Sustainable Chemistry and Pharmacy最新文献

{"title":"Polymorphic transformation of seashell waste to develop smart composite films: An environmentally benign and sustainable approach","authors":"Anushree S. Bhat ,&nbsp;Sumanta Sahoo ,&nbsp;Madhusudhana M. Devadiga ,&nbsp;Nannan Wang ,&nbsp;Oluwafunmilola Ola ,&nbsp;Ankur Sood ,&nbsp;Santosh K. Tiwari","doi":"10.1016/j.scp.2025.102165","DOIUrl":"10.1016/j.scp.2025.102165","url":null,"abstract":"<div><div>Unremitting escalation in global population has compounded the overall demand for food, including seafood, leading to an accumulation of waste seashells causing landfills, which poses serious environmental concerns. To confront this challenge, the present work aims to utilize seashells as a potential candidate to serve as fillers during the fabrication process of polymer films. This study presents an extensive high-energy ball-milling process of seashells using planetary ball-milling for 36h. The study demonstrates a polymorphic transformation of calcium carbonate (CaCO₃) present in the seashell from calcite to aragonite. Furthermore, these processed seashells are incorporated as fillers in the polyvinyl alcohol (PVA) matrix to create a composite film using the electrospinning technique. The milled seashells and the corresponding fabricated films are systematically evaluated through various physicochemical evaluations, including microscopic and spectroscopic methods, to demonstrate the accumulation of finer seashell particles within the hollow fiber. The formation of seashell particles as a function of processing time has been comprehensively studied in this work. Additionally, the fabricated films were also examined for their antibacterial activities. The work demonstrates an environmentally benign and sustainable approach to making biocompatible and antibacterial films, with applications in the fields of agriculture, food packaging, and food science.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"47 ","pages":"Article 102165"},"PeriodicalIF":5.8,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144903110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Study on the coupling treatment of wool fiber with laccase/dopamine","authors":"Ye Wu ,&nbsp;Yunli Wang ,&nbsp;Weilin Xu","doi":"10.1016/j.scp.2025.102175","DOIUrl":"10.1016/j.scp.2025.102175","url":null,"abstract":"<div><div>Wool, a natural protein fiber, is widely utilized in the textile industry due to its exceptional warmth retention and comfort. Nevertheless, the scale structure of wool fibers often results in felting shrinkage during processing and practical use. To address this, we propose a laccase/dopamine coupling treatment approach for wool fibers. Laccase, an eco-friendly enzyme, effectively removes scales from wool fibers. Concurrently, dopamine, a biomimetic material, is oxidized by laccase to form a polydopamine (PDA) coating on the wool fibers, thereby mitigating damage caused by scale removal. <strong>Through orthogonal optimization, key parameters were established: laccase concentration (1800 U/L), dopamine concentration (6 g/L), and treatment time (150 min). This optimized process significantly enhanced performance: breaking strength increased by 8.91 % (from 19.42 cN to 21.15 cN), and felting ball volume expanded by 19.62 % (from 14.73 cm³ to 17.62 cm³).</strong> The instrument analysis results demonstrate that laccase efficiently removes wool scales and collaborates with dopamine to establish a PDA coating, thereby augmenting the mechanical properties of the fibers. The effects of modification treatments on the dyeing properties and fastness of wool fibers, along with the long-term durability of the modified wool, were systematically investigated. In addition, aspects concerning the scalability, reproducibility, and commercial viability of the treatment process were discussed in detail. The laccase/dopamine coupling treatment method presents an eco-friendly strategy for wool processing, enhancing shrink resistance and mechanical properties while aligning with the principles of green chemistry and sustainable development, with broad application potential.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"47 ","pages":"Article 102175"},"PeriodicalIF":5.8,"publicationDate":"2025-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144903022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Clove essential oil impregnated cellulose paper as a sustainable sorbent for rapid microextraction of sedative drugs in complex beverages matrices","authors":"Lateefa A. Al-Khateeb","doi":"10.1016/j.scp.2025.102171","DOIUrl":"10.1016/j.scp.2025.102171","url":null,"abstract":"<div><div>A novel disposable in-tip cellulose paper (DICP) device, functionalized with clove essential oil (CEO), was developed for the microextraction of five sedative and antihistaminic drugs viz. chlorpheniramine, pheniramine, ketamine, diazepam, and lorazepam; from beverages commonly encountered in drug-facilitated crimes (DFCs), including fruit juice, tea, milk, and water. The DICP device was fabricated by dip-coating cellulose paper (CP) with 2 % CEO (in hexane), cutting into rectangular strips, and inserting them into a 1000 μL micropipette tip. The extraction involved 30 aspiration–dispensing cycles for analyte adsorption, followed by 20 cycles for desorption using 0.5 mL ethanol. The method exhibited excellent linearity (0.1–5 μg mL⁻¹; R² &gt; 0.994) with limits of quantification between 0.071 and 0.094 μg mL⁻¹, accuracy ranging from 85.9 % to 111.9 %, and intra- and inter-day precision below 8.7 % and 14.7 % RSD, respectively. Matrix effects remained below 13 % across all beverage types. The extraction mechanism is based on hydrophobic, hydrogen bonding, and π–π interactions between CEO and the analytes. The DICP platform supports high-throughput operation (12 samples/hour) and requires no auxiliary equipment. It is also highly cost-effective, as a single cellulose disc (150 mm diameter) yields approximately 30 extraction strips. Green analytical performance metrics; CACI (85), ComplexMoGAPI (85), and AGREE (0.64); underscore the method's sustainability, simplicity, and practicality. Applicability was further demonstrated through blind sample analysis at multiple concentration levels, simulating real forensic scenarios and confirming the method's reliability and operational feasibility for routine casework.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"47 ","pages":"Article 102171"},"PeriodicalIF":5.8,"publicationDate":"2025-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144895919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Green and sustainable utilization of underutilized exudate gums from the Himalayan region: Advances in nutraceutical and pharmaceutical applications","authors":"Abhishek Anand ,&nbsp;Pratiksha ,&nbsp;Tridip Boruah ,&nbsp;Arun Kumar Gupta ,&nbsp;Hemanta Chutia ,&nbsp;Bindu Naik ,&nbsp;Vijay Kumar","doi":"10.1016/j.scp.2025.102160","DOIUrl":"10.1016/j.scp.2025.102160","url":null,"abstract":"<div><div>Exudate gums-natural polysaccharides secreted by trees and shrubs under stress-are widely utilized in food, pharmaceutical, and cosmetic industries due to their diverse functional properties. However, exudate gums sourced from the Himalayan region remain largely underutilized and underexplored. This review uniquely focuses on the green and sustainable utilization of Himalayan exudate gums such as gum ghatti, karaya, kondagogu, and tragacanth, which are rich in bioactive compounds. Unlike conventional reviews, it critically compiles recent findings on their nutraceutical and pharmacological potentials, including antioxidant, antimicrobial, and anti-diabetic activities. The review further emphasizes their low toxicity, biodegradability, cost-effectiveness, and applicability as eco-friendly additives in functional foods, pharmaceuticals, and biomedical fields. Importantly, it discusses novel advancements in modification technologies and synergistic blending with other hydrocolloids-that have significantly enhanced the functional, rheological, and bioactive attributes of exudate gums. These technological interventions have expanded their applicability in emerging areas like controlled drug delivery, tissue engineering, and sustainable packaging. Additionally, the review highlights the potential of commercializing these undervalued biopolymers to contribute to food security and regional economic development. By consolidating evidence from studies conducted between 2010 and 2025, this work provides a comprehensive roadmap for advancing research and promoting the sustainable industrial application of Himalayan exudate gums.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"47 ","pages":"Article 102160"},"PeriodicalIF":5.8,"publicationDate":"2025-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144903021","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Assessing the carbon reduction potential of high-performance concrete in urban construction","authors":"Cai Wu ,&nbsp;Peiyuan Zhou ,&nbsp;Qing Li ,&nbsp;Juan Li ,&nbsp;Daopei Zhu","doi":"10.1016/j.scp.2025.102170","DOIUrl":"10.1016/j.scp.2025.102170","url":null,"abstract":"<div><div>This study evaluates the environmental and economic performance of four high-performance concretes (HPCs) in urban construction, aiming to support structural optimization and low-carbon development. The selected HPCs include Ultra-High Performance Concrete (UHPC), Coarse Aggregate UHPC (UHPC-CA), Ultra-High Performance Fiber-Reinforced Concrete (UHPFRC), and Ultra-High Performance Geopolymer Concrete (UHPGC). A life-cycle-based evaluation framework is established based on a real 11-story reinforced concrete frame column system. Four high-performance concrete replacement schemes are assessed under equivalent load-bearing requirements to compare carbon emissions, material costs, and structural performance from material production to on-site construction. Results show that UHPC-CA reduces emissions by 17 % and cost by 8 %, while maintaining mechanical capacity. UHPFRC improves axial capacity by 142.5 % with a moderate 8 % cost increase and an overall emission reduction. UHPGC achieves the highest carbon savings, reducing emissions by 35.3 % through the use of a cement-free geopolymer binder. This study is among the first to combine environmental, economic, and structural indicators in a comparative assessment of multiple HPCs within realistic construction scenarios. It also incorporates regional emission and cost data from five major Chinese cities, enhancing the practical relevance of the results. The findings provide valuable insights for the promotion of green concrete technologies and the implementation of sustainable urban building strategies.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"47 ","pages":"Article 102170"},"PeriodicalIF":5.8,"publicationDate":"2025-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144893123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synergistic ionic liquid-silver catalysis for ambient CO2 conversion to α-alkylidene cyclic carbonates","authors":"Ruiyu Zhang ,&nbsp;Xinyi Sun ,&nbsp;Jingshun Zhang ,&nbsp;Li Wang ,&nbsp;Jinglai Zhang","doi":"10.1016/j.scp.2025.102172","DOIUrl":"10.1016/j.scp.2025.102172","url":null,"abstract":"<div><div>The carboxylative cyclization of propargylic alcohols with CO₂ constitutes an atom-economical approach for CO₂ utilization, yielding versatile <em>α</em>-alkylidene cyclic carbonates that serve as key intermediates in pharmaceutical synthesis and polymer production. Despite its synthetic value, this transformation typically requires harsh reaction conditions and exhibits unsatisfied efficiency. It is necessary to develop the advanced catalytic systems. A series of glutarimide-based ionic liquids were developed and their synergistic effects with various silver co-catalysts were evaluated. The [BZTMA][GLU]/Ag₂CO₃ system demonstrated exceptional performance, achieving 97.6 % yield under remarkably mild conditions (6 mol% Ag₂CO₃, 30 °C, 0.1 MPa CO₂). Comprehensive structure-activity relationship studies revealed two critical parameters governing catalytic efficiency: the ionic interaction falls within the range of −5.20 to −11.26 kcal mol⁻¹ and the CO₂ absorption exceeds 1.33 mol for per mol of ionic liquid. Mechanistic investigations combining multinuclear ¹H NMR, ¹³C NMR and density functional theory (DFT) calculations elucidated the cooperative activation pathway. The ionic liquid facilitates substrate activation through hydrogen bonding, while the silver complex preferentially activates the alkyne moiety, collectively enabling efficient cyclization through a well-orchestrated catalytic cycle.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"47 ","pages":"Article 102172"},"PeriodicalIF":5.8,"publicationDate":"2025-08-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144889290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Interactive co-pyrolysis of end-of-life tires and plastic wastes: A combined TGA-IR-MS and COMSOL investigation","authors":"Ahmad Yaghi,&nbsp;Labeeb Ali,&nbsp;Mohammednoor Altarawneh","doi":"10.1016/j.scp.2025.102167","DOIUrl":"10.1016/j.scp.2025.102167","url":null,"abstract":"<div><div>The accumulation of waste tires (WT) poses a significant environmental challenge due to the rubbery structure, which makes them difficult to store, digest, or recycle in typical waste recycling facilities. Thermal degradation of WT has often been investigated as a potential waste-to-energy approach, but products obtained from the pyrolysis of tires render them not suitable for direct use. Therefore, this research highlights products and degradation behavior of WT pyrolysis and their co-pyrolysis with plastic wastes such as polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET). The integrated TGA-IR-MS system effectively mimics real-life thermal degradation and gas evolution processes by sequentially analyzing the decomposition behavior, gaseous emissions, and final pyrolysis byproducts, which resemble those found in large-scale industrial thermal recycling systems. The results revealed that plastic waste alters the thermal profile of WT, reduces residue formation, and promotes the conversion of D-limonene into BTX compounds (benzene, toluene, xylene) via radical mechanisms. Moreover, the experimental setup was modeled using COMSOL to understand the temperature profile. Outcomes reported herein address multiple Sustainable Development Goals (SDGs), specifically related to affordable and clean energy and sustainable cities (7, 11, and 13).</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"47 ","pages":"Article 102167"},"PeriodicalIF":5.8,"publicationDate":"2025-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144863198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Development of thermally efficient high volume fly ash-rubberized concrete using nano silica: A sustainable solution for energy-sensitive construction","authors":"Musa Adamu ,&nbsp;Ranjit J. Singh ,&nbsp;Anuja Charpe ,&nbsp;Ashwin Raut ,&nbsp;Yasser E. Ibrahim ,&nbsp;Hani Alanazi","doi":"10.1016/j.scp.2025.102169","DOIUrl":"10.1016/j.scp.2025.102169","url":null,"abstract":"<div><div>The construction industry faces increasing pressure to adopt sustainable materials that not only minimize environmental impact but also improve thermal efficiency in buildings and pavements. Conventional concrete, despite its structural strength, is thermally inefficient and contributes significantly to CO₂ emissions. While previous studies have explored either high-volume fly ash (HVFA) or rubberized concrete independently, this study presents a novel integration of HVFA with crumb rubber (CR) and nano silica (NS) to achieve both environmental and thermal performance goals. Additionally, it incorporates computational fluid dynamics (CFD) simulation to evaluate heat transfer behavior—an approach not commonly employed in similar material systems. This study addresses these limitations by developing a High-Volume Fly Ash Rubberized Concrete (HVFA-RC) incorporating 50 % fly ash as partial cement replacement, crumb rubber (0–30 %) as fine aggregate substitute, and 2 % nano silica by weight of binder to improve early-age strength and microstructure. Five mix designs were tested for mechanical, durability, and thermal properties, and further analyzed using CFD-based simulations in ANSYS CFX. Results revealed that increasing CR content reduced compressive strength and increased porosity; however, the addition of NS mitigated these effects by densifying the matrix. The optimized mix (C30N3) exhibited the lowest thermal conductivity (0.87 W/m·K), reduced thermal expansion (6.17 × 10⁻⁶/°C), and minimal heat transfer coefficient (5 W/m²·K), indicating superior insulation performance. This research demonstrates the practical feasibility of producing multifunctional concrete from industrial by-products and nanomaterials. The proposed composite offers enhanced thermal resistance and sustainability, making it a promising candidate for energy-efficient and thermally sensitive construction applications.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"47 ","pages":"Article 102169"},"PeriodicalIF":5.8,"publicationDate":"2025-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144863199","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-efficiency and recyclable non-ionic ternary hydrophobic deep eutectic solvent for vortex-assisted microextraction of diclofenac sodium from water","authors":"Shuli Pan ,&nbsp;Kai Chen ,&nbsp;Sa Sun,&nbsp;Yinyin Qian,&nbsp;Kaijia Xu","doi":"10.1016/j.scp.2025.102163","DOIUrl":"10.1016/j.scp.2025.102163","url":null,"abstract":"<div><div>This work presents a novel vortex-assisted liquid-liquid microextraction (VA-LLME) technique based on non-ionic ternary hydrophobic deep eutectic solvents (DESs) for the highly efficient extraction of diclofenac sodium (DIC). Departing from conventional binary systems, four kinds of ternary hydrophobic DES (two acid-based two alcohol-based) were systematically designed. Among them, menthol:decanoic acid:oleic acid ([Men][DA][OA]) with a molar ratio of 1:2:1 was selected as the extractant, with its structural characteristics confirmed through Fourier transform-infrared spectroscopy (FT-IR) and ¹H Nuclear Magnetic Resonance (¹H NMR) analysis. The effects of ionic strength, solution pH, vortex time, and DES volume were investigated. The optimal extraction conditions were obtained by RSM optimization and the extraction efficiency could reach 99.7 %. In addition, the [Men][DA][OA] (1:2:1) demonstrated exceptional recyclability through back-extraction regeneration, maintaining extraction efficiency of 96.3 % after six successive cycles. The recovery experiments were also carried out and satisfactory recoveries (82.3 %–97.2 %) were obtained with relative standard deviations below 3.6 %. The extraction mechanism was investigated through the use of ¹H NMR, X-ray photoelectron spectroscopy (XPS), and fluorescence microscope. The results indicated that the formation of water-in-DES (W/DES) microstructure played a crucial role in the extraction process. Furthermore, the greenness of the developed method was confirmed by AGREEprep and ComplexGAPI tools. This work establishes an efficient and sustainable microextraction platform that combines the advantages of ternary DES design with energy-efficient vortex-assisted mixing, demonstrating significant potential for pharmaceutical contaminant remediation in environmental matrices.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"47 ","pages":"Article 102163"},"PeriodicalIF":5.8,"publicationDate":"2025-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144864404","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sustainable hexavalent chromium removal from aqueous solutions using novel plant-based biocoagulants: Comparative performance, mechanism elucidation, and economic evaluation","authors":"Ali Zourif ,&nbsp;Salma Kouniba ,&nbsp;Konouz Hamidallah ,&nbsp;Nisrine Nouj ,&nbsp;Mohamed Elsenety ,&nbsp;Mohamed El Guendouzi","doi":"10.1016/j.scp.2025.102168","DOIUrl":"10.1016/j.scp.2025.102168","url":null,"abstract":"<div><div>This study evaluates the effectiveness of three natural biocoagulants; walnut husk powder, avocado seed powder, and palm petiole waste for removing hexavalent chromium from aqueous solutions. Key operational parameters, including pH, coagulant dose, and particle size, were optimized using the Box-Behnken design. The biocoagulants-flocculants were comprehensively characterized before and after treatment using techniques such as XRD, FTIR, XRD, SEM-EDX, and ZP measurements to elucidate the mechanisms of chromium removal. Under optimized conditions, all biocoagulants-flocculants demonstrated significant removal efficiencies: walnut husk powder (92.47 %), avocado seed powder (ASP, 94.09 %), and palm petiole waste (PPW, 98.56 %). Cost analysis identified ASP as the most economical option, with a treatment cost of 0.0015 USD/m³. Reusability studies revealed that PPW retained the highest performance over multiple cycles, achieving 66.81 % removal efficiency after five reuse cycles. These findings highlight the efficacy, mechanisms, and scalability of these biocoagulants-flocculants as sustainable solutions for hexavalent chromium removal in water treatment applications.</div></div>","PeriodicalId":22138,"journal":{"name":"Sustainable Chemistry and Pharmacy","volume":"47 ","pages":"Article 102168"},"PeriodicalIF":5.8,"publicationDate":"2025-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144863197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}