一种新型含咪唑二羧酸配体2D + 2D→3D聚catenated框架镍(II)配位聚合物

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-08-02 DOI:10.1080/15533174.2015.1004448

Li-li Yang

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引用次数: 0

摘要

采用水热法合成了一种新的配位聚合物{[Ni(sdb)(bimb)1.5]·H2O} (1) (H2sdb = 4,4′-磺酰基-二羧酸，bimb = 1,4-双(1-咪唑基)-2,5-二甲基苯)，并用元素分析、红外光谱和x射线衍射对其进行了表征。配合物{[Ni(sdb)(bimb)1.5]·H2O}(1)，单斜，空间群P21/c, a = 13.494(5)Å， b = 14.313(5) Å， c = 17.803(5) Å， β = 97.792(5)°，V = 3407(2) Å3, Z = 4, Mr = 738.43, Dc = 1.440 g/cm3, F(000) = 1532，µ= 0.689 mm−1。最后的细化得到了6688次反射的R = 0.0351, wR = 0.0950。x射线衍射分析表明，配合物1呈现三维2D + 2D→3D框架。

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A New Ni(II) Coordination Polymer Based on Imidazole-Containing and Dicarboxylate Ligands with Polycatenated 2D + 2D → 3D Framework

A new coordination polymer, {[Ni(sdb)(bimb)1.5]·H2O} (1) (H2sdb = 4,4'-sulfonyl- dicarboxylic acid and bimb = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene) has been prepared by hydrothermal synthesis and characterized by elemental analysis, IR, and X-ray diffraction. Complex {[Ni(sdb)(bimb)1.5]·H2O} (1), monoclinic, space group P21/c with a = 13.494(5)Å, b = 14.313(5) Å, c = 17.803(5) Å, β = 97.792(5)°, V = 3407(2) Å3, Z = 4, Mr = 738.43, Dc = 1.440 g/cm3, F(000) = 1532, and µ = 0.689 mm−1. The final refinement gave R = 0.0351and wR = 0.0950 for 6688 reflections with I > 2σ(I). X-ray diffraction analysis reveals that complex 1 shows a three-dimensional 2D + 2D → 3D Framework.

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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5 months