辅助配体对Zn(II)配合物的影响:合成、结构和发光

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-04-05 DOI:10.1080/15533174.2015.1137042

Z. Xiang, Tao Wang, Lu Lu, Xiren Wu, Yanchun Sun

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引用次数: 0

摘要

合成了两个Zn基配合物{[Zn(L3)(2,2′-bipy)(H2O)2]n·L3}(1)和[Zn(L3)2(phen)(H2O)] (2) (HL3 = 3-(4-羟基苯基)丙酸，2,2′-bipy = 2,2′-联吡啶，phen = 1,10-菲罗啉)，并通过单晶衍射分析对其结构进行了表征。1和2都有单核单元，它们通过氢键相互作用进一步连接成不同的二维层。此外，还讨论了1-2的发光特性和稳定性。

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Effect Ancillary Ligands on the Zn(II) Complexes: Syntheses, Structure, and Luminescence

Two Zn-based complexes, namely {[Zn(L3)(2,2′-bipy)(H2O)2]n·L3} (1), and [Zn(L3)2(phen)(H2O)] (2) (HL3 = 3-(4-hydroxyphenyl)propanoic acid, 2,2′-bipy = 2,2′-bipyridine and phen = 1,10-phenanthroline), have been synthesized and structurally characterized by single-crystal diffraction analysis. Both 1 and 2 have mononuclear units, which are further linked into different 2D layers via the hydrogen bond interactions. Furthermore, the luminescent and stable properties of 1–2 are also discussed.

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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审稿时长

5 months