Surface and Interface Analysis最新文献_第8页

Fabrication of molecularly imprinted polymer‐based interdigital sensor for L‐ascorbic acid L -抗坏血酸分子印迹聚合物数字间传感器的制备

4区化学

Surface and Interface Analysis Pub Date : 2023-11-07 DOI: 10.1002/sia.7266

Muafia Akbar, Nauman Sadiq, Memoona Shakoor, Muhammad Shafique, Anum Tahir, Muhammad Zahid, Ghulam Mustafa

{"title":"Fabrication of molecularly imprinted polymer‐based interdigital sensor for L‐ascorbic acid","authors":"Muafia Akbar, Nauman Sadiq, Memoona Shakoor, Muhammad Shafique, Anum Tahir, Muhammad Zahid, Ghulam Mustafa","doi":"10.1002/sia.7266","DOIUrl":"https://doi.org/10.1002/sia.7266","url":null,"abstract":"The level of L‐ascorbic acid (AA) in various natural and artificial foods, medicines and other substances must be determined for biological and agricultural purposes. In this study, an AA‐imprinted poly (methacrylic acid)‐based receptor was synthesized by thermal free‐radical bulk polymerization for the detection of ascorbic acid using the methacrylic acid as monomer, ethylene glycol dimethacrylate (EGDMA) as cross‐linker, and azobisisobutyronitrile (AIBN) as initiator, in the presence of a porogenic solvent dimethyl sulfoxide (DMSO). The synthesized molecularly imprinted polymer (MIP) was used as a receptor. Immobilization of the receptor layer on IDEs provided a suitable sensor for AA detection by measuring changes in electrical parameters including inductance, capacitance, and resistance with the help of LCR meter. In the series and parallel inductance, the lowest detection limits were 0.13 and 0.001 ppm, respectively. While, for series and parallel capacitance, the lowest detection limits were 0.01548 and 1.3698 ppm, respectively. In the case of resistance, the lowest limit of detection was 0.0076 and 0.08121 ppm in series and parallel, respectively. The imprinted polymer‐based sensor showed sensitivity, selectivity, and reversibility for ascorbic acid.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":"238 5","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135476222","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comparative investigation on organosilicon film growth by cyclonic plasma using hexamethyldisilazane and hexamethyldisilazane/nitrogen gas mixture 六亚甲基二氮氮和六亚甲基二氮氮/氮气混合物在旋流等离子体中生长有机硅薄膜的比较研究

4区化学

Surface and Interface Analysis Pub Date : 2023-10-29 DOI: 10.1002/sia.7263

Li‐Yu Wu, Shu‐Mei Wang, Ya‐Shin Ji, Chun Huang

{"title":"Comparative investigation on organosilicon film growth by cyclonic plasma using hexamethyldisilazane and hexamethyldisilazane/nitrogen gas mixture","authors":"Li‐Yu Wu, Shu‐Mei Wang, Ya‐Shin Ji, Chun Huang","doi":"10.1002/sia.7263","DOIUrl":"https://doi.org/10.1002/sia.7263","url":null,"abstract":"This study aimed to discover the surface characteristics of cyclonic plasma‐deposited films and the effect of nitrogen gas addition. The influence of nitrogen gas addition on the surface characteristics of organosilicon films in hexamethyldisilazane (HMDSN) and HMDSN/nitrogen (HMDSN/N 2 ) cyclonic plasmas at atmospheric pressure was evaluated. It was found that the addition of nitrogen gas is a crucial factor affecting organosilicon film growth in the plasma cyclone in one atmosphere. SEM, AFM, and ATR‐FTIR results indicated that on adding nitrogen gas, the surface morphology became rougher, the peak corresponding to the Si–O–Si group was detected at approximately 1050 cm −1 , the degree of porosity was relatively low, and the proportion of the SiCHx group decreased. In general, the surface energies of the films deposited in the HMDSN discharge and the HMDSN/N 2 gas mixture discharge exhibited similar features. SEM and AFM evaluations showed high roughness values of 44.5 nm for the film formation in the HMDSN/N 2 gas mixture discharge, while the films grown in the HMDSN discharge exhibited a relatively flat surface with a roughness of 24.5 nm. Based on ATR‐FTIR detection, cyclonic plasma‐deposited films deposited in the HMDSN discharge obtained organic moieties, while the films generated in the HMDSN/N 2 gas mixture discharge exhibited strong Si–O–Si absorption signals. A possible nano‐organosilicon film growth that prevails in atmospheric pressure plasma deposition is proposed based on atmospheric‐pressure plasma chemistry, nitrogen gas addition, and experimental observations.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":"68 6","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136136049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chemical functionality of surfaces for the characteristic adsorption of melamine 三聚氰胺特性吸附表面的化学功能

4区化学

Surface and Interface Analysis Pub Date : 2023-10-25 DOI: 10.1002/sia.7265

Mohit Tiwari, Sudip K. Pattanayek

{"title":"Chemical functionality of surfaces for the characteristic adsorption of melamine","authors":"Mohit Tiwari, Sudip K. Pattanayek","doi":"10.1002/sia.7265","DOIUrl":"https://doi.org/10.1002/sia.7265","url":null,"abstract":"The surface functionality leading to a high reversibility adsorption of melamine was determined. Four different silane coupling agents, namely, 3‐(tri‐methoxysilyl) propyl methacrylate (TMSPMA), n‐propyl tri‐methoxy‐silane (PTMS), 3‐(tri‐ethoxysilyl) propionitrile (TESPN), and tri‐methoxy‐(octadecyl) silane (OTMS) were taken for making chemical functionality methacrylate, short methyl, nitrile, and extended methyl group respectively. The adsorption behavior of melamine over the substrates with four functionalities was determined using quartz crystal microbalance (QCM). The adsorption kinetics and adsorption isotherms of the adsorption studies were analyzed. The initial adsorption rate depends on the hydrophobicity and roughness of the surfaces. However, the subsequent adsorption rate depends on the specific interaction. The data of equilibrium adsorbed mass at various equilibrium concentrations were fitted with the modified Brunauer–Emmett–Teller (BET) and Freundlich adsorption isotherms. The estimated model parameters were analyzed and compared with the reported parameters of the relevant systems. There is good agreement between our results and the reported results. In addition, very high adsorption with a very high binding constant was observed for the adsorption of melamine OTMS surface. On the other hand, high adsorption with an intermediate layer binding constant for the adsorption of melamine on the methacrylate surface was observed. Based on this, we propose using acrylate chemical functionality to develop molecularly imprinted polymer‐based melamine sensors.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":"36 3","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135170821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Large‐area growth of monolayer MoS₂ by using atmospheric‐pressure chemical vapor deposition with nucleation controlling process 常压化学气相沉积法在成核控制过程中大面积生长单层MoS2

4区化学

Surface and Interface Analysis Pub Date : 2023-10-23 DOI: 10.1002/sia.7264

Binbin Ding, Changjun Zhu, Tianming Wang, Lianbi Li, Zebin Li, Lin Cheng, Song Feng, Guoqing Zhang, Yuan Zang, Jichao Hu, Lei Li, Caijuan Xia

引用次数: 0

Effect of liquid ammonia and protease on surface modification and shrink resistance of wool 液氨和蛋白酶对羊毛表面改性及抗收缩性能的影响

4区化学

Surface and Interface Analysis Pub Date : 2023-10-22 DOI: 10.1002/sia.7262

Xianqin Shang, Qiang Wang, Zhe Jiang, Haitao Ma

引用次数: 0

Simultaneous measurement of impurities and composition by secondary ion mass spectrometry with optical emission spectrometry 二次离子质谱法与光学发射光谱法同时测定杂质和成分

4区化学

Surface and Interface Analysis Pub Date : 2023-10-13 DOI: 10.1002/sia.7255

Takashi Miyamoto, Shigenori Numao, Junichiro Sameshima, Masanobu Yoshikawa

{"title":"Simultaneous measurement of impurities and composition by secondary ion mass spectrometry with optical emission spectrometry","authors":"Takashi Miyamoto, Shigenori Numao, Junichiro Sameshima, Masanobu Yoshikawa","doi":"10.1002/sia.7255","DOIUrl":"https://doi.org/10.1002/sia.7255","url":null,"abstract":"Various secondary particles are emitted when the surface of solid matter is irradiated with ions. This phenomenon has been utilized in several methods to analyze target materials. In analytical techniques, the method used to detect secondary ions is called “secondary ion mass spectrometry (SIMS).” In contrast, “secondary ion mass spectrometry with optical emission spectrometry (SIMS‐OES)” detects photons emitted from sputtered, excited atoms. Both SIMS and OES can characterize a sample surface and perform local elemental analysis of the surface, depth profiling of elements, and detection of any atom. SIMS with high sensitivity has mainly been developed for the impurity analyses of semiconductors. However, no research has been reported on applications using SIMS‐OES or a combination of SIMS and SIMS‐OES. In this study, we prove that atomic emission can be observed via ion irradiation. In addition, we show that the composition analysis is possible using the SIMS‐OES method. Herein, impurity and composition analyses were enabled by utilizing atomic emission. Moreover, we proved that an assessment with high‐depth direction resolution is feasible by etching the circumference of a crater in advance.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":"24 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135853673","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structural, electronic, and thermoelectric properties of hydroxyl groups adsorption on SnO₂ (110) surface: A first‐principles study 羟基在SnO2(110)表面吸附的结构、电子和热电性质:第一性原理研究

4区化学

Surface and Interface Analysis Pub Date : 2023-10-10 DOI: 10.1002/sia.7261

N. Bouchelarem, F. Bouamra, M. Derbal, M. Rérat

引用次数: 0

Surface analysis insight note: Multivariate curve resolution of an X‐ray photoelectron spectroscopy image 表面分析洞察注:X射线光电子能谱图像的多变量曲线分辨率

4区化学

Surface and Interface Analysis Pub Date : 2023-10-05 DOI: 10.1002/sia.7260

Behnam Moeini, Neal Gallagher, Matthew R. Linford

{"title":"Surface analysis insight note: Multivariate curve resolution of an X‐ray photoelectron spectroscopy image","authors":"Behnam Moeini, Neal Gallagher, Matthew R. Linford","doi":"10.1002/sia.7260","DOIUrl":"https://doi.org/10.1002/sia.7260","url":null,"abstract":"This Insight Note follows a series of three previous insight notes on X‐ray photoelectron spectroscopy image analysis that focused on the importance of analyzing the raw data, the use of summary statistics, and principal component analysis (PCA). The same X‐ray photoelectron spectroscopy image data set was analyzed in all three notes. We now show an analysis of this same data set using multivariate curve resolution (MCR). MCR is a widely used exploratory data analysis method. Because of MCR's nonnegativity constraints, it has the important advantage of producing factors that look like real spectra. That is, both its scores and loadings are positive, so its results are often more interpretable than those from PCA. The requirements for preprocessing data are also, in general, lower for MCR compared with PCA. To help determine the number of factors that best describe the data set, a series of MCR models with different numbers of factors was created. Based on the chemical reasonableness of its factors, a two‐factor model was selected. Scores plots/images show the regions of the image that correspond to these two factors.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":"77 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134976018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Tribochemistry effect on the friction reduction of Al₂O₃/ethylene glycol composite lubricant between steel self‐mated tribosystem 摩擦化学对Al2O3/乙二醇复合润滑剂钢间摩擦减量的影响

4区化学

Surface and Interface Analysis Pub Date : 2023-09-21 DOI: 10.1002/sia.7259

Peng Liu, Qing Xu, Renhui Zhang

引用次数: 0

Electronic structure and optical absorption property of BaTiO₃/BiCoO₃ BaTiO3/BiCoO3的电子结构及光学吸收性能

4区化学

Surface and Interface Analysis Pub Date : 2023-09-18 DOI: 10.1002/sia.7258

Lijing Wei, Ling Pang, Shaoyuan Pang, Jianan Sun, Pan Yang, Jianxin Guo

{"title":"Electronic structure and optical absorption property of BaTiO<sub>3</sub>/BiCoO<sub>3</sub>","authors":"Lijing Wei, Ling Pang, Shaoyuan Pang, Jianan Sun, Pan Yang, Jianxin Guo","doi":"10.1002/sia.7258","DOIUrl":"https://doi.org/10.1002/sia.7258","url":null,"abstract":"In this paper, we calculated the different forms of BaTiO 3 /BiCoO 3 composite structure, predicting their visible light absorption performance based on the electronic structure using the first principles calculations. Firstly, six possible compounds that come from BaTiO 3 and BiCoO 3 were constructed. By calculating the different antiferromagnetic (AFM) structures of strip, columnar, and layered composite structures, it is found that the ground state of the composite structure changes to G‐type AFM structure from C‐type AFM structure of pure BiCoO 3 under the influence of BaTiO 3 . Energy band calculations show that band gaps of three composite structures are smaller than those of pure BaTiO 3 and pure BiCoO 3 . Furthermore, density of states analysis shows that the conduction band minimum (CBM) and valence band maximum (VBM) of three composite structures are mainly from the contribution of Co 3 d and O 2 p . For the characteristic that CBM and VBM of materials come from different atoms, it would reduce the recombination opportunities of electrons and holes and is conducive to the increase of photoelectric conversion efficiency under visible light irradiation. The calculation of optical properties shows that optical absorption coefficients of three composite structures are much larger than that of BaTiO 3 , especially the layered composite structure. There is a high absorption peak near 500 nm of the solar spectral irradiation maximum, which is significantly important to improve the optical energy conversion efficiency of the composite materials. The work provides an effective way for the application of wide band gap ferroelectric materials in ferroelectric photovoltaic.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":"224 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135208099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0