二聚体配合物的合成及磁性

Lu Lu, Wang Jun, Xiren Wu, B. Xie, Yu Wu
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引用次数: 0

摘要

合成了一种新的cu基配合物{[Cu2(L)2(phen)2(NO3)]·NO3} (1) (HL =对羟基苯乙酸,phen = 1,10-菲罗啉),并进行了结构表征。单晶x射线分析表明,化合物1具有双核Cu(II)单元,由两个羧酸基和一个硝酸盐基连接。与phen螯合的n -供体配体与Cu(II)中心结合,存在较弱的Cu-Cu键相互作用。此外,还详细讨论了化合物1的磁性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and Magnetism of a Dimeric Complex
A new Cu-based complex of {[Cu2(L)2(phen)2(NO3)]·NO3} (1) (HL = p-hydroxy phenylacetic acid, phen = 1,10-phenanthroline) has been synthesized and structurally characterized. Single-crystal X-ray analyses reveal that compound 1 has a dinuclear Cu(II) unit linking by two carboxylate groups and one nitrate group. The chelating N-donor ligand with phen binds to Cu(II) centers and there is weaker Cu-Cu bond interaction as well. Furthermore, the magnetic property of compound 1 was discussed in detail.
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