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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry最新文献

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A Deep Analysis on Widely Used Condensation Route for Preparing Aminophosphines: Synthesis and Spectral Characterization of an Aminobis(chlorophosphine), (NC4H8N)[P(i-Pr2N)Cl]2 广泛应用的缩合合成氨基膦途径的深入分析:氨基合成物(氯膦)(NC4H8N)[P(i-Pr2N)Cl]的合成与光谱表征
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-14 DOI: 10.1080/15533174.2015.1040163
J. Gopalakrishnan
{"title":"A Deep Analysis on Widely Used Condensation Route for Preparing Aminophosphines: Synthesis and Spectral Characterization of an Aminobis(chlorophosphine), (NC4H8N)[P(i-Pr2N)Cl]2","authors":"J. Gopalakrishnan","doi":"10.1080/15533174.2015.1040163","DOIUrl":"https://doi.org/10.1080/15533174.2015.1040163","url":null,"abstract":"Aminophosphines are useful as ligands and the most convenient method to synthesize is the condensation route that is straightforward, simple and easy to execute and get the products. RxPClz (x = 0–2, y = 1–3) and amines are widely used as phosphorus and nitrogen substrates. Vast examples such as Phx(R2N)yPClz [x < 3; y > 0; z < 3] are available in the literature which used condensation route. A deep analysis was carried out on this route and the author analyzes various parameters that affect product formation, purity, and yield. Using the optimized conditions, (NC4H8N)[P(i-Pr2N)Cl]2 was prepared and spectrally characterized.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75069046","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Halogenation Reactions of Phosphiniminocyclotrithiazenes: Search for New Inorganic Heterocycles 膦亚胺环三噻吩的卤化反应:寻找新的无机杂环
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-14 DOI: 10.1080/15533174.2015.1066804
J. Gopalakrishnan, U. Swarnalatha, S. M. Rao
{"title":"Halogenation Reactions of Phosphiniminocyclotrithiazenes: Search for New Inorganic Heterocycles","authors":"J. Gopalakrishnan, U. Swarnalatha, S. M. Rao","doi":"10.1080/15533174.2015.1066804","DOIUrl":"https://doi.org/10.1080/15533174.2015.1066804","url":null,"abstract":"Though the chemistry of tetrasulfur tetranitride is very well developed and studied, that of phosphiniminocyclotrithiazenes is not. Reactions of symmetrically substituted R3PN-S3N3 [R = Ph, OC4H8N, MeNC4H8N, and C5H10N] with halogens and halogen sources (SO2Cl2, PhICl2, Br2, and I2) gave rise to various products. In case of R = Ph, the ring-retained product, while for others, ring-degraded products were obtained. A novel cyclotrithiazene heterocycle, [Ph3PN]2S3N3+I3− containing a tetracoordinated sulfur atom with two phosphinimino substituents was obtained, which was further established by IR, NMR (1H-, 13C-, and 31P-) and elemental analysis. Cyclic voltammetric studies indicated the redox behavior as well as the presence of triiodide. Theoretical calculations clearly indicate the residence of maximum positive charge (close to unity) on the tetracoordinated sulfur atom.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84160695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrothermal Synthesis, Crystal Structure, and Luminescent Property of a New Cd(II) Coordination Polymer With Three-Fold Interpenetrated pcu Topology 一种具有三层互穿pcu拓扑结构的新型Cd(II)配位聚合物的水热合成、晶体结构和发光性能
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-14 DOI: 10.1080/15533174.2015.1004452
Xiuling Feng, Wanping Chen, B. Xiang
{"title":"Hydrothermal Synthesis, Crystal Structure, and Luminescent Property of a New Cd(II) Coordination Polymer With Three-Fold Interpenetrated pcu Topology","authors":"Xiuling Feng, Wanping Chen, B. Xiang","doi":"10.1080/15533174.2015.1004452","DOIUrl":"https://doi.org/10.1080/15533174.2015.1004452","url":null,"abstract":"A new three-dimensional (3D) coordination polymer, [Cd(pda)(bib)0.5] n(1), [H2pda=1,4-phenylenediacetic acid and bib=1,4-bis(2-methyl-imidazol-1-yl) butane] was prepared by hydrothermal syntheses and characterized by single-crystal X-ray diffraction, FT-IR spectroscopy, and elemental analysis. Crystal structure determination revealed that complex 1 features a threefold interpenetrated pcu framework. Furthermore, the luminescent property for complex 1 is also investigated in solid state at room temperature.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91243484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, Spectroscopic elucidation, Pharmacological and docking studies of N, N'-bis(pyridin-4 ylcarbonyl)benzene-1,2-dicarboxamide ligand based bioactive Copper(II) complexes N, N'-双(吡啶-4羰基)苯-1,2-二羧基酰胺配体生物活性铜(II)配合物的合成、光谱解析、药理及对接研究
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-05 DOI: 10.1080/15533174.2015.1137040
M. A. Malik, R. Sheikh, M. Wani, S. Al‐Thabaiti, Salman A. Khan
{"title":"Synthesis, Spectroscopic elucidation, Pharmacological and docking studies of N, N'-bis(pyridin-4 ylcarbonyl)benzene-1,2-dicarboxamide ligand based bioactive Copper(II) complexes","authors":"M. A. Malik, R. Sheikh, M. Wani, S. Al‐Thabaiti, Salman A. Khan","doi":"10.1080/15533174.2015.1137040","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137040","url":null,"abstract":"","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/15533174.2015.1137040","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"59884916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Magnetism of a Dimeric Complex 二聚体配合物的合成及磁性
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-05 DOI: 10.1080/15533174.2015.1137043
Lu Lu, Wang Jun, Xiren Wu, B. Xie, Yu Wu
{"title":"Synthesis and Magnetism of a Dimeric Complex","authors":"Lu Lu, Wang Jun, Xiren Wu, B. Xie, Yu Wu","doi":"10.1080/15533174.2015.1137043","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137043","url":null,"abstract":"A new Cu-based complex of {[Cu2(L)2(phen)2(NO3)]·NO3} (1) (HL = p-hydroxy phenylacetic acid, phen = 1,10-phenanthroline) has been synthesized and structurally characterized. Single-crystal X-ray analyses reveal that compound 1 has a dinuclear Cu(II) unit linking by two carboxylate groups and one nitrate group. The chelating N-donor ligand with phen binds to Cu(II) centers and there is weaker Cu-Cu bond interaction as well. Furthermore, the magnetic property of compound 1 was discussed in detail.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89517908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Syntheses, Structures, and Luminescence of Two Complexes 两种配合物的合成、结构和发光
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-05 DOI: 10.1080/15533174.2015.1137041
Z. Xiang, Tao Wang, Jun Wang, Yu Wu, Yanchun Sun, B. Xie
{"title":"Syntheses, Structures, and Luminescence of Two Complexes","authors":"Z. Xiang, Tao Wang, Jun Wang, Yu Wu, Yanchun Sun, B. Xie","doi":"10.1080/15533174.2015.1137041","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137041","url":null,"abstract":"Two new complexes, namely {[La(L3)3(2,2′-bipy)]n·H2O} (1), and [Zn(L3)2(4,4′-bipy)]n (2) (HL3 = o-hydroxy phenylpropionic acid, 2,2′-bipy = 2,2′-bipyridine and 4,4′-bipy = 4,4′-bipyridine), have been synthesized and structurally characterized by single-crystal diffraction analysis. 1 has a dinuclear motif, which is further linked into 2D layer via the hydrogen bond interactions. 2 shows 1D covalent zigzag chain constructed by 4,4′-bipy ligands. Furthermore, the luminescent properties of 1–2 show the mild emissive power and feature.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79730322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Synthesis, Crystal Structures, and Insulin Enhancement of Vanadium(V) Complexes Derived From 2-Bromo-N’-(2-hydroxybenzylidene)benzohydrazide 2-溴- n ' -(2-羟基苄基)苯并肼衍生钒(V)配合物的合成、晶体结构和胰岛素增强
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-05 DOI: 10.1080/15533174.2015.1137039
Yubin Sun, Qinglan Xie, Wei Li, Yi Ding, Y. Ye
{"title":"Synthesis, Crystal Structures, and Insulin Enhancement of Vanadium(V) Complexes Derived From 2-Bromo-N’-(2-hydroxybenzylidene)benzohydrazide","authors":"Yubin Sun, Qinglan Xie, Wei Li, Yi Ding, Y. Ye","doi":"10.1080/15533174.2015.1137039","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137039","url":null,"abstract":"Two new mononuclear vanadium(V) complexes with the formula [VOLX] [X = benzohydroxamate for 1, and X = 8-hydroxyquinoline for 2; L = 2-bromo-N’-(2-hydroxybenzylidene)benzohydrazide], have been prepared. The complexes have been characterized by physicochemical methods and single crystal X-ray determination. The V atoms in both complexes are coordinated by the three donor atoms of L, two donor atoms of X, and one oxo group, forming octahedral coordination. Insulin-mimetic tests on C2C12 muscle cells using biovision glucose assay indicates that the complexes significantly stimulated cell glucose utilization with cytotoxicity at 0.10 g L−1.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74324759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Effect Ancillary Ligands on the Zn(II) Complexes: Syntheses, Structure, and Luminescence 辅助配体对Zn(II)配合物的影响:合成、结构和发光
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-05 DOI: 10.1080/15533174.2015.1137042
Z. Xiang, Tao Wang, Lu Lu, Xiren Wu, Yanchun Sun
{"title":"Effect Ancillary Ligands on the Zn(II) Complexes: Syntheses, Structure, and Luminescence","authors":"Z. Xiang, Tao Wang, Lu Lu, Xiren Wu, Yanchun Sun","doi":"10.1080/15533174.2015.1137042","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137042","url":null,"abstract":"Two Zn-based complexes, namely {[Zn(L3)(2,2′-bipy)(H2O)2]n·L3} (1), and [Zn(L3)2(phen)(H2O)] (2) (HL3 = 3-(4-hydroxyphenyl)propanoic acid, 2,2′-bipy = 2,2′-bipyridine and phen = 1,10-phenanthroline), have been synthesized and structurally characterized by single-crystal diffraction analysis. Both 1 and 2 have mononuclear units, which are further linked into different 2D layers via the hydrogen bond interactions. Furthermore, the luminescent and stable properties of 1–2 are also discussed.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91153516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microwave-Assisted Iodination: Synthesis of Heavily Iodinated 10-Vertex and 12-Vertex Boron Clusters 微波辅助碘化:重碘化10顶点和12顶点硼团簇的合成
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-02 DOI: 10.1080/15533174.2014.988819
M. Juhasz, G. R. Matheson, Paul Chang, Aaron J. Rosenbaum, D. Juers
{"title":"Microwave-Assisted Iodination: Synthesis of Heavily Iodinated 10-Vertex and 12-Vertex Boron Clusters","authors":"M. Juhasz, G. R. Matheson, Paul Chang, Aaron J. Rosenbaum, D. Juers","doi":"10.1080/15533174.2014.988819","DOIUrl":"https://doi.org/10.1080/15533174.2014.988819","url":null,"abstract":"Microwave-assisted syntheses of heavily iodinated 10-vertex and 12-vertex closo boron clusters are reported. Salts of closo-B10I102−, 1-carba-closo-CHB9H4I5−, 1-carba-closo-CB11H6I6−, 1-carba-closo-CHB11I11−, and B12I122− were prepared in yields of 80% or better. All molecules were characterized by NMR and IR spectroscopy and mass spectrometry. The crystal structure of [Et4N][CHB9H4I5] was determined by single crystal X-ray diffraction. This salt crystallizes in the monoclinic P2(1)/c space group, a = 9.74427(12) Å, b = 20.7512(2) Å, c = 13.06589(17) Å, b = 101.2176(12)°, V = 2591.52(6) Å3, Z = 4, and rc = 2.262 g/cm3.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78267769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 13
Synthesis, Morphological and Optical Properties of Nano-Crystalline Solid CuxS Thin Films 纳米固相CuxS薄膜的合成、形貌及光学性能
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-02 DOI: 10.1080/15533174.2014.988815
Swati Mehra, Ajaya K. Singh, Gautam Sheel Thool, V. Ganesan
{"title":"Synthesis, Morphological and Optical Properties of Nano-Crystalline Solid CuxS Thin Films","authors":"Swati Mehra, Ajaya K. Singh, Gautam Sheel Thool, V. Ganesan","doi":"10.1080/15533174.2014.988815","DOIUrl":"https://doi.org/10.1080/15533174.2014.988815","url":null,"abstract":"Metal chalcogenide thin films of copper sulfide (CuxS) were grown on glass substrate using the chemical bath deposition. The CuxS thin film XRD studies reveal chalcocite low and covellite phases called as copper-rich and copper-poor form. The average grain size was calculated in the range of 8.87–69.65 nm. The optical band gap was estimated using Tauc's plot and found to be 3.02–4.06 eV. Optical properties exhibit that film find application in photovoltaic and photo thermal fields. AFM studies show formation of spherical shaped nanoparticle together with fine particles ranging 10 to 500 nm, evenly distributed showing homogeneity in polycrystalline thin film formation. SEM studies reveal spherical grain formation with cracks and pin holes at some places.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78007470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
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