{"title":"镁盐掺入PVA聚合物电解质的结构、功能和电性能研究:等效电路分析","authors":"Shaik Imran Ahmad, Parthiban Venkatachalapathy, Sunita Sundari Gunturi","doi":"10.1007/s11581-025-06437-4","DOIUrl":null,"url":null,"abstract":"<div><p>The structural, functional and electrical characteristics have been investigated for poly (vinyl alcohol) (PVA)-based polymer electrolyte with the incorporation of magnesium salt which mainly explains the electrical properties of the material in the present work. Here the polymer electrolyte is synthesized in different concentration of polymer and salt through solution casting technique in ambient temperature and the material is identified as PMgx. The structural and functional characteristics were analysed for the confirmation of polymer and salt complex formation. The AC impedance (ACI) studied for PMgx exhibits maximum ionic conductivity (<i>σ</i>) up to 1.26 × 10<sup>–5</sup> S.cm<sup>−1</sup>. The equivalent electrical circuit (EEC) of the material is studied by fitting the cole–cole (CC) plot from the AC impedance data. Then, electrical characteristics like bode plots, dielectric characteristics and electric modulus analysis were analysed, which explains about the charge transfer characteristics, dielectric properties, and dielectric relaxation phenomenon of the material, where the relaxation time is 1.59 × 10<sup>–7</sup> s. Furthermore, the dielectric relaxation phenomenon has been analysed through Havriliak-Negami (HN) fitting, and dielectric strength of the material was analysed. The complex capacitance is studied with respect to the use of stainless-steel plate in the study. Then, AC conductivity of the material with respect to frequency was analysed, where the ion conduction mechanism is studied.</p></div>","PeriodicalId":599,"journal":{"name":"Ionics","volume":"31 8","pages":"8027 - 8041"},"PeriodicalIF":2.6000,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation of structural, functional and electrical properties of PVA polymer electrolyte incorporated with magnesium salt: analysing equivalent electrical circuit\",\"authors\":\"Shaik Imran Ahmad, Parthiban Venkatachalapathy, Sunita Sundari Gunturi\",\"doi\":\"10.1007/s11581-025-06437-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The structural, functional and electrical characteristics have been investigated for poly (vinyl alcohol) (PVA)-based polymer electrolyte with the incorporation of magnesium salt which mainly explains the electrical properties of the material in the present work. Here the polymer electrolyte is synthesized in different concentration of polymer and salt through solution casting technique in ambient temperature and the material is identified as PMgx. The structural and functional characteristics were analysed for the confirmation of polymer and salt complex formation. The AC impedance (ACI) studied for PMgx exhibits maximum ionic conductivity (<i>σ</i>) up to 1.26 × 10<sup>–5</sup> S.cm<sup>−1</sup>. The equivalent electrical circuit (EEC) of the material is studied by fitting the cole–cole (CC) plot from the AC impedance data. Then, electrical characteristics like bode plots, dielectric characteristics and electric modulus analysis were analysed, which explains about the charge transfer characteristics, dielectric properties, and dielectric relaxation phenomenon of the material, where the relaxation time is 1.59 × 10<sup>–7</sup> s. Furthermore, the dielectric relaxation phenomenon has been analysed through Havriliak-Negami (HN) fitting, and dielectric strength of the material was analysed. The complex capacitance is studied with respect to the use of stainless-steel plate in the study. Then, AC conductivity of the material with respect to frequency was analysed, where the ion conduction mechanism is studied.</p></div>\",\"PeriodicalId\":599,\"journal\":{\"name\":\"Ionics\",\"volume\":\"31 8\",\"pages\":\"8027 - 8041\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2025-06-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ionics\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11581-025-06437-4\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ionics","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11581-025-06437-4","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Investigation of structural, functional and electrical properties of PVA polymer electrolyte incorporated with magnesium salt: analysing equivalent electrical circuit
The structural, functional and electrical characteristics have been investigated for poly (vinyl alcohol) (PVA)-based polymer electrolyte with the incorporation of magnesium salt which mainly explains the electrical properties of the material in the present work. Here the polymer electrolyte is synthesized in different concentration of polymer and salt through solution casting technique in ambient temperature and the material is identified as PMgx. The structural and functional characteristics were analysed for the confirmation of polymer and salt complex formation. The AC impedance (ACI) studied for PMgx exhibits maximum ionic conductivity (σ) up to 1.26 × 10–5 S.cm−1. The equivalent electrical circuit (EEC) of the material is studied by fitting the cole–cole (CC) plot from the AC impedance data. Then, electrical characteristics like bode plots, dielectric characteristics and electric modulus analysis were analysed, which explains about the charge transfer characteristics, dielectric properties, and dielectric relaxation phenomenon of the material, where the relaxation time is 1.59 × 10–7 s. Furthermore, the dielectric relaxation phenomenon has been analysed through Havriliak-Negami (HN) fitting, and dielectric strength of the material was analysed. The complex capacitance is studied with respect to the use of stainless-steel plate in the study. Then, AC conductivity of the material with respect to frequency was analysed, where the ion conduction mechanism is studied.
期刊介绍:
Ionics is publishing original results in the fields of science and technology of ionic motion. This includes theoretical, experimental and practical work on electrolytes, electrode, ionic/electronic interfaces, ionic transport aspects of corrosion, galvanic cells, e.g. for thermodynamic and kinetic studies, batteries, fuel cells, sensors and electrochromics. Fast solid ionic conductors are presently providing new opportunities in view of several advantages, in addition to conventional liquid electrolytes.