Infrared plastic optics and photonic devices using chalcogenide hybrid inorganic/organic polymers via inverse vulcanization of elemental sulfur

IF 26 1区 化学 Q1 POLYMER SCIENCE
Jeffrey Pyun , Robert A. Norwood
{"title":"Infrared plastic optics and photonic devices using chalcogenide hybrid inorganic/organic polymers via inverse vulcanization of elemental sulfur","authors":"Jeffrey Pyun ,&nbsp;Robert A. Norwood","doi":"10.1016/j.progpolymsci.2024.101865","DOIUrl":null,"url":null,"abstract":"<div><p>Since the invention of inverse vulcanization and high sulfur content polymers, termed <em>Chalcogenide Hybrid Inorganic/Organic Polymers</em>, the application of these polymers as optical materials for IR optics &amp; photonics has garnered interest from groups around the world. Earlier publications and review papers have focused on the polymer chemistry aspects of inverse vulcanization, however, recent work in the past decade has seen tremendous new advances in polymer processing, rheology, and optical component (nano-micro) fabrication of lenses and photonic devices across the infrared spectrum. There is an urgent need for a review surveying both new polymer chemistry and polymer engineering aspects of this important new field, for the integration of these new optical polymers into imaging, communications, and sensing systems. In this submission, we review the fabrication and polymer processing of inverse vulcanized organopolysulfides made from elemental sulfur for IR optics and photonics. We survey recent work in the SWIR and MWIR spectrum for the development of integrated photonics devices using high sulfur content polymers, along with the fabrication and testing of LWIR bulk plastic optics using this new class of optical polymers.</p></div>","PeriodicalId":413,"journal":{"name":"Progress in Polymer Science","volume":"156 ","pages":"Article 101865"},"PeriodicalIF":26.0000,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0079670024000820","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

Abstract

Since the invention of inverse vulcanization and high sulfur content polymers, termed Chalcogenide Hybrid Inorganic/Organic Polymers, the application of these polymers as optical materials for IR optics & photonics has garnered interest from groups around the world. Earlier publications and review papers have focused on the polymer chemistry aspects of inverse vulcanization, however, recent work in the past decade has seen tremendous new advances in polymer processing, rheology, and optical component (nano-micro) fabrication of lenses and photonic devices across the infrared spectrum. There is an urgent need for a review surveying both new polymer chemistry and polymer engineering aspects of this important new field, for the integration of these new optical polymers into imaging, communications, and sensing systems. In this submission, we review the fabrication and polymer processing of inverse vulcanized organopolysulfides made from elemental sulfur for IR optics and photonics. We survey recent work in the SWIR and MWIR spectrum for the development of integrated photonics devices using high sulfur content polymers, along with the fabrication and testing of LWIR bulk plastic optics using this new class of optical polymers.

Abstract Image

通过元素硫的反向硫化,使用铬化杂化无机/有机聚合物的红外塑料光学和光子设备
自反向硫化和高硫含量聚合物(被称为 "卤化铝杂化无机/有机聚合物")发明以来,这些聚合物作为光学材料在红外光学& 光子学领域的应用引起了世界各地研究团体的兴趣。早期的出版物和综述论文主要集中在反硫化的聚合物化学方面,然而,在过去十年中,聚合物加工、流变学以及红外光谱透镜和光子设备的光学元件(纳米-微米)制造方面取得了巨大的新进展。为了将这些新型光学聚合物集成到成像、通信和传感系统中,迫切需要对这一重要新领域的新型聚合物化学和聚合物工程方面进行综述。在这篇论文中,我们回顾了由元素硫制成的反硫化有机多硫化物在红外光学和光子学领域的制造和聚合物加工。我们考察了最近在使用高含硫聚合物开发集成光子器件的 SWIR 和 MWIR 光谱方面所做的工作,以及使用这种新型光学聚合物制造和测试 LWIR 块状塑料光学器件的情况。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Progress in Polymer Science
Progress in Polymer Science 化学-高分子科学
CiteScore
48.70
自引率
1.10%
发文量
54
审稿时长
38 days
期刊介绍: Progress in Polymer Science is a journal that publishes state-of-the-art overview articles in the field of polymer science and engineering. These articles are written by internationally recognized authorities in the discipline, making it a valuable resource for staying up-to-date with the latest developments in this rapidly growing field. The journal serves as a link between original articles, innovations published in patents, and the most current knowledge of technology. It covers a wide range of topics within the traditional fields of polymer science, including chemistry, physics, and engineering involving polymers. Additionally, it explores interdisciplinary developing fields such as functional and specialty polymers, biomaterials, polymers in drug delivery, polymers in electronic applications, composites, conducting polymers, liquid crystalline materials, and the interphases between polymers and ceramics. The journal also highlights new fabrication techniques that are making significant contributions to the field. The subject areas covered by Progress in Polymer Science include biomaterials, materials chemistry, organic chemistry, polymers and plastics, surfaces, coatings and films, and nanotechnology. The journal is indexed and abstracted in various databases, including Materials Science Citation Index, Chemical Abstracts, Engineering Index, Current Contents, FIZ Karlsruhe, Scopus, and INSPEC.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信