Sustainable Materials and Technologies最新文献

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Experimental investigation and machine learning models for predicting flexural and tensile strengths of recycled concrete: Bridging the gap between sustainable materials and structural design 用于预测再生混凝土抗弯和抗拉强度的实验研究和机器学习模型:弥合可持续材料与结构设计之间的差距
IF 8.6 2区 工程技术
Sustainable Materials and Technologies Pub Date : 2024-10-18 DOI: 10.1016/j.susmat.2024.e01149
Syed Minhaj Saleem Kazmi, Muhammad Junaid Munir
{"title":"Experimental investigation and machine learning models for predicting flexural and tensile strengths of recycled concrete: Bridging the gap between sustainable materials and structural design","authors":"Syed Minhaj Saleem Kazmi,&nbsp;Muhammad Junaid Munir","doi":"10.1016/j.susmat.2024.e01149","DOIUrl":"10.1016/j.susmat.2024.e01149","url":null,"abstract":"<div><div>The sustainability of structural components requires recycled aggregate concrete (RC) to achieve adequate flexural and split tensile strengths for practical use. These strengths depend on mix design and the properties of recycled coarse aggregates (R-CA). The variability in R-CA sources and the inherent heterogeneity of RC complicate strength predictions. No existing model accounts for this variability, leaving a gap between sustainable materials and structural design. This study develops machine learning-based models to predict the flexural and split tensile strengths of RC, regardless of R-CA source and properties. Key factors such as water absorption, effective water-to-cement ratio, coarse aggregate-to-cement ratio, and R-CA replacement ratio are used for predictions. The impact of different R-CA types on RC and natural aggregate concrete (NC) is also experimentally analyzed. A dataset of 353 test results from this study and 33 prior studies is used, and various machine learning algorithms (MLA) are evaluated. Results show a 41 % and 23 % reduction in flexural and split tensile strengths of RC compared to NC, but acid and mechanically treated R-CA can recover up to 94 % and 93 % of NC's strengths, respectively. Among all MLA models, the gradient boost model depicted the highest accuracy in predictions for the flexural and tensile strengths of both RC and NC. This research introduces new equations and a C/C++ tool for predicting RC and NC strengths, contributing to sustainable concrete design and bridging the gap between research and practical application.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"42 ","pages":"Article e01149"},"PeriodicalIF":8.6,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electricity supply resiliency evaluation by a hybrid renewable energy system for a petrochemical plant: Frameworks and quantitative assessment methodologies 石化厂混合可再生能源系统的电力供应弹性评估:框架和定量评估方法
IF 8.6 2区 工程技术
Sustainable Materials and Technologies Pub Date : 2024-10-18 DOI: 10.1016/j.susmat.2024.e01139
Samaneh Habibzadeh, Mohammad Hossein Jahangir, Fatemeh Razi Astaraei
{"title":"Electricity supply resiliency evaluation by a hybrid renewable energy system for a petrochemical plant: Frameworks and quantitative assessment methodologies","authors":"Samaneh Habibzadeh,&nbsp;Mohammad Hossein Jahangir,&nbsp;Fatemeh Razi Astaraei","doi":"10.1016/j.susmat.2024.e01139","DOIUrl":"10.1016/j.susmat.2024.e01139","url":null,"abstract":"<div><div>The escalation of harm inflicted upon energy systems, has spurred the investigation of energy system resilience. In this regard, the measurement of resilience capacity can serve as a valuable metric for assessing the energy system's ability to withstand a variety of events that may result in potential adverse outcomes. For renewable energy systems, the measurement of resilience is imperative due to the inherent unpredictability and unreliability in their nature. Often, resilience studies lack the comprehensiveness required to fully comprehend the intricate interdependencies within integrated hybrid renewable energy systems. This research delineates the essential factors required to facilitate a comprehensive understanding and advancement in the quantification of such integrated systems in small-scale. Pardis Petrochemical Company, located in Asalouyeh city, Iran, has been chosen as case study. Four distinct configurations of hybrid renewable energy systems—comprising Photovoltaic panels, Photovoltaic panels + Wind Turbines, Photovoltaic panels + Wave energy converters, and Photovoltaic panels + Wind Turbines + Wave energy converters— connected to grid, have been developed. These configurations are the result of a multi-objective optimization process, considering the following metrics: the cost of electricity (as an economic metric), CO<sub>2</sub> emissions (as an environmental metric), loss of power supply probability (as a reliability metric), and exergy efficiency (as a technical metric). Subsequently, a methodological framework for multicriteria decision support is introduced. This framework is constructed based on primary resilience dimensions, namely: “resist,” “restabilize,” “technology,” and “withstand” serve as a tool for measuring the resiliency of the optimized configurations. The findings indicate that the Photovoltaic panels + Wind Turbines + Wave Energy Converters configuration is as the most resilient system among the studied alternatives.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"42 ","pages":"Article e01139"},"PeriodicalIF":8.6,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of a 2D/2D g-C3N4@ZnTDA nanosheets catalyst for highly efficient degradation of 2,4-dibromophenol and improved flame retardancy of polyurethane foam 制备 2D/2D g-C3N4@ZnTDA 纳米片催化剂,用于高效降解 2,4-二溴苯酚并改善聚氨酯泡沫的阻燃性能
IF 8.6 2区 工程技术
Sustainable Materials and Technologies Pub Date : 2024-10-18 DOI: 10.1016/j.susmat.2024.e01154
Zhoumei Xu, Fukai Chu, Chuanshen Wang, Xin Wang, Yanbei Hou, Weizhao Hu, Lei Song
{"title":"Fabrication of a 2D/2D g-C3N4@ZnTDA nanosheets catalyst for highly efficient degradation of 2,4-dibromophenol and improved flame retardancy of polyurethane foam","authors":"Zhoumei Xu,&nbsp;Fukai Chu,&nbsp;Chuanshen Wang,&nbsp;Xin Wang,&nbsp;Yanbei Hou,&nbsp;Weizhao Hu,&nbsp;Lei Song","doi":"10.1016/j.susmat.2024.e01154","DOIUrl":"10.1016/j.susmat.2024.e01154","url":null,"abstract":"<div><div>High charge separation and transfer efficiency are considered as key factors of photocatalysts in wastewater treatment applications. In this work, a high performance photocatalyst g-C<sub>3</sub>N<sub>4</sub>@ZnTDA was designed and applied through a facile solvothermal strategy. The microstructural, morphological, physicochemical, and photoelectrochemical properties of g-C<sub>3</sub>N<sub>4</sub>@ZnTDA were fully characterized. The photocatalytic activity of g-C<sub>3</sub>N<sub>4</sub>@ZnTDA nanoparticles under visible light source in degrading the 2,4-dibromophenol(2,4-dB) contaminants was also successfully studied. Additionally, the g-C<sub>3</sub>N<sub>4</sub>@ZnTDA composite demonstrates easy operation and good regeneration ability, making it highly promising for the efficient removal of phenolic pollutants from wastewater. Besides, a novel reutilization method for used catalyst as flame retardant and for PU foams was successfully testified. The MCN-3 as a fire-safety coating could reduce the heat release and improve flame retardancy of PU composites. This work opens a new window for valuable inspiration and structural design of reutilized MOF composites.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"42 ","pages":"Article e01154"},"PeriodicalIF":8.6,"publicationDate":"2024-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recycling of spent heat pack towards Fe-Fe3O4@NC catalyst for ORR in direct methanol fuel cells and Al-air batteries 在直接甲醇燃料电池和铝-空气电池中回收利用废热包中的 Fe-Fe3O4@NC 催化剂,用于 ORR
IF 8.6 2区 工程技术
Sustainable Materials and Technologies Pub Date : 2024-10-17 DOI: 10.1016/j.susmat.2024.e01153
Keyru Serbara Bejigo , Ruby Alphonse Raj , Sang-Jae Kim
{"title":"Recycling of spent heat pack towards Fe-Fe3O4@NC catalyst for ORR in direct methanol fuel cells and Al-air batteries","authors":"Keyru Serbara Bejigo ,&nbsp;Ruby Alphonse Raj ,&nbsp;Sang-Jae Kim","doi":"10.1016/j.susmat.2024.e01153","DOIUrl":"10.1016/j.susmat.2024.e01153","url":null,"abstract":"<div><div>The effective repurposing of waste materials is crucial for sustainable development. The widespread use of disposable iron-based chemical warmers (IBCW) generates substantial solid waste annually. In this study, IBCWs were repurposed as raw materials to synthesize different electrocatalyst composites comprising metallic and oxide forms of iron embedded in nitrogen-doped carbon (NC). The composites were evaluated as oxygen reduction reaction (ORR) catalysts. The optimized Fe-Fe<sub>3</sub>O<sub>4</sub>@NC demonstrated enhanced ORR kinetics, with an onset potential of 0.92 V and a half-wave potential of 0.86 V vs. RHE. As an air cathode for direct methanol fuel cell (DMFC), Fe-Fe<sub>3</sub>O<sub>4</sub>@NC achieved a power density of 33.3 mW cm<sup>−2</sup> at 88 mA cm<sup>−2</sup>, demonstrating its practical applicability. Additionally, a quasi solid-state aluminium-air battery (SAAB) was assembled using this catalyst as the air cathode with a PVA-KOH gel electrolyte and the separator. The quasi SAAB exhibited an open circuit voltage (OCV) of 1.46 V, a power density of 40 mW cm<sup>-2</sup>, and good rate capability compared to Pt/C. The combined effect of metallic and oxide iron with nitrogen doping enhances the overall catalytic activity. This study demonstrates that IBCWs can be effectively transformed into valuable catalysts for renewable energy applications, enabling clean and sustainable utilization of waste materials.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"42 ","pages":"Article e01153"},"PeriodicalIF":8.6,"publicationDate":"2024-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142555649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing electromagnetic interference mitigation: A comprehensive study on the synthesis and shielding capabilities of polypyrrole/cobalt ferrite nanocomposites 增强电磁干扰缓解能力:聚吡咯/钴铁氧体纳米复合材料的合成与屏蔽能力综合研究
IF 8.6 2区 工程技术
Sustainable Materials and Technologies Pub Date : 2024-10-16 DOI: 10.1016/j.susmat.2024.e01150
Moustafa A. Darwish , M.M. Salem , Alex V. Trukhanov , Walaa Abd-Elaziem , Atef Hamada , Di Zhou , Anwer S. Abd El-Hameed , M. Khalid Hossain , Enas H. El-Ghazzawy
{"title":"Enhancing electromagnetic interference mitigation: A comprehensive study on the synthesis and shielding capabilities of polypyrrole/cobalt ferrite nanocomposites","authors":"Moustafa A. Darwish ,&nbsp;M.M. Salem ,&nbsp;Alex V. Trukhanov ,&nbsp;Walaa Abd-Elaziem ,&nbsp;Atef Hamada ,&nbsp;Di Zhou ,&nbsp;Anwer S. Abd El-Hameed ,&nbsp;M. Khalid Hossain ,&nbsp;Enas H. El-Ghazzawy","doi":"10.1016/j.susmat.2024.e01150","DOIUrl":"10.1016/j.susmat.2024.e01150","url":null,"abstract":"<div><div>In a society increasingly infiltrated by digital and networking technologies, designing electromagnetic interference (EMI) shielding materials is critical for safeguarding sensitive electronic equipment and ensuring the smooth functioning of essential communication networks. This study focuses on the optimization of the properties of cobalt ferrite (CoFe<sub>2</sub>O<sub>4</sub>)/polypyrrole (PPy) nanocomposites made by in-situ polymerization used for electromagnetic (EM) shielding based on their magnetic and dielectric losses. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), vibrating sample magnetometer (VSM), and vector network analyzer (VNA) were employed to study the materials' physical and chemical characteristics. The findings demonstrate that the magnetic and electric properties of the materials composed of CoFe<sub>2</sub>O<sub>4</sub> and PPy are substantially altered by the integration of CoFe<sub>2</sub>O<sub>4</sub> and PPy. Adding PPy to CoFe<sub>2</sub>O<sub>4</sub> reduces the real and imaginary parts of magnetic permeability, and the conductivity, dielectric constant, and dielectric loss are increased. These effects are advantageous for EM shielding applications. The high electromagnetic shielding performance mainly results from the enhanced interfacial polarization induced by interface region among CoFe<sub>2</sub>O<sub>4</sub> and PPy molecules. The influence of the PPy matrix in altering the dielectric and magnetic loss factors (<em>tanδ</em><sub><em>E</em></sub> and <em>tanδ</em><sub><em>M</em></sub>) of the embedded ferrite particles is pronounced. Although CoFe<sub>2</sub>O<sub>4</sub> shows excellent attenuation characteristics, it cannot optimally match impedance with free space, particularly at higher frequencies. In addition, material thickness and shielding efficiency adjust the reflection loss (<em>RL</em>) performance. The prepared composites can attenuate more than 95 % of the incident electromagnetic waves. This study emphasizes the benefits of employing composite materials in EMI shielding designs and the combined advantages of conductive and magnetic materials.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"42 ","pages":"Article e01150"},"PeriodicalIF":8.6,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142446958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable recycling of pure aluminum from waste chips under supergravity-enhanced separation: A cleaning process 在超重力增强分离条件下从废铝屑中可持续回收纯铝:一种清洁工艺
IF 8.6 2区 工程技术
Sustainable Materials and Technologies Pub Date : 2024-10-16 DOI: 10.1016/j.susmat.2024.e01148
Bolin Sun, Lei Guo, Zhe Wang, Xi Lan, Zhancheng Guo
{"title":"Sustainable recycling of pure aluminum from waste chips under supergravity-enhanced separation: A cleaning process","authors":"Bolin Sun,&nbsp;Lei Guo,&nbsp;Zhe Wang,&nbsp;Xi Lan,&nbsp;Zhancheng Guo","doi":"10.1016/j.susmat.2024.e01148","DOIUrl":"10.1016/j.susmat.2024.e01148","url":null,"abstract":"<div><div>Large quantities of chips containing high levels of aluminum are always inevitably produced during machining process of aluminum products, which is a valuable renewable resource. In this paper, an environmental-friendly method for direct and continuous recovery of same-level recycled Al from waste chips under supergravity-induced was proposed. The oxide film covering the surface of the molten Al-chips was easily disrupted under super-gravity, and subsequently almost all of Al melt detached from the oxide film and flowed rapidly through the microporous ceramic foam filter, with a yield ratio of more than 97 %. During this process, all fine broken oxide-film particles and large amounts of primary iron-rich particles in the melt were captured in the complex channels of the filter, resulting in clean 1xxx series recycled Al with free inclusions and impurity iron content of less than 0.28 wt%. In addition, a sustainable process and a continuous centrifugal unit for recycling aluminum chips were designed, the economic and environmental advantages of which demonstrate the feasibility of sustainable regeneration of aluminum chip resources on an industrial scale via supergravity technique.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"42 ","pages":"Article e01148"},"PeriodicalIF":8.6,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stable and reusable electrospun bio-composite fibrous membranes based on PLA and natural fillers for air filtration applications 基于聚乳酸和天然填料的稳定且可重复使用的电纺生物复合纤维膜,用于空气过滤应用
IF 8.6 2区 工程技术
Sustainable Materials and Technologies Pub Date : 2024-10-11 DOI: 10.1016/j.susmat.2024.e01146
Roberto Scaffaro , Maria Clara Citarrella
{"title":"Stable and reusable electrospun bio-composite fibrous membranes based on PLA and natural fillers for air filtration applications","authors":"Roberto Scaffaro ,&nbsp;Maria Clara Citarrella","doi":"10.1016/j.susmat.2024.e01146","DOIUrl":"10.1016/j.susmat.2024.e01146","url":null,"abstract":"<div><div>Today, air pollution due to fine dust is one of the most critical environmental challenges. To mitigate the potential further environmental impact of air filtration devices, it is essential to explore the use of biodegradable polymers combined with natural fillers, preferably sourced from waste materials, to develop stable, reusable and UV-resistant air filters suitable for outdoor applications. In this work, composite fibrous membranes based on polylactic acid (PLA) and natural fillers were prepared via electrospinning and tested for air filtration applications. Air filtration performances were evaluated at different flow rates, temperature and humidity condition, aiming to simulate outdoor conditions. The addition of 10 wt% of <em>Opuntia Ficus Indica</em> (OFI), <em>Posidonia Oceanica Leaves</em> (POL) or lignin (LIG) particles to PLA solution led to a decrease in fibers diameter increasing membranes filtration performances. PLA/OFI, PLA/POL and PLA/LIG composite membranes exhibited filtration efficiencies of 97.2 %, 99.4 %, 99.6 % for PM<sub>3</sub> at a flow rate of 32 L/min, and pressure drops of 114, 103, 105 Pa, respectively. The membranes demonstrated stability maintaining good filtration efficiency across different environmental conditions and after multiple reuse cycles. The addition of OFI and LIG powders also provided effective UV resistance, crucial for ensuring the longevity and performance of air filters exposed to outdoor conditions. These findings underscore the potential of these biodegradable composite membranes for sustainable indoor and outdoor air filtration solutions.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"42 ","pages":"Article e01146"},"PeriodicalIF":8.6,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exceptionally boosted absorption of silicates by interfacial junctions and direct light–heat–energy storage using Mg(OH)2–(Co2SiO4–Co3O4) 利用界面结和 Mg(OH)2-(Co2SiO4-Co3O4)的直接光热储能技术异常提高硅酸盐的吸收率
IF 8.6 2区 工程技术
Sustainable Materials and Technologies Pub Date : 2024-10-10 DOI: 10.1016/j.susmat.2024.e01142
Rui-Min Hao, En-Xu Ren, Wei Ran, Zhi-Bin Xu, Qin-Pei Wu
{"title":"Exceptionally boosted absorption of silicates by interfacial junctions and direct light–heat–energy storage using Mg(OH)2–(Co2SiO4–Co3O4)","authors":"Rui-Min Hao,&nbsp;En-Xu Ren,&nbsp;Wei Ran,&nbsp;Zhi-Bin Xu,&nbsp;Qin-Pei Wu","doi":"10.1016/j.susmat.2024.e01142","DOIUrl":"10.1016/j.susmat.2024.e01142","url":null,"abstract":"<div><div>Near-infrared (NIR) light absorption is essential for the effective utilization of photothermal solar energy, which is realized via the surface plasmon resonance of a high density of free charge carriers (FCCs). Herein, we demonstrate that S-scheme interfacial junctions (IJs) can substantially increase the FCC density and intensify absorption of silicates from the ultraviolet to NIR region. Numerous p–n IJs with S-scheme types are constructed within sheet-like Co<sub>3</sub>O<sub>4</sub>–Co<sub>2</sub>SiO<sub>4</sub> nanoparticles, exceptionally boosting the light absorption capability over the entire solar spectrum. Moreover, this absorber can improve the photothermal performance of Mg(OH)<sub>2</sub> via a mixture of Mg(OH)<sub>2</sub>–(Co<sub>3</sub>O<sub>4</sub>–Co<sub>2</sub>SiO<sub>4</sub>) composite. The photothermal dehydration conversion of Mg(OH)<sub>2</sub> in this mixture considerably improves by 6.7 times under 30-min irradiation. The reversibility of the photothermal hydration–dehydration cycles of Mg(OH)<sub>2</sub> improves by 18.3 times, and the thermal storage kinetics substantially improves via the reduction of the activation energy of dehydration (reduction of 25.4 %). Results indicate that Mg(OH)<sub>2</sub>–Co<sub>3</sub>O<sub>4</sub>–Co<sub>2</sub>SiO<sub>4</sub> is a promising candidate for a one-step system of photothermal conversion and energy storage.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"42 ","pages":"Article e01142"},"PeriodicalIF":8.6,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-activation of carbons derived from bio-waste cabbage for a green supercapacitor based on seawater electrolyte 基于海水电解质的绿色超级电容器的生物废白菜衍生碳的自激活功能
IF 8.6 2区 工程技术
Sustainable Materials and Technologies Pub Date : 2024-10-10 DOI: 10.1016/j.susmat.2024.e01143
Authit Phakkhawan , Aparporn Sakulkalavek , Narong Chanlek , Supinya Nijpanich , Yuvarat Ngernyen , Siritorn Buranurak , Samuk Pimanpang , Pawinee Klangtakai
{"title":"Self-activation of carbons derived from bio-waste cabbage for a green supercapacitor based on seawater electrolyte","authors":"Authit Phakkhawan ,&nbsp;Aparporn Sakulkalavek ,&nbsp;Narong Chanlek ,&nbsp;Supinya Nijpanich ,&nbsp;Yuvarat Ngernyen ,&nbsp;Siritorn Buranurak ,&nbsp;Samuk Pimanpang ,&nbsp;Pawinee Klangtakai","doi":"10.1016/j.susmat.2024.e01143","DOIUrl":"10.1016/j.susmat.2024.e01143","url":null,"abstract":"<div><div>Carbonized carbons (CC) derived from cabbage were self-activated via a carbonization process at 500–900 °C in Ar. CC synthesized at 800 °C (CC-800), containing KCl, CaCO<sub>3</sub>, Ca(ClO)<sub>2</sub>, K<sub>2</sub>SO<sub>4</sub>, and Ca<sub>5</sub>(PO<sub>4</sub>)<sub>3</sub>(OH), has the highest specific surface area (<em>S</em><sub>BET</sub>, 130.04 m<sup>2</sup> g<sup>−1</sup>), a high specific capacitance (64.06 F g<sup>−1</sup>), and an excellent rate capability (65.12 %). After washing the CC-800 powder in either deionized (DI) water (AC-DI) or hydrochloric acid (HCl) followed by DI water (AC-HCl-DI), <em>S</em><sub>BET</sub> values increased to 919.22 and 1146.51 m<sup>2</sup> g<sup>−1</sup>, respectively. KCl, Ca(ClO)<sub>2</sub>, and K<sub>2</sub>SO<sub>4</sub> are removed from the AC-DI, whereas all compounds are washed from the AC-HCl-DI. Removing these compounds enlarges <em>S</em><sub>BET</sub> values, specific capacitance (114.47 F g<sup>−1</sup> at 0.5 A g<sup>−1</sup>), and rate capability (68.95 %). A high capacitance retention of 97.56 % after 20,000 cycles was achieved from the AC-HCl-DI electrode with 6 M KOH. 0.6 M NaCl and seawater were applied as green electrolytes with the AC-HCl-DI electrode, resulting in the promising specific capacitance of 116.89 and 102.21 F g<sup>−1</sup> at 0.5 A g<sup>−1</sup>, respectively. Symmetric AC-HCl-DI/seawater/AC-HCl-DI cell gives a high energy density of 2.32 Wh kg<sup>−1</sup> at a large power density of 0.25 kW kg<sup>−1</sup>. The four serial AC-HCl-DI/seawater/AC-HCl-DI coin cells could light an LED over 60 s.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"42 ","pages":"Article e01143"},"PeriodicalIF":8.6,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142532032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advancements in ZnO-based photocatalysts for effective rhodamine dye removal from water 基于氧化锌的光催化剂在有效去除水中罗丹明染料方面取得的进展
IF 8.6 2区 工程技术
Sustainable Materials and Technologies Pub Date : 2024-10-09 DOI: 10.1016/j.susmat.2024.e01138
Madhurima Das , Avishek Ghatak , Preetam Guha Ray , Urszula Stachewicz
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