Ahmed I. Osman, Mahmoud Nasr, Eric Lichtfouse, Mohamed Farghali, David W. Rooney
{"title":"Hydrogen, ammonia and methanol for marine transportation","authors":"Ahmed I. Osman, Mahmoud Nasr, Eric Lichtfouse, Mohamed Farghali, David W. Rooney","doi":"10.1007/s10311-024-01757-9","DOIUrl":"10.1007/s10311-024-01757-9","url":null,"abstract":"","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 5","pages":"2151 - 2158"},"PeriodicalIF":15.0,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141315662","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Classical and advanced isotherms to model the adsorption of drugs, dyes and metals on activated carbonaceous materials: a review","authors":"Issam Mechnou, Sarra Meskini, Esseddik Elqars, Az-Iddin Chham, Miloudi Hlaibi","doi":"10.1007/s10311-024-01759-7","DOIUrl":"10.1007/s10311-024-01759-7","url":null,"abstract":"<div><p>Water contamination is a major health issue that can be addressed by using carbonaceous materials to adsorb and filter pollutants, yet adsorption mechanisms need to be better understood to improve the adsorption efficiency. Here we review the models that are used to study the mechanisms of adsorption of drugs, dyes and metal ions on carbonaceous materials, with emphasis on classical and advanced isotherms. We discuss the fitting frequency, lignocellulosic and fossil fuel-derived adsorbents, biomass composition, activating agents, surface functions, the carbonization temperature, the medium temperature effect and the use of several isotherms to explain the same mechanism. The adsorption capacity can reach up to 2651 mg of contaminant per g of lignocellulosic materials and 1274 mg of contaminant per g of fossil materials. Isotherm validation commonly depends on several parameters. The adsorption on lignocellulosic carbonaceous materials is best described by the Langmuir isotherm. In contrast, adsorption on fossil materials is best described by the Redlich-Peterson isotherm. Advanced and classical isotherms are in good agreement in 44% of reports.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 5","pages":"2375 - 2404"},"PeriodicalIF":15.0,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10311-024-01759-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141320010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ahmed K. Rashwan, Hala A. Younis, Asem M. Abdelshafy, Ahmed I. Osman, Mohamed R. Eletmany, Mahmoud A. Hafouda, Wei Chen
{"title":"Plant starch extraction, modification, and green applications: a review","authors":"Ahmed K. Rashwan, Hala A. Younis, Asem M. Abdelshafy, Ahmed I. Osman, Mohamed R. Eletmany, Mahmoud A. Hafouda, Wei Chen","doi":"10.1007/s10311-024-01753-z","DOIUrl":"10.1007/s10311-024-01753-z","url":null,"abstract":"<div><p>Fossil fuel-based products should be replaced by products derived from modern biomass such as plant starch, in the context of the future circular economy. Starch production globally surpasses 50 million tons annually, predominantly sourced from maize, rice, and potatoes. Here, we review plant starch with an emphasis on structure and properties, extraction, modification, and green applications. Modification techniques comprise physical, enzymatic, and genetic methods. Applications include stabilization of food, replacement of meat, three-dimensional food printing, prebiotics, encapsulation, bioplastics, edible films, textiles, and wood adhesives. Starch from maize, potatoes, and cassava shows amylose content ranging from 20 to 30% in regular varieties to 70% in high-amylose varieties. Extraction by traditional wet milling achieves starch purity up to 99.5%, while enzymatic methods maintain higher structural integrity, which is crucial for pharmaceutical applications. Enzymatic extraction improves starch yield by of up to 20%, reduces energy consumption by about 30%, and lowers wastewater production by up to 50%, compared to conventional methods. Sustainable starch modification can reduce the carbon footprint of starch production by up to 40%. Modified starches contribute to approximately 70% of the food texturizers market. The market of starch in plant-based meat alternatives has grown by over 30% in the past five years. Similarly, the use of biodegradable starch-based plastics by the bioplastic industry is growing over 20% annually, driven by the demand for sustainable packaging.Kindly check and confirm the layout of Table 1.Layout is right</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 5","pages":"2483 - 2530"},"PeriodicalIF":15.0,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10311-024-01753-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141315613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Amit Kumar, Pankaj Sharma, Gaurav Sharma, Pooja Dhiman, Genene Tessema Mola, Mohamed Farghali, Ahmed K. Rashwan, Mahmoud Nasr, Ahmed I. Osman, Tongtong Wang
{"title":"Simultaneous hydrogen production and photocatalytic pollutant removal: a review","authors":"Amit Kumar, Pankaj Sharma, Gaurav Sharma, Pooja Dhiman, Genene Tessema Mola, Mohamed Farghali, Ahmed K. Rashwan, Mahmoud Nasr, Ahmed I. Osman, Tongtong Wang","doi":"10.1007/s10311-024-01756-w","DOIUrl":"10.1007/s10311-024-01756-w","url":null,"abstract":"<div><p>Pollution and the rising energy demand are two major society issues, requiring urgent solutions. Here, we review the simultaneous production of hydrogen and removal of pollutants, with a focus on mechanisms, synthesis of photocatalysts, and applications. Remarkably, this method utilizes organic pollutants as sacrificial agents for photocatalytic hydrogen production, thus both reducing pollution and producing energy. Metal-doped, cocatalyst-loaded, organic and inorganic composite, heterostructure and heterojunction photocatalysts are described. We present applications to the removal of antibiotics and organic dyes. Pollutant degradation rates range from 5.3 to 100%, with hydrogen evolution of 13.7–2724.89 μmol·g<sup>–1</sup>h<sup>–1</sup>.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 5","pages":"2405 - 2424"},"PeriodicalIF":15.0,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10311-024-01756-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141304409","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yasmin Vieira, Julia Eduarda Spode, Guilherme Luiz Dotto, Jordana Georgin, Dison Stracke Pfingsten Franco, Glaydson Simões dos Reis, Eder Cláudio Lima
{"title":"Paracetamol environmental remediation and ecotoxicology: a review","authors":"Yasmin Vieira, Julia Eduarda Spode, Guilherme Luiz Dotto, Jordana Georgin, Dison Stracke Pfingsten Franco, Glaydson Simões dos Reis, Eder Cláudio Lima","doi":"10.1007/s10311-024-01751-1","DOIUrl":"10.1007/s10311-024-01751-1","url":null,"abstract":"<div><p>Paracetamol, a common pain reliever, has seen a significant rise in use, particularly during the Coronavirus Disease 2019 (COVID-19) pandemic. This widespread consumption has led to increased levels of paracetamol in the environment through wastewater discharge. This raises concerns about its potential impact on aquatic ecosystems. Here, we review the state-of-the-art methods for removing paracetamol from wastewater, focusing on adsorption techniques. We explore how different materials and operational conditions influence the effectiveness of this approach. We also discuss the potential of combining adsorption with oxidative methods for enhanced removal. We further assess the environmental impact by critically examining the ecotoxicological effects of paracetamol on aquatic organisms. This analysis compares established toxicity values with those observed in studies using real wastewater samples. Finally, we highlight the specific needs for further research and development of efficient and sustainable strategies to mitigate paracetamol pollution, ensuring the safety of both human and aquatic life.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 5","pages":"2343 - 2373"},"PeriodicalIF":15.0,"publicationDate":"2024-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141304536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Carbon dioxide sequestration with carbonic anhydrase nanobiocatalysts: a review","authors":"Devendra Sillu, Varenyam Achal","doi":"10.1007/s10311-024-01755-x","DOIUrl":"10.1007/s10311-024-01755-x","url":null,"abstract":"<div><p>Lowering the adverse effects of climate change requires advanced methods to decrease atmospheric levels of carbon dioxide. Here, we review the use of carbonic anhydrase nanobiocatalysts for carbon dioxide sequestration, with emphasis on inorganic, organic, and polymeric nanomaterials. Inorganic nanomaterials include metal and metal oxide, carbon-based, and nonmetallic nanomaterials. Hybrid nanomaterials comprise metal–organic frameworks and nanoflowers. Factors influencing the properties of nanobiocatalysts such as interactions between carbonic anhydrase and the nanoscale support are presented. The immobilization of carbonic anhydrase onto nanomaterials overcomes the limitations associated with its free form, such as short shelf life, challenging separation, and poor reusability. We discuss the potential for large-scale applications.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 5","pages":"2213 - 2239"},"PeriodicalIF":15.0,"publicationDate":"2024-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141251666","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Annaleise R. Klein, Jade J. Basinski, Aurore Niyitanga Manzi, Cynthia X. Cheng, Marcos Sanchez, Wiriya Thongsomboon, Ludmilla Aristilde
{"title":"Phosphorus recycling by mineral-catalyzed ribonucleotide cleavage on iron and manganese oxides","authors":"Annaleise R. Klein, Jade J. Basinski, Aurore Niyitanga Manzi, Cynthia X. Cheng, Marcos Sanchez, Wiriya Thongsomboon, Ludmilla Aristilde","doi":"10.1007/s10311-024-01754-y","DOIUrl":"10.1007/s10311-024-01754-y","url":null,"abstract":"<div><p>Phosphorus is an essential element influencing both food security via plant fertilization, and water pollution through excessive phosphorus use, yet the phosphorus cycle in ecosystems is poorly known. In particular, beyond adsorption, the role of iron and manganese oxides in catalyzing the abiotic dephosphorylation of biomolecules is debated. Here, we studied the reactions of ribonucleotides, containing different phosphate bonding, with goethite, hematite, and birnessite. We employed both high-resolution mass spectrometry of solution species and molecular modeling simulations of ribonucleotide-mineral complexes. Results disclose an up to fivefold preferential hydrolytic cleavage of a phosphoanhydride bond over a phosphoester bond, indicating that mineral-catalyzed reactions reflect the hierarchy reported for the activity of phosphatase enzymes. The fourfold higher catalytic reactivity of goethite and birnessite versus hematite is explained by mineral-specific binding rather than surface area differences. Corresponding simulated adsorbate conformations at the water–mineral interfaces are proposed. Overall, our findings provide new insights on the catalytic recycling of organic phosphorus species by mineral oxides.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 6","pages":"2627 - 2633"},"PeriodicalIF":15.0,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10311-024-01754-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141251793","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ying Chen, Cheng Cheng, Wenqing Xu, Yanfan Cui, Yan Tian, Yulin Jiang, Yangyang Yuan, Ruirui Qian, Yujie Wang, Liping Zheng, Houyang Chen, Tao Luo
{"title":"Occurrence, toxicity and removal of polystyrene microplastics and nanoplastics in human sperm","authors":"Ying Chen, Cheng Cheng, Wenqing Xu, Yanfan Cui, Yan Tian, Yulin Jiang, Yangyang Yuan, Ruirui Qian, Yujie Wang, Liping Zheng, Houyang Chen, Tao Luo","doi":"10.1007/s10311-024-01752-0","DOIUrl":"10.1007/s10311-024-01752-0","url":null,"abstract":"<div><p>Polystyrene microplastics, especially those smaller than 10 μm, reduce male fertility in murine models, but whether they affect male reproduction in humans is poorly understood. Here, we studied polystyrene microplastics smaller than 10 μm in human semen samples and evaluated their toxicity to human sperm. We also tested the use of magnetic iron oxide nanoparticles to remove nanoplastics and decrease their toxicity in human sperm. Results show that human semen is contaminated by approximately 3.57 ± 0.32 μg/mL polystyrene microplastics smaller than 10 μm. Polystyrene nanoplastics of 25–100 nm penetrate and damage human sperm at semen-relevant concentrations of 5 and 50 μg of nanoplastic per mL, while 0.5–10 μm polystyrene microplastics bind to the sperm. We also found that 25-nm polystyrene nanoplastics exhibited a synergistic toxicity with bisphenol A on human sperm. Nonetheless, we observed that environmental microplastics released from disposable paper cups do not pose a significant hazard to human sperm under our conditions. Furthermore, magnetic iron oxide nanoparticles can aggregate and coprecipitate with 25-nm polystyrene nanoplastics to eliminate their adverse effects on human sperm.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 5","pages":"2159 - 2165"},"PeriodicalIF":15.0,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141177735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sivakumar Akash, Sankar Sudharsan Rameshwar, Baskaran Sivaprakash, Natarajan Rajamohan, Dai-Viet N. Vo
{"title":"Detection and remediation of pharmaceutical pollutants using metal oxide nanoparticle-functionalized carbon nanotubes: a review","authors":"Sivakumar Akash, Sankar Sudharsan Rameshwar, Baskaran Sivaprakash, Natarajan Rajamohan, Dai-Viet N. Vo","doi":"10.1007/s10311-024-01749-9","DOIUrl":"10.1007/s10311-024-01749-9","url":null,"abstract":"<div><p>Some pharmaceutical and personal care products, including endocrine disruptors, are polluting ecosystems, thus requiring advanced materials and methods for detection and remediation. Here we review carbon nanotubes for detection and remediation of pharmaceutical and personal care products, with focus on green synthesis of hybrid carbon nanotubes, removal of pollutants, and deep learning networks to predicts adsorption. Pollutants include bisphenol, phthalates, tetracycline, and ciprofloxacin. We found that magnetic carbon nanotubes are easily recovered from water with a relatively low production cost. Functionalized carbon dots/carbon nanotube hybrids can detect ciprofloxacin contamination at 0.001 mg/L. Some studies report the adsorption of 95% or the photocatalytic degradation of 100% of pollutants using magnetic carbon nanotubes.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 5","pages":"2319 - 2341"},"PeriodicalIF":15.0,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141182435","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Subcritical water conversion of biomass to biofuels, chemicals and materials: a review","authors":"Kapil Khandelwal, Somaye Seraj, Sonil Nanda, Ramin Azargohar, Ajay K. Dalai","doi":"10.1007/s10311-024-01750-2","DOIUrl":"10.1007/s10311-024-01750-2","url":null,"abstract":"<div><p>The use of fossil fuels has been essential to the development of society, but has also contributed partly to global warming. For example, carbon dioxide emissions from fossil fuels and industries have increased by 60% since 1990, calling for the recycling of modern biomass in the context of a carbon neutral economy. Here we review the hydrothermal conversion of biomass into biofuels, chemicals and biomaterials with emphasis on subcritical water properties, hydrolysis of biomass, steam explosion, fractionation, carbonization, liquefaction, gasification, and fractionation of bio-oil. We observe that hydrothermal conversion of biomass in the presence of water at subcritical conditions produces value-added compounds with high process efficiency. Subcritical water allows rapid reaction rates, low mass transfer resistance, and gas-like diffusivity.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 5","pages":"2191 - 2211"},"PeriodicalIF":15.0,"publicationDate":"2024-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141182427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}