Organic Electronics最新文献

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High-CRI warm white OLEDs based on TADF-Doped Exciplex Co-host Structure enabled by efficient reverse intersystem crossing 基于tadf掺杂激复共主结构的高显色温白光oled的高效反向系统间交叉
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-03-01 DOI: 10.1016/j.orgel.2025.107229
Zeyu Jia, Xiangqiong Xie, Zhenyong Guo, Zhiqi Kou
{"title":"High-CRI warm white OLEDs based on TADF-Doped Exciplex Co-host Structure enabled by efficient reverse intersystem crossing","authors":"Zeyu Jia,&nbsp;Xiangqiong Xie,&nbsp;Zhenyong Guo,&nbsp;Zhiqi Kou","doi":"10.1016/j.orgel.2025.107229","DOIUrl":"10.1016/j.orgel.2025.107229","url":null,"abstract":"<div><div>In this work, we present a high-performance warm white organic light-emitting diode (WOLED) achieving a maximum color rendering index (CRI) of 95, based on a novel TADF-Doped Exciplex Co-host Structure. The device design integrates a blue exciplex (mCP:PO-T2T) as the host material, sensitizing ultrathin phosphorescent layers emitting green, yellow, and red light. By systematically varying the thickness of spacer and ultrathin layers, the position of the exciton recombination zone was finely tuned, revealing its critical role in exciton transport dynamics and energy transfer efficiency. To optimize exciton transport pathways, the TADF material 4CzTPN was strategically incorporated into the spacer layers. This incorporation significantly altered the exciton transfer mechanism by facilitating efficient reverse intersystem crossing (RISC) and promoting Förster energy transfer from the exciplex to phosphorescent emitters. Consequently, this approach not only reduces triplet exciton density, mitigating Dexter transfer losses, but also enhances exciton utilization efficiency. As a result, the WOLED achieves warm white light emission with a high CRI closely aligned with the Planckian locus on the CIE chromaticity diagram. These findings demonstrate the transformative potential of the TADF-Doped Exciplex Co-host Structure for developing efficient and color-stable WOLEDs, paving the way for next-generation lighting and display technologies.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"141 ","pages":"Article 107229"},"PeriodicalIF":2.7,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143578807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A rapid UV/Vis assisted designing of benzodithiophene based polymers by machine learning to predict their light absorption for photovoltaics 基于机器学习的苯二噻吩基聚合物的快速紫外/可见辅助设计,以预测其对光伏的光吸收
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-22 DOI: 10.1016/j.orgel.2025.107227
Abrar U. Hassan , Cihat Güleryüz , Sajjad H. Sumrra , Sadaf Noreen , Mohamed H.H. Mahmoud
{"title":"A rapid UV/Vis assisted designing of benzodithiophene based polymers by machine learning to predict their light absorption for photovoltaics","authors":"Abrar U. Hassan ,&nbsp;Cihat Güleryüz ,&nbsp;Sajjad H. Sumrra ,&nbsp;Sadaf Noreen ,&nbsp;Mohamed H.H. Mahmoud","doi":"10.1016/j.orgel.2025.107227","DOIUrl":"10.1016/j.orgel.2025.107227","url":null,"abstract":"<div><div>As global energy demands escalate, developing high-performance photovoltaic (PV) materials through accelerated design methodologies is imperative. A machine learning (ML) assisted predictive models are used to accelerate the design of benzodithiophene (BDT)-based polymers for their PV applications. The current approach leverages a curated dataset of 191 compounds with experimental UV–Vis spectra, mapped to molecular electronic descriptors via RDKit. Random Forest modeling yields a predictive framework (R<sup>2</sup> = 0.98) for predicting their maximum absorption (<em>λ</em><sub>max</sub>). After it, their 5000 new designs as novel polymers, identifying top performers with Synthetic Accessibility Likelihood Index scores up to 57, ensuring synthesis feasibility have also been designed. Feature importance analysis highlights MaxPartialCharge and Aromatic rings as crucial descriptors. The designed materials exhibit optimal energy gaps (1.35–2.0 eV), paving the way for efficient PV devices. The computed UV–Vis spectra of best predicted polymers are studied with their <em>λ</em><sub>max</sub> range of 487–987 nm showing a significant redshift behavior. The designed polymers presents and good potential towards and they can be good candidates for organic solar cell applications.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"141 ","pages":"Article 107227"},"PeriodicalIF":2.7,"publicationDate":"2025-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143535403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Developed non-fullerene acceptors with modified BTPT-OD donor core: A DFT and TD-DFT methods to boost organic solar cell performances 开发具有修饰BTPT-OD供体核心的非富勒烯受体:DFT和TD-DFT方法提高有机太阳能电池的性能
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-21 DOI: 10.1016/j.orgel.2025.107226
Walid Taouali , Amel Azazi , Rym Hassani , Entesar H. EL-Araby , Kamel Alimi
{"title":"Developed non-fullerene acceptors with modified BTPT-OD donor core: A DFT and TD-DFT methods to boost organic solar cell performances","authors":"Walid Taouali ,&nbsp;Amel Azazi ,&nbsp;Rym Hassani ,&nbsp;Entesar H. EL-Araby ,&nbsp;Kamel Alimi","doi":"10.1016/j.orgel.2025.107226","DOIUrl":"10.1016/j.orgel.2025.107226","url":null,"abstract":"<div><div>In this study, density functional theory (DFT) and time-dependent (TD) DFT were employed in order to conduct electronic structure predictions of four novel non-fullerene acceptors (NF2-NF5) generated from the recently synthesized acceptor BTPT-OD (NF1). We provided detailed information about charge transfer and optoelectronic properties of tailored structures, and we compared them to the reference compound. Compared to the energy gap of the reference molecule (2.09 eV), all developed molecules showed a smaller energy gap (2.00–2.08 eV). The created molecules, NF3 and NF4, exhibit high dipole moments of 8.902 D and 6.988 D, respectively, which may enhance the charge transfer rate. Maximum absorption of NF3-NF5 compounds (<em>λ</em><sub>max</sub>, 686.7–694.6 nm) revealed a red shift in absorption as compared to the primary molecule NF1 (<em>λ</em><sub>max</sub> = 676.9 nm). Based on the earlier research (J. Comput. Chem. 2023, 44, 2130–2148), we employed the recently modified Scharber plot to highlight the role of a narrower electronic gap in the proposed non-fullerene acceptors to enhance the power conversion efficiency. Among all tailored molecules, NF3 showed enhanced photovoltaic parameters; it exhibits a short circuit current density of J<sub>sc</sub> = 11.34 mA/cm<sup>2</sup>, an open circuit voltage of V<sub>OC</sub> = 1.09 V, and a power conversion efficiency of PCE = 5.35 %, while reference molecule photovoltaic parameters are J<sub>sc</sub> = 09.43 mA/cm<sup>2</sup>, V<sub>OC</sub> = 1.03 V, and PCE = 4.21 %.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107226"},"PeriodicalIF":2.7,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143488939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Compact model for threshold voltage of organic thin film transistors 有机薄膜晶体管阈值电压的紧凑模型
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-20 DOI: 10.1016/j.orgel.2025.107222
Liang Yin, Jiaye Shen, Nianduan Lu
{"title":"Compact model for threshold voltage of organic thin film transistors","authors":"Liang Yin,&nbsp;Jiaye Shen,&nbsp;Nianduan Lu","doi":"10.1016/j.orgel.2025.107222","DOIUrl":"10.1016/j.orgel.2025.107222","url":null,"abstract":"<div><div>Compact model of threshold voltage plays an important role in circuit design, material screening, and device analysis for organic thin-film transistors (OTFTs). In this work, by using the variable range hopping theory and the concept of transport energy, a novel compact model for the threshold voltage of organic thin film transistor has proposed. Based on the presented model, the varieties of temperature, channel length and drain voltage dependence of threshold voltage can be well described. Good agreement between the model and experimental data is demonstrated.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107222"},"PeriodicalIF":2.7,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143509982","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Robust universal bipolar host materials with thermally activated delayed fluorescence for high-performance OLEDs 具有热激活延迟荧光的高性能oled坚固的通用双极宿主材料
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-20 DOI: 10.1016/j.orgel.2025.107223
Ruiqi Sun , Xiaobin Dong , Maoxing Yu , Zeyan Zhuang , Ben Zhong Tang , Zujin Zhao
{"title":"Robust universal bipolar host materials with thermally activated delayed fluorescence for high-performance OLEDs","authors":"Ruiqi Sun ,&nbsp;Xiaobin Dong ,&nbsp;Maoxing Yu ,&nbsp;Zeyan Zhuang ,&nbsp;Ben Zhong Tang ,&nbsp;Zujin Zhao","doi":"10.1016/j.orgel.2025.107223","DOIUrl":"10.1016/j.orgel.2025.107223","url":null,"abstract":"<div><div>Robust host materials play a critical role in improving efficiency and stability for organic light-emitting diodes (OLEDs). To address the challenges of exciton quenching and imbalanced charge transport in traditional unipolar host systems, herein, we design two V-shaped bipolar host materials, <em>v</em>-CzTRZ and <em>v</em>-InCzTRZ, consisting of a carbazole (Cz)/7,7-dimethyl-5,7-dihydroindeno[2,1-<em>b</em>]carbazole (InCz) donor, a triazine (TRZ) acceptor and a <em>o</em>-terphenyl bridge. Their thermal stability, electrochemical properties, electrical structures, optical characteristics, charge transport capabilities, and applicability as host materials are systematically investigated. <em>v</em>-InCzTRZ exhibits pronounced thermally activated delayed fluorescence (TADF) property and superior charge transport ability, rendering it an efficient and versatile host material for a wide range of luminescent materials, including noble metal-containing phosphors, and purely organic classical TADF and multi-resonance (MR) TADF emitters. The OLED using <em>v</em>-InCzTRZ as host for phosphorescent Ir(tptpy)<sub>2</sub>acac exhibits an excellent maximum external quantum efficiency (<em>η</em><sub>ext,max</sub>) of 37.24 % and an ultrahigh luminance of 248500 cd m<sup>−2</sup> with a minimal efficiency roll-off of only 2.8 % at 1000 cd m<sup>−2</sup> luminance. Besides, the OLED utilizing <em>v</em>-InCzTRZ as host for MR-TADF emitter of BN2 achieves an outstanding <em>η</em><sub>ext,max</sub> of 38.78 %, much better than those using common host materials. These results demonstrate the high potential of V-shaped bipolar hosts for high-performance OLEDs.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107223"},"PeriodicalIF":2.7,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143478575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel near-unity 0D organic-inorganic copper-based halide TEA2Cu2Br4 for high-efficiency and stable ultraviolet photodetectors 新型近统一的0D有机-无机铜基卤化物TEA2Cu2Br4用于高效稳定的紫外光电探测器
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-19 DOI: 10.1016/j.orgel.2025.107215
Ruoyao Xu , Xiaoyun Liu , Zhuye Bi , Xinyi Zhu , Peizhou Li , Xiangrong Cao , Yulu Sun , Zhiyuan Xu , Hebing Tang , Jungang Wang , Weilun Cai , Daolei Mo , Yunxuan Wang , Jie Xu , Yingzhuang Ma , Hua Dong , Fang Yuan
{"title":"Novel near-unity 0D organic-inorganic copper-based halide TEA2Cu2Br4 for high-efficiency and stable ultraviolet photodetectors","authors":"Ruoyao Xu ,&nbsp;Xiaoyun Liu ,&nbsp;Zhuye Bi ,&nbsp;Xinyi Zhu ,&nbsp;Peizhou Li ,&nbsp;Xiangrong Cao ,&nbsp;Yulu Sun ,&nbsp;Zhiyuan Xu ,&nbsp;Hebing Tang ,&nbsp;Jungang Wang ,&nbsp;Weilun Cai ,&nbsp;Daolei Mo ,&nbsp;Yunxuan Wang ,&nbsp;Jie Xu ,&nbsp;Yingzhuang Ma ,&nbsp;Hua Dong ,&nbsp;Fang Yuan","doi":"10.1016/j.orgel.2025.107215","DOIUrl":"10.1016/j.orgel.2025.107215","url":null,"abstract":"<div><div>Low-dimensional copper-based halides have attracted significant attention in the development of ultraviolet photodetectors (PDs) owing to their non-toxic nature, wide band gap, strong light absorption, and long carrier diffusion length. However, the performance of these devices has been constrained by the material's intrinsically low photoluminescence quantum yields (PLQYs), uneven grain size, and agglomeration. In this study, we synthesized a novel 0D copper-based halide [N(C<sub>2</sub>H<sub>5</sub>)<sub>4</sub>]<sub>2</sub>Cu<sub>2</sub>Br<sub>4</sub> (TEA<sub>2</sub>Cu<sub>2</sub>Br<sub>4</sub>) using a simple solution-based method and demonstrated high-performance ultraviolet PDs based on this material. TEA<sub>2</sub>Cu<sub>2</sub>Br<sub>4</sub> exhibits a unique dendritic structure with exceptionally long crystals and an outstanding PLQY approaching unity, reflecting a very low trap density and excellent stability. Moreover, the PD device based on TEA<sub>2</sub>Cu<sub>2</sub>Br<sub>4</sub> crystals achieved remarkably impressive responsivity (<em>R</em>) of 5.07 A/W, high detectivity (<em>D</em>∗) of 7.04 × 10<sup>12</sup> Jones, and fast response rates (<em>τ</em><sub>r</sub> of 11.52 ms and <em>τ</em><sub>f</sub> of 11.22 ms), demonstrating superior detection capabilities. Notably, the device maintains 90 % of its photocurrent output after 3000 h of aging without encapsulation, highlighting its exceptional stability. This work indicates TEA<sub>2</sub>Cu<sub>2</sub>Br<sub>4</sub> as an ideal active material for the development of high-performance and stable PDs, offering a promising pathway towards environmentally friendly optoelectronic devices.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107215"},"PeriodicalIF":2.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143474605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Buckled stretchable organic light-emitting diode array with planar light-emitting pixels by strain engineering 基于应变工程的平面发光像素屈曲可拉伸有机发光二极管阵列
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-19 DOI: 10.1016/j.orgel.2025.107216
Shi-Xin Jia, Da Yin, Hao-Yang Zhang, Su-Heng Li, Yue-Feng Liu, Jing Feng
{"title":"Buckled stretchable organic light-emitting diode array with planar light-emitting pixels by strain engineering","authors":"Shi-Xin Jia,&nbsp;Da Yin,&nbsp;Hao-Yang Zhang,&nbsp;Su-Heng Li,&nbsp;Yue-Feng Liu,&nbsp;Jing Feng","doi":"10.1016/j.orgel.2025.107216","DOIUrl":"10.1016/j.orgel.2025.107216","url":null,"abstract":"<div><div>Stretchable organic light-emitting diodes (SOLEDs) based on buckled structures have been widely studied and offer broad application prospects in wearable electronics, deformable displays and electronic skin due to their high brightness and efficiency, large stretchability, and straightforward fabrication process. However, buckles are composed of a large number of wavy microstructures which bring large bending strain and uneven surface to the light-emitting regions. These negative factors increase the risk of device performance degradation, reduce the brightness uniformity, and distort the pixels. The negative effects are amplified by changes of the buckles’ morphology during stretching. In this paper, we solve these issues in buckled SOLEDs by strain engineering. Strain isolation islands are introduced into the flexible substrate to bear the compressive stress from the elastic tape and protect the light-emitting regions from forming buckles. As a result, a buckled SOLED array with planar light-emitting regions have been obtained. It shows a maximum one-dimensional (1D) stretchability of 50 % and a two-dimensional stretchability (2D) of 30 %. The pixels in the SOELD array exhibit efficient, stable and uniform electroluminescent (EL) performance. After 1000 times of cyclic stretching, the current efficiency, shape and area of each pixel in the array barely change, demonstrating the potential of the SOLEDs for stretchable display applications.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107216"},"PeriodicalIF":2.7,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143478574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Light-emitting electrochemical cells based on mechanochromic, thermally activated delayed fluorescence fish-shaped structures consisting of carbazole derivatives as emitters in the active layer 基于机械致变色、热激活延迟荧光鱼形结构的发光电化学电池,该结构由咔唑衍生物组成,在活性层中作为发射器
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-16 DOI: 10.1016/j.orgel.2025.107214
Marzieh Rabiei , Raheleh Ghahary , Mozhgan Hosseinnezhad , Arvydas Palevicius , Andrius Vilkauskas , Giedrius Janusas , Sohrab Nasiri , Jean Michel Nunzi , Juozas Padgurskas , Raimundas Rukuiza
{"title":"Light-emitting electrochemical cells based on mechanochromic, thermally activated delayed fluorescence fish-shaped structures consisting of carbazole derivatives as emitters in the active layer","authors":"Marzieh Rabiei ,&nbsp;Raheleh Ghahary ,&nbsp;Mozhgan Hosseinnezhad ,&nbsp;Arvydas Palevicius ,&nbsp;Andrius Vilkauskas ,&nbsp;Giedrius Janusas ,&nbsp;Sohrab Nasiri ,&nbsp;Jean Michel Nunzi ,&nbsp;Juozas Padgurskas ,&nbsp;Raimundas Rukuiza","doi":"10.1016/j.orgel.2025.107214","DOIUrl":"10.1016/j.orgel.2025.107214","url":null,"abstract":"<div><div>This study surveys the design and synthesis of fish-shaped structures based on carbazole derivatives for applications in light-emitting electrochemical cells (LEECs). Two thermally activated delayed fluorescent dyes (TADF) 5-(3,6-di-tert-butyl-9H-carbazol-9-yl)-10-((3-methoxy-9H-carbazol-9-yl) phenyl) anthracene (dye 1) and 5-(phenoxazine)-10-((3-methoxy-9H-carbazol-9-yl) phenyl) anthracene (dye 2) were synthesized as emitters in the active layer by coupling reaction technique. Separation of the HOMO-LUMO distributions was observed when the HOMOs localized on the methoxycarbazole and phenoxazine derivatives, respectively, and the LUMO consistently localized on the anthracene derivative. The dye consisting of a tert-butyl carbazole derivative showed a lower the variation of singlet-triplet splitting (ΔE<sub>ST</sub>) value of 0.04 eV than the other counterpart, and reverse intersystem crossing (RISC) dominated for both dyes. The crystalline dyes exhibited mechanochromic behavior when the photoluminescence (PL) spectrum of the mechanically stimulated dyes was red-shifted. The space charge limited current (SCLC) technique proved that the dye consisting of a phenoxazine derivative had a higher carrier mobility of 6.14 × 10<sup>−4</sup> for holes and 2.12 × 10<sup>−4</sup> cm<sup>2</sup> V<sup>−1</sup> s<sup>−1</sup> for electrons in tandem. Based on the mechanochromic behavior of the dyes initially, the fabricated LEECs also exhibited mechanochromic feature, and the EL spectra of the flexible devices showed a red shift in the emission spectra after stretching. In addition, the external quantum efficiency (EQE) of both flexible devices increased to 0.33 % after stretching. Furthermore, iridium complex [Ir(buoppy)<sub>2</sub>(dmapzpy)]PF<sub>6</sub> is used as a promising host for the development of high-performance LEECs. Therefore, brightness and EQE values were increased to 6629 cd m<sup>−2</sup> and 7.13 %, respectively.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"141 ","pages":"Article 107214"},"PeriodicalIF":2.7,"publicationDate":"2025-02-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143526580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and application of dithieno[3,2-b:2′,3′-d]thiophene conjugated copolymer for organic field effect transistors and nitrogen dioxide sensors 有机场效应晶体管和二氧化氮传感器用二噻吩[3,2-b:2 ',3 ' -d]共轭共聚物的合成与应用
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-14 DOI: 10.1016/j.orgel.2025.107213
Zichun Cong , Lian Chen , Ziqiang Hu , Linyan Jia , Qingfang Ma , Qinghua Pan , Chaowei Hao , Jianhua Gao
{"title":"Synthesis and application of dithieno[3,2-b:2′,3′-d]thiophene conjugated copolymer for organic field effect transistors and nitrogen dioxide sensors","authors":"Zichun Cong ,&nbsp;Lian Chen ,&nbsp;Ziqiang Hu ,&nbsp;Linyan Jia ,&nbsp;Qingfang Ma ,&nbsp;Qinghua Pan ,&nbsp;Chaowei Hao ,&nbsp;Jianhua Gao","doi":"10.1016/j.orgel.2025.107213","DOIUrl":"10.1016/j.orgel.2025.107213","url":null,"abstract":"<div><div>In order to achieve high-performance gas sensors based on polymer field-effect transistors (FETs) for detecting super-low concentrations of NO<sub>2</sub> gas, a novel copolymer poly(2,6-bis(3-dodecylthio-2-thienyl)-dithieno[3,2-b:2′,3′-d]thiophene) (PDTT-TTSC12) was synthesized through direct arylation polycondensation by using the palladium-catalyzed C–H activation with the unsubstituted dithieno[3,2-b:2′,3′-d]thiophene and dibrominated 4,4-bis(dodecylmercapto)- 2,2-bidithiophene as polymerization precursors. The polymer PDTT-TTSC12 was used to construct OFETs by solution method and exhibits p-type characteristics with the hole mobility of 6.4 × 10<sup>−3</sup> cm <sup>2</sup>V<sup>−1</sup>s<sup>−1</sup>. The polymer-based OFETs were further used to detect the NO<sub>2</sub>, and the sensors show strong sensing response and excellent selectivity for NO<sub>2</sub>, with the ratio of current change (ΔI/I<sub>0</sub> (%)) as high as 57 % to 1000 ppb NO<sub>2</sub>. And the ΔI/I<sub>0</sub> (%) can still maintain at 2.54 % and the relative sensitivity (RS) value reaches as high as 254 % ppm<sup>−1</sup> when the gas concentration drops to 10 ppb, which demonstrates that the limit of detection for NO<sub>2</sub> can be improved to ppb level by low-cost polymer-based OFETs.</div></div>","PeriodicalId":399,"journal":{"name":"Organic Electronics","volume":"140 ","pages":"Article 107213"},"PeriodicalIF":2.7,"publicationDate":"2025-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143437718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of thermal effects on natural organic honey memristive thin film for resistive switching memory applications 用于电阻开关存储器的天然有机蜂蜜记忆薄膜的热效应评价
IF 2.7 4区 工程技术
Organic Electronics Pub Date : 2025-02-13 DOI: 10.1016/j.orgel.2025.107210
Ying Zhi Seah , Zoe Templin , Zhigang Xiao , Li Jiang , Kuan Yew Cheong , Feng Zhao
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