以{Cd6(COO)12}为亚基的新型棒状六核Cd(II)化合物的合成、结构和发光性能

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-08-02 DOI:10.1080/15533174.2015.1004441

Xiaohui Li, Qifeng Liu, Yanli Dong

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引用次数: 4

摘要

通过Cd(II)离子与对苯二甲酸配体的热反应，成功合成了新的Cd(II)配位聚合物{Cd3(pbdc)3(e-murea)(DMF)}n·n(e-murea) (1,h2pbdc =对苯二甲酸，e-murea = 1,3-二甲基-2-咪唑烷酮，DMF = n, n '-二甲基甲酰胺)。单晶x射线结构分析表明，1具有以棒状六核{Cd6(COO)12}团簇为构建亚基的二维层框架。此外，还研究了1在室温下的发光特性。

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Synthesis, Structure, and Luminescent Property of a New Cd(II) Compound With Rod-Shaped Hexanuclear {Cd6(COO)12} as Building Subunits

A new Cd(II) coordination polymer, namely {Cd3(pbdc)3(e-murea)(DMF)}n·n(e-murea) (1, H2pbdc = terephthalic acid, e-murea = 1,3-dimethyl-2-imidazolidinone, DMF = N,N'-dimethylformamide), has been successfully synthesized via the urothermal reactions of Cd(II) ions and terephthalic acid ligand. Single-crystal X-ray structural analysis reveals that 1 features a two-dimensional layer framework with rod-shaped hexanuclear {Cd6(COO)12} clusters as building subunits. In addition, the luminescent property of 1 was also studied at room temperature.

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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审稿时长

5 months