{"title":"Metal, Metal-Oxides and Metal-Organic Frameworks for Environmental Remediation","authors":"","doi":"10.1007/978-3-030-68976-6","DOIUrl":"https://doi.org/10.1007/978-3-030-68976-6","url":null,"abstract":"","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82234868","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"EOV Editorial Board","authors":"","doi":"10.1080/15533174.2016.1208527","DOIUrl":"https://doi.org/10.1080/15533174.2016.1208527","url":null,"abstract":"","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76741577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis, Pyrolytic, and Antibacterial Study of 3-[(E)-(2-phenylhydrazinylidene)methyl]pyridine(PHMP) and Its Transition Metal Complexes","authors":"S. Rehman, A. Faiz, R. Nawaz, N. Ali","doi":"10.1080/15533174.2012.762682","DOIUrl":"https://doi.org/10.1080/15533174.2012.762682","url":null,"abstract":"Phenyl hydrazine and pyridine-3-carbaldehyde were coupled to form a new Schiff base 3-[(E)-(2-phenylhydrazinylidene)methyl]pyridine(PHMP), followed by the formation of its transition metal derivatives (i.e., Co(II), Cu(II), and Zn(II) complexes). All of them were characterized by physical and spectral methods such as 1H-NMR, IR, elemental analysis, UV-Vis spectra, and conductance studies. Thermal study was carried out with TG/DTA method to understand the degradation pattern of the newly synthesized ligand and its complexes. Antibacterial study was carried out with both the gram-positive (Bacillus subtilis, Staphylococcus aureus, Staphylococcus epidermis, Streptococcus pneumonia) and gram-negative bacteria (Pseudomonas aeruginosa, Salmonella typhi, Escherichia coli). The complexes showed medium activity as compared to the standard imipenem.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78087914","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. Mortazavi, H. Rajabi, A. Ansari, M. Ghaedi, K. Dashtian
{"title":"Preparation of silver nanoparticle loaded on activated carbon and its application for removal of malachite green from aqueous solution","authors":"K. Mortazavi, H. Rajabi, A. Ansari, M. Ghaedi, K. Dashtian","doi":"10.1080/15533174.2016.1228670","DOIUrl":"https://doi.org/10.1080/15533174.2016.1228670","url":null,"abstract":"AbstractAdsorption of malachite green (MG) onto silver nanoparticles loaded on activated carbon (Ag-NP-AC) was investigated. Useful information about this material was obtained by different techniques such as Brunauer Emmett and teller (BET), filed emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD) and Transmission electron microscopy. This reasonable low-cost, simple preparation and eco-friendly adsorbent is superior and alternative material to the current expensive substance for treatment of high amount of waste water. The influence of adsorbent dosage, initial dye concentration, and pH and contact time was examined to achieve and ascertain the optimal experimental conditions. The optimum dosage, pH and contact time for Ag-NP-AC were obtained to be 0.020 g, pH 5.00 and 25.0 min, respectively. The adsorption of malachite green obey the pseudo-second-order and intra-particle diffusion rate equation with 99.7% removal percentage at adsorbent dose of 0.025 g for 5–50 mg/L initial concen...","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/15533174.2016.1228670","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"59884834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Two Zinc(II) Complexes with 1D Chain and 2D Layer Directed by Competitive Coordination of the Mixed Ligands: Syntheses, Crystal Structures, and Fluorescent Properties","authors":"P. Dai, Hong-Kun Zhao, E. Yang, Xiao‐Jun Zhao","doi":"10.1080/15533174.2015.1004429","DOIUrl":"https://doi.org/10.1080/15533174.2015.1004429","url":null,"abstract":"Two new competitive coordination-directed zinc(II) complexes, [Zn2(bpp)2(na)4]n (1) and [Zn(bpp)2(nas)2]n (2) (bpp = 1,3-bi(4-pyridyl)propane, na− = 1-naphthoate, and nas− = 2-aminonaphthalene-1-sulfonate), were hydrothermally synthesized by varying carboxylate- or sulfonate-containing coligands. Structural analyses reveal that complex 1 modified by terminal na− spacers possesses a bent one-dimensional chain bridged by ditopic bpp linkers. By contrast, complex 2 with two monodentate nas− ligands exhibits a two-dimensional layered structure extended by four equatorial bpp connectors. Obviously, the increase on the dimensionality of 2 than 1 is significantly resulting from the competitive coordination of the two mixed ligands with differently tunable binding groups to variable metal polyhedra. In addition, both complexes with analogously high thermal stability display strong fluorescent emissions at room temperature resulting from the ligand-to-metal or intraligand charge-transfer, suggesting their hopeful applications as efficient fluorescent materials.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76044562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
G. Sheng, Xiao Han, Y. Ye, Jingzhu Ren, Z. You, Hailiang Zhu
{"title":"Synthesis, Characterization, and Crystal Structures of New Oxovanadium(V) Complexes With Mixed Nicotinohydrazone and 8-Hydroxyquinoline Ligands","authors":"G. Sheng, Xiao Han, Y. Ye, Jingzhu Ren, Z. You, Hailiang Zhu","doi":"10.1080/15533174.2015.1004432","DOIUrl":"https://doi.org/10.1080/15533174.2015.1004432","url":null,"abstract":"Two similar oxovanadium(V) complexes, [VOL1L′] (1) and [VOL2L′] (2), were prepared by the reaction of [VO(acac)2] (where acac = acetylacetonate), 8-hydroxyquinoline (HL′) with N′-(5-fluoro-2-hydroxybenzylidene)nicotinohydrazide (H2L1) and N′-(3-bromo-5-chloro-2-hydroxybenzylidene)nicotinohyrazide (H2L2), respectively, in methanol. Crystal and molecular structures of the complexes were determined by elemental analysis, infrared, and UV-vis spectra and single-crystal X-ray diffraction. The nicotinohydrazone ligands coordinate to the V atoms through the phenolate oxygen, imino nitrogen, and enolate oxygen. The 8-hydroxyquinoline ligand coordinates to the V atom through the phenolate oxygen and pyridine nitrogen. The V atoms in both complexes are in octahedral coordination.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89448781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yan Zhang, Pingping Zhou, Wei Liu, Zhong-qiang Zhang
{"title":"Construction of a New Co(II) Coordination Polymer With Excellent Photocatalytic Property","authors":"Yan Zhang, Pingping Zhou, Wei Liu, Zhong-qiang Zhang","doi":"10.1080/15533174.2015.1004439","DOIUrl":"https://doi.org/10.1080/15533174.2015.1004439","url":null,"abstract":"A new Co(II) coordination polymer, namely [Co2(mbdc)(ATAZ)2(H2O)2]n·nH2O (1; H2mbdc = isophthalic acid, HATAZ = 3-amino-1,2,4-triazole) has been synthesized via the solvothermal reactions of Co(NO3)2, isophthalic acid and 3-amino-1,2,4-triazole. Single-crystal X-ray diffraction analysis reveals that compound 1 features a 3 D pillar-layer framework based on Co(II)-aminotriazole layers and mbdc2− pillars, which can be simplified into a noninterpenetrated pcu topological network. The photocatalytic studies on compound 1 indicate that it can be used as an active catalyst for the photodegradation of methylene blue under UV light.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73622236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A New Ni(II) Coordination Polymer Based on Imidazole-Containing and Dicarboxylate Ligands with Polycatenated 2D + 2D → 3D Framework","authors":"Li-li Yang","doi":"10.1080/15533174.2015.1004448","DOIUrl":"https://doi.org/10.1080/15533174.2015.1004448","url":null,"abstract":"A new coordination polymer, {[Ni(sdb)(bimb)1.5]·H2O} (1) (H2sdb = 4,4'-sulfonyl- dicarboxylic acid and bimb = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene) has been prepared by hydrothermal synthesis and characterized by elemental analysis, IR, and X-ray diffraction. Complex {[Ni(sdb)(bimb)1.5]·H2O} (1), monoclinic, space group P21/c with a = 13.494(5)Å, b = 14.313(5) Å, c = 17.803(5) Å, β = 97.792(5)°, V = 3407(2) Å3, Z = 4, Mr = 738.43, Dc = 1.440 g/cm3, F(000) = 1532, and µ = 0.689 mm−1. The final refinement gave R = 0.0351and wR = 0.0950 for 6688 reflections with I > 2σ(I). X-ray diffraction analysis reveals that complex 1 shows a three-dimensional 2D + 2D → 3D Framework.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85297226","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis, Structure, and Luminescent Property of a New Cd(II) Compound With Rod-Shaped Hexanuclear {Cd6(COO)12} as Building Subunits","authors":"Xiaohui Li, Qifeng Liu, Yanli Dong","doi":"10.1080/15533174.2015.1004441","DOIUrl":"https://doi.org/10.1080/15533174.2015.1004441","url":null,"abstract":"A new Cd(II) coordination polymer, namely {Cd3(pbdc)3(e-murea)(DMF)}n·n(e-murea) (1, H2pbdc = terephthalic acid, e-murea = 1,3-dimethyl-2-imidazolidinone, DMF = N,N'-dimethylformamide), has been successfully synthesized via the urothermal reactions of Cd(II) ions and terephthalic acid ligand. Single-crystal X-ray structural analysis reveals that 1 features a two-dimensional layer framework with rod-shaped hexanuclear {Cd6(COO)12} clusters as building subunits. In addition, the luminescent property of 1 was also studied at room temperature.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77784804","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. K. Lermontova, Guo‐Ping Yang, Xun Wang, Yaoyu Wang, Q. Shi
{"title":"Synthesis, Crystal Structure, and Properties of a New Zinc(II) Coordination Polymer With Mixed 4,4′-biphenyldisulfonic Acid and N-Donor Ligands","authors":"E. K. Lermontova, Guo‐Ping Yang, Xun Wang, Yaoyu Wang, Q. Shi","doi":"10.1080/15533174.2011.614999","DOIUrl":"https://doi.org/10.1080/15533174.2011.614999","url":null,"abstract":"A new zinc(II) coordination polymer, namely [Zn(bipy)2(H2O)4]n·n(dsba) (1), has been synthesized by the mixed 4,4′-biphenyldisulfonic acid (H2dsba) and 4,4′-bipyridine (bipy) ligands with Zinc(II) salt under the common solution evaporation method. The results of the X-ray crystal diffraction analysis show that complex 1 belongs to the monoclinic system with P21/c space group. The unit cell constants of complex 1 are a = 9.2579 Å, b = 12.2016 Å, c = 14.447 Å, α = γ = 90˚, β = 93.476˚. Complex 1 exhibits a three-dimensional supramolecular network based on the discrete structure by utilizing various H-bonded interactions. In addition, the properties of complex 1, such as the elemental analysis, FT-IR spectroscopy, X-ray powder diffraction, and fluorescence spectroscopy were also characterized and are discussed in detailed.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88402994","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}