Materials Science and Engineering: A最新文献

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The influence of rolling on the microstructure, mechanical properties, and in vitro degradation of biomedical Zn-2Cu alloy treated by ultrasound 轧制对超声处理医用Zn-2Cu合金显微组织、力学性能及体外降解的影响
IF 7 2区 材料科学
Materials Science and Engineering: A Pub Date : 2026-03-01 Epub Date: 2026-02-13 DOI: 10.1016/j.msea.2026.149920
Weibin Cui , Qinglin Li , Jing Yang , Yirui Zhang , Hongkai Qiao , Pengtao Zhang
{"title":"The influence of rolling on the microstructure, mechanical properties, and in vitro degradation of biomedical Zn-2Cu alloy treated by ultrasound","authors":"Weibin Cui ,&nbsp;Qinglin Li ,&nbsp;Jing Yang ,&nbsp;Yirui Zhang ,&nbsp;Hongkai Qiao ,&nbsp;Pengtao Zhang","doi":"10.1016/j.msea.2026.149920","DOIUrl":"10.1016/j.msea.2026.149920","url":null,"abstract":"<div><div>Zn alloys are considered ideal materials for in vivo implants owing to their moderate degradation rates. The addition of Cu significantly enhances the antibacterial properties of Zn-Cu alloys, making them suitable for degradable implants such as orthopedic bone plates and bone screws. However, cast Zn-Cu alloys exhibit a poor strength-plasticity balance, which limits their ability to meet the mechanical performance requirements of bone implants. This study combined ultrasonic treatment with rolling processes to systematically investigate the microstructural evolution, mechanical properties, and degradation behavior of Zn-2Cu alloys prepared under different rolling conditions. The results revealed that after rolling, the α-Zn grains was significant refined into equiaxed grains with average sizes of 474 nm, 613 nm, and 591 nm. Additionally, sub-micron fine CuZn<sub>5</sub> precipitates formed, with average sizes of 610.7 nm, 503.9 nm, and 568.8 nm. Tensile tests revealed that 5-pass rolling at 200 °C significantly improved the mechanical properties of Zn-2Cu alloys compared with the unrolled condition. The ultimate tensile strength (UTS), yield strength (YS), and elongation (El) were increased from 178 MPa, 161 MPa, and 3.01% to 378 MPa, 367 MPa, and 58.1%, respectively. Electrochemical polarization tests indicated that the 5-pass heat-rolled (HR-5), 5-pass cold-rolled (CR-5), and 2-pass heat-rolled (HR-2) alloys in Hank's solution exhibited degradation rates of 1.865 mm/year, 0.418 mm/year, and 1.207 mm/year, respectively. After 7 days of immersion corrosion in Hank's solution, the degradation rates followed the order of HR-5 (35.94 μm/year) &gt; HR-2 (20.06 μm/year) &gt; CR-5 (25.08 μm/year). These results suggested that multi-process composite regulation can achieve an optimal balance between alloy strength and plasticity. This study provides a theoretical and technical basis for designing and fabricating next-generation biodegradable Zn alloy implants and highlights their potential applications in orthopedic medical devices.</div></div>","PeriodicalId":385,"journal":{"name":"Materials Science and Engineering: A","volume":"956 ","pages":"Article 149920"},"PeriodicalIF":7.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147403403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-performance soldering achieved through an energy-efficient magnetic field-assisted microwave hybrid joining: A multiscale study via molecular dynamics and first-principles calculations 通过高能效磁场辅助微波混合连接实现高性能焊接:通过分子动力学和第一性原理计算的多尺度研究
IF 7 2区 材料科学
Materials Science and Engineering: A Pub Date : 2026-03-01 Epub Date: 2026-02-12 DOI: 10.1016/j.msea.2026.149915
Shuai Zhang , Chen Zeng , Zhehao Gan , Jinhong Liu , Peng He , Tianran Ding , Weimin Long , Sujuan Zhong , Yew-Hoong Wong , Shuye Zhang
{"title":"High-performance soldering achieved through an energy-efficient magnetic field-assisted microwave hybrid joining: A multiscale study via molecular dynamics and first-principles calculations","authors":"Shuai Zhang ,&nbsp;Chen Zeng ,&nbsp;Zhehao Gan ,&nbsp;Jinhong Liu ,&nbsp;Peng He ,&nbsp;Tianran Ding ,&nbsp;Weimin Long ,&nbsp;Sujuan Zhong ,&nbsp;Yew-Hoong Wong ,&nbsp;Shuye Zhang","doi":"10.1016/j.msea.2026.149915","DOIUrl":"10.1016/j.msea.2026.149915","url":null,"abstract":"<div><div>To advance high-reliability and sustainable electronic packaging, this study proposes a magnetic field-assisted microwave hybrid joining (MMHJ) strategy. By incorporating Ni@Sn nanoparticles and Ni-plated carbon fibers (CF@Ni@Sn) into a Sn-3Ag-0.5Cu (SAC305) matrix, we systematically investigated the magnetoelectric response of the composite solder, with particular emphasis on grain orientation kinetics and microstructural evolution. Under a customized longitudinal magnetic field, the CF reinforcements achieved precise directional alignment, while Ni solute segregation was effectively suppressed. This synergetic modulation promoted β-Sn grain refinement and a substantial increase in dislocation density. Utilizing a 2 kW microwave field (<em>f</em> = 2.45 GHz), the MMHJ-processed composite joints attained a peak shear strength of 58.58 MPa within a 40 s duration-a 30.41% improvement over conventional SAC305 while slashing energy consumption by 93.92%. After 1200 thermal cycles, the MMHJ-Cu/SAC-0.5NCF@/Cu joints retained a 26.61% strength advantage, highlighting their excellent service durability. Mechanistically, the non-equilibrium interactions within the microwave-reinforcement architecture were analyzed through dielectric and magnetic tensor analysis. By integrating molecular dynamics (MD) simulations of interfacial atomic flux with DFT-based field perturbation theory, the regulatory role of thermoelectromagnetic hydrodynamic (TEMHD) effects on intermetallic compound (IMC) morphogenesis was revealed. These multiscale insights establish a rigorous physical foundation for the experimentally observed advances in high-efficiency soldering.</div></div>","PeriodicalId":385,"journal":{"name":"Materials Science and Engineering: A","volume":"956 ","pages":"Article 149915"},"PeriodicalIF":7.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146172671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “The effect of prior austenite grain size on hierarchical structures of lath martensite in a 22MnB5 steel” [Mater. Sci. Eng. A 951 (2026) 149544] “奥氏体晶粒尺寸对22MnB5钢板条马氏体分层组织的影响”的勘误[材料]。科学。Eng。A 951 (2026) 149544]
IF 7 2区 材料科学
Materials Science and Engineering: A Pub Date : 2026-03-01 Epub Date: 2026-02-17 DOI: 10.1016/j.msea.2026.149914
Chien-Yu Tseng , Ming-Yi Cheng , Tzu-Ching Tsao , Po-Han Chiu , Yu-An Chen , Chu-Jen Chen , R.D.K. Misra , Yo-Lun Yang , Te-Cheng Su , Chih-Yuan Chen , Jer-Ren Yang
{"title":"Corrigendum to “The effect of prior austenite grain size on hierarchical structures of lath martensite in a 22MnB5 steel” [Mater. Sci. Eng. A 951 (2026) 149544]","authors":"Chien-Yu Tseng ,&nbsp;Ming-Yi Cheng ,&nbsp;Tzu-Ching Tsao ,&nbsp;Po-Han Chiu ,&nbsp;Yu-An Chen ,&nbsp;Chu-Jen Chen ,&nbsp;R.D.K. Misra ,&nbsp;Yo-Lun Yang ,&nbsp;Te-Cheng Su ,&nbsp;Chih-Yuan Chen ,&nbsp;Jer-Ren Yang","doi":"10.1016/j.msea.2026.149914","DOIUrl":"10.1016/j.msea.2026.149914","url":null,"abstract":"","PeriodicalId":385,"journal":{"name":"Materials Science and Engineering: A","volume":"956 ","pages":"Article 149914"},"PeriodicalIF":7.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147403417","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simultaneous enhancement of strength and plasticity in WAAM 2319 aluminum alloy by bidirectional rolling+ heat treatment 双向轧制+热处理同时提高WAAM 2319铝合金的强度和塑性
IF 7 2区 材料科学
Materials Science and Engineering: A Pub Date : 2026-03-01 Epub Date: 2026-02-04 DOI: 10.1016/j.msea.2026.149834
Haomin Ma , Hongwei Li , Xin Zhang , Mei Zhan
{"title":"Simultaneous enhancement of strength and plasticity in WAAM 2319 aluminum alloy by bidirectional rolling+ heat treatment","authors":"Haomin Ma ,&nbsp;Hongwei Li ,&nbsp;Xin Zhang ,&nbsp;Mei Zhan","doi":"10.1016/j.msea.2026.149834","DOIUrl":"10.1016/j.msea.2026.149834","url":null,"abstract":"<div><div>Wire arc additive manufacturing (WAAM) enables the integral fabrication of aluminum alloy components with high ribs and thin webs. However, coarse grains, residual crystalline phases (RCPs), and porosity defects weaken mechanical properties and limit applications. Although interlayer plastic deformation during WAAM can improve the microstructure and porosity defect, it exhibits limitations in deformation degree and uniformity. To address this, this study proposes an asynchronous bidirectional rolling process integrated with heat treatment (surface rolling → recrystallization annealing → side rolling → T6 ageing) to enhance the properties of WAAM 2319 aluminum alloy. Compared to conventional rolling, bidirectional rolling demonstrates superior microstructural uniformity and strength-plasticity balance. This superiority stems from the bidirectional rolling combined with intermediate annealing: it refines grains and reduces porosity while inducing alternating compressive-tensile strains within preferentially oriented RCPs. This effectively blunts brittle second-phase particles and accelerates their separation and migration. Consequently, it promotes the formation of longer and thinner <span><math><mrow><msup><mi>θ</mi><mo>′</mo></msup></mrow></math></span> phases after solution-ageing treatment, thereby enhancing the precipitation strengthening effect. Furthermore, it significantly delays the formation of pore-induced matrix cracking (PIMC) and interfacial bonded voids (IDVs), which alleviates local stress concentrations and thus improves plasticity.</div></div>","PeriodicalId":385,"journal":{"name":"Materials Science and Engineering: A","volume":"955 ","pages":"Article 149834"},"PeriodicalIF":7.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructural gradients and associated mechanical properties in the rapid solidification microstructure of hypo-eutectic Al-10at.%Cu obtaining after scanned-laser melting 亚共晶Al-10at快速凝固组织的组织梯度及相关力学性能。扫描激光熔化后获得的%Cu
IF 7 2区 材料科学
Materials Science and Engineering: A Pub Date : 2026-03-01 Epub Date: 2026-01-29 DOI: 10.1016/j.msea.2026.149818
M.T. Alamoudi , J.M.K. Wiezorek
{"title":"Microstructural gradients and associated mechanical properties in the rapid solidification microstructure of hypo-eutectic Al-10at.%Cu obtaining after scanned-laser melting","authors":"M.T. Alamoudi ,&nbsp;J.M.K. Wiezorek","doi":"10.1016/j.msea.2026.149818","DOIUrl":"10.1016/j.msea.2026.149818","url":null,"abstract":"<div><div>Scanned-laser surface melting strategies have been developed to establish morphologically graded rapid solidification (RS) microstructures in bulk alloy specimens of hypoeutectic Al-10Cu. Using electron microscopy and instrumented nanoindentation location-specific mechanical properties have been determined for three morphologically distinct RS microstructure regions that are characterisitic of Al-10Cu, i.e., the transition, α-cell and banded-grain zone. RS microstructure and mechanical property evolution in response to isothermal annealing (120 s ≤ t ≤ 480 s; 180 °C &lt; T ≤ 280 °C) are reported and discussed. Melt pools induced by single-pass scans showed evidence of Marangoni-effect driven mixing and uneven composition retained in the melt. Multi-pass scans and using multiple scan speeds, 1 m/s ≤ v<sub>b</sub> ≤ 4 m/s, produced compositionally more uniform melts before forming RS microstructures exhibiting the three morphologically distinct zones. Nanoindentation hardness of the transition, α-cell and banded-grain zones, increased from 2.7 GPa to 3.3 GPa and up to 3.4 GPa, respectively. Annealing caused an initial hardening response attributed to precipitation reactions, followed by moderate coarsening and up to ∼15 % hardness drop. Since the morphologically distinct RS microstructures zones in Al-Cu alloys form for characteristic composition specific solidification velocities, this study illustrates how properties correlate with solidification microstructure selection maps and assists development of processing schema for tayloring properties in Al–Cu parts prepared by laser melting processes.</div></div>","PeriodicalId":385,"journal":{"name":"Materials Science and Engineering: A","volume":"955 ","pages":"Article 149818"},"PeriodicalIF":7.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Achieving synergistic strengthening of selective laser melted titanium alloy with CoCrFeNi medium-entropy alloy 选择性激光熔化钛合金与CoCrFeNi中熵合金的协同强化
IF 7 2区 材料科学
Materials Science and Engineering: A Pub Date : 2026-03-01 Epub Date: 2026-02-05 DOI: 10.1016/j.msea.2026.149897
Laiba Shaukat , Yizhou Tang , Yifeng Xiong , Faming Zhang
{"title":"Achieving synergistic strengthening of selective laser melted titanium alloy with CoCrFeNi medium-entropy alloy","authors":"Laiba Shaukat ,&nbsp;Yizhou Tang ,&nbsp;Yifeng Xiong ,&nbsp;Faming Zhang","doi":"10.1016/j.msea.2026.149897","DOIUrl":"10.1016/j.msea.2026.149897","url":null,"abstract":"<div><div>Additive manufacturing of titanium matrix composites is often limited by particles-matrix interfacial mismatch. Here, CoCrFeNi medium-entropy alloy (MEA) powder was co-processed with Ti-6Al-4V (Ti64) via selective laser melting (SLM) to enable in-situ alloying rather than discrete particle reinforcement. The SLM thermal cycle drives near-complete dissolution of the MEA and produces a nanoscale dual-phase architecture of acicular α′ martensite and metastable β. Electron backscatter diffraction EBSD reveals a chemically homogeneous yet mechanically heterogeneous α′/β dual-phase microstructure with random texture and reduced lattice strain, indicating suppressed epitaxial growth and refined phase distribution. Mechanical properties are significantly enhanced: the 3 wt% MEA composition achieves an ultimate tensile strength of 1411 MPa with 8.2% elongation, alongside concurrent increases in yield strength and hardness. Strength-ductility synergy arises from the cooperative action of transformation-induced plasticity (TRIP), hetero-deformation-induced (HDI) strengthening, associated with α′/β mechanical contrast, and extreme grain refinement, with plasticity partitioned across α′/β interphase boundaries and dislocation-rich cellular structures. By eliminating discrete reinforcement/matrix interfaces, this in-situ alloying route circumvents the conventional interfacial constraint in TMCs and provides a viable pathway for designing high-performance Ti-based composite.</div></div>","PeriodicalId":385,"journal":{"name":"Materials Science and Engineering: A","volume":"955 ","pages":"Article 149897"},"PeriodicalIF":7.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146171635","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructure-controlled low-cycle fatigue of 2026 Al alloy in T4 and T6 tempers: roles of SⅠ precipitates and grain-boundary GBPs / PFZs 2026铝合金T4和T6回火组织控制的低周疲劳:SⅠ相和晶界GBPs / pfz的作用
IF 7 2区 材料科学
Materials Science and Engineering: A Pub Date : 2026-03-01 Epub Date: 2026-02-03 DOI: 10.1016/j.msea.2026.149884
Wenbin Zhang , Huizhong Li , Xiaopeng Liang , Zhengfeng Lv , Zhiyuan Cheng , Zhaohui Yan , Xiaofen Tan
{"title":"Microstructure-controlled low-cycle fatigue of 2026 Al alloy in T4 and T6 tempers: roles of SⅠ precipitates and grain-boundary GBPs / PFZs","authors":"Wenbin Zhang ,&nbsp;Huizhong Li ,&nbsp;Xiaopeng Liang ,&nbsp;Zhengfeng Lv ,&nbsp;Zhiyuan Cheng ,&nbsp;Zhaohui Yan ,&nbsp;Xiaofen Tan","doi":"10.1016/j.msea.2026.149884","DOIUrl":"10.1016/j.msea.2026.149884","url":null,"abstract":"<div><div>The 2026 aluminum alloy is a damage-tolerant structural material for aerospace applications, where low-cycle fatigue (LCF) resistance is critical to structural safety. In this work, strain-controlled LCF tests with strain amplitudes of 0.6%–0.9% were performed on a 2026 Al alloy in two typical tempers (T4 and T6), and the fatigue behavior was correlated with microstructural evolution. The fatigue life was evaluated using the Coffin–Manson relationship, while an energy-based hysteresis model was employed to extract the intrinsic fatigue damage capacity W<sub>0</sub> and the damage-transition exponent β. The T4 temper exhibits more homogeneous intragranular deformation, assisted by dispersed quenched-in dislocation loops and thermally stable Al<sub>3</sub>Zr dispersoids, together with the absence of grain-boundary precipitates, leading to a microvoid-dominated damage mode. Consequently, the T4 temper shows high fatigue ductility (εf' = 17.3, c = −1.44) and a higher damage capacity (W<sub>0</sub> = 2511 × 10<sup>6</sup> J/m<sup>3</sup>). In contrast, the T6 temper contains a high density of shearable S<sub>Ⅰ</sub> precipitates, which sustain a higher fatigue strength (σf' = 1127 MPa) but promote localized cyclic deformation and microcrack-dominated damage with subsurface crack initiation. Within the energy-based framework, the larger β in the T6 temper indicates a more nonlinear conversion from cyclic hysteresis work to effective damage under localized deformation, consistent with its crack-initiation mode. These results clarify the distinct roles of S<sub>Ⅰ</sub> precipitates and intragranular dislocation-loop / Al<sub>3</sub>Zr features in controlling LCF response, providing guidance for tailoring temper states of Al–Cu–Mg alloys for different fatigue-service scenarios.</div></div>","PeriodicalId":385,"journal":{"name":"Materials Science and Engineering: A","volume":"956 ","pages":"Article 149884"},"PeriodicalIF":7.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147403396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
TiC nanoparticles tune phase stability and deformation mechanisms in directed energy deposition processed Fe60Co15Ni15Cr10 medium-entropy alloy composites TiC纳米颗粒调节定向能沉积制备Fe60Co15Ni15Cr10中熵合金复合材料的相稳定性和变形机制
IF 7 2区 材料科学
Materials Science and Engineering: A Pub Date : 2026-03-01 Epub Date: 2026-01-27 DOI: 10.1016/j.msea.2026.149839
Soung Yeoul Ahn , Eun Seong Kim , Sang Guk Jeong , Stefanus Harjo , Takuro Kawasaki , Wu Gong , Hyun-Joong Kim , Soon-Jik Hong , Sun Ig Hong , Hyeonseok Kwon , Jung Gi Kim , Hyoung Seop Kim
{"title":"TiC nanoparticles tune phase stability and deformation mechanisms in directed energy deposition processed Fe60Co15Ni15Cr10 medium-entropy alloy composites","authors":"Soung Yeoul Ahn ,&nbsp;Eun Seong Kim ,&nbsp;Sang Guk Jeong ,&nbsp;Stefanus Harjo ,&nbsp;Takuro Kawasaki ,&nbsp;Wu Gong ,&nbsp;Hyun-Joong Kim ,&nbsp;Soon-Jik Hong ,&nbsp;Sun Ig Hong ,&nbsp;Hyeonseok Kwon ,&nbsp;Jung Gi Kim ,&nbsp;Hyoung Seop Kim","doi":"10.1016/j.msea.2026.149839","DOIUrl":"10.1016/j.msea.2026.149839","url":null,"abstract":"<div><div>Additive manufacturing (AM) of particle-reinforced metal matrix composites (MMCs) offers opportunities not only for mechanical strengthening but also for tailoring matrix phase stability and deformation behavior. In this study, TiC (2 wt%) nanoparticles were incorporated into Fe<sub>60</sub>Co<sub>15</sub>Ni<sub>15</sub>Cr<sub>10</sub> (at%) medium-entropy alloy (MEA) using directed energy deposition (DED) process. Despite the severe thermal conditions of the DED process, a substantial fraction of TiC remained, while partial decomposition released C and Ti elements into the matrix. This chemical modification stabilized the γ-austenite matrix phase and suppressed deformation-induced martensitic transformation (DIMT), which is typically active in the Fe<sub>60</sub>Co<sub>15</sub>Ni<sub>15</sub>Cr<sub>10</sub> MEA. Instead, the composite exhibited a transition toward slip-dominated deformation. Microstructural observation revealed that dispersed and semi-coherent TiC particles, together with solute partitioning from decomposed nanoparticles, altered grain boundary morphology and promoted distributed plastic flow. <em>In-situ</em> neutron diffraction accompanied with tensile test confirmed enhanced dislocation activity in the early stage of deformation, supporting the deformation mechanism shift from DIMT-assisted hardening to dislocation-mediated slip. These results highlight the critical role of nanoparticle-induced phase stability variation in governing deformation mechanisms, offering new insights into designing AM-processed MMCs beyond conventional strength-oriented strategies.</div></div>","PeriodicalId":385,"journal":{"name":"Materials Science and Engineering: A","volume":"955 ","pages":"Article 149839"},"PeriodicalIF":7.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146077036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrogen embrittlement and mechanical response of 304L steel with ZrC additions 添加ZrC后304L钢的氢脆及力学响应
IF 7 2区 材料科学
Materials Science and Engineering: A Pub Date : 2026-03-01 Epub Date: 2026-01-27 DOI: 10.1016/j.msea.2026.149824
A. Stubbers , B.P. Rocky , C. Gilleland , R. Shrestha , C. San Marchi , R.P. Wilkerson , G.B. Thompson , C.R. Weinberger
{"title":"Hydrogen embrittlement and mechanical response of 304L steel with ZrC additions","authors":"A. Stubbers ,&nbsp;B.P. Rocky ,&nbsp;C. Gilleland ,&nbsp;R. Shrestha ,&nbsp;C. San Marchi ,&nbsp;R.P. Wilkerson ,&nbsp;G.B. Thompson ,&nbsp;C.R. Weinberger","doi":"10.1016/j.msea.2026.149824","DOIUrl":"10.1016/j.msea.2026.149824","url":null,"abstract":"<div><div>While stainless steels are widely used for hydrogen storage infrastructure, they can still be vulnerable to hydrogen embrittlement justifying the need to further improve their hydrogen resiliency. Here, we investigate the potential for transition metal carbide additions to improve the hydrogen compatibility of austenitic stainless steels. ZrC nanoparticles were dispersed in contents of 0.01–10 wt% in 304 L stainless steel powder, mixed via high energy ball milling, and subsequently consolidated using direct current sintering. To assess hydrogen compatibility, the tensile properties of similarly processed 304 L without ZrC nanoparticles were compared to 304 L with the ZrC additions; both materials were evaluated prior to and after hydrogen exposure (non-charged and H-precharged, respectively). Depending upon the ZrC phase fraction, the yield strengths varied from ∼325 to 560 MPa in the non-charged condition and from ∼375 to 550 MPa in the H-precharged condition. Strain at failure varied from ∼5 to 90 % and from ∼5 to 35 % in the non-charged and hydrogen-precharged conditions, respectively. Results from stress-strain profiles demonstrate limited efficacy of ZrC as a method to mitigate hydrogen embrittlement entirely but does demonstrate the potency of ZrC inclusions as strengthening addition to 304 L alloys without a loss of ductility.</div></div>","PeriodicalId":385,"journal":{"name":"Materials Science and Engineering: A","volume":"955 ","pages":"Article 149824"},"PeriodicalIF":7.0,"publicationDate":"2026-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146077031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correcting oxygen-impurity artifacts in refractory alloys: A case study of the V-Zr system 纠正难熔合金中的氧杂质伪影:以V-Zr体系为例
IF 7 2区 材料科学
Materials Science and Engineering: A Pub Date : 2026-03-01 Epub Date: 2026-02-09 DOI: 10.1016/j.msea.2026.149906
Yu-Ning Chiu , Shao-Yu Yen , Wei-Chen Wu , Shih-Kang Lin
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