IF 17.3 1区材料科学

Matter Pub Date : 2025-03-05 DOI: 10.1016/j.matt.2024.101944

Hong Luo , Zhimin Pan , Tao Yang , Weiwei Chang , Dawei Zhang , Hongxu Cheng , Xiaogang Li , Dierk Raabe

{"title":"A high-entropy alloy for superior resistance to biogenic sulfuric acid corrosion and hydrogen embrittlement","authors":"Hong Luo , Zhimin Pan , Tao Yang , Weiwei Chang , Dawei Zhang , Hongxu Cheng , Xiaogang Li , Dierk Raabe","doi":"10.1016/j.matt.2024.101944","DOIUrl":"10.1016/j.matt.2024.101944","url":null,"abstract":"<div><div>The growing demand for metallic materials resistant to both environmental corrosion and hydrogen embrittlement under municipal wastewater conditions presents a significant challenge. Achieving superior resistance to both simultaneously is difficult due to microbial and acid-induced corrosion in wastewater alongside hydrogen embrittlement caused by the generation of free hydrogen during corrosion. These complex loading scenarios require materials capable of withstanding both forms of degradation. Here, we present a FeCoMnNiCu alloy, designed using the multiprincipal element concept, which forms a protective passive film and exhibits high resistance to both microbial and oxidative acid-induced corrosion. Furthermore, it shows exceptional resistance to hydrogen embrittlement with a hydrogen embrittlement index of approximately 4.01%. This is achievable because the alloy has a very low hydrogen diffusion coefficient and promotes hydrogen-induced twinning through the reduction of stacking fault energy. These properties establish the new alloy as a promising solution for components exposed to corrosive, hydrogen-rich municipal wastewater environments.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 3","pages":"Article 101944"},"PeriodicalIF":17.3,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142939646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

3D printing of alloys with AB reaction at room temperature

IF 17.3 1区材料科学

Matter Pub Date : 2025-03-05 DOI: 10.1016/j.matt.2025.101999

Weicheng Kong , Yuling Lu , Ximin Yuan , Meng Zhu , Qilin Wu , Ke Yao , Tao Fu , Yong He

引用次数: 0

Upcycling biomass to graphene at room temperature

IF 17.3 1区材料科学

Matter Pub Date : 2025-03-05 DOI: 10.1016/j.matt.2025.102011

Yi Yao , Shengtong Niu , Xuesong Li

引用次数: 0

High-performance full-color radiative cooling films: Unlocking potential for broad adoption and commercialization

IF 17.3 1区材料科学

Matter Pub Date : 2025-03-05 DOI: 10.1016/j.matt.2025.101995

Ningning Cao , Yansu Hou , Bin Zhu , Jia Zhu

引用次数: 0

Omni-functional single materials for opto-mechanical soft robotics

IF 17.3 1区材料科学

Matter Pub Date : 2025-03-05 DOI: 10.1016/j.matt.2025.102012

Kyung-Sub Kim , Sung-Woo Kim , Seung-Kyun Kang

引用次数: 0

π-d conjugated coordination mediated catalysis for four-electron-transfer fast-charging aqueous zinc-iodine batteries π-d共轭配位介导催化四电子转移快速充电锌碘水电池

IF 17.3 1区材料科学

Matter Pub Date : 2025-03-05 DOI: 10.1016/j.matt.2024.11.026

Deyang Guan , Zhaohui Deng , Wen Luo , Chaojie Cheng , Feiyue Wang , Hongwei Cai , Ruixi Chen , Pei Wang , Mingyu Wu , Chenjing Han , Zhiyuan Liu , Dongliang Ma , Liqiang Mai

{"title":"π-d conjugated coordination mediated catalysis for four-electron-transfer fast-charging aqueous zinc-iodine batteries","authors":"Deyang Guan , Zhaohui Deng , Wen Luo , Chaojie Cheng , Feiyue Wang , Hongwei Cai , Ruixi Chen , Pei Wang , Mingyu Wu , Chenjing Han , Zhiyuan Liu , Dongliang Ma , Liqiang Mai","doi":"10.1016/j.matt.2024.11.026","DOIUrl":"10.1016/j.matt.2024.11.026","url":null,"abstract":"<div><div>π-d conjugated coordination polymers (CCPs) with unique stacking structures are developed for the nanoconfinement of iodine by chemisorption in an aqueous Zn-I<sub>2</sub> battery. The stacking structure allows for the accumulation of localized electrons on a well-ordered atomic array, which enhances the built-in electric field, thereby optimizing the environment for the evolution of iodine species. The assembled I<sup>−</sup>/I<sup>0</sup> two-electron-transfer Zn-I<sub>2</sub> battery provides a specific capacity of 226.4 mAh g<sup>−1</sup> at 0.4 A g<sup>−1</sup> (an overpotential of 42 mV) and achieves 60,000 cycles at 10 A g<sup>−1</sup>. The assembled I<sup>−</sup>/I<sup>0</sup>/I<sup>+</sup> four-electron-transfer Zn-I<sub>2</sub> battery provides a specific capacity of up to 337.1 mAh g<sup>−1</sup> at 5 A g<sup>−1</sup> with outstanding rate performance (155.6 mAh g<sup>−1</sup> at 50 A g<sup>−1</sup>) and cycle performance (12,000 cycles at 10 A g<sup>−1</sup>). This study employs targeted molecular design and systematic optimization to develop a high-performance aqueous Zn-I<sub>2</sub> battery electrode material enabled with the promising four-electron transfer reaction.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 3","pages":"Article 101932"},"PeriodicalIF":17.3,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142832841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Increased resistance to photooxidation in Dion-Jacobson lead halide perovskites: Implication for perovskite device stability Dion-Jacobson卤化铅钙钛矿的抗光氧化性增强：对钙钛矿器件稳定性的影响

IF 17.3 1区材料科学

Matter Pub Date : 2025-03-05 DOI: 10.1016/j.matt.2024.11.031

Zhilin Ren , Juraj Ovčar , Tik Lun Leung , Yanling He , Yin Li , Dongyang Li , Xinshun Qin , Hongbo Mo , Zhengtian Yuan , Jueming Bing , Martin P. Bucknall , Luca Grisanti , Muhammad Umair Ali , Peng Bai , Tao Zhu , Ali Ashger Syed , Jingyang Lin , Jingbo Wang , Abdul Khaleed , Wenting Sun , Aleksandra B. Djurišić

{"title":"Increased resistance to photooxidation in Dion-Jacobson lead halide perovskites: Implication for perovskite device stability","authors":"Zhilin Ren , Juraj Ovčar , Tik Lun Leung , Yanling He , Yin Li , Dongyang Li , Xinshun Qin , Hongbo Mo , Zhengtian Yuan , Jueming Bing , Martin P. Bucknall , Luca Grisanti , Muhammad Umair Ali , Peng Bai , Tao Zhu , Ali Ashger Syed , Jingyang Lin , Jingbo Wang , Abdul Khaleed , Wenting Sun , Aleksandra B. Djurišić","doi":"10.1016/j.matt.2024.11.031","DOIUrl":"10.1016/j.matt.2024.11.031","url":null,"abstract":"<div><div>2D metal halide perovskites have enabled significant stability improvements in perovskite devices, particularly in resistance to moisture. However, some 2D perovskites are even more susceptible to photooxidation compared to 3D perovskites. This is particularly true for more commonly investigated Ruddlesden-Popper (RP) perovskites, which exhibit increased susceptibility to photoinduced degradation compared to Dion-Jacobson (DJ) perovskites. Comparisons between different RP and DJ perovskites reveal that this phenomenon cannot be explained by commonly proposed differences in superoxide ion generation, interlayer distance, or lattice structural rigidity differences. Instead, the resistance to photooxidation of DJ perovskites can be attributed to a decreased likelihood of double deprotonation events (compared to single deprotonation events in RP perovskites) required for the loss of organic cations and perovskite decomposition. Consequently, DJ perovskites are less susceptible to oxidative degradation (induced both photo- and electrochemically), which leads to improved operational stability of solar cells based on these materials.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 3","pages":"Article 101937"},"PeriodicalIF":17.3,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142858056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Guiding the rational design of biocompatible metal-organic frameworks for drug delivery

IF 17.3 1区材料科学

Matter Pub Date : 2025-03-05 DOI: 10.1016/j.matt.2025.101958

Dhruv Menon , David Fairen-Jimenez

引用次数: 0

Ultratransparent, stretchable, and durable electromagnetic wave absorbers

IF 17.3 1区材料科学

Matter Pub Date : 2025-03-05 DOI: 10.1016/j.matt.2024.101956

Runa Zhang , Bin Yuan , Fei Pan , Hongsheng Liang , Haojie Jiang , Hongtao Guo , Yongchao Rao , Shuhuai Zheng , Lingyang Ruan , Changsheng Wu , Yang Yang , Wei Lu

{"title":"Ultratransparent, stretchable, and durable electromagnetic wave absorbers","authors":"Runa Zhang , Bin Yuan , Fei Pan , Hongsheng Liang , Haojie Jiang , Hongtao Guo , Yongchao Rao , Shuhuai Zheng , Lingyang Ruan , Changsheng Wu , Yang Yang , Wei Lu","doi":"10.1016/j.matt.2024.101956","DOIUrl":"10.1016/j.matt.2024.101956","url":null,"abstract":"<div><div>The growing demand for soft robotics, smart displays, and optoelectronics has driven extensive research into expanding the palette of transparent, stretchable, and durable materials and devices. However, existing electromagnetic wave (EMW) absorbers lack one or more of these key attributes. Herein, we present an EMW absorber that combines ultratransparency (94%), high stretchability (824% fracture strain), and remarkable mechanical and environmental durability. This breakthrough is enabled by a phase-separated terpolymer ionogel. Its effective absorption bandwidth (EAB) of 7.85 GHz in the X and Ku bands significantly outperforms that of all other gel-based materials (<6 GHz) and ranks among the best of all absorbers, whether transparent, stretchable, or neither. This ionogel also demonstrates long-term stability alongside other fascinating properties such as hydrophobicity, skin-like modulus, fatigue and puncture resistance, ability to self-clean, and anti-freezing/icing capabilities. These findings add a key element to the palette, paving the way for next-generation transparent, stretchable devices and ionotronics.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 3","pages":"Article 101956"},"PeriodicalIF":17.3,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143026845","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Open-air spray deposition of PCBM/BCP electron transport layer for inverted perovskite solar cells

IF 17.3 1区材料科学

Matter Pub Date : 2025-03-05 DOI: 10.1016/j.matt.2025.101990

Justin P. Chen , Thomas W. Colburn , Juliet Risner-Jamtgaard , Arturas Vailionis , Andrew Barnum , Margarita Golding , Abigail Carbone , Austin C. Flick , Reinhold H. Dauskardt

{"title":"Open-air spray deposition of PCBM/BCP electron transport layer for inverted perovskite solar cells","authors":"Justin P. Chen , Thomas W. Colburn , Juliet Risner-Jamtgaard , Arturas Vailionis , Andrew Barnum , Margarita Golding , Abigail Carbone , Austin C. Flick , Reinhold H. Dauskardt","doi":"10.1016/j.matt.2025.101990","DOIUrl":"10.1016/j.matt.2025.101990","url":null,"abstract":"<div><div>A [6,6]-phenyl C<sub>61</sub> butyric acid methyl ester (PCBM) and bathocuproine (BCP) electron transport layer (ETL) is spray deposited in open air directly on top of a perovskite at linear speeds of 9 m/min. The PCBM precursor ink contains a binary mixture of 1:1 chlorobenzene:chloroform, which optimizes spray wettability on the perovskite surface and allows quick solvent evaporation. A near-infrared heating module additionally provides a flash cure (<5 s) for the formation of smooth, large-area PCBM films (∼20 cm<sup>2</sup>). A BCP solution in isopropanol is subsequently sprayed to form an ultrathin (<5 nm) film and characterized with a suite of high-resolution metrologies. The spray-deposition processing and near-infrared treatment do not damage the underlying perovskite. Inverted architecture devices containing the sprayed ETL achieve a champion efficiency of 20.3% and demonstrate stable performance without additional interlayers or surface treatments. The technoeconomic cost of the open-air spray process is compared against traditional vacuum-based evaporation, resulting in a decrease in manufacturing costs by 26%.</div></div>","PeriodicalId":388,"journal":{"name":"Matter","volume":"8 3","pages":"Article 101990"},"PeriodicalIF":17.3,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143427248","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

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