Jinshu Huang, Tengyu Liu, Keping Wang, Zhuochun Huang, Junqi Wang, Samuel Lalthazuala Rokhum, Hu Li
{"title":"Room-temperature and carbon-negative production of biodiesel via synergy of geminal-atom and photothermal catalysis","authors":"Jinshu Huang, Tengyu Liu, Keping Wang, Zhuochun Huang, Junqi Wang, Samuel Lalthazuala Rokhum, Hu Li","doi":"10.1007/s10311-024-01723-5","DOIUrl":"10.1007/s10311-024-01723-5","url":null,"abstract":"<div><p>Catalytic biodiesel production with bases can be achieved under relatively mild conditions. However, the basicity of solid alkali catalysts originates usually from electron-rich atoms such as oxygen and nitrogen, rather than electron-deficient metal species. This typically induces aggregation and leaching of active sites, and difficulty in recycling. Here we synthesized a photothermal catalyst made of stable and uniformly dispersed graphene-like biomaterial anchored neighboring potassium single atoms. The production of biodiesel from various acidic oils over this catalyst was evaluated by life cycle assessment and cost analysis. Infrared thermal imaging and finite element simulations were used to study the light-induced self-heating process. We further studied the alkaline behavior of neighboring potassium single atoms by carbon dioxide chemisorption and quantum calculations. Results show biodiesel yield of 99.6% at room temperature, which is explained by a good local photothermal effect at the solar interface and the presence of superalkali sites in the atomic potassium-containing biomaterial. The global warming potential measured for this system resulted in a net negative CO<sub>2</sub> emission of −10.8 kg CO<sub>2</sub>eq/kg. The photothermal catalyst can be recycled with almost no decline in reactivity.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 4","pages":"1607 - 1613"},"PeriodicalIF":15.0,"publicationDate":"2024-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140230359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zahra Teimouri, Sonil Nanda, Nicolas Abatzoglou, Ajay K. Dalai
{"title":"Application of activated carbon in renewable energy conversion and storage systems: a review","authors":"Zahra Teimouri, Sonil Nanda, Nicolas Abatzoglou, Ajay K. Dalai","doi":"10.1007/s10311-023-01690-3","DOIUrl":"10.1007/s10311-023-01690-3","url":null,"abstract":"<div><p>The consumption of renewable energy should increase by 300% by 2050 compared to 2010 due to the rising demand for green electricity, stringent government mandates on low-carbon fuels, and competitive biofuel production costs, thus calling for advanced methods of energy production. Here we review the use of activated carbon, a highly porous graphitic form of carbon, as catalyst and electrode for for energy production and storage. The article focuses on synthesis of activated carbon, hydrogen production and storage, biodiesel production, energy recovery, and the use of machine learning. The textural properties and surface chemistry of activated carbon can be engineered using acid and base treatments, hetero-atom doping, and optimization of the activation conditions to improve the efficiency of renewable energy production and storage. Machine learning allows to optimize the synthesis of catalysts, electrodes and bioproducts, with benefits to the biorefinery industries.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"1073 - 1092"},"PeriodicalIF":15.0,"publicationDate":"2024-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140229813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Biofilm formation, occurrence, microbial communication, impact and characterization methods in natural and anthropic systems: a review","authors":"Punniyakotti Elumalai, Xuke Gao, Jinjie Cui, Arunagiri Santhosh Kumar, Perumal Dhandapani, Punniyakotti Parthipan, Obulisamy Parthiba Karthikeyan, Jayaraman Theerthagiri, Soorathep Kheawhom, Myong Yong Choi","doi":"10.1007/s10311-024-01715-5","DOIUrl":"10.1007/s10311-024-01715-5","url":null,"abstract":"<div><p>A biofilm is a layer of microbes that have aggregated to form a colony. The colony attaches to a surface with a slime layer which protects the microorganisms, promoting their growth and survival. Biofilms occur in various environments such as soils, sediments, wastewater, water pipelines, water purifying systems, cooling water systems, medical devices, archaeological monuments, marine vessels, and hospitals. Biofilms may induce adverse effects such as fostering drug-resistant strains. Here, we review biofilms with focus on their formation, occurrence in water systems, impact, microbial interactions, and characterization methods. Communication includes cell-to-cell interactions by quorum sensing, interactions mediated by flagella, gene, and signaling molecules, and interactions mediated by extracellular polymeric substances. Characterization methods comprise surface-enhanced Raman scattering spectroscopy, confocal laser scanning microscopy, scanning electron microscopy, fluorescence microscopy, sensors, and metagenomics analysis.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"1297 - 1326"},"PeriodicalIF":15.0,"publicationDate":"2024-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140246674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Waqas Waqas, Ye Yuan, Sardar Ali, Mengqian Zhang, Muhammad Shafiq, Wajid Ali, Yongyi Chen, Zifei Xiang, Ruixiang Chen, Mhd Ikhwanuddin, Hongyu Ma
{"title":"Toxic effects of heavy metals on crustaceans and associated health risks in humans: a review","authors":"Waqas Waqas, Ye Yuan, Sardar Ali, Mengqian Zhang, Muhammad Shafiq, Wajid Ali, Yongyi Chen, Zifei Xiang, Ruixiang Chen, Mhd Ikhwanuddin, Hongyu Ma","doi":"10.1007/s10311-024-01717-3","DOIUrl":"10.1007/s10311-024-01717-3","url":null,"abstract":"<div><p>The contamination of seafood by heavy metals is a rising health issue in the context of pollution caused by increasing industrialization and urbanization. Crustaceans are particularly susceptible to heavy metal pollution in aquatic ecosystems due to their benthic and sedimentary lifestyle. Here we review crustaceans contamination by heavy metals with a focus on metal sources and dynamics, interaction of metals with other pollutants, metal analysis, bioconcentration and bioaccumulation, toxicity, and strategies to control metals. We observed that crustaceans tend to accumulate more heavy metals than other aquatic animals. Consequently, in certain regions of the world, consuming crustaceans as food may potentially threaten human health. The bioavailability, transport, and interaction of heavy metals with other pollutants depend on various factors, potentially leading to differential toxicity. Heavy metals induce multiple toxic effects on crustaceans, including metabolic dysfunction, genotoxic effects, respiratory impairments, DNA damage, sperm mobility, and quantity, and these poisonous effects will intensify with prolonged exposure time and increasing concentration. The concentration of heavy metals in crustacean samples is usually determined by inductively coupled plasma optical emission spectrometry and mass spectrometry. Approaches to reducing this potential threat include proper industrial wastewater treatment and using low-cost adsorbent materials in aquaculture.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"1391 - 1411"},"PeriodicalIF":15.0,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140257214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Placental transfer and hazards of silver nanoparticles exposure during pregnancy: a review","authors":"Yapeng Han, Chengxi Li, Yán Wāng","doi":"10.1007/s10311-024-01709-3","DOIUrl":"10.1007/s10311-024-01709-3","url":null,"abstract":"<div><p>Many products contain silver nanoparticles, which are adsorbed by living organisms and then go through biological barriers. In particular, penetration of silver nanoparticles through the placental barrier is likely to damage the offspring. Here, we review hazards of silver nanoparticles with focus on exposure during pregnancy, toxicokinetics at maternal and fetal layers, ex vivo and in vivo placenta transfer models, and factors affecting the transfer. Exposure occurs by oral uptake, inhalation, dermal contact, and systemic administration. Toxicokinetics include absorption, distribution in tissues, metabolism and excretion. The accumulation efficiency is primarily influenced by the mode of exposure. Injection exhibits the highest bioavailability, followed by inhalation and oral uptake. Particles within the range of tens of nanometers are capable of crossing the placenta, according to an ex vivo placental perfusion model. In contrast, larger particles in the range of hundreds of nanometers are expelled outside. Due to the size restriction of the trophoblast channel, which typically ranges from 15 to 25 nm, it is possible for silver nanoparticles with an average size of around 20 nm to passively enter the placenta through the pericellular pathway, such as diffusion. On the other hand, larger silver nanoparticles may be delivered to the placenta through endocytosis, which can occur via phagocytosis, receptor-mediated or independent mechanisms.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"1365 - 1389"},"PeriodicalIF":15.0,"publicationDate":"2024-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140258317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Natural and engineered enzymes for polyester degradation: a review","authors":"Rey-Ting Guo, Xian Li, Yu Yang, Jian-Wen Huang, Panpan Shen, Rock Keey Liew, Chun-Chi Chen","doi":"10.1007/s10311-024-01714-6","DOIUrl":"10.1007/s10311-024-01714-6","url":null,"abstract":"<div><p>Plastic pollution is becoming a major health issue due to the recent discovery of microplastics and nanoplastics in living organisms and the environment, calling for advanced technologies to remove plastic waste. Here we review enzymes that degrade plastics with focus on plastic properties, protein engineering and polymers such as poly(ethylene terephthalate), poly(butylene adipate-co-terephthalate), poly(lactic acid), polyamide and polyurethane. The mechanism of action of natural and engineered enzymes has been probed by experimental and computation approaches. The performance of polyester-degrading enzymes has been improved via directed evolution, structure-guided rational design and machine learning-aided strategies. The improved enzymes display higher stability at elevated temperatures, and tailored substrate-binding sites.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"1275 - 1296"},"PeriodicalIF":15.0,"publicationDate":"2024-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10311-024-01714-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140260555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Md. Reazuddin Repon, Barshan Dev, Md Ashikur Rahman, Sigita Jurkonienė, Aminoddin Haji, Md. Abdul Alim, Eglė Kumpikaitė
{"title":"Textile dyeing using natural mordants and dyes: a review","authors":"Md. Reazuddin Repon, Barshan Dev, Md Ashikur Rahman, Sigita Jurkonienė, Aminoddin Haji, Md. Abdul Alim, Eglė Kumpikaitė","doi":"10.1007/s10311-024-01716-4","DOIUrl":"10.1007/s10311-024-01716-4","url":null,"abstract":"<div><p>The rising pollution by synthetic dyes from the textile industry is a serious health problem calling for safer chemicals and textile production methods. As an alternative, bio-based colorants are increasingly used for food, cosmetics, flavors, medical applications. Here we review bio-based textile dyeing with focus on dye classification, methods to improve dyeing, and mordants and bio-mordants. Dyes are classified according to their origin such as plant, animal, mineral, microbes, and waste; their chemical structure, e.g., indigoid, flavonoid, and tannin dyes; their color; and their application such as mordant dyes and direct dyes. Methods to improve dyeing include sonication, plasma, ultraviolet, microwave, and gamma irradiation. Most bio-based dyes are biodegradable, renewable, non-hazardous, non-allergic, and simple to use. Yet bio-based dyes are limited by poor color fastness and a constrained palette of shades. These limitations can be resolved by using mordants on textile materials. Bio-mordants enhance the bonding of natural dyes to the fabric, resulting in textiles that exhibit excellent washing fastness.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"1473 - 1520"},"PeriodicalIF":15.0,"publicationDate":"2024-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140260832","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis and environmental applications of biochar-supported nano-zero-valent iron composites: a review","authors":"Xinlian Zhong, Yujian Lai, Xuemei Wang, Menglu Wang, Wei Han, Meng Zhang, Hongbing Ji","doi":"10.1007/s10311-024-01712-8","DOIUrl":"10.1007/s10311-024-01712-8","url":null,"abstract":"<div><p>In the context of increasing pollution of almost all environmental media, there is a need for efficient and sustainable techniques to remove contaminants. Here, we review the biochar-supported nano-zero-valent iron composites with focus on their synthesis from wood, sludges and agricultural waste, and on their application to the removal of heavy metals in waters and soils. We also discuss removal mechanisms. We observe that metal removal rates of 90% and above can be achieved. The composite performance is influenced by the biochar feedstock, the pyrolysis temperature, generally within 300–1000 °C, and the iron/carbon ratio, e.g. 4:1, 2:1, and 1:2. Removal mechanisms include adsorption, reduction, and co-precipitation. We also discuss the optimization of preparation methods, their application in real environments, and the removal mechanisms for complex pollutants.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"1345 - 1363"},"PeriodicalIF":15.0,"publicationDate":"2024-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140264802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Conversion of lignocellulosic biomass-derived compounds to 2-ethylhexanol: a review","authors":"Chongran Sun, Shuangfei Zhang, Binyuan Gao, Tao Yang, Yuguang Wang, Haina Cheng, Hongbo Zhou, Zhu Chen","doi":"10.1007/s10311-024-01710-w","DOIUrl":"10.1007/s10311-024-01710-w","url":null,"abstract":"<div><p>The demand for 2-ethylhexanol is rising in several sectors, yet this chemical is actually almost exclusively produced from petroleum resources, calling for sustainable alternatives. Here we review the production of 2-ethylhexanol from lignocellulosic biomass-derived chemicals with emphasis on 2-ethylhexanol synthesis and applications. 2-Ethylhexanol can be synthesized from ethanol, butanol, butyraldehyde, and syngas. Applications comprise biofuels, lubricants, plasticizers, and surfactants.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"22 3","pages":"1093 - 1113"},"PeriodicalIF":15.0,"publicationDate":"2024-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140266313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}