Matter最新文献_第7页

Perturbing dynamics of active emulsions and their collectives 活性乳剂及其集体的扰动动力学

IF 18.9 1区材料科学

Matter Pub Date : 2025-09-11 DOI: 10.1016/j.matt.2025.102419

Muhammad Turab Ali Khan, Gaurav Gardi, Ren Hao Soon, Mingchao Zhang, Metin Sitti

引用次数: 0

Transformable and stimuli-responsive liquid metal for integrated, sustainable, and biomimetic DNA-based data storage 转化和刺激响应液态金属集成，可持续的，仿生dna为基础的数据存储

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102145

Yakun Gao , Biao Ma , Gangsheng Chen , Chengtao Xu , Ziyan Kong , Yanjie Chen , Chao Zhao , Duxin Chen , Wenwu Yu , Hong Liu

{"title":"Transformable and stimuli-responsive liquid metal for integrated, sustainable, and biomimetic DNA-based data storage","authors":"Yakun Gao , Biao Ma , Gangsheng Chen , Chengtao Xu , Ziyan Kong , Yanjie Chen , Chao Zhao , Duxin Chen , Wenwu Yu , Hong Liu","doi":"10.1016/j.matt.2025.102145","DOIUrl":"10.1016/j.matt.2025.102145","url":null,"abstract":"<div><div>DNA data storage has emerged as a promising solution to address the challenges of data explosion due to its high storage density and durability. However, traditional storage architectures require substrate replacement and the use of environmentally unfriendly chemicals for multistep operations, hindering seamless and sustainable storage. Here, we report liquid metal<span><span> (LM)-DNA, an integrated and sustainable DNA storage architecture that leverages a responsive liquid metal as a functionality-adaptive storage medium. LM-DNA allows cascaded storage operations within a single medium, including enzymatic DNA synthesis, hermetic encapsulation through thermal activation, and </span>electrokinetic<span><span> decapsulation driven by the electrocapillary effect. The green enzymatic DNA data writing and physical data encapsulation/decapsulation avoid toxic chemicals, ensuring a more sustainable route for DNA storage. Furthermore, the fluidity of liquid metal enables </span>biomimetic<span> operations such as file splitting, merging, and reshaping, offering unprecedented flexibility in information management. LM-DNA provides a promising foundation for advancing sustainable and biomimetic information storage technologies.</span></span></span></div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102145"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143933557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The staggered-layer induced elasticity strengthening mechanism in flexible Bi2Te3 柔性Bi2Te3中错开层诱导的弹性强化机制

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102166

Xiege Huang , Luoqi Wu , Mingyuan Hu , Xiaobin Feng , Pengcheng Zhai , Wenjuan Li , Bo Duan , Jiaqing He , Guodong Li , Qingjie Zhang , William A. Goddard III

{"title":"The staggered-layer induced elasticity strengthening mechanism in flexible Bi2Te3","authors":"Xiege Huang , Luoqi Wu , Mingyuan Hu , Xiaobin Feng , Pengcheng Zhai , Wenjuan Li , Bo Duan , Jiaqing He , Guodong Li , Qingjie Zhang , William A. Goddard III","doi":"10.1016/j.matt.2025.102166","DOIUrl":"10.1016/j.matt.2025.102166","url":null,"abstract":"<div><div><span><span>Wearable flexible devices require the development of thermoelectric (TE) materials with high strength<span>, excellent elastic bendability, and superior ductility. Here we report a staggered-layer strategy that overcomes the strength-flexibility dilemma. Our findings indicate that the newly formed strong Bi–Bi </span></span>covalent bond<span> between the staggered layer leads to an average 40% increase in the bond energy of the van der Waals Te–Te bond. A large Poisson’s ratio leads to a high maximum linear elastic strain (</span></span><span><math><mrow><msubsup><mi>ε</mi><mi>E</mi><mi>max</mi></msubsup></mrow></math></span><span><span>), enhancing shear strength by 83.3%, which is consistent with a 92.2% increase in micro-pillar </span>compressive strength<span>. The narrow stiffness gap and bond energy gap facilitate the coordinated deformation that maintains sustained linear elasticity during compression. Moreover, the low BFCs of the Te–Te and Te–Bi bonds (0.72 eV/Å</span></span><sup>2</sup> and 3.85 eV/Å<sup>2</sup><span><span>) contribute to the experimentally observed bending flexibility. This staggered-layer-induced elasticity strengthening mechanism offers a promising strategy for the rational design of highly reliable wearable </span>TE devices.</span></div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102166"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144104161","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Stimuli-responsive nanomaterials for targeted drug delivery in inflammatory bowel disease: Advances and emerging directions 用于炎症性肠病靶向药物递送的刺激反应纳米材料：进展和新兴方向

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102249

Wenpeng Huang , Jessica C. Hsu , Jingwei Zhou , Glen S. Kwon , Lei Kang , Chen Hua , Weibo Cai

{"title":"Stimuli-responsive nanomaterials for targeted drug delivery in inflammatory bowel disease: Advances and emerging directions","authors":"Wenpeng Huang , Jessica C. Hsu , Jingwei Zhou , Glen S. Kwon , Lei Kang , Chen Hua , Weibo Cai","doi":"10.1016/j.matt.2025.102249","DOIUrl":"10.1016/j.matt.2025.102249","url":null,"abstract":"<div><div>Inflammatory bowel disease (IBD) is a chronic and increasingly prevalent gastrointestinal disorder that remains difficult to treat due to the limited efficacy of conventional therapies, often compromised by premature drug release and systemic side effects. Stimuli-responsive nanomaterials have emerged as a promising solution, enabling targeted and controlled drug delivery at inflamed sites to enhance therapeutic outcomes and reduce toxicity. This review systematically examines the recent development and application of these smart nanomaterial drug-delivery systems for IBD therapy over the past years. By responding to the unique pathological features of the IBD microenvironment, these systems enable improved drug targeting and site-specific release. Despite significant progress, challenges such as scalable manufacturing, long-term safety, and clinical translation remain. Future research may focus on reducing batch-to-batch variation, conducting comprehensive safety assessments, and integrating personalized medicine approaches to fully harness the potential of stimuli-responsive nanomaterials in IBD treatment.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102249"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144930733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mechanical crease in 2D materials—A platform for large spin splitting and persistent spin helix 二维材料中的机械折痕——大自旋分裂和持续自旋螺旋的平台

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102378

Sunny Gupta , Manoj N. Mattur , Boris I. Yakobson

{"title":"Mechanical crease in 2D materials—A platform for large spin splitting and persistent spin helix","authors":"Sunny Gupta , Manoj N. Mattur , Boris I. Yakobson","doi":"10.1016/j.matt.2025.102378","DOIUrl":"10.1016/j.matt.2025.102378","url":null,"abstract":"<div><div>Spin-based information processing promises energy-efficient next-generation electronics, crucial amid the growing energy demands of artificial intelligence. Materials with large spin-split electronic states with exotic persistent spin helix (PSH) texture are critical for such devices; however, only a few materials in nature meet the strict symmetry requirements for PSH texture, limiting material options. We report the striking phenomenon that mechanical crease, unique to 2D materials, enables spin splitting and PSH texture by inducing flexoelectric polarization and asymmetric hybridization. Using first-principles calculations and analytical models, we demonstrate this effect in various 2D materials and reveal two critical features, curvature-induced band shifts and flexoelectricity-driven spin splitting, which are essential to create PSH texture. Notably, bent 2D MoTe<sub>2</sub> exhibits high spin splitting of ∼0.16 eV and an attractively small spin precession length of ∼1 nm, the best known. This work reveals a fundamental design framework to create elusive PSH states in 2D materials, opening exciting avenues for spin-based electronic devices.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102378"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144933767","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Realizing one-dimensional single-crystalline topological nanomaterials through thermomechanical epitaxy 通过热机械外延实现一维单晶拓扑纳米材料

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102128

Naijia Liu , Yi-Xiang Yang , Cai Lu , Sebastian A. Kube , Arindam Raj , Sungwoo Sohn , Xiaoyu Zhang , Miguel B. Costa , Ze Liu , Jan Schroers

{"title":"Realizing one-dimensional single-crystalline topological nanomaterials through thermomechanical epitaxy","authors":"Naijia Liu , Yi-Xiang Yang , Cai Lu , Sebastian A. Kube , Arindam Raj , Sungwoo Sohn , Xiaoyu Zhang , Miguel B. Costa , Ze Liu , Jan Schroers","doi":"10.1016/j.matt.2025.102128","DOIUrl":"10.1016/j.matt.2025.102128","url":null,"abstract":"<div><div><span><span>Applications and characterizations of topological materials benefit from nanostructures where enhanced surface-to-volume ratios amplify topological states. However, realizing one-dimensional topological </span>nanomaterials has been limited by existing </span>fabrication methods<span><span>. Here, we present thermomechanical epitaxy (TME)—a general technique for fabricating one-dimensional topological nanomaterials. By applying pressure on bulk topological materials against rigid nanocavities, interface diffusion drives epitaxial growth of high-quality, single-crystalline nanowires at wafer scale. As this diffusional mechanism is prevalent across general materials, it enables a versatile approach to realize one-dimensional nanomaterials from a diverse spectrum of topological phases covering topological insulators and topological </span>semimetals<span> and realize one-dimensional nanomaterials that have not been achieved with state-of-the-art technology. Our theoretical framework predicts materials suitable for TME by correlating phase stability with pressure-induced chemical potential. The proposed method expands the accessible space of topological nanomaterials and bolsters the potential for advancements in physical science and next-generation nanodevices.</span></span></div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102128"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144933927","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hierarchically porous carnosine-Zn microspheres 分层多孔肌肽-锌微球

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102108

Yu Chen , Shai Zilberzwige-Tal , Nathan D. Rosenmann , Julia Oktawiec , Ashley K. Nensel , Qing Ma , Sasha Lichtenstein , Ehud Gazit , Nathan C. Gianneschi

{"title":"Hierarchically porous carnosine-Zn microspheres","authors":"Yu Chen , Shai Zilberzwige-Tal , Nathan D. Rosenmann , Julia Oktawiec , Ashley K. Nensel , Qing Ma , Sasha Lichtenstein , Ehud Gazit , Nathan C. Gianneschi","doi":"10.1016/j.matt.2025.102108","DOIUrl":"10.1016/j.matt.2025.102108","url":null,"abstract":"<div><div><span><span><span><span>Hierarchically porous materials have broad applications in biotechnology and medicine, yet current fabrication methods often lack scalability and </span>biocompatibility. Here, we present a peptide-coordination self-assembly approach to prepare hierarchically porous </span>microspheres composed of naturally occurring </span>carnosine<span> dipeptide and coordinated Zn(II) ions. Metal coordination led to microsphere formation featuring interconnected channels with a hierarchically porous structure. Characterization with scanning electron and </span></span>transmission electron microscopy<span><span>, as well as with extended X-ray absorption fine structure, confirmed its nanofibrous architecture and local Zn(II) coordination environment. Liquid cell transmission electron microscopy<span><span><span>, in turn, provided real-time insight into the assembly process, revealing a stepwise process from nanoclusters<span> to nanofibers and ultimately to porous </span></span>microspheres<span>. The carnosine-Zn(II) microspheres<span> exhibit intrinsic blue fluorescence and high porosity, containing both micropores and </span></span></span>mesopores<span><span>, which facilitate efficient mass transport and biomolecule immobilization. We leverage these properties to generate reusable, cell-free synthesis nanoreactors, to enhance </span>DNA transcription and translation and protect against </span></span></span>nuclease degradation.</span></div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102108"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143853252","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Coupled optical and structural properties of two-dimensional metal-halide perovskites across phase transitions 二维金属卤化物钙钛矿跨相变的耦合光学和结构性质

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102146

Perry W. Martin , Rand L. Kingsford , Seth R. Jackson , Garrett W. Collins , Jolene N. Keller , Emily J. Dalley , Connor G. Bischak

{"title":"Coupled optical and structural properties of two-dimensional metal-halide perovskites across phase transitions","authors":"Perry W. Martin , Rand L. Kingsford , Seth R. Jackson , Garrett W. Collins , Jolene N. Keller , Emily J. Dalley , Connor G. Bischak","doi":"10.1016/j.matt.2025.102146","DOIUrl":"10.1016/j.matt.2025.102146","url":null,"abstract":"<div><div>Ruddlesden-Popper (RP) metal-halide hybrid perovskites<span><span><span> have emerged as a promising class of two-dimensional (2D) materials for optoelectronics and thermal energy storage. These materials consist of alternating layers of </span>organic cations<span><span> and inorganic octahedra<span>. The organic cations often undergo order-to-disorder phase transitions near room temperature<span>, leading to subtle changes in the inorganic layer that impact their optoelectronic properties. To elucidate how structural changes influence optoelectronic properties, we interrogate a series of 2D lead bromide and iodide perovskites<span> with different-length alkylammonium cations. We find that the octahedra become either more or less distorted at the phase transition temperature, depending on the identity of the cation and </span></span></span></span>halide<span>, and that octahedral motion occurs either continuously with temperature or abruptly across a phase transition. Our study directly links structural dynamics to reversible changes in the </span></span></span>optical properties<span> of 2D perovskites and realizes the potential for dynamically switchable optoelectronics with hybrid materials.</span></span></div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102146"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143933555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sustainable organic solar cells via renewable biomass and circular recycling 可持续有机太阳能电池通过可再生生物质和循环利用

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102291

Longfei Jia , Maoheng Wu , Min Ru , Yaxiong Li , Sunsun Li , Changlei Xia , Wenchao Zhao

{"title":"Sustainable organic solar cells via renewable biomass and circular recycling","authors":"Longfei Jia , Maoheng Wu , Min Ru , Yaxiong Li , Sunsun Li , Changlei Xia , Wenchao Zhao","doi":"10.1016/j.matt.2025.102291","DOIUrl":"10.1016/j.matt.2025.102291","url":null,"abstract":"<div><div>With the rapid growth in power-conversion efficiency and extended lifetimes of organic solar cells (OSCs), their sustainability has emerged as a critical challenge in the path to commercialization. This review comprehensively explores three key strategies to enhance sustainability, reduce costs, and expedite market entry: eco-friendly manufacturing, renewable raw materials, and component recycling. We discuss the substitution of conventional halogen solvents with biomass-derived alternatives for processing organic semiconductor films, as well as the use of green additives in organic active layers. Additionally, we summarize recent research on renewable raw materials sourced from biological organisms for use as flexible substrates, electrodes, interlayers, and interfacial modifiers. The review also systematically addresses the recovery of valuable materials, such as transparent conductive substrates, metal electrodes, and active layers in OSCs. Finally, we offer perspectives on future material design, optimization, and recycling strategies to achieve OSCs' sustainability.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 9","pages":"Article 102291"},"PeriodicalIF":17.5,"publicationDate":"2025-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144930736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

From Caladan to Arrakis: Significance of environmental and ecological sustainability of materials 从卡拉丹到阿拉基斯：材料的环境和生态可持续性的意义

IF 17.5 1区材料科学

Matter Pub Date : 2025-09-03 DOI: 10.1016/j.matt.2025.102383

Linjun Qin , Guorui Liu

引用次数: 0