Photoiniferter polymerization: Illuminating the history, ascendency, and renaissance

IF 26 1区化学 Q1 POLYMER SCIENCE

Progress in Polymer Science Pub Date : 2024-09-01 DOI:10.1016/j.progpolymsci.2024.101871

Rhys W. Hughes , Megan E. Lott , Rebecca A. Olson S, Brent S. Sumerlin

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Abstract

In this perspective, we explore the historical evolution, photochemical processes, and distinct utility of photoiniferter polymerization. We aim to provide a practical guide encompassing the selection of iniferter and monomer, coupled with the optimization of light wavelengths to conduct efficient photoiniferter polymerizations. We delve into the impact of iniferter structure on photophysical properties and the resulting polymerization behavior. Furthermore, we highlight ongoing research efforts employing photoiniferter polymerization, emphasizing its potential applications in cutting-edge areas of research such as 3D printing and the synthesis of ultra-high molecular weight polymers ( $\geq$ 10⁶ g mol^-1). Through this perspective, we aim to clarify both the fundamental principles and the practical considerations of photoiniferter polymerization, ultimately advancing its utility and paving the way for innovative applications in polymer science.

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光iferter 聚合：照亮历史、崛起与复兴

从这个角度，我们探讨了光增感剂聚合的历史演变、光化学过程和独特用途。我们旨在提供一份实用指南，其中包括如何选择增韧剂和单体，以及如何优化光波长以进行高效的光增韧剂聚合。我们深入探讨了增韧剂结构对光物理性质和聚合行为的影响。此外，我们还重点介绍了正在进行的采用光增塑剂聚合的研究工作，强调了其在 3D 打印和合成超高分子量聚合物（≥106 g mol-1）等前沿研究领域的潜在应用。通过这一视角，我们旨在阐明光iferter 聚合的基本原理和实际考虑因素，最终提高其实用性，为聚合物科学的创新应用铺平道路。

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来源期刊

Progress in Polymer Science 化学-高分子科学

CiteScore

48.70

自引率

1.10%

发文量

审稿时长

38 days

期刊介绍： Progress in Polymer Science is a journal that publishes state-of-the-art overview articles in the field of polymer science and engineering. These articles are written by internationally recognized authorities in the discipline, making it a valuable resource for staying up-to-date with the latest developments in this rapidly growing field. The journal serves as a link between original articles, innovations published in patents, and the most current knowledge of technology. It covers a wide range of topics within the traditional fields of polymer science, including chemistry, physics, and engineering involving polymers. Additionally, it explores interdisciplinary developing fields such as functional and specialty polymers, biomaterials, polymers in drug delivery, polymers in electronic applications, composites, conducting polymers, liquid crystalline materials, and the interphases between polymers and ceramics. The journal also highlights new fabrication techniques that are making significant contributions to the field. The subject areas covered by Progress in Polymer Science include biomaterials, materials chemistry, organic chemistry, polymers and plastics, surfaces, coatings and films, and nanotechnology. The journal is indexed and abstracted in various databases, including Materials Science Citation Index, Chemical Abstracts, Engineering Index, Current Contents, FIZ Karlsruhe, Scopus, and INSPEC.