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Stalling CO2 evolution at high voltage by a catalytically induced LiF-rich interphase 通过催化诱导富liff间相延缓高压下CO2的演化
IF 21.1 1区 材料科学
Materials Today Pub Date : 2025-03-07 DOI: 10.1016/j.mattod.2025.02.017
Ziwei Liu , Lingfeng Shi , Ke Yue , Hua Huo , Jiyuan Jian , Guangxiang Zhang , Chi Ma , Xu Yang , Chunyu Du , Pengjian Zuo , Geping Yin , Xinyong Tao , Tiefeng Liu , Yulin Ma
{"title":"Stalling CO2 evolution at high voltage by a catalytically induced LiF-rich interphase","authors":"Ziwei Liu ,&nbsp;Lingfeng Shi ,&nbsp;Ke Yue ,&nbsp;Hua Huo ,&nbsp;Jiyuan Jian ,&nbsp;Guangxiang Zhang ,&nbsp;Chi Ma ,&nbsp;Xu Yang ,&nbsp;Chunyu Du ,&nbsp;Pengjian Zuo ,&nbsp;Geping Yin ,&nbsp;Xinyong Tao ,&nbsp;Tiefeng Liu ,&nbsp;Yulin Ma","doi":"10.1016/j.mattod.2025.02.017","DOIUrl":"10.1016/j.mattod.2025.02.017","url":null,"abstract":"<div><div>Charging LiCoO<sub>2</sub> (LCO) to a higher voltage could increase deliverable capacity for higher energy density batteries while the catalytic activity of Cobalt (Co) is also rising, inevitably triggering electrolyte decomposition. Stable and robust cathode electrolyte interphase (CEI) is critical to creating physical isolation between cathode and electrolyte, hopefully relieving the interfacial side reaction including electrolyte decomposition. Here, we propose a catalytically induced strategy in yttrium-based interphase that selectively adsorbs PF<sub>6</sub><sup>-</sup> for the preferential formation of LiF-rich CEI. Meanwhile, for bare LCO, we also reveal the uncontrolled decomposition of ethylene carbonate (EC) at high voltage, resulting in CO<sub>2</sub> release to seriously disorder CEI. Correspondingly, along with constructing a robust LiF-rich CEI and in turn inhibiting CO<sub>2</sub> release, the Y-modified LCO cathode exhibits a reversible capacity of 119 mAh g<sup>−1</sup> at 10 C and capacity retention of 93.12 % after 100 cycles at 1 C, which is much better than 62.30 % for the pristine LCO with serve electrolyte decomposition. This work unequivocally sheds light on the potential of interfacial modification to regulate the CEI chemistries in high-voltage batteries.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 69-81"},"PeriodicalIF":21.1,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833636","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in 3D-printed triboelectric nanogenerators and supercapacitors for self-sustainable energy systems 用于自我可持续能源系统的3d打印摩擦电纳米发电机和超级电容器的进展
IF 21.1 1区 材料科学
Materials Today Pub Date : 2025-03-07 DOI: 10.1016/j.mattod.2025.02.010
Sumin Cho , Muhammad Ramzan Khawar , Yoonsang Ra , Sunmin Jang , Donghan Lee , Dongik Kam , Soban Ali Shah , Donghyeon Yoo , Yasir Javed , Awais Ahmad , Younghoon Lee , Hee Jae Hwang , Chengkuo Lee , Dongwhi Choi
{"title":"Advances in 3D-printed triboelectric nanogenerators and supercapacitors for self-sustainable energy systems","authors":"Sumin Cho ,&nbsp;Muhammad Ramzan Khawar ,&nbsp;Yoonsang Ra ,&nbsp;Sunmin Jang ,&nbsp;Donghan Lee ,&nbsp;Dongik Kam ,&nbsp;Soban Ali Shah ,&nbsp;Donghyeon Yoo ,&nbsp;Yasir Javed ,&nbsp;Awais Ahmad ,&nbsp;Younghoon Lee ,&nbsp;Hee Jae Hwang ,&nbsp;Chengkuo Lee ,&nbsp;Dongwhi Choi","doi":"10.1016/j.mattod.2025.02.010","DOIUrl":"10.1016/j.mattod.2025.02.010","url":null,"abstract":"<div><div>In the current era of intelligent systems, the advancement of self-powered energy systems is crucial. With the ubiquitous development of small-scale stable energy systems, a transformative impact on Internet of Things (IoT) ecosystems has been observed. These systems require self-sustaining power-generation and storage capabilities. Triboelectric Nanogenerators (TENGs) have emerged as a prime solution for harvesting mechanical energy at small scales, particularly low-frequency energy, which is often overlooked because of its adaptability to harsh conditions. Supercapacitors (SCs) have attracted attention as promising energy-storage counterparts for TENGs because of their exceptional charge/discharge efficiencies and output characteristics. The integration of 3D printing (3DP) technology with TENGs and SCs, which leverages benefits, such as rapid prototyping, cost efficiency, and compact design, has been proposed as a revolutionary step in enhancing multifaceted artificial intelligence applications. However, the development of 3DP technologies for advanced TENG and SC systems presents challenges, often with a trade-off between optimal performance and practical application. This review methodically categorizes the advancements in surface modification, mechanical systems, and applications of 3DP-based TENGs, along with the material and electrode design and configuration of 3DP-based SCs. Furthermore, it addresses the challenges faced by each category. Thus, this review explored the challenges and prospects of integrating 3DP-based TENGs and SCs as a novel, self-sustainable energy solution to catalyze the next wave of rapid IoT ecosystem development.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 189-211"},"PeriodicalIF":21.1,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833527","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances and perspectives of hard carbon anode modulated by defect/hetero elemental engineering for sodium ion batteries 钠离子电池用缺陷/异质工程调制硬碳阳极的研究进展与展望
IF 21.1 1区 材料科学
Materials Today Pub Date : 2025-03-06 DOI: 10.1016/j.mattod.2025.02.014
Haihan Zhang , Siyuan Lin , Chengyong Shu , Zexun Tang , Xiaowei Wang , Yuping Wu , Wei Tang
{"title":"Advances and perspectives of hard carbon anode modulated by defect/hetero elemental engineering for sodium ion batteries","authors":"Haihan Zhang ,&nbsp;Siyuan Lin ,&nbsp;Chengyong Shu ,&nbsp;Zexun Tang ,&nbsp;Xiaowei Wang ,&nbsp;Yuping Wu ,&nbsp;Wei Tang","doi":"10.1016/j.mattod.2025.02.014","DOIUrl":"10.1016/j.mattod.2025.02.014","url":null,"abstract":"<div><div>Sodium-ion batteries (SIBs) serve as a promising complement to lithium-ion batteries for large-scale energy storage, leveraging the abundance of sodium resources and notable safety advantages. The key advancement in SIB industrialization hinges on identifying a cost-effective and high-performance anode material, similar to the graphite anode in lithium-ion batteries. Hard carbon emerges as prime anode materials for SIBs, boasting high specific capacity, low sodium storage potential, and wide availability. However, practical applications of hard carbon encounters challenges such as low initial Coulombic efficiency (ICE), inadequate long-term cycling stability, and poor rate performance. Recent research has focused on the optimization of hard carbon electrodes through functional design. In this comprehensive review, we have meticulously examined the progress in enhancing sodium storage performance through microstructural modulation within hard carbon, encompassing four pivotal aspects: heteroatom doping, incorporation of oxygen functional groups, surface coating, and intrinsic defect engineering. Progress in implementing these strategies is scrutinized, while the merits and challenges of each defect engineering approach are discussed. This review also looks into forthcoming opportunities and challenges in the practical application process of hard carbon electrodes in SIBs.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 231-252"},"PeriodicalIF":21.1,"publicationDate":"2025-03-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Local structure modulations of single-atom catalysts in sulfur electrocatalysis: A comprehensive review 硫电催化中单原子催化剂的局部结构调制:综述
IF 21.1 1区 材料科学
Materials Today Pub Date : 2025-03-05 DOI: 10.1016/j.mattod.2025.02.007
Gaoran Li , Jianjun Zhang , Zhenzhen Wu , Hongyang Li , Yingze Song , Shanqing Zhang
{"title":"Local structure modulations of single-atom catalysts in sulfur electrocatalysis: A comprehensive review","authors":"Gaoran Li ,&nbsp;Jianjun Zhang ,&nbsp;Zhenzhen Wu ,&nbsp;Hongyang Li ,&nbsp;Yingze Song ,&nbsp;Shanqing Zhang","doi":"10.1016/j.mattod.2025.02.007","DOIUrl":"10.1016/j.mattod.2025.02.007","url":null,"abstract":"<div><div>Single-atom catalysts (SACs) hold great promise for powering fast and durable sulfur electrochemistry in lithium-sulfur batteries (LSBs). The rational manipulation of SAC local structure is a key strategy for boosting catalytic activity and enhancing battery performance, spurring significant research interest in recent years. This comprehensive review combs through the latest progress of SACs in LSBs, with a particular emphasis on the modulations of their local structure and catalytic behaviors. These advancements are classified into three main categories, i.e., center-substrate matchup, coordination adjustment, and composite synergism, according to the primary design principle and the polysulfide catalytic conversion mechanism. Furthermore, we critically and systematically investigate the remaining challenges in LSBs and suggest strategic solutions in the design, synthesis, and application of SACs. By providing a systematic summary and profound insights into the local structure modulation, this review offers guidance for the development of advanced SACs and practically viable LSBs.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 141-170"},"PeriodicalIF":21.1,"publicationDate":"2025-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual crosslinkable bioink for direct and embedded 3D bioprinting at physiological temperature 用于生理温度下直接和嵌入式3D生物打印的双交联生物链接
IF 21.1 1区 材料科学
Materials Today Pub Date : 2025-03-04 DOI: 10.1016/j.mattod.2025.02.005
Yaxin Wang , Hexin Yue , Andong Liu , Yufei Cui , Yanhao Hou , Xiyao Ni , Rúben F. Pereira , Boyang Huang , Cian Vyas , Paulo Bartolo
{"title":"Dual crosslinkable bioink for direct and embedded 3D bioprinting at physiological temperature","authors":"Yaxin Wang ,&nbsp;Hexin Yue ,&nbsp;Andong Liu ,&nbsp;Yufei Cui ,&nbsp;Yanhao Hou ,&nbsp;Xiyao Ni ,&nbsp;Rúben F. Pereira ,&nbsp;Boyang Huang ,&nbsp;Cian Vyas ,&nbsp;Paulo Bartolo","doi":"10.1016/j.mattod.2025.02.005","DOIUrl":"10.1016/j.mattod.2025.02.005","url":null,"abstract":"<div><div>Bioprinting at physiological temperature (PT) is desirable to maintain cell viability during and after printing, especially for tissue and organ scale constructs requiring a long fabrication time. Typically, bioinks show a temperature viscosity dependence and exhibit poor printability at PT, limiting construct complexity and shape fidelity. Embedded bioprinting offers opportunities to print low viscosity bioinks, however, the consideration of PT is often neglected. In this study, a dual thermoresponsive and photocrosslinkable bioink was developed comprising gelatin methacryloyl (GelMA) and either methylcellulose (MC) or methylcellulose methacrylate (MCMA). This bioink serves as both a direct extrusion bioink and as a support bath for embedded bioprinting. Both MC and gelatin show synergistic thermosensitive rheological properties which was exploited to enable bioprinting at both room temperature and PT to create a semi-interpenetrating or interconnected polymer network with tuneable properties. The bioinks show sol–gel transitions at temperatures of &lt; 27 °C and &gt; 33 °C, representing the contribution from GelMA and MC/MCMA, respectively, and improved thixotropic, and self-healing behaviour at PT. These rheological properties significantly improve printability at a range of temperatures (18–37 °C) and allows the bioink to function as a support bath at PT. Moreover, higher cell viability (&gt;90 %) post-bioprinting was observed in PT bioprinted constructs. The cell response in bioprinted constructs was dependent on bioink composition and cell density, with low polymer concentration and increased cell densities favouring the spreading and proliferation of adipose-derived stem cells. Acting as a support bath, the bioink enabled fabrication at PT of complex cell-laden structures through embedded bioprinting. This allowed spatial patterning of a variety of cell types and perfusable channels with the support bath acting as a matrix to provide long-term support and as a reservoir of cells. The bioinks successfully expand bioprinting capability at PT for both direct and embedded bioprinting and has promising potential to fabricate large-scale tissue models for tissue engineering applications.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 1-16"},"PeriodicalIF":21.1,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833641","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrolyte-free potassium ions intercalated in 2D layered metal oxide for imitating spatiotemporal biological neural dynamics 无电解质钾离子嵌入二维层状金属氧化物模拟时空生物神经动力学
IF 21.1 1区 材料科学
Materials Today Pub Date : 2025-03-04 DOI: 10.1016/j.mattod.2025.02.008
Gichang Noh , Jeongho Kim , Dong Yeon Woo , Min-gyu Kim , Hyeri Yoo , Han Beom Jeong , Yooyeon Jo , Eunpyo Park , Dae Kyu Lee , Min Jee Kim , Min-kyung Jo , In Soo Kim , Talip Serkan Kasirga , Dong Han Ha , Soo Young Kim , Gyu Weon Hwang , Sangtae Kim , Chul-Ho Lee , Heejun Yang , Hu Young Jeong , Joon Young Kwak
{"title":"Electrolyte-free potassium ions intercalated in 2D layered metal oxide for imitating spatiotemporal biological neural dynamics","authors":"Gichang Noh ,&nbsp;Jeongho Kim ,&nbsp;Dong Yeon Woo ,&nbsp;Min-gyu Kim ,&nbsp;Hyeri Yoo ,&nbsp;Han Beom Jeong ,&nbsp;Yooyeon Jo ,&nbsp;Eunpyo Park ,&nbsp;Dae Kyu Lee ,&nbsp;Min Jee Kim ,&nbsp;Min-kyung Jo ,&nbsp;In Soo Kim ,&nbsp;Talip Serkan Kasirga ,&nbsp;Dong Han Ha ,&nbsp;Soo Young Kim ,&nbsp;Gyu Weon Hwang ,&nbsp;Sangtae Kim ,&nbsp;Chul-Ho Lee ,&nbsp;Heejun Yang ,&nbsp;Hu Young Jeong ,&nbsp;Joon Young Kwak","doi":"10.1016/j.mattod.2025.02.008","DOIUrl":"10.1016/j.mattod.2025.02.008","url":null,"abstract":"<div><div>Alkali ions are crucial to physiological neural activities and their dynamics can be implemented in various iontronics. For the host materials for alkali ions, 2D layered materials have become the preferred choice thanks to their facilitating ion accommodation and movement between layers. Nevertheless, challenges such as the need for external electrolytes, pre-fabrication for ion intercalation, and thermodynamic stability during ion movements still persist. Consequently, the comprehensive understanding of the electrical dynamics associated with alkali ion movement has rarely been demonstrated in 2D layered materials so far. Here, we engineered an electrolyte-free high-crystalline 2D layered MnO<sub>2</sub> nanoplate with potassium ions by metal–organic chemical vapor deposition. The combination of potassium ions and layered MnO<sub>2</sub> exhibits electrically induced ion migration coupled with a subsequent phase transition, resulting in negative differential resistance. Furthermore, the material’s distinct hybrid plasticity, driven by its ion dynamics, provides a sophisticated platform for sequential motion recognition, valuable for assessing continuous motion across varied subjects. Finally, we demonstrate the broad applicability of our 2D K-MnO<sub>2</sub> and highlight its versatility in spatiotemporal ion modulation within three-terminal structures, showing potential for future advancements.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 27-38"},"PeriodicalIF":21.1,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
III-V quantum dots: A multidimensional exploration from eco-friendly materials to near infrared optoelectronic applications III-V 量子点:从环保材料到近红外光电应用的多维探索
IF 21.1 1区 材料科学
Materials Today Pub Date : 2025-03-03 DOI: 10.1016/j.mattod.2025.02.009
Ying-Ying Pan , Jia-Lin Pan , Ya-Kun Wang , Liang-Sheng Liao
{"title":"III-V quantum dots: A multidimensional exploration from eco-friendly materials to near infrared optoelectronic applications","authors":"Ying-Ying Pan ,&nbsp;Jia-Lin Pan ,&nbsp;Ya-Kun Wang ,&nbsp;Liang-Sheng Liao","doi":"10.1016/j.mattod.2025.02.009","DOIUrl":"10.1016/j.mattod.2025.02.009","url":null,"abstract":"<div><div>III-V (InP, InAs, InSb) quantum dots (QDs) have emerged as promising alternatives to lead/cadmium-based QDs due to their lower toxicity and tunable optoelectronic properties. Advances in colloidal synthesis have enabled the development of heterostructures, ligand engineering, and surface modifications in III-V QDs, allowing for spectral tunability from blue to near-infrared (NIR), narrow emission linewidths, and high quantum yields. Furthermore, III-V QDs exhibit higher covalency compared to lead/cadmium-based counterparts, enhancing their performance in various applications: the state-of-the-art InP QDs, with appealing optical and electronic properties, have demonstrated excellent in light-emitting diodes (LEDs); InAs QDs provide higher sensitivity and lower phototoxicity for biological imaging and light emission; and InSb QDs are becoming promising candidate for shortwave infrared (SWIR) photodetectors with bandgap tunability extending into the mid-infrared (MIR) range. Considering the growing significance of III-V QDs, it is timely to provide a focused review that summarizes the advancements in their synthesis methods, heterostructures, ligand engineering, surface modifications and shape engineering. Such a review will also explore the diverse applications of III-V QDs and their potential for future development. By highlighting key innovations and addressing current challenges, this review will offer valuable insights into the evolving role of III-V QDs in fields ranging from optoelectronics to biological imaging and infrared technologies.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 171-188"},"PeriodicalIF":21.1,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Emerging reactive oxygen and nitrogen species regulators for biomedical therapy: 2D MXenzymes 新兴的生物医学治疗活性氧和氮调节剂:2D mx酶
IF 21.1 1区 材料科学
Materials Today Pub Date : 2025-03-03 DOI: 10.1016/j.mattod.2025.02.004
Jingjing Si , Haihui Lan , Jessica An , Suxiang Ge , Wanyu Liu , YuMing Zhang , Xiaobo Mao , Weiwei He
{"title":"Emerging reactive oxygen and nitrogen species regulators for biomedical therapy: 2D MXenzymes","authors":"Jingjing Si ,&nbsp;Haihui Lan ,&nbsp;Jessica An ,&nbsp;Suxiang Ge ,&nbsp;Wanyu Liu ,&nbsp;YuMing Zhang ,&nbsp;Xiaobo Mao ,&nbsp;Weiwei He","doi":"10.1016/j.mattod.2025.02.004","DOIUrl":"10.1016/j.mattod.2025.02.004","url":null,"abstract":"<div><div>The burgeoning field of nanozymes has attracted significant attention recently, owing to their remarkable capabilities in modulating reactive oxygen and nitrogen species (RONS), offering promising therapeutic strategies for RONS-related diseases. Among these, two-dimensional MXene-based nanozymes (2D MXenzymes) have emerged as standout candidates due to their exceptional physicochemical properties, including vast specific surface area, hydrophilicity, outstanding electrical and optical characteristics, superior performance in redox reactions, versatile biocatalysis, effective RONS modulation, and inherent biocompatibility and biosafety. Given the ever-growing requirements of reasonably construct efficient and safe nanozymes according to demand, this review will delve into the potential of 2D MXenzymes for biomedical applications by examining three key aspects: their malleable electrical and optical properties, RONS regulatory mechanisms, and intrinsic biocompatibility and safety. We comprehensively summarize and discuss recent advancements in the strategies for enhancing RONS regulatory activity of 2D MXenzymes, particularly through surface modification, hybridization, and valence engineering. Additionally, we highlight the promising applications of these nanozymes in cancer, antibiosis, antioxidant, and anti-inflammatory therapy. Finally, we address the current challenges and future prospects in the field of biomedical therapy, drawing insights from representative studies.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"85 ","pages":"Pages 112-140"},"PeriodicalIF":21.1,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143833649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Emerging colored and transparent radiative cooling: Fundamentals, progress, and challenges 新兴彩色和透明辐射冷却:基础、进展和挑战
IF 21.1 1区 材料科学
Materials Today Pub Date : 2025-03-01 DOI: 10.1016/j.mattod.2024.12.012
Yalu Xin , Chen Li , Wei Gao , Yongping Chen
{"title":"Emerging colored and transparent radiative cooling: Fundamentals, progress, and challenges","authors":"Yalu Xin ,&nbsp;Chen Li ,&nbsp;Wei Gao ,&nbsp;Yongping Chen","doi":"10.1016/j.mattod.2024.12.012","DOIUrl":"10.1016/j.mattod.2024.12.012","url":null,"abstract":"<div><div>The worsening energy crisis and global warming have intensified interest in passive daytime radiative cooling (PDRC) technology. This technology consumes no energy and can directly dissipate heat to outer space. Despite advancements in the cooling mechanism, material design, preparation technologies, and practical applications, the traditional white or silver appearance does not meet aesthetic and functional needs, and potential light pollution limits their development. Recently, colored and transparent PDRC materials have been developed, providing solutions that satisfy aesthetic and functional requirements while delivering impressive cooling performance. This review overviews these emerging materials and strategies for colored and transparent PDRC. First, the cooling mechanism of PDRC is examined from the optics and thermodynamic perspective, and the current experimental methods for radiative cooling performance and the current state of traditional white and silver PDRC are summarized. Next, the design strategies, cooling performance, and application areas of colored and transparent PDRC are discussed in detail, and the problems existing in each type of material design are comprehensively analyzed. Furthermore, the challenges and potential research directions for the next generation of highly efficient PDRC are explored. This review aims to inspire further in-depth research into colored and transparent PDRC technology and promote its application across various fields.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"83 ","pages":"Pages 355-381"},"PeriodicalIF":21.1,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143601338","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Anode-less Li-based metal batteries and beyond: Challenges, strategies, and prospects 无阳极锂基金属电池及其他:挑战、策略和前景
IF 21.1 1区 材料科学
Materials Today Pub Date : 2025-03-01 DOI: 10.1016/j.mattod.2025.01.002
Huan Shi , Fulu Chu , Yamin Zhang, Yang Liu, Linrui Hou, Xuting Li, Changzhou Yuan
{"title":"Anode-less Li-based metal batteries and beyond: Challenges, strategies, and prospects","authors":"Huan Shi ,&nbsp;Fulu Chu ,&nbsp;Yamin Zhang,&nbsp;Yang Liu,&nbsp;Linrui Hou,&nbsp;Xuting Li,&nbsp;Changzhou Yuan","doi":"10.1016/j.mattod.2025.01.002","DOIUrl":"10.1016/j.mattod.2025.01.002","url":null,"abstract":"<div><div>Traditional lithium-ion batteries struggle to meet the escalating energy density demands of electric vehicles, electronic devices and other applications, precipitating a surge in interest towards high-energy–density (HED) batteries. Anode-less lithium metal batteries (AL-LMBs), which obviate excess metal inventory, emerge as an enticing HED solution with reduced production costs and attenuated safety concerns in contrast to conventional metal-based batteries. Nevertheless, the practical realization of AL-LMBs encounters formidable challenges, including low Coulombic efficiency (CE) and the specter of metal dendrite formation. Hence, delving into the electrochemical intricacies and failure mechanisms of AL-LMBs assumes paramount importance, alongside formulating efficacious strategies to actualize HED AL-LMBs. This review endeavors to spotlight recent strides in AL-LMB research, offering comprehensive insights into their practical deployment. It comprehensively synthesizes the evolution of AL-LMBs over the past two decades, delineates persisting hurdles, and scrutinizes recent breakthroughs in AL-LMBs through effective policies and collaborative strategies. Moreover, it explores cutting-edge innovations in Li-beyond (Na, K, Zn, and Al) anode-less metal batteries (AL-MBs), proffering promising avenues to surmount extant impediments. Ultimately, future opportunities and potential trajectories for AL-MBs are evaluated, with the aim of catalyzing deeper exploration in this burgeoning field.</div></div>","PeriodicalId":387,"journal":{"name":"Materials Today","volume":"83 ","pages":"Pages 446-483"},"PeriodicalIF":21.1,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143601216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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