广泛应用的缩合合成氨基膦途径的深入分析:氨基合成物(氯膦)(NC4H8N)[P(i-Pr2N)Cl]的合成与光谱表征

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-14 DOI:10.1080/15533174.2015.1040163

J. Gopalakrishnan

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引用次数: 1

摘要

氨基膦作为配体是很有用的，而最方便的合成方法是直接、简单、易于执行的缩合途径。RxPClz (x = 0-2, y = 1-3)和胺被广泛用作磷和氮的底物。例如Phx(R2N)yPClz [x < 3;Y > 0;采用缩合途径的文献中有Z < 3]。对这条路线进行了深入的分析，分析了影响产物形成、纯度和收率的各种参数。在优化条件下，制备了(NC4H8N)[P(i-Pr2N)Cl]2，并对其进行了光谱表征。

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A Deep Analysis on Widely Used Condensation Route for Preparing Aminophosphines: Synthesis and Spectral Characterization of an Aminobis(chlorophosphine), (NC4H8N)[P(i-Pr2N)Cl]2

Aminophosphines are useful as ligands and the most convenient method to synthesize is the condensation route that is straightforward, simple and easy to execute and get the products. RxPClz (x = 0–2, y = 1–3) and amines are widely used as phosphorus and nitrogen substrates. Vast examples such as Phx(R2N)yPClz [x < 3; y > 0; z < 3] are available in the literature which used condensation route. A deep analysis was carried out on this route and the author analyzes various parameters that affect product formation, purity, and yield. Using the optimized conditions, (NC4H8N)[P(i-Pr2N)Cl]2 was prepared and spectrally characterized.

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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5 months