结构、功能和电性能研究:等效电路分析

IF 2.6 4区 化学 Q3 CHEMISTRY, PHYSICAL
Ionics Pub Date : 2025-06-07 DOI:10.1007/s11581-025-06437-4
Shaik Imran Ahmad, Parthiban Venkatachalapathy, Sunita Sundari Gunturi
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引用次数: 0

摘要

本文研究了添加镁盐的聚乙烯醇(PVA)基聚合物电解质的结构、功能和电学特性,主要解释了该材料的电学性能。本文通过常温下的溶液铸造技术,在不同浓度的聚合物和盐中合成了聚合物电解质,材料被鉴定为PMgx。对其结构和功能特征进行了分析,以确定聚合物-盐络合物地层。PMgx的交流阻抗(ACI)显示最大离子电导率(σ)可达1.26 × 10-5 S.cm−1。通过拟合交流阻抗数据的cole-cole (CC)图,研究了材料的等效电路。分析了材料的波德图、介电特性和电模量等电学特性,解释了材料的电荷转移特性、介电特性和介电弛豫现象,其中弛豫时间为1.59 × 10-7 s。通过Havriliak-Negami (HN)拟合分析了介质弛豫现象,并对材料的介电强度进行了分析。本文研究了不锈钢板的复合电容特性。然后,分析了材料的交流电导率与频率的关系,研究了离子传导机理。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Investigation of structural, functional and electrical properties of PVA polymer electrolyte incorporated with magnesium salt: analysing equivalent electrical circuit

The structural, functional and electrical characteristics have been investigated for poly (vinyl alcohol) (PVA)-based polymer electrolyte with the incorporation of magnesium salt which mainly explains the electrical properties of the material in the present work. Here the polymer electrolyte is synthesized in different concentration of polymer and salt through solution casting technique in ambient temperature and the material is identified as PMgx. The structural and functional characteristics were analysed for the confirmation of polymer and salt complex formation. The AC impedance (ACI) studied for PMgx exhibits maximum ionic conductivity (σ) up to 1.26 × 10–5 S.cm−1. The equivalent electrical circuit (EEC) of the material is studied by fitting the cole–cole (CC) plot from the AC impedance data. Then, electrical characteristics like bode plots, dielectric characteristics and electric modulus analysis were analysed, which explains about the charge transfer characteristics, dielectric properties, and dielectric relaxation phenomenon of the material, where the relaxation time is 1.59 × 10–7 s. Furthermore, the dielectric relaxation phenomenon has been analysed through Havriliak-Negami (HN) fitting, and dielectric strength of the material was analysed. The complex capacitance is studied with respect to the use of stainless-steel plate in the study. Then, AC conductivity of the material with respect to frequency was analysed, where the ion conduction mechanism is studied.

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来源期刊
Ionics
Ionics 化学-电化学
CiteScore
5.30
自引率
7.10%
发文量
427
审稿时长
2.2 months
期刊介绍: Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.
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