A New Ni(II) Coordination Polymer Based on Imidazole-Containing and Dicarboxylate Ligands with Polycatenated 2D + 2D → 3D Framework

Li-li Yang
{"title":"A New Ni(II) Coordination Polymer Based on Imidazole-Containing and Dicarboxylate Ligands with Polycatenated 2D + 2D → 3D Framework","authors":"Li-li Yang","doi":"10.1080/15533174.2015.1004448","DOIUrl":null,"url":null,"abstract":"A new coordination polymer, {[Ni(sdb)(bimb)1.5]·H2O} (1) (H2sdb = 4,4'-sulfonyl- dicarboxylic acid and bimb = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene) has been prepared by hydrothermal synthesis and characterized by elemental analysis, IR, and X-ray diffraction. Complex {[Ni(sdb)(bimb)1.5]·H2O} (1), monoclinic, space group P21/c with a = 13.494(5)Å, b = 14.313(5) Å, c = 17.803(5) Å, β = 97.792(5)°, V = 3407(2) Å3, Z = 4, Mr = 738.43, Dc = 1.440 g/cm3, F(000) = 1532, and µ = 0.689 mm−1. The final refinement gave R = 0.0351and wR = 0.0950 for 6688 reflections with I > 2σ(I). X-ray diffraction analysis reveals that complex 1 shows a three-dimensional 2D + 2D → 3D Framework.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-08-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1004448","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

Abstract

A new coordination polymer, {[Ni(sdb)(bimb)1.5]·H2O} (1) (H2sdb = 4,4'-sulfonyl- dicarboxylic acid and bimb = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene) has been prepared by hydrothermal synthesis and characterized by elemental analysis, IR, and X-ray diffraction. Complex {[Ni(sdb)(bimb)1.5]·H2O} (1), monoclinic, space group P21/c with a = 13.494(5)Å, b = 14.313(5) Å, c = 17.803(5) Å, β = 97.792(5)°, V = 3407(2) Å3, Z = 4, Mr = 738.43, Dc = 1.440 g/cm3, F(000) = 1532, and µ = 0.689 mm−1. The final refinement gave R = 0.0351and wR = 0.0950 for 6688 reflections with I > 2σ(I). X-ray diffraction analysis reveals that complex 1 shows a three-dimensional 2D + 2D → 3D Framework.
一种新型含咪唑二羧酸配体2D + 2D→3D聚catenated框架镍(II)配位聚合物
采用水热法合成了一种新的配位聚合物{[Ni(sdb)(bimb)1.5]·H2O} (1) (H2sdb = 4,4′-磺酰基-二羧酸,bimb = 1,4-双(1-咪唑基)-2,5-二甲基苯),并用元素分析、红外光谱和x射线衍射对其进行了表征。配合物{[Ni(sdb)(bimb)1.5]·H2O}(1),单斜,空间群P21/c, a = 13.494(5)Å, b = 14.313(5) Å, c = 17.803(5) Å, β = 97.792(5)°,V = 3407(2) Å3, Z = 4, Mr = 738.43, Dc = 1.440 g/cm3, F(000) = 1532,µ= 0.689 mm−1。最后的细化得到了6688次反射的R = 0.0351, wR = 0.0950。x射线衍射分析表明,配合物1呈现三维2D + 2D→3D框架。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
自引率
0.00%
发文量
0
审稿时长
5 months
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信