Organic Electronics最新文献

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Compact model for threshold voltage of organic thin film transistors 有机薄膜晶体管阈值电压的紧凑模型
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-20 DOI: 10.1016/j.orgel.2025.107222
Liang Yin, Jiaye Shen, Nianduan Lu
{"title":"Compact model for threshold voltage of organic thin film transistors","authors":"Liang Yin,&nbsp;Jiaye Shen,&nbsp;Nianduan Lu","doi":"10.1016/j.orgel.2025.107222","DOIUrl":"10.1016/j.orgel.2025.107222","url":null,"abstract":"<div><div>Compact model of threshold voltage plays an important role in circuit design, material screening, and device analysis for organic thin-film transistors (OTFTs). In this work, by using the variable range hopping theory and the concept of transport energy, a novel compact model for the threshold voltage of organic thin film transistor has proposed. Based on the presented model, the varieties of temperature, channel length and drain voltage dependence of threshold voltage can be well described. Good agreement between the model and experimental data is demonstrated.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107222"},"PeriodicalIF":2.7,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143509982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Robust universal bipolar host materials with thermally activated delayed fluorescence for high-performance OLEDs 具有热激活延迟荧光的高性能oled坚固的通用双极宿主材料
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-20 DOI: 10.1016/j.orgel.2025.107223
Ruiqi Sun , Xiaobin Dong , Maoxing Yu , Zeyan Zhuang , Ben Zhong Tang , Zujin Zhao
{"title":"Robust universal bipolar host materials with thermally activated delayed fluorescence for high-performance OLEDs","authors":"Ruiqi Sun ,&nbsp;Xiaobin Dong ,&nbsp;Maoxing Yu ,&nbsp;Zeyan Zhuang ,&nbsp;Ben Zhong Tang ,&nbsp;Zujin Zhao","doi":"10.1016/j.orgel.2025.107223","DOIUrl":"10.1016/j.orgel.2025.107223","url":null,"abstract":"<div><div>Robust host materials play a critical role in improving efficiency and stability for organic light-emitting diodes (OLEDs). To address the challenges of exciton quenching and imbalanced charge transport in traditional unipolar host systems, herein, we design two V-shaped bipolar host materials, <em>v</em>-CzTRZ and <em>v</em>-InCzTRZ, consisting of a carbazole (Cz)/7,7-dimethyl-5,7-dihydroindeno[2,1-<em>b</em>]carbazole (InCz) donor, a triazine (TRZ) acceptor and a <em>o</em>-terphenyl bridge. Their thermal stability, electrochemical properties, electrical structures, optical characteristics, charge transport capabilities, and applicability as host materials are systematically investigated. <em>v</em>-InCzTRZ exhibits pronounced thermally activated delayed fluorescence (TADF) property and superior charge transport ability, rendering it an efficient and versatile host material for a wide range of luminescent materials, including noble metal-containing phosphors, and purely organic classical TADF and multi-resonance (MR) TADF emitters. The OLED using <em>v</em>-InCzTRZ as host for phosphorescent Ir(tptpy)<sub>2</sub>acac exhibits an excellent maximum external quantum efficiency (<em>η</em><sub>ext,max</sub>) of 37.24 % and an ultrahigh luminance of 248500 cd m<sup>−2</sup> with a minimal efficiency roll-off of only 2.8 % at 1000 cd m<sup>−2</sup> luminance. Besides, the OLED utilizing <em>v</em>-InCzTRZ as host for MR-TADF emitter of BN2 achieves an outstanding <em>η</em><sub>ext,max</sub> of 38.78 %, much better than those using common host materials. These results demonstrate the high potential of V-shaped bipolar hosts for high-performance OLEDs.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107223"},"PeriodicalIF":2.7,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143478575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel near-unity 0D organic-inorganic copper-based halide TEA2Cu2Br4 for high-efficiency and stable ultraviolet photodetectors 新型近统一的0D有机-无机铜基卤化物TEA2Cu2Br4用于高效稳定的紫外光电探测器
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-19 DOI: 10.1016/j.orgel.2025.107215
Ruoyao Xu , Xiaoyun Liu , Zhuye Bi , Xinyi Zhu , Peizhou Li , Xiangrong Cao , Yulu Sun , Zhiyuan Xu , Hebing Tang , Jungang Wang , Weilun Cai , Daolei Mo , Yunxuan Wang , Jie Xu , Yingzhuang Ma , Hua Dong , Fang Yuan
{"title":"Novel near-unity 0D organic-inorganic copper-based halide TEA2Cu2Br4 for high-efficiency and stable ultraviolet photodetectors","authors":"Ruoyao Xu ,&nbsp;Xiaoyun Liu ,&nbsp;Zhuye Bi ,&nbsp;Xinyi Zhu ,&nbsp;Peizhou Li ,&nbsp;Xiangrong Cao ,&nbsp;Yulu Sun ,&nbsp;Zhiyuan Xu ,&nbsp;Hebing Tang ,&nbsp;Jungang Wang ,&nbsp;Weilun Cai ,&nbsp;Daolei Mo ,&nbsp;Yunxuan Wang ,&nbsp;Jie Xu ,&nbsp;Yingzhuang Ma ,&nbsp;Hua Dong ,&nbsp;Fang Yuan","doi":"10.1016/j.orgel.2025.107215","DOIUrl":"10.1016/j.orgel.2025.107215","url":null,"abstract":"<div><div>Low-dimensional copper-based halides have attracted significant attention in the development of ultraviolet photodetectors (PDs) owing to their non-toxic nature, wide band gap, strong light absorption, and long carrier diffusion length. However, the performance of these devices has been constrained by the material's intrinsically low photoluminescence quantum yields (PLQYs), uneven grain size, and agglomeration. In this study, we synthesized a novel 0D copper-based halide [N(C<sub>2</sub>H<sub>5</sub>)<sub>4</sub>]<sub>2</sub>Cu<sub>2</sub>Br<sub>4</sub> (TEA<sub>2</sub>Cu<sub>2</sub>Br<sub>4</sub>) using a simple solution-based method and demonstrated high-performance ultraviolet PDs based on this material. TEA<sub>2</sub>Cu<sub>2</sub>Br<sub>4</sub> exhibits a unique dendritic structure with exceptionally long crystals and an outstanding PLQY approaching unity, reflecting a very low trap density and excellent stability. Moreover, the PD device based on TEA<sub>2</sub>Cu<sub>2</sub>Br<sub>4</sub> crystals achieved remarkably impressive responsivity (<em>R</em>) of 5.07 A/W, high detectivity (<em>D</em>∗) of 7.04 × 10<sup>12</sup> Jones, and fast response rates (<em>τ</em><sub>r</sub> of 11.52 ms and <em>τ</em><sub>f</sub> of 11.22 ms), demonstrating superior detection capabilities. Notably, the device maintains 90 % of its photocurrent output after 3000 h of aging without encapsulation, highlighting its exceptional stability. This work indicates TEA<sub>2</sub>Cu<sub>2</sub>Br<sub>4</sub> as an ideal active material for the development of high-performance and stable PDs, offering a promising pathway towards environmentally friendly optoelectronic devices.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107215"},"PeriodicalIF":2.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143474605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Buckled stretchable organic light-emitting diode array with planar light-emitting pixels by strain engineering 基于应变工程的平面发光像素屈曲可拉伸有机发光二极管阵列
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-19 DOI: 10.1016/j.orgel.2025.107216
Shi-Xin Jia, Da Yin, Hao-Yang Zhang, Su-Heng Li, Yue-Feng Liu, Jing Feng
{"title":"Buckled stretchable organic light-emitting diode array with planar light-emitting pixels by strain engineering","authors":"Shi-Xin Jia,&nbsp;Da Yin,&nbsp;Hao-Yang Zhang,&nbsp;Su-Heng Li,&nbsp;Yue-Feng Liu,&nbsp;Jing Feng","doi":"10.1016/j.orgel.2025.107216","DOIUrl":"10.1016/j.orgel.2025.107216","url":null,"abstract":"<div><div>Stretchable organic light-emitting diodes (SOLEDs) based on buckled structures have been widely studied and offer broad application prospects in wearable electronics, deformable displays and electronic skin due to their high brightness and efficiency, large stretchability, and straightforward fabrication process. However, buckles are composed of a large number of wavy microstructures which bring large bending strain and uneven surface to the light-emitting regions. These negative factors increase the risk of device performance degradation, reduce the brightness uniformity, and distort the pixels. The negative effects are amplified by changes of the buckles’ morphology during stretching. In this paper, we solve these issues in buckled SOLEDs by strain engineering. Strain isolation islands are introduced into the flexible substrate to bear the compressive stress from the elastic tape and protect the light-emitting regions from forming buckles. As a result, a buckled SOLED array with planar light-emitting regions have been obtained. It shows a maximum one-dimensional (1D) stretchability of 50 % and a two-dimensional stretchability (2D) of 30 %. The pixels in the SOELD array exhibit efficient, stable and uniform electroluminescent (EL) performance. After 1000 times of cyclic stretching, the current efficiency, shape and area of each pixel in the array barely change, demonstrating the potential of the SOLEDs for stretchable display applications.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107216"},"PeriodicalIF":2.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143478574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Light-emitting electrochemical cells based on mechanochromic, thermally activated delayed fluorescence fish-shaped structures consisting of carbazole derivatives as emitters in the active layer 基于机械致变色、热激活延迟荧光鱼形结构的发光电化学电池,该结构由咔唑衍生物组成,在活性层中作为发射器
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-16 DOI: 10.1016/j.orgel.2025.107214
Marzieh Rabiei , Raheleh Ghahary , Mozhgan Hosseinnezhad , Arvydas Palevicius , Andrius Vilkauskas , Giedrius Janusas , Sohrab Nasiri , Jean Michel Nunzi , Juozas Padgurskas , Raimundas Rukuiza
{"title":"Light-emitting electrochemical cells based on mechanochromic, thermally activated delayed fluorescence fish-shaped structures consisting of carbazole derivatives as emitters in the active layer","authors":"Marzieh Rabiei ,&nbsp;Raheleh Ghahary ,&nbsp;Mozhgan Hosseinnezhad ,&nbsp;Arvydas Palevicius ,&nbsp;Andrius Vilkauskas ,&nbsp;Giedrius Janusas ,&nbsp;Sohrab Nasiri ,&nbsp;Jean Michel Nunzi ,&nbsp;Juozas Padgurskas ,&nbsp;Raimundas Rukuiza","doi":"10.1016/j.orgel.2025.107214","DOIUrl":"10.1016/j.orgel.2025.107214","url":null,"abstract":"<div><div>This study surveys the design and synthesis of fish-shaped structures based on carbazole derivatives for applications in light-emitting electrochemical cells (LEECs). Two thermally activated delayed fluorescent dyes (TADF) 5-(3,6-di-tert-butyl-9H-carbazol-9-yl)-10-((3-methoxy-9H-carbazol-9-yl) phenyl) anthracene (dye 1) and 5-(phenoxazine)-10-((3-methoxy-9H-carbazol-9-yl) phenyl) anthracene (dye 2) were synthesized as emitters in the active layer by coupling reaction technique. Separation of the HOMO-LUMO distributions was observed when the HOMOs localized on the methoxycarbazole and phenoxazine derivatives, respectively, and the LUMO consistently localized on the anthracene derivative. The dye consisting of a tert-butyl carbazole derivative showed a lower the variation of singlet-triplet splitting (ΔE<sub>ST</sub>) value of 0.04 eV than the other counterpart, and reverse intersystem crossing (RISC) dominated for both dyes. The crystalline dyes exhibited mechanochromic behavior when the photoluminescence (PL) spectrum of the mechanically stimulated dyes was red-shifted. The space charge limited current (SCLC) technique proved that the dye consisting of a phenoxazine derivative had a higher carrier mobility of 6.14 × 10<sup>−4</sup> for holes and 2.12 × 10<sup>−4</sup> cm<sup>2</sup> V<sup>−1</sup> s<sup>−1</sup> for electrons in tandem. Based on the mechanochromic behavior of the dyes initially, the fabricated LEECs also exhibited mechanochromic feature, and the EL spectra of the flexible devices showed a red shift in the emission spectra after stretching. In addition, the external quantum efficiency (EQE) of both flexible devices increased to 0.33 % after stretching. Furthermore, iridium complex [Ir(buoppy)<sub>2</sub>(dmapzpy)]PF<sub>6</sub> is used as a promising host for the development of high-performance LEECs. Therefore, brightness and EQE values were increased to 6629 cd m<sup>−2</sup> and 7.13 %, respectively.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"141 ","pages":"Article 107214"},"PeriodicalIF":2.7,"publicationDate":"2025-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143526580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and application of dithieno[3,2-b:2′,3′-d]thiophene conjugated copolymer for organic field effect transistors and nitrogen dioxide sensors 有机场效应晶体管和二氧化氮传感器用二噻吩[3,2-b:2 ',3 ' -d]共轭共聚物的合成与应用
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-14 DOI: 10.1016/j.orgel.2025.107213
Zichun Cong , Lian Chen , Ziqiang Hu , Linyan Jia , Qingfang Ma , Qinghua Pan , Chaowei Hao , Jianhua Gao
{"title":"Synthesis and application of dithieno[3,2-b:2′,3′-d]thiophene conjugated copolymer for organic field effect transistors and nitrogen dioxide sensors","authors":"Zichun Cong ,&nbsp;Lian Chen ,&nbsp;Ziqiang Hu ,&nbsp;Linyan Jia ,&nbsp;Qingfang Ma ,&nbsp;Qinghua Pan ,&nbsp;Chaowei Hao ,&nbsp;Jianhua Gao","doi":"10.1016/j.orgel.2025.107213","DOIUrl":"10.1016/j.orgel.2025.107213","url":null,"abstract":"<div><div>In order to achieve high-performance gas sensors based on polymer field-effect transistors (FETs) for detecting super-low concentrations of NO<sub>2</sub> gas, a novel copolymer poly(2,6-bis(3-dodecylthio-2-thienyl)-dithieno[3,2-b:2′,3′-d]thiophene) (PDTT-TTSC12) was synthesized through direct arylation polycondensation by using the palladium-catalyzed C–H activation with the unsubstituted dithieno[3,2-b:2′,3′-d]thiophene and dibrominated 4,4-bis(dodecylmercapto)- 2,2-bidithiophene as polymerization precursors. The polymer PDTT-TTSC12 was used to construct OFETs by solution method and exhibits p-type characteristics with the hole mobility of 6.4 × 10<sup>−3</sup> cm <sup>2</sup>V<sup>−1</sup>s<sup>−1</sup>. The polymer-based OFETs were further used to detect the NO<sub>2</sub>, and the sensors show strong sensing response and excellent selectivity for NO<sub>2</sub>, with the ratio of current change (ΔI/I<sub>0</sub> (%)) as high as 57 % to 1000 ppb NO<sub>2</sub>. And the ΔI/I<sub>0</sub> (%) can still maintain at 2.54 % and the relative sensitivity (RS) value reaches as high as 254 % ppm<sup>−1</sup> when the gas concentration drops to 10 ppb, which demonstrates that the limit of detection for NO<sub>2</sub> can be improved to ppb level by low-cost polymer-based OFETs.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107213"},"PeriodicalIF":2.7,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143437718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of thermal effects on natural organic honey memristive thin film for resistive switching memory applications 用于电阻开关存储器的天然有机蜂蜜记忆薄膜的热效应评价
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-13 DOI: 10.1016/j.orgel.2025.107210
Ying Zhi Seah , Zoe Templin , Zhigang Xiao , Li Jiang , Kuan Yew Cheong , Feng Zhao
{"title":"Evaluation of thermal effects on natural organic honey memristive thin film for resistive switching memory applications","authors":"Ying Zhi Seah ,&nbsp;Zoe Templin ,&nbsp;Zhigang Xiao ,&nbsp;Li Jiang ,&nbsp;Kuan Yew Cheong ,&nbsp;Feng Zhao","doi":"10.1016/j.orgel.2025.107210","DOIUrl":"10.1016/j.orgel.2025.107210","url":null,"abstract":"<div><div>Natural organic honey as a potential memristive material for resistive switching random access memory (ReRAM) was investigated by evaluating the thermal effects on physical and chemical properties, surface morphology and roughness, and memory and synaptic behaviors of the dried honey film. Surface tension and surface adhesion of honey solutions which are critical for forming the uniform dried film were characterized by Goniometer on different honey concentrations from 0 % to 50 % by weight. Fourier transform infrared spectroscopy, differential scanning calorimetry, optical microscope, atomic force microscopy, and scanning electron microscope were applied to characterize honey films formed after drying the honey solutions at different baking temperatures and durations. Ag/honey/ITO ReRAM devices were fabricated from the dried honey films, and their memory and synaptic behaviors including resistive switching cycle, endurance, retention, and neural facilitation were compared. This study established a useful practice in optimizing the processing particularly critical drying conditions to form honey memristive films for sustainable resistive switching memory devices.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107210"},"PeriodicalIF":2.7,"publicationDate":"2025-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143437719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The impact of structural modifications in donor-acceptor systems on homojunction organic solar cell photovoltaic properties 供体-受体系统中的结构修饰对同质结有机太阳能电池光电特性的影响
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-12 DOI: 10.1016/j.orgel.2025.107212
Daniel-Florin Bogoșel , Gavril-Ionel Giurgi , Alexandru Balan , Alexandra Pop , Ion Grosu , Andreea Petronela Crișan , Anamaria Terec
{"title":"The impact of structural modifications in donor-acceptor systems on homojunction organic solar cell photovoltaic properties","authors":"Daniel-Florin Bogoșel ,&nbsp;Gavril-Ionel Giurgi ,&nbsp;Alexandru Balan ,&nbsp;Alexandra Pop ,&nbsp;Ion Grosu ,&nbsp;Andreea Petronela Crișan ,&nbsp;Anamaria Terec","doi":"10.1016/j.orgel.2025.107212","DOIUrl":"10.1016/j.orgel.2025.107212","url":null,"abstract":"<div><div>This study presents the synthesis and characterization of novel donor-π-acceptor (D-π-A) molecules specifically designed for inverted homojunction single-material organic solar cells (HOSCs). It explores how modifications in triarylamine-based donor groups and π-bridges impact the molecular organization, optical, electrochemical, and photovoltaic characteristics of these molecules. By systematically modifying features like π-bridge length and donor unit strength, the research aims to improve power conversion efficiency (<em>PCE</em>) and overall device performance. While the <em>PCE</em> values are relatively modest, the findings highlight design strategies that balance simplicity, robustness, and cost-effectiveness, offering valuable insights for advancing HOSCs in organic photovoltaic applications.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"141 ","pages":"Article 107212"},"PeriodicalIF":2.7,"publicationDate":"2025-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143526581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Navigating the relationship between voltage losses and efficiency in organic solar cells 有机太阳能电池中电压损失与效率之间的关系
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-12 DOI: 10.1016/j.orgel.2025.107211
Rokas Jasiunas , Vidmantas Jašinskas , Jianwei Yu , Nakul Jain , Xuehong Zhou , Jun Yuan , Rui Zhang , Huotian Zhang , Bei Yang , Andrius Gelzinis , Yingping Zou , Vidmantas Gulbinas , Feng Gao
{"title":"Navigating the relationship between voltage losses and efficiency in organic solar cells","authors":"Rokas Jasiunas ,&nbsp;Vidmantas Jašinskas ,&nbsp;Jianwei Yu ,&nbsp;Nakul Jain ,&nbsp;Xuehong Zhou ,&nbsp;Jun Yuan ,&nbsp;Rui Zhang ,&nbsp;Huotian Zhang ,&nbsp;Bei Yang ,&nbsp;Andrius Gelzinis ,&nbsp;Yingping Zou ,&nbsp;Vidmantas Gulbinas ,&nbsp;Feng Gao","doi":"10.1016/j.orgel.2025.107211","DOIUrl":"10.1016/j.orgel.2025.107211","url":null,"abstract":"<div><div>In recent years, organic solar cells (OSCs) have made significant progress, with power conversion efficiencies over 20 %, mainly due to advances in non-fullerene acceptors. Nevertheless, high voltage losses— especially those caused by non-radiative recombination — remain a major obstacle to further efficiency improvements. In contrast to traditional fullerene-based OSCs, state-of-the-art non-fullerene OSCs enable efficient charge generation and extraction even at small energy offsets (&lt;0.3 eV) between the HOMO levels of the donor and the acceptor materials (ΔHOMO). However, achieving low voltage loss while maintaining high fill factor and short-circuit current (Jsc) is a major challenge due to inherent trade-offs. In this study, we systematically investigate the relationship between voltage losses and the other two parameters in nine non-fullerene OSC devices with ΔHOMO in the range of about 0–0.5 eV. Both radiative and non-radiative voltage losses show a clear increase with ΔHOMO. However, no general correlation was found between the voltage loss, Jsc and FF. Only poorly performing IDTBR-based devices show clear increase of <em>J</em>sc with ΔHOMO, which, according to the transient absorption data, is caused by inefficient charge generation at low ΔHOMO attributable to high exciton binding energy or inferior molecule packing. At the same time, the opposite trend is observed for well-performing blends. These features suggest that variations of other blend parameters rather ΔHOMO cause variations of Jsc and FF overwhelming dependence on ΔHOMO.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107211"},"PeriodicalIF":2.7,"publicationDate":"2025-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143428890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of various parameters on sorting semiconducting carbon nanotubes using polyfluorene for high-performance field-effect transistors 用聚芴分选半导体碳纳米管制备高性能场效应晶体管
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-07 DOI: 10.1016/j.orgel.2025.107209
Changwoo Yu , Dongseong Yang , Kwang-Mo Kang , Dong-Yu Kim , Yoon-Chae Nah , Seung-Hoon Lee
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