Ruihe Jin, Jun Shi, Jing Yang, Ge Yin, Chunjie Xia, Xiongwei Wang, Min Liu, Yan Wu
{"title":"Efficient analysis of metabolites of industrial additives in cerebrospinal fluids","authors":"Ruihe Jin, Jun Shi, Jing Yang, Ge Yin, Chunjie Xia, Xiongwei Wang, Min Liu, Yan Wu","doi":"10.1007/s10311-024-01705-7","DOIUrl":"10.1007/s10311-024-01705-7","url":null,"abstract":"<div><p>Despite being protected by the blood–brain barrier and the blood–cerebrospinal fluid barrier, cerebrospinal fluids can contain contaminants that trigger neurotoxic effects, yet there are few effective methods to analyze metabolites of industrial additives. Here, we established a fast and robust analytical methodology, based on ultra-high performance liquid chromatography interfaced with triple quadrupole mass spectrometry, to quantitatively determine concentrations of metabolites of synthetic antioxidants, organophosphate esters, and phthalate esters in human cerebrospinal fluids. The developed method exhibited highly sensitive and stable instrumental performance, satisfactory recoveries, minimal matrix effects, and trace level detection limits. We identified and quantified thirty industrial additive metabolites in cerebrospinal fluid samples, at 0.58–13 ng/mL total concentrations.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"997 - 1003"},"PeriodicalIF":15.0,"publicationDate":"2024-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139938889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yunhui Xia, Yi Chen, Junhan Chen, Xiaodong Han, Xiaojian Wang, Dongmei Li
{"title":"Gestational exposure to a fluorotelomer alcohol causes behavioral abnormalities by disrupting the blood–brain barrier in offspring","authors":"Yunhui Xia, Yi Chen, Junhan Chen, Xiaodong Han, Xiaojian Wang, Dongmei Li","doi":"10.1007/s10311-024-01707-5","DOIUrl":"10.1007/s10311-024-01707-5","url":null,"abstract":"<div><p>Fluorotelomer alcohols are an alternative to neurotoxic perfluoroalkyl carboxylic acids, a sub-class of per- and poly-fluoroalkyl substances (PFAS). However, the effect of the fluorotelomer alcohol in offspring is poorly known. Here pregnant mice were exposed to various doses of the 6:2 fluorotelomer alcohol through intragastric administration from gestation day 8.5 until delivery. Results show that the fluorotelomer alcohol impaired the development of the blood–brain barrier and altered brain immune microenvironment, causing anxiety-like behavior and impairments in learning memory. Mechanistic studies suggest that this is due to the activation of the serine and threonine kinase AKT/nuclear factor kappa-b/matrix metalloproteinases signaling pathway, resulting in the degradation of the tight junction protein occludin, which in turn caused disruption of endothelial barrier function. Our findings represent the first evidence that gestational exposure to the 6:2 fluorotelomer alcohol causes neurotoxicity in offspring.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"967 - 973"},"PeriodicalIF":15.0,"publicationDate":"2024-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139938878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xueying Wang, Haijiao Liu, Yonggang Xue, Long Cui, Long Chen, Kin-fai Ho, Yu Huang
{"title":"Formation of environmentally persistent free radicals and their risks for human health: a review","authors":"Xueying Wang, Haijiao Liu, Yonggang Xue, Long Cui, Long Chen, Kin-fai Ho, Yu Huang","doi":"10.1007/s10311-024-01701-x","DOIUrl":"10.1007/s10311-024-01701-x","url":null,"abstract":"<div><p>Environmentally persistent free radicals are long-lived pollutants that maintain stability in air, soil, and water. They contribute to the production of reactive oxygen species in environmental media, leading to oxidative stress in biological organisms. This stress can provoke inflammation and damage to biological macromolecules, potentially resulting in cardiopulmonary dysfunction. In this review, we discuss the formation and classification of EPFRs. Typically, EPFRs form through electron transfer from organic compounds to transition metals during thermal processes. In metal-free environments, however, organic compounds can undergo bond cleavage, generating EPFRs under thermal conditions and light exposure. EPFRs are generally categorized into three types: oxygen-centered, carbon-centered, and those containing heteroatoms centered on either oxygen or carbon. We also provide a detailed summary of the fundamental characteristics of EPFRs in different environments such as air, soil, and water. Given their role as electron donors, EPFRs have potential applications in degrading organic pollutants in the environment. The review comprehensively addresses the deleterious impacts of EPFRs on organism health, highlighting risks to metabolic functions and cardiopulmonary health. Furthermore, it underscores the potential involvement of EPFRs as electron donors in atmospheric chemical reactions. The pivotal role of EPFRs in environmental pollutant transformation warrants more studies in future research endeavors.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"1327 - 1343"},"PeriodicalIF":15.0,"publicationDate":"2024-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139750215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Akash Balakrishnan, Meenu Mariam Jacob, Mahendra Chinthala, Nanditha Dayanandan, Muthamilselvi Ponnuswamy, Dai-Viet N. Vo
{"title":"Photocatalytic sponges for wastewater treatment, carbon dioxide reduction, and hydrogen production: a review","authors":"Akash Balakrishnan, Meenu Mariam Jacob, Mahendra Chinthala, Nanditha Dayanandan, Muthamilselvi Ponnuswamy, Dai-Viet N. Vo","doi":"10.1007/s10311-024-01696-5","DOIUrl":"10.1007/s10311-024-01696-5","url":null,"abstract":"<div><p>Water pollution and the energy demand are calling for sustainable technologies such as photocatalysis, yet actual methods are difficult to upscale due to the poor recovery and reusability of nanocatalysts. This issue could be solved by using photocatalytic sponges, which display high surface area and reusability. Here we review the applications of photocatalytic sponges for wastewater degradation, disinfection, carbon dioxide reduction, and hydrogen production. Photocatalytic sponges are fabricated by templating, dip coating, sol–gel, polymerization, electrospinning, and freeze drying. Remarkable results include the monolithic microreactor with Ag/AgCl coated on a polydopamine-modified melamine sponge, which exhibits a 100% methylene blue degradation in 15 min, with a reusability of five cycles. An hydrogen production rate of 11.33 mmol h<sup>−1</sup> g<sup>−1</sup> was obtained with the pyridazine-doped graphitic carbon nitride with nitrogen defects and a spongy structure.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 2","pages":"635 - 656"},"PeriodicalIF":15.0,"publicationDate":"2024-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139745260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ahmed I. Osman, Mahmoud Nasr, Mohamed Farghali, Ahmed K. Rashwan, Adel Abdelkader, Ala’a H. Al-Muhtaseb, Ikko Ihara, David W. Rooney
{"title":"Optimizing biodiesel production from waste with computational chemistry, machine learning and policy insights: a review","authors":"Ahmed I. Osman, Mahmoud Nasr, Mohamed Farghali, Ahmed K. Rashwan, Adel Abdelkader, Ala’a H. Al-Muhtaseb, Ikko Ihara, David W. Rooney","doi":"10.1007/s10311-024-01700-y","DOIUrl":"10.1007/s10311-024-01700-y","url":null,"abstract":"<div><p>The excessive reliance on fossil fuels has resulted in an energy crisis, environmental pollution, and health problems, calling for alternative fuels such as biodiesel. Here, we review computational chemistry and machine learning for optimizing biodiesel production from waste. This article presents computational and machine learning techniques, biodiesel characteristics, transesterification, waste materials, and policies encouraging biodiesel production from waste. Computational techniques are applied to catalyst design and deactivation, reaction and reactor optimization, stability assessment, waste feedstock analysis, process scale-up, reaction mechanims, and molecular dynamics simulation. Waste feedstock comprise cooking oil, animal fat, vegetable oil, algae, fish waste, municipal solid waste and sewage sludge. Waste cooking oil represents about 10% of global biodiesel production, and restaurants alone produce over 1,000,000 m<sup>3</sup> of waste vegetable oil annual. Microalgae produces 250 times more oil per acre than soybeans and 7–31 times more oil than palm oil. Transesterification of food waste lipids can produce biodiesel with a 100% yield. Sewage sludge represents a significant biomass waste that can contribute to renewable energy production.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"1005 - 1071"},"PeriodicalIF":15.0,"publicationDate":"2024-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10311-024-01700-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139739420","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Species-specific deformation of microalgae in the presence of microplastics","authors":"Fengyuan Chen, Yougen Chen, Ke Pan, Hongbin Liu","doi":"10.1007/s10311-024-01699-2","DOIUrl":"10.1007/s10311-024-01699-2","url":null,"abstract":"<div><p>Ocean pollution by microplastics represents a threat to phytoplankton health, yet there is few knowledge on physical interactions between microplastics and microalgal cell surfaces. We studied the contact between environmentally aged microplastics and four microalgal species by atomic force microscopy. After seven days, microalgae showed malformations at specific sites, and these malformations varied with species. Depending on whether the cell had a porous or a smooth surface, microplastics adsorbed to the cell surface via embedding or denting, leading to minor defects or noticeable wrinkles in cell walls. Results also showed that microplastics penetrate into microalgae. Such cellular engulfment of microplastics was less present in typical diatoms because diatoms bear a porous frustule capable of trapping tiny particles. Moreover, we observed a novel type of deformation, bowl-shaped depressions, only in non-porous microalgae. The geometric features of malformations are correlated with the shape and size of microplastics. Our findings reveal for the first time the species-specific deformation in microalgae due to microplastic exposure.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"953 - 959"},"PeriodicalIF":15.0,"publicationDate":"2024-02-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139704988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lin Ma, Zhixuan Li, Gang He, Guihua Liu, Mingfei Ji, Wenzhi Liu
{"title":"Effect of combined cadmium and doxycycline pollution on the nitrogen cycle in constructed ditch wetlands","authors":"Lin Ma, Zhixuan Li, Gang He, Guihua Liu, Mingfei Ji, Wenzhi Liu","doi":"10.1007/s10311-024-01697-4","DOIUrl":"10.1007/s10311-024-01697-4","url":null,"abstract":"<div><p>Rural drainage ditches serve as important sinks for heavy metals and antibiotics. However, the combined effects of heavy metals and antibiotics on ecological processes and functions in ditches remain unclear. We studied the combined effects of cadmium and doxycycline on nitrification, denitrification, anaerobic ammonia oxidation, and nitrous oxide emission rates in constructed ditch wetlands during 84 days. Results show that combined pollution decreased denitrification and anaerobic ammonia oxidation rates, but increased nitrous oxide production rates. The addition of either cadmium or doxycycline decreased the glucokinase and glyceraldehyde-3-phosphate dehydrogenase activities, and their combined pollution had a higher impact on adenosine triphosphate than on nicotinamide adenine dinucleotide. Moreover, the activities of the electron transport system, nitrate reductase, and nitrite reductase were enhanced by short-term pollutant exposure, but inhibited by long-term pollutant exposure. Structural equation modelling further revealed that electron production and transport impacted the rates of denitrification, anaerobic ammonia oxidation, and nitrous oxide production directly and indirectly by changing the activities of nitrate and nitrite reductases.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"989 - 995"},"PeriodicalIF":15.0,"publicationDate":"2024-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139695850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ahmed I. Osman, Mahmoud Nasr, Mohamed Farghali, Sara S. Bakr, Abdelazeem S. Eltaweil, Ahmed K. Rashwan, Eman M. Abd El-Monaem
{"title":"Machine learning for membrane design in energy production, gas separation, and water treatment: a review","authors":"Ahmed I. Osman, Mahmoud Nasr, Mohamed Farghali, Sara S. Bakr, Abdelazeem S. Eltaweil, Ahmed K. Rashwan, Eman M. Abd El-Monaem","doi":"10.1007/s10311-023-01695-y","DOIUrl":"10.1007/s10311-023-01695-y","url":null,"abstract":"<div><p>Membrane filtration is a major process used in the energy, gas separation, and water treatment sectors, yet the efficiency of current membranes is limited. Here, we review the use of machine learning to improve membrane efficiency, with emphasis on reverse osmosis, nanofiltration, pervaporation, removal of pollutants, pathogens and nutrients, gas separation of carbon dioxide, oxygen and hydrogen, fuel cells, biodiesel, and biogas purification. We found that the use of machine learning brings substantial improvements in performance and efficiency, leading to specialized membranes with remarkable potential for various applications. This integration offers versatile solutions crucial for addressing global challenges in sustainable development and advancing environmental goals. Membrane gas separation techniques improve carbon capture and purification of industrial gases, aiding in the reduction of carbon dioxide emissions.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 2","pages":"505 - 560"},"PeriodicalIF":15.0,"publicationDate":"2024-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10311-023-01695-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139695851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ahmed I. Osman, Bingbing Fang, Yubing Zhang, Yunfei Liu, Jiacheng Yu, Mohamed Farghali, Ahmed K. Rashwan, Zhonghao Chen, Lin Chen, Ikko Ihara, David W. Rooney, Pow-Seng Yap
{"title":"Life cycle assessment and techno-economic analysis of sustainable bioenergy production: a review","authors":"Ahmed I. Osman, Bingbing Fang, Yubing Zhang, Yunfei Liu, Jiacheng Yu, Mohamed Farghali, Ahmed K. Rashwan, Zhonghao Chen, Lin Chen, Ikko Ihara, David W. Rooney, Pow-Seng Yap","doi":"10.1007/s10311-023-01694-z","DOIUrl":"10.1007/s10311-023-01694-z","url":null,"abstract":"<div><p>The global expansion of the bioenergy industry raises concerns, emphasizing the need for careful evaluation and sustainable management. To facilitate this, life cycle assessments beyond greenhouse gas emissions and energy balance are essential, along with the standardization of assessment methodologies to enable meaningful comparisons. Here, we review life cycle assessment, chemical aspects, and policy implication of bioenergy production. We discuss life cycle assessment in terms of concepts, methods, impacts, greenhouse gases, land use, water consumption, bioethanol, biodiesel, biogas, and techno-economic analysis. Chemical aspects comprise reaction processes and means to improve efficiency. Concerning policies, tools, and frameworks that encourage sustainable energy production are presented. We found that carbon dioxide removal ranges from 45 to 99% in various bioenergy processes. The review also emphasizes the importance of chemistry in advancing sustainable bioenergy production for a more sustainable and secure energy future.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"1115 - 1154"},"PeriodicalIF":15.0,"publicationDate":"2024-02-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10311-023-01694-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139659886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Predicted tenfold increase of hydrogen solubility in water under pore confinement","authors":"Siqin Yu, Ruyi Zheng, Qinjun Kang, Mohamed Mehana","doi":"10.1007/s10311-024-01698-3","DOIUrl":"10.1007/s10311-024-01698-3","url":null,"abstract":"<div><p>Underground hydrogen storage in geological formations has gained interest as a potential solution for the global energy transition. The change of hydrogen solubility in underground confinement is a key challenge for safety and efficiency, yet there is few knowledge on hydrogen solubility under nanoconfinement in clays. Here we used molecular dynamic simulations to study hydrogen solubility in water at realistic storage conditions under the confinement of kaolinite. We find a solubility enhancement of tenfold under nanoscale confinement compared with that in the bulk for both hydrophobic and hydrophilic systems. Mechanisms driving this oversolubility are discussed.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"945 - 951"},"PeriodicalIF":15.0,"publicationDate":"2024-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139878730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}