一种具有三层互穿pcu拓扑结构的新型Cd(II)配位聚合物的水热合成、晶体结构和发光性能

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-14 DOI:10.1080/15533174.2015.1004452

Xiuling Feng, Wanping Chen, B. Xiang

{"title":"一种具有三层互穿pcu拓扑结构的新型Cd(II)配位聚合物的水热合成、晶体结构和发光性能","authors":"Xiuling Feng, Wanping Chen, B. Xiang","doi":"10.1080/15533174.2015.1004452","DOIUrl":null,"url":null,"abstract":"A new three-dimensional (3D) coordination polymer, [Cd(pda)(bib)0.5] n(1), [H2pda=1,4-phenylenediacetic acid and bib=1,4-bis(2-methyl-imidazol-1-yl) butane] was prepared by hydrothermal syntheses and characterized by single-crystal X-ray diffraction, FT-IR spectroscopy, and elemental analysis. Crystal structure determination revealed that complex 1 features a threefold interpenetrated pcu framework. Furthermore, the luminescent property for complex 1 is also investigated in solid state at room temperature.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Hydrothermal Synthesis, Crystal Structure, and Luminescent Property of a New Cd(II) Coordination Polymer With Three-Fold Interpenetrated pcu Topology\",\"authors\":\"Xiuling Feng, Wanping Chen, B. Xiang\",\"doi\":\"10.1080/15533174.2015.1004452\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new three-dimensional (3D) coordination polymer, [Cd(pda)(bib)0.5] n(1), [H2pda=1,4-phenylenediacetic acid and bib=1,4-bis(2-methyl-imidazol-1-yl) butane] was prepared by hydrothermal syntheses and characterized by single-crystal X-ray diffraction, FT-IR spectroscopy, and elemental analysis. Crystal structure determination revealed that complex 1 features a threefold interpenetrated pcu framework. Furthermore, the luminescent property for complex 1 is also investigated in solid state at room temperature.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-04-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2015.1004452\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1004452","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

采用水热合成方法制备了一种新的三维配位聚合物[Cd(pda)(bib)0.5] n(1)， [H2pda=1,4-苯二乙酸，bib=1,4-双(2-甲基咪唑-1-基)丁烷]，并用单晶x射线衍射、FT-IR光谱和元素分析对其进行了表征。晶体结构测定表明，配合物1具有三层互穿pcu框架。此外，还研究了配合物1在室温下的固态发光特性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Hydrothermal Synthesis, Crystal Structure, and Luminescent Property of a New Cd(II) Coordination Polymer With Three-Fold Interpenetrated pcu Topology

A new three-dimensional (3D) coordination polymer, [Cd(pda)(bib)0.5] n(1), [H2pda=1,4-phenylenediacetic acid and bib=1,4-bis(2-methyl-imidazol-1-yl) butane] was prepared by hydrothermal syntheses and characterized by single-crystal X-ray diffraction, FT-IR spectroscopy, and elemental analysis. Crystal structure determination revealed that complex 1 features a threefold interpenetrated pcu framework. Furthermore, the luminescent property for complex 1 is also investigated in solid state at room temperature.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

自引率

0.00%

发文量

审稿时长

5 months