Progress in Polymer Science最新文献_第5页

Rigorous recognition mode analysis of molecularly imprinted polymers—Rational design, challenges, and opportunities 分子印迹聚合物的严格识别模式分析--合理设计、挑战与机遇

IF 27.1 1区化学

Progress in Polymer Science Pub Date : 2024-01-19 DOI: 10.1016/j.progpolymsci.2024.101790

Yanxia Liu , Lulu Wang , Haitao Li , Lin Zhao , Yanfu Ma , Yagang Zhang , Jian Liu , Yen Wei

{"title":"Rigorous recognition mode analysis of molecularly imprinted polymers—Rational design, challenges, and opportunities","authors":"Yanxia Liu , Lulu Wang , Haitao Li , Lin Zhao , Yanfu Ma , Yagang Zhang , Jian Liu , Yen Wei","doi":"10.1016/j.progpolymsci.2024.101790","DOIUrl":"10.1016/j.progpolymsci.2024.101790","url":null,"abstract":"<div>Supramolecular chemistry now presents an elaborate „enabling tool“ that offers exciting opportunities for novel functional material design. One of the areas to benefit from recent advances in supramolecular chemistry is the field of molecularly imprinted polymers (MIPs), also known as “synthetic antibodies”. It uses the memory of template molecules to form tailor-made binding sites in the polymer matrix. This review provides insights from rigorous recognition mode analysis perspectives and highlights evolving approaches in MIPs. First, the principles and recognition mode of molecular imprinting technology are carefully reviewed. The similarities and major differences between MIPs and enzymes are discussed. The internal 3D structure model of MIP is depicted, the origin and consequences of binding site heterogeneity are highlighted, and methods for the optimization of the recognition degree and imprinting efficiency are summarized. The criteria for evaluating imprinting efficacy and the role of chiral recognition in molecular imprinting are discussed. Subsequently, important approaches for the design and synthesis of MIPs a reviewed. Relevant approaches include dye displacement strategy for MIP sensors, multi-functional group recognition, monomolecular imprinting using dendrimers, solvent programmable polymer (SPP) based on restricted rotation, template activated molecular imprinting strategy, molecular imprinting with click chemistry, and evolution of molecular imprinting with computational strategies. Finally, the exciting progress of MIPs for recognition of biomacromolecules such as proteins, bacteria and viruses are discussed. The goal of this review is thus to inspire new applications of MIP materials and to provide a guide for how these applications might become a reality.</div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"150 ","pages":"Article 101790"},"PeriodicalIF":27.1,"publicationDate":"2024-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139505125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydrogels for bioinspired soft robots 用于生物启发软机器人的水凝胶

IF 27.1 1区化学

Progress in Polymer Science Pub Date : 2024-01-18 DOI: 10.1016/j.progpolymsci.2024.101791

Chang Seo Park , Yong-Woo Kang , Hyeonuk Na , Jeong-Yun Sun

{"title":"Hydrogels for bioinspired soft robots","authors":"Chang Seo Park , Yong-Woo Kang , Hyeonuk Na , Jeong-Yun Sun","doi":"10.1016/j.progpolymsci.2024.101791","DOIUrl":"10.1016/j.progpolymsci.2024.101791","url":null,"abstract":"<div>Amid the ever-advancing landscape of industrial robotics, soft robots in particular have attracted substantial attention due to their remarkable structural adaptability and high efficiency and stability in dynamic environments. Living organisms are, in essence, natural soft robots, composed of diverse and efficient soft organs, each precisely performing assigned functions as a result of a long-term evolution. Fundamental components of organisms, such as material, designs, and working mechanisms, have been a paradigmatic model for the development of soft robots. Recently, these researches have been boosted with the advancement in hydrogel, a synthetic material that closely resembles the constituents of living organisms. The distinctive features of hydrogel - softness, stimuli-responsiveness, biocompatibility, ionicity, and transparency - have enabled the reproduction of nature-inspired strategies, significantly contributing to the progress in soft robots. In this review, we discuss how these properties have been exploited in various applications in soft robots to emulate blueprints found in nature. Moreover, we provide insightful perspectives on overcoming obstacles and research directions, offering a glimpse into future of soft robots.</div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"150 ","pages":"Article 101791"},"PeriodicalIF":27.1,"publicationDate":"2024-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139504737","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Conjugated microporous polymers for advanced chemical sensing applications 用于先进化学传感应用的共轭微孔聚合物

IF 27.1 1区化学

Progress in Polymer Science Pub Date : 2024-01-01 DOI: 10.1016/j.progpolymsci.2023.101770

Weisi He, Ju Duan, He Liu, Cheng Qian, Meifang Zhu, Weiyi Zhang, Yaozu Liao

{"title":"Conjugated microporous polymers for advanced chemical sensing applications","authors":"Weisi He, Ju Duan, He Liu, Cheng Qian, Meifang Zhu, Weiyi Zhang, Yaozu Liao","doi":"10.1016/j.progpolymsci.2023.101770","DOIUrl":"10.1016/j.progpolymsci.2023.101770","url":null,"abstract":"<div>Exploring advanced chemical sensing applications using porous materials is of critical importance for emerging industries such as Internet of Things, carbon neutrality, new energy resources, etc. Conjugated microporous polymers (CMPs), being well-renowned for their extended π-π conjugations, tunable pore structures, tailored chemical components, and high surface areas, have attracted increasing interests for chemical sensing applications. Here, recent milestones in the sensing applications of CMPs are presented, with an emphasis on the synthetic routes, structural requirements or parameters that dominate their sensing properties and functionalities. This review focuses on multiple chemical sensing devices including: i) fluorescent sensors, ii) electrochemical sensors, iii) colorimetric sensors, iv) resistive sensors, and v) versatile sensors. The key application areas of these CMPs-based sensors for detecting multiple matters including industrial exhausts, explosives, metal cations, halogen species, micropollutants, organic hazards, biological matters, and multiple. species, etc., are highlighted. The in-depth understanding of the sensing mechanisms and structure-property-function relationships of CMPs are also provided. Finally, a perspective on the future research directions and challenges of CMPs-based sensors is presented.</div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"148 ","pages":"Article 101770"},"PeriodicalIF":27.1,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138635620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Structural determinants of stimuli-responsiveness in amphiphilic macromolecular nano-assemblies 两亲大分子纳米组装中刺激-反应性的结构决定因素

IF 27.1 1区化学

Progress in Polymer Science Pub Date : 2024-01-01 DOI: 10.1016/j.progpolymsci.2023.101765

Hongxu Liu , Hung-Hsun Lu , Yasin Alp , Ruiling Wu , S. Thayumanavan

{"title":"Structural determinants of stimuli-responsiveness in amphiphilic macromolecular nano-assemblies","authors":"Hongxu Liu , Hung-Hsun Lu , Yasin Alp , Ruiling Wu , S. Thayumanavan","doi":"10.1016/j.progpolymsci.2023.101765","DOIUrl":"10.1016/j.progpolymsci.2023.101765","url":null,"abstract":"<div>Stimuli-responsive nano-assemblies from amphiphilic macromolecules could undergo controlled structural transformations and generate diverse macroscopic phenomenon under stimuli. Due to the controllable responsiveness, they have been applied for broad material and biomedical applications, such as biologics delivery, sensing, imaging, and catalysis. Understanding the mechanisms of the assembly-disassembly processes and structural determinants behind the responsive properties is fundamentally important for designing the next generation of nano-assemblies with programmable responsiveness. In this review, we focus on structural determinants of assemblies from amphiphilic macromolecules and their macromolecular level alterations under stimuli, such as the disruption of hydrophilic-lipophilic balance (HLB), depolymerization, decrosslinking, and changes of molecular packing in assemblies, which eventually lead to a series of macroscopic phenomenon for practical purposes. Applications of stimuli-responsive nano-assemblies in delivery, sensing and imaging were also summarized based on their structural features. We expect this review could provide readers an overview of the structural considerations in the design and applications of nano-assemblies and incentivize more explorations in stimuli-responsive soft matters.</div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"148 ","pages":"Article 101765"},"PeriodicalIF":27.1,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138571871","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent progress in CO2-based polyurethanes and polyureas 二氧化碳基聚氨酯和聚脲的最新进展

IF 27.1 1区化学

Progress in Polymer Science Pub Date : 2023-12-29 DOI: 10.1016/j.progpolymsci.2023.101780

Xu Ou , Yajuan Niu , Qinbo Liu , Legeng Li , Feifan Wei , Yongheng Cui , Yingjie Zhou , Feng Yan

{"title":"Recent progress in CO2-based polyurethanes and polyureas","authors":"Xu Ou , Yajuan Niu , Qinbo Liu , Legeng Li , Feifan Wei , Yongheng Cui , Yingjie Zhou , Feng Yan","doi":"10.1016/j.progpolymsci.2023.101780","DOIUrl":"https://doi.org/10.1016/j.progpolymsci.2023.101780","url":null,"abstract":"<div>As an abundant, renewable, and inexpensive carbon feedstock, CO2 can be converted into valuable products, creating substantial environmental and economic benefits. Polyurethanes (PUs) and polyureas (PUAs) with versatile properties have been commonly used in everyday life applications and possess vast market demand. CO2-sourced PUs and PUAs can alleviate the involvement of petroleum, and they have attracted ever-increasing attention from industry and academia because of their high economic value and fancy properties in many high-value-added material fields. This has led to their recognition as a promising strategy from the viewpoint of green and sustainable chemistry. In this review, the state-of-the-art research progress on CO2-based PUs and PUAs, with particular emphasis on their synthetic principles, modifications, applications, and degradability are summarized. Additionally, future considerations, prospects, and possible challenges in converting CO2 to nitrogenous polymers are also discussed. This review is intended to serve as a tutorial guide for the future development of novel CO2-sourced PUs and PUAs with unique properties and functions.</div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"149 ","pages":"Article 101780"},"PeriodicalIF":27.1,"publicationDate":"2023-12-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139111849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Monomer recycling of polyethylene terephthalate, polycarbonate and polyethers: Scalable processes to achieve high carbon circularity 聚对苯二甲酸乙二酯、聚碳酸酯和聚醚的单体回收：实现高碳循环的可扩展工艺

IF 27.1 1区化学

Progress in Polymer Science Pub Date : 2023-12-28 DOI: 10.1016/j.progpolymsci.2023.101783

Dambarudhar Parida , Annelore Aerts , Karolien Vanbroekhoven , Miet Van Dael , Harisekhar Mitta , Lingfeng Li , Walter Eevers , Kevin M. Van Geem , Elias Feghali , Kathy Elst

{"title":"Monomer recycling of polyethylene terephthalate, polycarbonate and polyethers: Scalable processes to achieve high carbon circularity","authors":"Dambarudhar Parida , Annelore Aerts , Karolien Vanbroekhoven , Miet Van Dael , Harisekhar Mitta , Lingfeng Li , Walter Eevers , Kevin M. Van Geem , Elias Feghali , Kathy Elst","doi":"10.1016/j.progpolymsci.2023.101783","DOIUrl":"10.1016/j.progpolymsci.2023.101783","url":null,"abstract":"<div>This review presents a comprehensive description of the current pathways used in the chemical recycling of oxygenated plastics, with a specific focus on poly(ethylene terephthalate) (PET), poly(bisphenol-A carbonate) (PC), and polyethers including anhydride-cured epoxies. For PC and PET, the emphasis is on processes that achieve high depolymerization efficiencies as well as monomer selectivity and the potential to simplify downstream processing for the recovery of pure monomers. In the case of epoxies, this work focuses on depolymerization processes that produce curable molecules, as studies on epoxy depolymerization are scarce. To assess scalability, different depolymerization pathways are compared for each polymer based on the process conditions and monomer yields. The review concludes with the discussion on potentials and challenges of the distinct depolymerization pathways that have been developed for oxygenated plastics, such as hydrolysis, alcoholysis, and reductive depolymerization.</div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"149 ","pages":"Article 101783"},"PeriodicalIF":27.1,"publicationDate":"2023-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139059587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent advances in polyhydroxyalkanoates degradation and chemical recycling 聚羟基烷酸酯降解和化学回收的最新进展

IF 27.1 1区化学

Progress in Polymer Science Pub Date : 2023-12-27 DOI: 10.1016/j.progpolymsci.2023.101781

Ali Dhaini , Valérie Hardouin-Duparc , Ali Alaaeddine , Jean-François Carpentier , Sophie M. Guillaume

{"title":"Recent advances in polyhydroxyalkanoates degradation and chemical recycling","authors":"Ali Dhaini , Valérie Hardouin-Duparc , Ali Alaaeddine , Jean-François Carpentier , Sophie M. Guillaume","doi":"10.1016/j.progpolymsci.2023.101781","DOIUrl":"10.1016/j.progpolymsci.2023.101781","url":null,"abstract":"<div>Plastics are nowadays essential to our daily life for a wide range of applications. In order to face the demand of polymer markets, given the depletion of fossil feedstocks from which they are still most commonly produced, and with the aim to develop more ecofriendly plastic materials, the need for renewable and/or recyclable polymers is huge. Polyhydroxyalkanoates (PHAs) are a class of polyesters that could meet the challenges of such a circular economy, as they currently stand as promising bio-based, degradable and recyclable alternatives to traditional non-degradable commodity polymers that are polyolefins. PHAs typically feature different side-chain substituents on the repeating units, which beside the stereochemistry along the polymer backbone and the intrinsic characteristics of the macromolecules, are key parameters that dictate and enable tuning of their thermal, mechanical, and recyclability performances. PHAs are thus a large family of versatile polymers that are currently of topical interest in light of their end-of-life options. This review discusses the chemical recycling of natural, biosynthetic and synthetic PHAs, mainly focusing on the most common examples, namely poly(3-hydroxybutyrate) (PHB), and its related copolymers. The most relevant non-biotechnological approaches, including pyrolysis-type processes, and solvolysis with especially hydrolysis and alcoholysis, whether they are catalyzed or not, are then addressed. The latest advances on the degradation, depolymerization and upcycling of PHAs, show promising outcomes for a close-carbon cycle economy with a favorable environmental impact, as exemplified from the most recent literature.</div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"149 ","pages":"Article 101781"},"PeriodicalIF":27.1,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139059781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Azobenzene-containing polymer for solar thermal energy storage and release: Advances, challenges, and opportunities 用于太阳能热能储存和释放的含偶氮苯聚合物：进展、挑战和机遇

IF 27.1 1区化学

Progress in Polymer Science Pub Date : 2023-12-27 DOI: 10.1016/j.progpolymsci.2023.101782

Xingtang Xu , Jie Feng , Wen-Ying Li , Guojie Wang , Wei Feng , Haifeng Yu

{"title":"Azobenzene-containing polymer for solar thermal energy storage and release: Advances, challenges, and opportunities","authors":"Xingtang Xu , Jie Feng , Wen-Ying Li , Guojie Wang , Wei Feng , Haifeng Yu","doi":"10.1016/j.progpolymsci.2023.101782","DOIUrl":"10.1016/j.progpolymsci.2023.101782","url":null,"abstract":"<div>Molecular solar thermal (MOST) fuels have attracted enormous research enthusiasm in solar energy conversion and storage, which can generate high-energy isomers upon harvesting photon energy and release heat on demand through reversible isomerization of molecular photo-switches such as azobenzene. However, the pristine azobenzene suffers from limitations like low energy density, short half-life and narrow absorption waveband. Recently, numerous azobenzene-based MOST fuels have been developed by various strategies including molecular engineering and template self-assembly to enhance the storage capacities, among which azobenzene-containing polymers (i.e., ‘azopolymers’) are the most promising materials for the development of MOST fuels. In this review, the state-of-the-art advances in azopolymer MOST fuels are systematically summarized. The critical parameters of azobenzene-based MOST fuels are highlighted. Various kinds of azopolymers for solar thermal energy storage and release such as azobenzene compound/polymer composites, linear azopolymers, dendrimer azopolymers, and other types of azopolymers are addressed. The most promising advantages and challenges of azopolymers for MOST fuels are analyzed, and emerging strategies as well as opportunities for future development are discussed with the goal to promote future development of MOST fuels towards innovative applications.</div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"149 ","pages":"Article 101782"},"PeriodicalIF":27.1,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139041760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Conducting polymers: Towards printable transparent electrodes 导电聚合物:迈向可印刷透明电极

IF 27.1 1区化学

Progress in Polymer Science Pub Date : 2023-12-02 DOI: 10.1016/j.progpolymsci.2023.101766

Stefania Aivali, Catherine Beaumont, Mario Leclerc

引用次数: 0

Therapeutic supramolecular polymers: Designs and applications 治疗性超分子聚合物:设计与应用

IF 27.1 1区化学

Progress in Polymer Science Pub Date : 2023-12-02 DOI: 10.1016/j.progpolymsci.2023.101769

Han Wang , Jason Mills , Boran Sun , Honggang Cui

{"title":"Therapeutic supramolecular polymers: Designs and applications","authors":"Han Wang , Jason Mills , Boran Sun , Honggang Cui","doi":"10.1016/j.progpolymsci.2023.101769","DOIUrl":"10.1016/j.progpolymsci.2023.101769","url":null,"abstract":"<div>The self-assembly of low-molecular-weight building motifs into supramolecular polymers has unlocked a new realm of materials with distinct properties and tremendous potential for advancing medical practices. Leveraging the reversible and dynamic nature of non-covalent interactions, these supramolecular polymers exhibit inherent responsiveness to their microenvironment, physiological cues, and biomolecular signals, making them uniquely suited for diverse biomedical applications. In this review, we intend to explore the principles of design, synthesis methodologies, and strategic developments that underlie the creation of supramolecular polymers as carriers for therapeutics, contributing to the treatment and prevention of a spectrum of human diseases. We delve into the principles underlying monomer design, emphasizing the pivotal role of non-covalent interactions, directionality, and reversibility. Moreover, we explore the intricate balance between thermodynamics and kinetics in supramolecular polymerization, illuminating strategies for achieving controlled sizes and distributions. Categorically, we examine their exciting biomedical applications: individual polymers as discrete carriers for therapeutics, delving into their interactions with cells, and in vivo dynamics; and supramolecular polymeric hydrogels as injectable depots, with a focus on their roles in cancer immunotherapy, sustained drug release, and regenerative medicine. As the field continues to burgeon, harnessing the unique attributes of therapeutic supramolecular polymers holds the promise of transformative impacts across the biomedical landscape.</div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"148 ","pages":"Article 101769"},"PeriodicalIF":27.1,"publicationDate":"2023-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138481191","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0