Water science and engineering最新文献

{"title":"Morphodynamic signatures derived from daily surface elevation dynamics can explain the morphodynamic development of tidal flats","authors":"Tim J. Grandjean ,&nbsp;Jaco C. de Smit ,&nbsp;Jim van Belzen ,&nbsp;Gregory S. Fivash ,&nbsp;Jeroen van Dalen ,&nbsp;Tom Ysebaert ,&nbsp;Tjeerd J. Bouma","doi":"10.1016/j.wse.2022.11.003","DOIUrl":"10.1016/j.wse.2022.11.003","url":null,"abstract":"<div><p>Understanding the sensitivity of tidal flats to environmental changes is challenging. Currently, most studies rely on process-based models to systematically explain the morphodynamic evolution of tidal flats. In this study, we proposed an alternative empirical approach to explore tidal flat dynamics using statistical indices based on long-term time series of daily surface elevation development. Surface elevation dynamic (SED) indices focus on the magnitude and period of surface elevation changes, while morphodynamic signature (MDS) indices relate sediment dynamics to environmental drivers. The statistical analyses were applied to an intervention site in the Netherlands to determine the effect of recently constructed groynes on the tidal flat. Using these analyses, we were able to (1) detect a reduction in the daily SED and (2) determine that the changes in the daily SED were predominantly caused by the reduction in wave impact between the groynes rather than the reduction in tidal currents. Overall, the presented results showed that the combination of novel statistical indices provides new insights into the trajectories of tidal flats, ecosystem functioning, and sensitivity to physical drivers (wind and tides). Finally, we suggested how the SED and MDS indices may help to explore the future trajectories and climate resilience of intertidal habitats.</p></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"16 1","pages":"Pages 14-25"},"PeriodicalIF":4.0,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48803983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mangrove forests as a nature-based solution for coastal flood protection: Biophysical and ecological considerations","authors":"Rosanna van Hespen ,&nbsp;Zhan Hu ,&nbsp;Bas Borsje ,&nbsp;Michela De Dominicis ,&nbsp;Daniel A. Friess ,&nbsp;Svetlana Jevrejeva ,&nbsp;Maarten G. Kleinhans ,&nbsp;Maria Maza ,&nbsp;Celine E.J. van Bijsterveldt ,&nbsp;Tom Van der Stocken ,&nbsp;Bregje van Wesenbeeck ,&nbsp;Danghan Xie ,&nbsp;Tjeerd J. Bouma","doi":"10.1016/j.wse.2022.10.004","DOIUrl":"10.1016/j.wse.2022.10.004","url":null,"abstract":"<div><p>Nature-based coastal protection is increasingly recognised as a potentially sustainable and cost-effective solution to reduce coastal flood risk. It uses coastal ecosystems such as mangrove forests to create resilient designs for coastal flood protection. However, to use mangroves effectively as a nature-based measure for flood risk reduction, we must understand the biophysical processes that govern risk reduction capacity through mangrove ecosystem size and structure. In this perspective, we evaluate the current state of knowledge on local physical drivers and ecological processes that determine mangrove functioning as part of a nature-based flood defence. We show that the forest properties that comprise coastal flood protection are well-known, but models cannot yet pinpoint how spatial heterogeneity of the forest structure affects the capacity for wave or surge attenuation. Overall, there is relatively good understanding of the ecological processes that drive forest structure and size, but there is a lack of knowledge on how daily bed-level dynamics link to long-term biogeomorphic forest dynamics, and on the role of combined stressors influencing forest retreat. Integrating simulation models of forest structure under changing physical (e.g. due to sea-level change) and ecological drivers with hydrodynamic attenuation models will allow for better projections of long-term natural coastal protection.</p></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"16 1","pages":"Pages 1-13"},"PeriodicalIF":4.0,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44548488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Engineering application of submerged water jets for sediment removal in a tidal riverbed","authors":"Chaiyuth Chinnarasri","doi":"10.1016/j.wse.2022.07.002","DOIUrl":"10.1016/j.wse.2022.07.002","url":null,"abstract":"<div><p>Sediment deposition problems have attracted the interest of engineers and researchers. Several experimental studies have been conducted on scour depth using turbulent jets. However, field observation and monitoring have rarely been reported. This study aimed to eliminate sediments on a tidal riverbed using a prototype device, which consisted of a set of submerged vertical water nozzles and submerged horizontal air nozzles. The effectiveness of the water jet in sediment removal during spring and neap tides was evaluated. The quantitative relationships of dimensionless parameters, such as (1) the relative sediment scour volume versus the number of flows from the jet exit, (2) the relative sediment scour volume versus the relative scour depth, and (3) the relative scour size versus the relative jet intensity, were analyzed. The results showed that the freshwater flowing to the sea affected the sediment scour volume during the falling cycle of spring tides. In contrast, the rising cycle of spring tides retarded the freshwater flow, resulting in a decrease in the sediment scour volume. A steep water surface slope accelerated the river flow and further influenced the cross-flow current around the study area. As a result, a highly diffusive turbulent flow was produced, causing suspended sediments to be rapidly removed from the scour hole center. An increase in the number of flows from the jets led to intensified diffusion of turbulent energy into the flow. The rapidly varying water depth caused jet energy to be dissipated before approaching the riverbed, and it significantly affected the scour process during the spring-tide period. The proposed equations can be used to estimate the scour volume, scour size, and re-suspended sediments in tidal rivers within defined ranges of parameters.</p></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"15 4","pages":"Pages 348-357"},"PeriodicalIF":4.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674237022000461/pdfft?md5=228044e568adb4fa3b303e3e30cb7184&pid=1-s2.0-S1674237022000461-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45824103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Potential hydraulic connectivity of coal mine aquifers based on statistical analysis of hydrogeochemistry","authors":"Xiang Zhao ,&nbsp;Wei-hua Peng ,&nbsp;Kai Chen ,&nbsp;Xin-yi Qiu ,&nbsp;Lin-hua Sun","doi":"10.1016/j.wse.2022.08.004","DOIUrl":"10.1016/j.wse.2022.08.004","url":null,"abstract":"<div><p>Mining activities interfere with the natural groundwater chemical environment, which may lead to hydrogeochemical changes of aquifers and mine water inrush disasters. This study analyzed the hydrochemical compositions of 80 water samples in three aquifers and developed a water source identification model to explore the control factors and potential hydraulic connection of groundwater chemistry in a coal mine. The results showed that the hydrochemical types of the three aquifers were different. The main hydrochemical compositions of the loose-layer, coal-bearing, and limestone aquifers were HCO₃·Cl–Na, SO₄·HCO₃–Na, and SO₄–Na·Ca, respectively. The correlation, Unmix, and factor analyses showed that the hydrochemical composition of groundwater was controlled by the dissolution of soluble minerals (such as calcite, dolomite, gypsum, and halite) and the weathering of silicate minerals. The factor score plot combined with Q-mode cluster analysis demonstrated no remarkable hydraulic connection among the three aquifers in the study area. The water source identification model effectively identified the source of inrush water. Moreover, the mixing ratio model rationally quantified the contributions of the three aquifers to inrush water.</p></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"15 4","pages":"Pages 285-293"},"PeriodicalIF":4.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674237022000643/pdfft?md5=f79a5bfc9132b609f8a0ae628e749851&pid=1-s2.0-S1674237022000643-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48993768","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"An efficient approach for mesoscale fracture modeling of fully-graded hydraulic concrete","authors":"Lei Xu,&nbsp;Lei Jiang,&nbsp;Ye-fei Huang,&nbsp;Qing-wen Ren","doi":"10.1016/j.wse.2022.09.002","DOIUrl":"10.1016/j.wse.2022.09.002","url":null,"abstract":"<div><p>Large coarse aggregates used in fully-graded hydraulic concrete necessitate large specimens for numerical modeling. This leads to a high computational cost for mesoscale modeling and thus slows the development of multiscale modeling of hydraulic mass concrete structures. To overcome this obstacle, an efficient approach for mesoscale fracture modeling of fully-graded hydraulic concrete was developed based on the concept of the governing mesostructure. The mesostructure was characterized by a critical aggregate size. Coarse aggregates smaller than the critical size were homogenized into mortar matrices. Key issues in mesostructure generation of fully-graded hydraulic concrete are discussed, as is the development of mesoscale finite element modeling methodology. The basic concept and implementation procedures of the proposed approach are also described in detail. The numerical results indicated that the proposed approach not only significantly improves the computational efficiency of mesoscale modeling but also captures the dominant fracturing mechanism at the mesoscale and reproduces reasonable fracture properties at the macroscale. Therefore, the proposed approach can serve as a basis for multiscale fracture modeling of hydraulic mass concrete structures.</p></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"15 4","pages":"Pages 337-347"},"PeriodicalIF":4.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674237022000679/pdfft?md5=4eb6264e63a80808744cd5d76f0bd2cb&pid=1-s2.0-S1674237022000679-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47468875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Distribution characteristics and controlling factors of typical antibiotics and antibiotic resistance genes in river networks in western area of Wangyu River, China","authors":"Jing-jing Zhang ,&nbsp;Juan Chen ,&nbsp;Chao Wang ,&nbsp;Pei-fang Wang ,&nbsp;Han Gao ,&nbsp;Yu Hu","doi":"10.1016/j.wse.2022.08.001","DOIUrl":"10.1016/j.wse.2022.08.001","url":null,"abstract":"<div><p>Antibiotics and antibiotic resistance genes (ARGs) pose health risks in aquatic environments because of their persistence and mobility. River networks can provide a perfect opportunity for exploring the occurrence and enrichment of ARGs and antibiotics in freshwater environments. On this basis, the abundances of four types of antibiotics (sulfonamides, quinolones, tetracyclines, and macrolides) and 13 ARGs (<em>sul</em>І, <em>sul</em>ІІ, <em>tet</em>A, <em>tet</em>B, <em>tet</em>O, <em>tet</em>W, <em>qnr</em>A, <em>qnr</em>S, <em>qnr</em>D, <em>erm</em>B, <em>erm</em>F, <em>erm</em>C, and <em>ere</em>A) were measured in the river networks of the west bank of the Wangyu River in China. The spatial distribution and temporal variation of these antibiotics and ARGs were characterized, and their controlling factors were analyzed. All four types of antibiotics were detected with high frequencies between 41% and 100%. Quinolone antibiotics exhibited the highest average concentration (286.53 ng/L). The concentrations of quinolones, tetracyclines, and macrolides were significantly higher in the winter than in the summer, whereas the concentration of sulfonamides was higher in wet periods than in dry periods. Of the 13 ARGs, <em>sul</em>I was the most abundant (1.28 × 10⁵ copies per milliliter), followed by <em>sul</em>II and <em>tet</em>O (5.41 × 10⁴ and 4.45 × 10⁴ copies per milliliter, respectively). The canonical correspondence analysis showed that environmental factors, including dissolved oxygen, water temperature, total nitrogen, pH, and total phosphorus, had significant effects on the abundance of ARGs. <em>sul</em>І, <em>sul</em>ІІ, <em>tet</em>A, and <em>tet</em>B were significantly correlated with <em>16S</em> ribosomal RNA sequences, indicating that the bacterioplankton community might affect the distribution of ARGs. The correlation heat map analysis showed that the spread of ARGs was influenced by specific bacterial groups, such as Acidobacteria and Cyanobacteria, indicating that these bacterioplankton may be the hosts of environmental ARGs.</p></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"15 4","pages":"Pages 318-327"},"PeriodicalIF":4.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674237022000618/pdfft?md5=26d474ce99fcb0f5712cd9cdcef64e15&pid=1-s2.0-S1674237022000618-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42346418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Chromium adsorption on surface activated biochar made from tannery liming sludge: A waste-to-wealth approach","authors":"Md. Abul Hashem ,&nbsp;Sofia Payel ,&nbsp;Sadia Mim ,&nbsp;Md. Anik Hasan ,&nbsp;Md. Shahruk Nur-A-Tomal ,&nbsp;Md. Aminur Rahman ,&nbsp;Majher I. Sarker","doi":"10.1016/j.wse.2022.09.001","DOIUrl":"10.1016/j.wse.2022.09.001","url":null,"abstract":"<div><p>In a beamhouse, liming plays a key role in the removal of hair/wool and epidermis, but problems are created when waste liming sludge is discharged to the environment. The treatment of tannery wastewater is another major challenge to the industry. In this study, thermally-activated biochars derived from liming sludge were studied for their effective adsorption of chromium (Cr) from the tannery wastewater. The thermally activated biochars (B500, B550, B600, and B650) were prepared at different temperatures from the liming sludge. Their characteristics before and after the treatment were investigated using Fourier transform infrared spectroscopy, energy dispersive X-ray spectroscopy, Brunauer–Emmett–Teller, and scanning electron microscopy analyses. The related functional groups (C–H, O–H, C–N, and =C–O) and chromium adsorption capacity were determined according to the surface morphology, element contents (C, O, Ca, Na, Al, Mg, and Si), surface area (5.8–9.2 m²/g), pore size (5.22–5.53 nm), and particle size (652–1 034 nm) of the experimental biochars. The biochar originated at 600°C from the tannery liming sludge (B600) had a greater surface area with a chromium adsorption capacity of 99.8% in comparison to B500, B550, and B650 biochars. This study developed an innovative way of utilizing liming sludge waste to minimize the pollution load and wastewater treatment cost in the tannery industry.</p></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"15 4","pages":"Pages 328-336"},"PeriodicalIF":4.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674237022000667/pdfft?md5=62f6980610d8648bb5a0d2c68ff2807e&pid=1-s2.0-S1674237022000667-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49158404","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Application of multi-criteria decision-making methods to identification of soil moisture monitoring sites in an urban catchment in South Australia","authors":"Dinesh Chammika Ratnayake,&nbsp;Guna A. Hewa,&nbsp;David J. Kemp,&nbsp;Alaa A. Ahmed","doi":"10.1016/j.wse.2022.09.003","DOIUrl":"10.1016/j.wse.2022.09.003","url":null,"abstract":"<div><p>When choosing sites for monitoring of soil moisture for hydrological purposes, a suitable process that considers the factors influencing soil moisture level should be followed. In this study, two multi-criteria decision-making (MCDM) methods, the multi-influencing factor (MIF) method and the analytical hierarchy process (AHP) method, were used to identify the optimal soil moisture monitoring (SMM) sites in the Dry Creek Catchment in South Australia. The most representative areas for nine SMM sites were obtained using the MIF method, considering the factors of rainfall, soil type, land use, catchment slope, elevation, and upslope accumulated area (UAA). The AHP method was used to select the optimal sites using the site-specific criteria. 30.3% of the catchment area in the Australian Water Resources Assessment Landscape (AWRA-L) Grid_DC2 can be considered acceptable as representative area with the MIF method. Four potential sites were evaluated for each AWRA-L grid using the relative weights of the site-specific criteria with the AHP method. The Grid_DC2 required two sites that had the highest overall weight chosen with the AHP analysis. The procedure was repeated for the remaining four AWRA-L grids within the study area to select the required SMM sites.</p></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"15 4","pages":"Pages 294-304"},"PeriodicalIF":4.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674237022000680/pdfft?md5=f2c45ee87c971f1ea9fdb862c193f1d7&pid=1-s2.0-S1674237022000680-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41754150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Packing, compressibility, and crushability of rockfill materials with polydisperse particle size distributions and implications for dam engineering","authors":"Chao-min Shen ,&nbsp;Si-hong Liu ,&nbsp;Liu-jiang Wang ,&nbsp;Ji-du Yu ,&nbsp;Hao Wei ,&nbsp;Ping Wu","doi":"10.1016/j.wse.2022.07.003","DOIUrl":"10.1016/j.wse.2022.07.003","url":null,"abstract":"<div><p>In rockfill dam engineering, particle breakage of rockfill materials is one of the major factors resulting in dam settlement. In this study, one-dimensional compression tests on a series of coarse granular materials with artificially-graded particle size distributions (PSDs) were carried out. The tests focused on understanding the role of initial PSDs in the dense packing density, compressibility and crushability of coarse granular materials. The effects of fractal dimension (<em>D</em>) and size polydispersity (<em>θ</em>) of PSDs were quantitatively analyzed. Two different loading stages were identified from the logarithms of the stress–strain relationships, with the turning point marked as the yield stress. A similar effect of initial PSDs was observed on the packing density and low-pressure modulus of coarse granular materials. The packing density and low-pressure modulus increased monotonically with <em>θ</em>, and their peak values were attained at a <em>D</em> value of approximately 2.2. However, there was no unique correspondence between the dense packing density and low-pressure modulus. The particle breakage was influenced differently by the initial PSDs, and it decreased with the values of <em>D</em> and <em>θ</em>. The emergence of the unique ultimate state was also identified from both the compression curves and PSDs of the samples after the tests. The potential implications of the test results in the design of both low and high rockfill dams were also demonstrated.</p></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"15 4","pages":"Pages 358-366"},"PeriodicalIF":4.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1674237022000606/pdfft?md5=51babb4146bc3ff08b1a0faea3edb8f1&pid=1-s2.0-S1674237022000606-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41705555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of Fe3O4 nanoparticles on magnetic xerogel composites for enhanced removal of fluoride and arsenic from aqueous solution","authors":"Sasirot Khamkure ,&nbsp;Victoria Bustos-Terrones ,&nbsp;Nancy Jakelin Benitez-Avila ,&nbsp;María Fernanda Cabello-Lugo ,&nbsp;Prócoro Gamero-Melo ,&nbsp;Sofía Esperanza Garrido-Hoyos ,&nbsp;Juan Marcos Esparza-Schulz","doi":"10.1016/j.wse.2022.07.001","DOIUrl":"10.1016/j.wse.2022.07.001","url":null,"abstract":"<div><p>Fe₃O₄ magnetic xerogel composites were prepared by polycondensation of resorcinol (R)–formaldehyde reaction via a sol–gel process in an aqueous solution through varying the molar ratio of Fe₃O₄ nanoparticles (MNPs), catalyst (C), and water (W) content. MNPs were obtained by co-precipitation (MC), oxidation of iron salts (MO), or solvothermal synthesis (MS). Both MNPs and magnetic xerogels were examined regarding the performance of arsenic and fluoride removal in a batch system. The MC-based MNPs had higher adsorption capacities for both fluoride (202.9 mg/g) and arsenic (3.2 mg/g) than other MNPs in optimum conditions. The X-ray diffraction, Fourier transform infrared spectroscopy, and energy-dispersive X-ray spectroscopy confirmed that Fe was composed into the polymeric matrix of magnetic xerogels that contained 0.59%–4.42% of Fe with a molar ratio of MNPs (M) to R between 0.01 and 0.10. With low R/C and optimum M/R ratios, an increase in the surface area of magnetic xerogels affected the fluoride and arsenic adsorption capacities. The magnetic xerogel composites with the MC-based MNPs prepared at a fixed R/C ratio (100) and at different R/W (0.05–0.06) and M/R (0.07–0.10) ratios had a high arsenic removal efficiency of 100% at an As(V) concentration of 0.1 mg/L and pH of 3.0. The maximum adsorption capacities of magnetic xerogels were approximately five times higher than those of the xerogels without MNP composites. Therefore, Fe₃O₄ nanoparticles enhanced the adsorption of arsenate and fluoride. The variations of alkaline catalyst and water content significantly affected the resulting properties of textural and surface chemistry of magnetic xerogel composites.</p></div>","PeriodicalId":23628,"journal":{"name":"Water science and engineering","volume":"15 4","pages":"Pages 305-317"},"PeriodicalIF":4.0,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S167423702200045X/pdfft?md5=7051493c57b82f2f7c37ee6b215d7dfe&pid=1-s2.0-S167423702200045X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49549865","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}