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Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry最新文献

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Synthesis, Structural Characterization, and Magnetic Properties of Two Iron(II) Complexes With Triazole- and Imidazole-Related Ligands 两种与三唑和咪唑相关配体的铁(II)配合物的合成、结构表征和磁性能
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-18 DOI: 10.1080/15533174.2015.1137056
Qingqing Liu, Li-Jing Yang, Yang‐Hui Luo, Wen Wang, Yang Ling, Baiwang Sun
{"title":"Synthesis, Structural Characterization, and Magnetic Properties of Two Iron(II) Complexes With Triazole- and Imidazole-Related Ligands","authors":"Qingqing Liu, Li-Jing Yang, Yang‐Hui Luo, Wen Wang, Yang Ling, Baiwang Sun","doi":"10.1080/15533174.2015.1137056","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137056","url":null,"abstract":"Two new mononuclear iron (II) coordination complexes: Fe(L1)2(SCN)2 (1, L1:5-dimethylether-4-(4-methylphenyl)-3-(2-pyridinyl)-1,2,4-triazole) and Fe(L2)3(ClO4)2 (2, L2 :1-ethyl acetate-2-(2-pyridinyl)-imidazole), for the exploration of spin-crossover compounds have been synthesized and characterized. Structural analysis revealed that the framework of complex 1 is featured with 1-D chain structure connected by weak π···π interactions between the adjacent L1 ligands, while complex 2 featured with various kinds of weak intermolecular hydrogen bonding interactions between Fe(L2)32+ cation and ClO4− anion, which lead to a close crystal packing. The intermolecular interactions have shown a significant influence on the physical properties, and magnetic measurements of complexes 1 and 2 in the solid state at the room temperature revealed that the weak intermolecular interactions in 1 resulted in HS (high-spin) state, while the strong interactions in 2 lead to LS (low-spin) state over the whole temperature range.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79302609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sonochemical Preparation and Characterization of Modified CuO Nanocrystalline With Bioactive Chiral Diacids Derived From Different Natural Amino Acids 由不同天然氨基酸衍生的具有生物活性的手性二酸修饰氧化铜纳米晶的声化学制备及表征
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-18 DOI: 10.1080/15533174.2015.1137047
S. Mallakpour, M. Vahabi
{"title":"Sonochemical Preparation and Characterization of Modified CuO Nanocrystalline With Bioactive Chiral Diacids Derived From Different Natural Amino Acids","authors":"S. Mallakpour, M. Vahabi","doi":"10.1080/15533174.2015.1137047","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137047","url":null,"abstract":"To improve the dispersion ability of CuO nanoparticles (NPs), their surface was modified by chiral diacids (DAs) containing amino acids. The surface modification process was achieved using ultrasonic irradiation. DA could be absorbed on the surface of CuO. The carboxyl groups of DA may interact with surface of CuO NPs and form covalent bond with it. Interactions between DAs and CuO NPs were investigated by different techniques. The X-ray diffraction patterns proved that modification process does not change the crystalline phase of CuO. The results confirmed successful deposition of the organic functional groups on the surface of NPs.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84058978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Crystal Structure and Luminescent Property of a New Heterometallic Coordination Polymer Based on 1D –{Ca–(COO)2–Cu–(COO)2–Ca}n– Chains 基于一维- {Ca - (COO) 2-Cu - (COO) 2-Ca}n -链的新型杂金属配位聚合物的晶体结构和发光性能
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-18 DOI: 10.1080/15533174.2015.1137058
Guixiang Zou, Jing Gao
{"title":"Crystal Structure and Luminescent Property of a New Heterometallic Coordination Polymer Based on 1D –{Ca–(COO)2–Cu–(COO)2–Ca}n– Chains","authors":"Guixiang Zou, Jing Gao","doi":"10.1080/15533174.2015.1137058","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137058","url":null,"abstract":"A new heterometallic coordination polymer, namely [CuCa(tdc)2(DMA)(H2O)2]n (1, H2tdc = 2,5-thiophenedicarboxylic acid, DMA = N, N-dimethylacetamide) has been solvothermally synthesized by the reactions of CuCl2, CaCl2, and H2tdc. X-ray structural analysis reveals that compound 1 features a 3D heterometallic framework based on one-dimensional –{Ca–(COO)2–Cu–(COO)2–Ca}n– chains. Moreover, the luminescent properties of compound 1 and desolvated 1 were also investigated at room temperature.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83370475","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Syntheses, Structures, and Luminescence of Three Manganese Coordination Polymers With Flexible Bistriazole and Rigid Benzenedicarboxylate Ligands 三种具有柔性双三唑和刚性苯二甲酸盐配体的锰配位聚合物的合成、结构和发光
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-18 DOI: 10.1080/15533174.2015.1137044
Jian‐Xin Chen, Xia Zhu, Shan Zhao, Bao‐Long Li, Zhang Yong
{"title":"Syntheses, Structures, and Luminescence of Three Manganese Coordination Polymers With Flexible Bistriazole and Rigid Benzenedicarboxylate Ligands","authors":"Jian‐Xin Chen, Xia Zhu, Shan Zhao, Bao‐Long Li, Zhang Yong","doi":"10.1080/15533174.2015.1137044","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137044","url":null,"abstract":"Three Mn(II) coordination polymers, {[Mn(bte)0.5(bdc)(H2O)]•H2O} (1), {[Mn(bte)(I-bdc)(H2O)]•H2O}n (2), and [Mn(btp)(bdc)(H2O)]•2.5H2O (3), were synthesized (bte = 1,2-bis(1,2,4-triazol-1-yl)ethane, btp = 1,3-bis(1,2,4-triazol-1-yl)propane, bdc = 1,3-benzenebiscarboxylate, I-bdc = 5-iodoisophthalate). 1 is an unusual (3,4)-connected 2D network with the point symbol of (42•6)(42•63•8). 2 is an independent 1D metal-organic nanotube (MONT). The combination of rings and two chains forms independent 1D MONT. The I groups of each 1D MONT polythread into two adjacent 1D MONTs to form a (1D → 2D) polythreaded array. 3 shows the undulated 2D (4,4) network and a double-layer hydrogen bonding network. The luminescence and thermal stability were investigated.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72802394","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
A New 3D Pillar-Layered Zn(II) Coordination Polymer Constructed From the Mixed Flexible Polycarboxylate and Bis(pyridyl)-Based Ligands 由柔性聚羧酸酯和双(吡啶基)配体构建的新型三维柱状层状Zn(II)配位聚合物
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-18 DOI: 10.1080/15533174.2015.1137048
Hui-min Liu
{"title":"A New 3D Pillar-Layered Zn(II) Coordination Polymer Constructed From the Mixed Flexible Polycarboxylate and Bis(pyridyl)-Based Ligands","authors":"Hui-min Liu","doi":"10.1080/15533174.2015.1137048","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137048","url":null,"abstract":"A new Zn(II) coordination polymer, namely [Zn3(TTHA)(bpp)(H2O)3]n·4n(H2O) (1 H6TTHA = 1,3,5-triazine-2,4,6-triamine hexaacetic acid, bpp = 1,3-di(4-pyridyl)propane), has been synthesized by the hydrothermal self-assembly of Zn(NO3)2·6H2O, H6TTHA and bpp. Single-crystal x-ray diffraction analysis reveals that compound 1 features a 3D framework, which can be described as the 2D layers constructed by the Zn(II) ions and TTHA6– ligands pillared by the bpp ligands. Furthermore, the thermal stability and luminescent property of compound 1 were investigated.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85948340","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Tuning the Emission Color of Cyclometalated Iridium Complex by Extending the π-Electron Delocalization of the Aromatic Chromophore: Synthesis, Photophysical Properties, and X-Ray Crystal Structure 利用芳香族发色团π-电子离域扩展调节环金属化铱配合物的发射色:合成、光物理性质和x射线晶体结构
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-18 DOI: 10.1080/15533174.2015.1137051
M. O. Ahmed, H. Al-Masri, Leong Weng Kee, Rakesh Ganguly
{"title":"Tuning the Emission Color of Cyclometalated Iridium Complex by Extending the π-Electron Delocalization of the Aromatic Chromophore: Synthesis, Photophysical Properties, and X-Ray Crystal Structure","authors":"M. O. Ahmed, H. Al-Masri, Leong Weng Kee, Rakesh Ganguly","doi":"10.1080/15533174.2015.1137051","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137051","url":null,"abstract":"The authors report the preparation, crystal structure, and emission properties of Ir(btq)2(acac) (btq = 2-benzo[4,5-]thienylquinoline) (1). The compound has been characterised by UV-vis, fluorescence, MALDI-TOF, and 1H and 13C NMR spectroscopy. The crystal structure was also elucidated by X-ray diffraction methods. Its characteristics in terms of optical and structural properties are compared with the reported cyclometalated Ir(III) complex Ir(btp)2(acac) (2) (btp = 2-benzo[4,5-]thienylpyridine). Complex 1 shows 53 nm red-shift emission compared to the related complex 2.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83232553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Inducing Catalytic Activity in the Dark of TiO2/WO3 Mixed Metal Oxides by Using an In Situ Polymerized Semiconductive Polymeric Binder 原位聚合半聚合物粘结剂在黑暗中诱导TiO2/WO3混合金属氧化物的催化活性
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-18 DOI: 10.1080/15533174.2015.1137049
Nuttaporn Jaritkaun, J. Wootthikanokkhan, C. Piewnuan, Pailin Ngaotrakanwiwat, S. Chiarakorn
{"title":"Inducing Catalytic Activity in the Dark of TiO2/WO3 Mixed Metal Oxides by Using an In Situ Polymerized Semiconductive Polymeric Binder","authors":"Nuttaporn Jaritkaun, J. Wootthikanokkhan, C. Piewnuan, Pailin Ngaotrakanwiwat, S. Chiarakorn","doi":"10.1080/15533174.2015.1137049","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137049","url":null,"abstract":"Mixed metal oxides (TiO2/WO3) containing polythiophene binder were prepared. The molar ratios of TiO2/WO3/thiophene used for an in situ polymerization were varied from 1/2/0 to 1/2/0.6. Catalytic activities of the metal oxides were studied by following up the degradation of methylene blue under various illumination conditions. With the presence of the polymeric binder in the system, the activity in the dark was induced whereas those under both UV and visible light were maintained. The amount of polymer also played a role. The catalytic activities decreased with increasing monomer content. The results are discussed in light of morphology characterized by TEM-EDX.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88972807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Biodegradable Polymer-Based Ternary Blends for Adsorption of Heavy Metal From Simulated Industrial Wastewater 可生物降解聚合物基三元共混物对模拟工业废水中重金属的吸附
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-18 DOI: 10.1080/15533174.2015.1137052
N. Prakash, S. A. Vendan, P. Sudha, N. Renganathan
{"title":"Biodegradable Polymer-Based Ternary Blends for Adsorption of Heavy Metal From Simulated Industrial Wastewater","authors":"N. Prakash, S. A. Vendan, P. Sudha, N. Renganathan","doi":"10.1080/15533174.2015.1137052","DOIUrl":"https://doi.org/10.1080/15533174.2015.1137052","url":null,"abstract":"The ternary blends consisting of biodegradable polymer-based ternary blends composites were prepared by the solution blending method with glutaraldehyde. Prepared ternary blends were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, and differential scanning calorimetry. Subsequently, the adsorbent activity for heavy metal, chromium, was estimated in terms of the existent initial concentration, adsorbent dose, contact time, and pH. The adsorption study was performed for the pH ranging from pH 4.0 to 8.0. It was observed that the sorption efficiency, increased with increasing the pH of the solution from 4.0 to 5.5. At low pH values of the solution, the amine groups were propagated to various degrees, reducing the number of binding sites available for metal ion uptake so that the extent of chromium uptake is low in the high concentrations of protons. Moreover, the protonation of amine groups is induced an electrostatic repulsion of cations. When the pH of the solution was more than 5.5, the sorption rate began to decrease. Besides, the quantity of adsorbate on absorbent was fitted as a function in Langmuir and Freundlich isotherm. The sorption kinetics were tested for pseudo first- and pseudo second-order reactions. The kinetic experimental data correlated with the second-order kinetic model and rate constants of sorption for kinetic models were calculated and accordingly, the correlation coefficients were obtained. The investigation emphasized that the composite was very effective for the adsorption of Cr (VI).","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/15533174.2015.1137052","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72493247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
A New Zn(II) Coordination Polymer Constructed by Flexible Carboxylate and Rigid Imidazole-Containing Coligands With a 2D+2D→3D Polycatenated Structure 具有二维+二维→三维聚catenated结构的柔性羧酸盐与刚性咪唑配体构建的新型Zn(II)配位聚合物
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-14 DOI: 10.1080/15533174.2015.1004453
Xiuling Feng, Wanping Chen, B. Xiang
{"title":"A New Zn(II) Coordination Polymer Constructed by Flexible Carboxylate and Rigid Imidazole-Containing Coligands With a 2D+2D→3D Polycatenated Structure","authors":"Xiuling Feng, Wanping Chen, B. Xiang","doi":"10.1080/15533174.2015.1004453","DOIUrl":"https://doi.org/10.1080/15533174.2015.1004453","url":null,"abstract":"A new Zn (II) coordination polymer with benzophenone-4,4′-dicarboxylic acid (H2bpdc) and 1,4-bis(imidazol-1-yl)benzene (bib) has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and EA. Complex, {[Zn(bpdc) (bib)]·2H2O}n(1), is triclinic, space group P-1 with a = 8.958(5), b = 11.336(5), c = 14.150(5) Å,α = 111.109(5), β = 95.077 (5)° γ = 98.504(5), V = 1310.0 (10) Å3, Z = 2, Mr = 579.86, Dc = 1.470 g/cm3, F(000) = 596, and µ = 0.991 mm−1. The final refinement gave R = 0.0352 and wR = 0.0964 for 5191 reflections with I > 2σ(I). X-ray diffraction analysis reveals that the complex 1 displays a 2D+2D→3D polycatenated structure.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88052651","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Magnetically Separable MnxZn1-xFe2O4; (0.0 ≤ x ≤ 0.5) Nanostructures: Structural, Morphological, Opto-Magnetic, and Photocatalytic Properties 磁性可分离MnxZn1-xFe2O4(0.0≤x≤0.5)纳米结构:结构、形态、光磁和光催化性质
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-14 DOI: 10.1080/15533174.2015.1004454
A. Manikandan, S. Antony
{"title":"Magnetically Separable MnxZn1-xFe2O4; (0.0 ≤ x ≤ 0.5) Nanostructures: Structural, Morphological, Opto-Magnetic, and Photocatalytic Properties","authors":"A. Manikandan, S. Antony","doi":"10.1080/15533174.2015.1004454","DOIUrl":"https://doi.org/10.1080/15533174.2015.1004454","url":null,"abstract":"Mn2+ doped ZnFe2O4 nanocrystals have been successfully synthesized by one-pot autocombustion method. The synthesized MnxZn1-xFe2O4 nanocrystals were characterized by XRD, FT-IR, HR-SEM, TEM, EDX, BET, DRS, PL, and VSM. The results indicated that the prepared spinel MnxZn1-xFe2O4 nanocrystals showed high crystallinity and uniform size distribution with particle-like morphologies. The present study leads to enhance the photocatalytic activity of MnxZn1-xFe2O4 with the addition of TiO2. Having established that spinel MnxZn1-xFe2O4 was photocatalytically active, the mixed oxide catalysts of MnxZn1-xFe2O4 -TiO2 were also tested for the photocatalytic degradation of 4-chlorophenol.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85165900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
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