Advances in Colloid and Interface Science最新文献

{"title":"Bio-based materials regulating interfacial behavior of multiphase systems during CO2 geological utilization and storage: A review","authors":"Zesen Peng ,&nbsp;Yueliang Liu ,&nbsp;Hanchi Zheng ,&nbsp;Xing Huang ,&nbsp;Zhenhua Rui ,&nbsp;Jirui Zou ,&nbsp;Andrey Afanasyev","doi":"10.1016/j.cis.2025.103646","DOIUrl":"10.1016/j.cis.2025.103646","url":null,"abstract":"<div><div>CO₂ geological utilization and storage involve complex multiphase interfacial behaviors that significantly influence the overall efficiency. Recently, bio-based materials have attracted increasing attention as promising candidates for interfacial regulation owing to their structural diversity, abundance, and environmental compatibility. This review summarizes recent advances in utilizing biomass-derived materials to regulate interfacial behaviors in subsurface multiphase systems. The relationship between interfacial behaviors and CO₂ utilization and sequestration is discussed under typical scenarios. Molecular structures, functional group characteristics, and environmental compatibility of bio-based materials are systematically reviewed. This article highlights the adsorption behaviors of bio-based molecules at liquid/liquid, solid/liquid, and gas/liquid interfaces, interfacial molecular arrangement and distribution, and spontaneous self-assembly behaviors. Effects of these materials on key interfacial properties including interfacial tension (IFT), wettability, and capillary forces are further analyzed. This study also examines some dynamic interfacial phenomena, such as the formation of multilamellar vesicle structures that accelerate mass transfer between phases, the synergistic interactions between nanoparticles and small biomolecules at solid-liquid interfaces under electrostatic forces, and the role of bio-based materials in promoting CO₂ transfer by providing additional adsorption sites. These insights offer new perspectives for fundamental understanding of interfacial mass transfer. Finally, the review outlines future research trends in studying the regulation of multiphase interfacial behaviors by bio-based materials, emphasizing the need for in situ microscopic characterization techniques to support their efficient application in CO₂ geological utilization and storage.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"346 ","pages":"Article 103646"},"PeriodicalIF":19.3,"publicationDate":"2025-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144933559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A review on surface and interface engineering of nanocellulose and its application in smart packaging","authors":"Yuhan Hou ,&nbsp;Zhijun Wu ,&nbsp;Wen Qin ,&nbsp;Douglas A. Loy ,&nbsp;Derong Lin","doi":"10.1016/j.cis.2025.103645","DOIUrl":"10.1016/j.cis.2025.103645","url":null,"abstract":"<div><div>Cellulose is an abundant and renewable natural resource with broad applications in solving environmental pollution and promoting sustainable resource utilisation. Nanocellulose, owing to its unique physicochemical properties, can be incorporated into food packaging materials in various forms, endowing smart packaging with enhanced functionality. Its porosity, large pore size and high surface area make nanocellulose a valuable component in smart packaging systems, particularly following modification via interface and surface engineering. This paper reviewed the research status of nanocellulose in sensor-based smart packaging and smart controlled-release packaging, and highlighted its unique physicochemical properties modified by surface and interface engineering as well as the the enhanced functionalities these properties bring to smart packaging. However, the application of engineered nanocellulose in smart packaging is still in its infancy. This paper also summarized current limitations and discussed possible future directions for development.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"345 ","pages":"Article 103645"},"PeriodicalIF":19.3,"publicationDate":"2025-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144904465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Decoding physical environment's role in protein phase transition","authors":"Wan-Yi Ge,&nbsp;Da-Chuan Yin","doi":"10.1016/j.cis.2025.103643","DOIUrl":"10.1016/j.cis.2025.103643","url":null,"abstract":"<div><div>Phase transitions, as fundamental phenomena in physical sciences, are well-studied and a full theoretical framework has been established. The research has recently expanded into biological sciences after the milestone discovery of liquid-liquid phase separation (LLPS), and the latest studies are focusing not only LLPS but also liquid-solid phase transition (LSPT). These phase transitions are important fundamental biological processes such as formation of membraneless organelles, and pathogenesis of diseases such as neurodegenerative diseases, type 2 diabetes, and amyloidogenic disorders. These findings provide unprecedented perspectives for deciphering the physicochemical principles underlying living systems and associated disease pathogenesis. In this review we systematically analyze the hierarchical progression of phase transition pathways, delineating how physical factors (e.g., temperature, magnetic field, electric field, etc.) govern transition kinetics and final state selection. The methodological section provides a comprehensive review of experimental techniques applicable in studying phase transitions in biological systems. The elucidation of biological phase transitions is fundamentally important in that it not only provides a novel paradigm for understanding spatiotemporal regulation of cellular organization, but also provides mechanistic insights for developing therapeutic strategies targeting pathological phase transitions. Notably, the identification of physical modulation mechanisms can help to develop non-pharmacological intervention strategies, potentially revolutionizing treatment approaches for protein-misfolding disorders through precisely controlled phase manipulation.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"345 ","pages":"Article 103643"},"PeriodicalIF":19.3,"publicationDate":"2025-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144908631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Review of gold-ligand interactions: Implications for metallurgical processes and nanoparticle synthesis","authors":"Foad Raji,&nbsp;Yongjun Peng","doi":"10.1016/j.cis.2025.103644","DOIUrl":"10.1016/j.cis.2025.103644","url":null,"abstract":"<div><div>Gold, essential in both metallurgical extraction and nanoparticle-based technologies, plays a central role in catalysis, sensing and biomedicine. Its interactions with organic ligands are critical for efficient gold recovery through flotation and leaching as well as for synthesizing gold nanoparticles. These interactions, primarily governed by anchoring atoms, sulfur, nitrogen, phosphorus, oxygen, and carbon, define the strength, geometry and selectivity of the gold-ligand interface. This review evaluates how each anchoring atom affects adsorption mechanisms, including chemisorption, donor-acceptor interactions and dispersive forces in metallurgical and nanoparticle contexts. Sulfur-based ligands, essential in flotation and leaching, form strong Au<img>S bonds at high-coordination atop/hollow sites or undercoordinated adatoms, modulated by redox conditions. Nitrogen-based ligands, less effective in extraction, are vital in nanoparticle synthesis due to selective binding to gold adatoms. Phosphorus-based ligands, weaker in extraction, hold promise for nanoparticle engineering, leveraging electronic and steric properties. Oxygen-anchoring ligands with weak Au<img>O interactions have limited relevance in extraction but stabilize nanoparticles via multidentate and non-covalent interactions. Carbon-based ligands, especially N-heterocyclic carbenes, create highly stable Au<img>C bonds, crucial for nanoparticle synthesis despite limited extraction use. The review advocates an interdisciplinary approach to advance fundamental understanding and practical applications of gold technologies. Bridging metallurgical and colloidal-interface perspectives provides valuable insights for improving gold recovery methods and developing innovative gold-based nanomaterials for diverse advanced applications.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"345 ","pages":"Article 103644"},"PeriodicalIF":19.3,"publicationDate":"2025-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144904466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Surfactants, cellulose nanocrystals, and chitosan: Their contributions to pesticide delivery systems","authors":"Gaili Cao,&nbsp;Youchao Teng,&nbsp;Weinan Zhao,&nbsp;Han Gia Nguyen,&nbsp;Kam Chiu Tam","doi":"10.1016/j.cis.2025.103642","DOIUrl":"10.1016/j.cis.2025.103642","url":null,"abstract":"<div><div>Improving pesticide utilization efficiency is vital for environmental sustainability, economic growth, and the protection of human and animal health, particularly in water-based formulations. Numerous studies have shown that surfactants can enhance pesticide encapsulation and improve deposition efficiency on plant surfaces. This review examines the roles of surfactants in pesticide formulations from the perspective of their structural classifications, including conventional, gemini, trimeric, and polymeric surfactants, with a particular focus on how molecular structure influences the droplet behavior and delivery performance. We highlight the applications and functional roles of sustainable, biodegradable, and renewable biomaterials, specifically cellulose nanocrystals (CNC), chitosan, and their derivatives, in foliage- and soil-applied pesticide delivery systems. While both CNC and chitosan possess excellent carrier properties, attaining high deposition efficiency on plant surfaces continues to be a significant challenge. Combining the biomaterials with surfactants offers an effective strategy to improve pesticide utilization. Additionally, this review outlines the current understanding of droplet dynamics on hydrophobic and superhydrophobic plant surfaces, highlighting the mechanisms and formulation strategies used to control droplet behavior and enhance deposition. Finally, we outline key challenges and future directions for the development of next-generation pesticides that integrate high efficacy, reduced environmental impact, and long-term sustainability, thereby advancing the future of eco-friendly crop protection systems.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"345 ","pages":"Article 103642"},"PeriodicalIF":19.3,"publicationDate":"2025-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144892797","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Exploring innovations in antimicrobial protective mask filters: A review","authors":"Ogechukwu Vincentia Ezeh ,&nbsp;Juan Jose Ternero-Hidalgo ,&nbsp;Rans Miguel Nunag Lintag ,&nbsp;Wei Han ,&nbsp;King Lun Yeung","doi":"10.1016/j.cis.2025.103635","DOIUrl":"10.1016/j.cis.2025.103635","url":null,"abstract":"<div><div>Mask filters are necessary for personal protection. The COVID-19 pandemic exemplified this need. Nonetheless, they can pose risk of transmission as captured microbes or respiratory droplets can remain viable on filters and propagate under ideal environmental conditions. It became evident during the COVID-19 pandemic that conventional masks alone are insufficient for ensuring adequate safety and disrupting the route of spread. Equipping protective masks with antimicrobial property is fundamental to overcoming the survivability of microbes on the surface of filter media and ensuring personal safety. Consequently, this has become a significant research focus, with a sharp upsurge in publications in the COVID-19 era. In this work, we present a comprehensive review of crucial advancements in antimicrobial mask filters, emphasizing the relevance of this topic within the contemporary framework of the COVID-19 pandemic, in addition to the anticipated performance standards associated with the expanding market of antimicrobial protective mask filters.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"345 ","pages":"Article 103635"},"PeriodicalIF":19.3,"publicationDate":"2025-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144890474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Colloidal soft matters-based flexible energy storage devices: Design and application","authors":"Wenna Wu ,&nbsp;Jialin Jia ,&nbsp;Junkang Yang ,&nbsp;Tao Zhang ,&nbsp;Jingcheng Hao","doi":"10.1016/j.cis.2025.103629","DOIUrl":"10.1016/j.cis.2025.103629","url":null,"abstract":"<div><div>With the continuous growth of energy demand and the pursuit of sustainable energy systems, the development of efficient, reliable and environmentally friendly energy storage devices has become a research hotspot. Colloidal soft matter, with its controllable self-assembly behavior endowing unique porous nanochannel structure, high specific surface area and tunable rheological properties, provides new approaches for the innovative design of energy storage devices. Here, we systematically review the design strategies of colloidal soft matter-based energy storage devices, covering the optimization of key components such as electrolytes and electrode materials. It mainly focuses on the design and development of various liquid crystals electrolytes (1D columnar, 2D smectic, and 3D bicontinuous cubic liquid crystal), emulsions-based electrolytes (microemulsions-, Pickering emulsions-, Bijel-, high internal phase emulsions-, and novel emulsions-based electrolytes), gel-based electrolytes (hydrogel, organogel, ionogel, and eutectogel electrolytes), as well as emulsion-, hydrogel-, and aerogel-based electrode materials. By rationally utilizing the characteristics of colloidal soft matter, the energy density, power density and cycle stability of energy storage devices can be effectively enhanced. In terms of application, the potential applications of multifunctional supercapacitors and batteries are discussed in detail. It also anticipates future research directions, such as the optimization of synergistic effects of electrolytes and electrodes, the development of novel colloidal soft substances, and the advancement of multifunctional integration of energy storage devices. This review provides a systematic reference for further research on colloidal soft substances in the field of green energy storage.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"345 ","pages":"Article 103629"},"PeriodicalIF":19.3,"publicationDate":"2025-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144865731","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advanced biomaterials in tissue engineering: A critical review of nanocomposites based on bacterial cellulose, MXenes, hydroxyapatite, and metal particles for regenerative medicine","authors":"Mira Davlet ,&nbsp;Kateryna Smyrnova ,&nbsp;Alexander Pogrebnjak","doi":"10.1016/j.cis.2025.103634","DOIUrl":"10.1016/j.cis.2025.103634","url":null,"abstract":"<div><div>Soft and hard tissues have limited regenerative potential that fuels the search for advanced biomaterials able to mimic their complex dynamics better. Individually, bacterial cellulose (BC) provides excellent biocompatibility but lacks inherent bioactivity and functional properties needed to promote tissue regeneration. Hydroxyapatite (HAp) offers osteoconductivity but shows brittleness. Metal nanoparticles (MNPs) have antioxidant, antimicrobial, and drug-delivery properties, but may be toxic. Lastly, MXenes possess good conductivity but lack knowledge of their long-term biocompatibility. To address these material limitations, approaches like genetic modifications to BC synthesis and surface modifications of MXenes and MNPs are explored. This review examines synthesis methods, structural properties, and biomedical applications of individual and hybrid materials based on BC, MXene, HAp, and MNPs. Analysis of existing composite materials establishes a strong recognition of their compatibility, which supports the possibility of their successful integration into a multifunctional BC/MXene/MNP/HAp four-component composite. It is expected to exhibit a combination of osteoinduction, electrical conductivity, antibacterial activity, and structural support to improve tissue repair. However, challenges include the potential cytotoxicity of MNPs and limited studies on the broader impact of MXenes on gene expression beyond specific markers. This review sheds light on the development of a new composite material that can address current limitations in biomaterial functionality by summarizing current knowledge and highlighting critical gaps. It aims to establish a foundation and inspire future studies towards rationally designing BC/MXene/MNP/HAp composites for advanced regenerative therapies.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"345 ","pages":"Article 103634"},"PeriodicalIF":19.3,"publicationDate":"2025-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144865730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Functionalized Ionogels with self-healing performance: Material design, chemistry aspects, applications, and future prospects","authors":"Fatemeh Ahangaran","doi":"10.1016/j.cis.2025.103633","DOIUrl":"10.1016/j.cis.2025.103633","url":null,"abstract":"<div><div>Nowadays, functionalized ionogels have attracted considerable research attention because of their superior benefits including excellent mechanical properties, conductivity, transparency, stretchability, adhesivity, biocompatibility, recyclability, shape memory, 3D printability, and self-healability. The self-healing performance implements the ability to autonomously repair the damaged ionogels through the covalent or non-covalent reversible bonds without any external intervention at ambient conditions. The healing strategy is influenced by the type of polymer, ionic liquid, and synthesis procedures. The present review introduces the polymers and ionic liquids (ILs) for the preparation of multifunctional ionogels with the focus on self-healing ability. Therefore, the diverse functionalities of ionogels are introduced, followed by the deep delve with strategies of preparation of self-healing ionogels. The potential uses of functionalized self-healing ionogels in wearable electronics and sensors, solid-state electrolytes, triboelectric nanogenerators, lubricating materials, and transistor devices are also discussed. Finally, the developmental prospects of the new generations of functionalized self-healing ionogels for future research are presented. The current review provides insights into the development of a novel generation of material with excellent characteristics for future academic research, and paves the path toward practical applications.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"345 ","pages":"Article 103633"},"PeriodicalIF":19.3,"publicationDate":"2025-08-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144860291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Chitosan and its functionalized derivatives for heavy metal ion elimination: A review of synthesis, mechanisms, and characterization studies","authors":"Prabhat Kumar Patel ,&nbsp;Ramagopal V.S. Uppaluri","doi":"10.1016/j.cis.2025.103632","DOIUrl":"10.1016/j.cis.2025.103632","url":null,"abstract":"<div><div>Due to its widespread distribution, lower environmental impact, sustainability, and antimicrobial attributes, chitosan is a multifunctional polysaccharide. Composite materials composed of chitosan convey the promotion of a viable and environmentally friendly engagement and eliminate the growing worries associated with the ecological contamination being caused by the metallic ions. Due to its special coordination property, chitosan combines with other beneficial substances. This feature improves its qualities and fosters the realization of a concentric economy through the deployment of numerous relevant methods. For example, for the concentration range of 100-2000 mg L^-1, alginate aerogel with melamine chitosan performed exceptionally well with the assessed Pb adsorption capacity of 1331.6 mg g^-1 and desorption efficacy of 60% up to 8 adsorption-desorption cycles and with the 0.05 M HNO₃ eluent. The article details many methods that promote successful modification of chitosan for the desired application in terms of environmental remediation. After providing a summary of popular chitosan harvesting and transformation procedures, the authors delve further into the influence of the manufacturing processes on the structural characteristics and functionality of chitosan-assisted composite materials. The most comprehensive evaluation being undertaken to date has been detailed in this study, and henceforth, the article engages the readers to uniquely categorize and methodologically understand the most recent research advances in the chosen field of study. Also, the ecological and financial consequences of chitosan-assisted compound utilization have been evaluated in terms of the viability and proximity scenarios. Also, relevant characterization tools have been detailed for the betterment of the understanding related to the real-world application scenarios. Finally, the difficulties and potential pathways for the chitosan-assisted compounds were addressed. Accordingly, the outcomes can be used as pragmatic advice for further advances in the policy and application matters associated with the environmental remediation with the chitosan-based resins.</div></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"345 ","pages":"Article 103632"},"PeriodicalIF":19.3,"publicationDate":"2025-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144841144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}