{"title":"二聚体配合物的合成及磁性","authors":"Lu Lu, Wang Jun, Xiren Wu, B. Xie, Yu Wu","doi":"10.1080/15533174.2015.1137043","DOIUrl":null,"url":null,"abstract":"A new Cu-based complex of {[Cu2(L)2(phen)2(NO3)]·NO3} (1) (HL = p-hydroxy phenylacetic acid, phen = 1,10-phenanthroline) has been synthesized and structurally characterized. Single-crystal X-ray analyses reveal that compound 1 has a dinuclear Cu(II) unit linking by two carboxylate groups and one nitrate group. The chelating N-donor ligand with phen binds to Cu(II) centers and there is weaker Cu-Cu bond interaction as well. Furthermore, the magnetic property of compound 1 was discussed in detail.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Magnetism of a Dimeric Complex\",\"authors\":\"Lu Lu, Wang Jun, Xiren Wu, B. Xie, Yu Wu\",\"doi\":\"10.1080/15533174.2015.1137043\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A new Cu-based complex of {[Cu2(L)2(phen)2(NO3)]·NO3} (1) (HL = p-hydroxy phenylacetic acid, phen = 1,10-phenanthroline) has been synthesized and structurally characterized. Single-crystal X-ray analyses reveal that compound 1 has a dinuclear Cu(II) unit linking by two carboxylate groups and one nitrate group. The chelating N-donor ligand with phen binds to Cu(II) centers and there is weaker Cu-Cu bond interaction as well. Furthermore, the magnetic property of compound 1 was discussed in detail.\",\"PeriodicalId\":22118,\"journal\":{\"name\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-04-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/15533174.2015.1137043\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1137043","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A new Cu-based complex of {[Cu2(L)2(phen)2(NO3)]·NO3} (1) (HL = p-hydroxy phenylacetic acid, phen = 1,10-phenanthroline) has been synthesized and structurally characterized. Single-crystal X-ray analyses reveal that compound 1 has a dinuclear Cu(II) unit linking by two carboxylate groups and one nitrate group. The chelating N-donor ligand with phen binds to Cu(II) centers and there is weaker Cu-Cu bond interaction as well. Furthermore, the magnetic property of compound 1 was discussed in detail.