Surface and Interface Analysis最新文献

Effect of Surface Dissolution on the Floatability of Brucite in Three Anionic Collector Systems 表面溶解对三种阴离子收集器系统中白云石漂浮性的影响

IF 1.7 4区化学

Surface and Interface Analysis Pub Date : 2024-09-05 DOI: 10.1002/sia.7355

Xiufeng Gong, Jin Yao, Wanzhong Yin, Ningbo Song, Yulian Wang

{"title":"Effect of Surface Dissolution on the Floatability of Brucite in Three Anionic Collector Systems","authors":"Xiufeng Gong, Jin Yao, Wanzhong Yin, Ningbo Song, Yulian Wang","doi":"10.1002/sia.7355","DOIUrl":"https://doi.org/10.1002/sia.7355","url":null,"abstract":"This study investigated the relation between the solubility and floatability of the soluble mineral brucite, focusing on the concentration characteristics of dissolved Mg2+ in brucite under three dissolution methods and the surface characteristics after dissolution. Some common rules of brucite flotation in three anionic collectors were discovered. Results of a flotation test showed that for three anionic collector systems of sodium oleate, sodium dodecyl sulfonate, and oxidized paraffin soap, the flotation recovery rate of brucite increased with the time of dissolution and decreased with the removal of dissolved Mg2+, but the flotation recovery rate is lower than that of untreated brucite. Inductively coupled plasma spectroscopy indicated that the content of dissolved Mg2+ in brucite slurry increases with increasing brucite content or dissolution time. Zeta potential measurements showed that the ability of dissolved Mg2+ to increase the surface potential of brucite follows the order of H2SO4 action > HCl action > H2O action. Adsorption capacity measurements showed that the presence of dissolved Mg2+ after dissolution is not beneficial for the adsorption of the three collectors on the surface of brucite. The capacity of the adsorption collectors follows the order of brucite after H2O dissolution > brucite after HCl dissolution > brucite after H2SO4 dissolution. Scanning electron microscopy and X‐ray photoelectron spectroscopy analyses indicated that the surface dissolution promoted the dissolution of Mg2+ on brucite surface in the solution, reducing the number of Mg sites on brucite surface and deteriorating the collection effect of the collector.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142187368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation and Properties of Mo/Ti/Sn Conductivity Conversion Coatings on 6063 Aluminum Alloy 6063 铝合金上的钼/钛/硒导电转换涂层的制备与性能

IF 1.7 4区化学

Surface and Interface Analysis Pub Date : 2024-09-03 DOI: 10.1002/sia.7352

Aihua Yi, Min Liu, Wenfang Li, Yuying Liu, Yeping Mo, Zhiquan Huang, Xiaolan Chen

{"title":"Preparation and Properties of Mo/Ti/Sn Conductivity Conversion Coatings on 6063 Aluminum Alloy","authors":"Aihua Yi, Min Liu, Wenfang Li, Yuying Liu, Yeping Mo, Zhiquan Huang, Xiaolan Chen","doi":"10.1002/sia.7352","DOIUrl":"https://doi.org/10.1002/sia.7352","url":null,"abstract":"Conductivity chromium‐free conversion coatings on aluminum substrates were achieved by utilizing Na2SnO3 and Mo/Ti solutions. The composition and morphology of the coatings were characterized using XPS, SEM, EDS, AFM, and Raman spectroscopies. The corrosion behavior of the coatings in 3.5‐wt% NaCl solution was investigated through a dynamic potential polarization method and EIS analysis. Mott–Schottky and UV–Vis analyses were used to determine the semiconductor properties of the coatings, including carrier concentration and band gap. The results revealed that the main components of the coating were Al2O3, SnO2, MoO3, and MoO2 and the coating presented a double‐layer structure, including a transition layer close to the substrate and a compact layer on the surface. The coating also exhibited the properties of a p‐type semiconductor. The electrical contact resistance value of adding Na2SnO3 decreased from 0.4331 to 0.1343 Ω/in2 (in 200 psi), while the band gap decreased from 2.281 to 2.232 eV.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142187370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Nanosilicon Stabilized With Ligands: Effect of High‐Energy Proton Beam on Luminescent Properties 配体稳定的纳米硅：高能质子束对发光特性的影响

IF 1.7 4区化学

Surface and Interface Analysis Pub Date : 2024-08-31 DOI: 10.1002/sia.7354

Leonid A. Aslanov, Vladimir B. Zaitsev, Valery N. Zakharov, Igor K. Kudryavtsev, Vladimir M. Senyavin, Petr B. Lagov, Elena P. Romanteeva

引用次数: 0

Structural Analysis and Electrical Property of Acid‐Treated MWCNT 酸处理 MWCNT 的结构分析和电学特性

IF 1.7 4区化学

Surface and Interface Analysis Pub Date : 2024-08-29 DOI: 10.1002/sia.7353

Jaekwang Lee, Hyunwoo Lim, Joo‐yeon Ha, Seungjae Lee, Heesoo Lee

{"title":"Structural Analysis and Electrical Property of Acid‐Treated MWCNT","authors":"Jaekwang Lee, Hyunwoo Lim, Joo‐yeon Ha, Seungjae Lee, Heesoo Lee","doi":"10.1002/sia.7353","DOIUrl":"https://doi.org/10.1002/sia.7353","url":null,"abstract":"The electrical properties of acid‐treated CNT were investigated in terms of functional group and microstructure. A mixture of HNO3 and H2SO4 was used to acid treatment of CNT, and acid‐treated CNTs were synthesized by the mixture for 0 to 5 h. In crystal structure analysis, as acid treatment time was increased, the intensity of graphite diffraction peak was decreased and shifted to lower angle. It indicates a decrease in the crystallinity of CNT surface and lattice contraction by loss of carbon atoms. The distribution of oxygen on CNT surface was observed by TEM analysis confirming that functional groups and structural defects were formed. ID/IG ratio and average distance between defects (LD) were calculated using Raman spectroscopy to analyze the structural characteristics of CNT, and the greatest decrease was identified from p‐CNT to 2h‐CNT, resulting in the formation of functional groups and the changes in structural defects on CNT surface by acid treatment in the initial stage. Bonding state on CNT surface was analyzed through XPS analysis, and functional groups such as CO and COH were confirmed in acid‐treated CNT. Sheet resistance was measured to analyze the electrical properties of CNT, and 3h‐CNT showed the lowest sheet resistance at 25.28 Ω.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142187371","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Combined Experimental and Periodic DFT Study of the Size Dependence of Adsorption Properties of Oxide‐Supported Metal Nanoclusters: A Case of NO on Ni/Al2O3 氧化物支撑金属纳米团簇吸附特性的尺寸依赖性实验与周期 DFT 结合研究：氮氧化物在 Ni/Al2O3 上的吸附情况

IF 1.7 4区化学

Surface and Interface Analysis Pub Date : 2024-08-22 DOI: 10.1002/sia.7350

Tamerlan T. Magkoev, Yong Men, Reza Behjatmanesh‐Ardakani, Mohammadreza Elahifard, Vladimir T. Abaev, Petrakis Chalikidi, Taymuraz T. Magkoev, Oleg G. Ashkhotov

{"title":"Combined Experimental and Periodic DFT Study of the Size Dependence of Adsorption Properties of Oxide‐Supported Metal Nanoclusters: A Case of NO on Ni/Al2O3","authors":"Tamerlan T. Magkoev, Yong Men, Reza Behjatmanesh‐Ardakani, Mohammadreza Elahifard, Vladimir T. Abaev, Petrakis Chalikidi, Taymuraz T. Magkoev, Oleg G. Ashkhotov","doi":"10.1002/sia.7350","DOIUrl":"https://doi.org/10.1002/sia.7350","url":null,"abstract":"It is demonstrated by means of ultra high vacuum (UHV) surface‐sensitive techniques and periodic density functional theory (DFT) calculations that the electronic and NO− adsorption properties of nanosized Ni clusters deposited onto the α‐Al2O3 (0001) surface significantly depend upon the size of the cluster. The properties of the Ni cluster of the size of 2 nm and lower are predominantly determined by the formation of the Ni/Al2O3 interface bond notably polarized towards the oxide. As a result, the metal cluster acquires a net positive charge manifested by the bond strengthening of adsorbed NO compared to the bulk Ni substrate. With the increasing size of the cluster, the Ni/Al2O3 interfacial bond depolarizes due to the growing of lateral Ni–Ni interaction. With a mean coverage of Ni on the alumina surface exceeding 0.25 equivalent monolayers, their properties in terms of adsorption behavior of NO resemble those that are characteristic for the bulk Ni substrate. Such a size dependence offers an opportunity to tune the properties of metal clusters and the metal/oxide system as a whole, for example, to achieve the required electronic and adsorption‐reaction properties.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142187372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A spectroscopic ellipsometry study of TiO2:ZrO2 on TiN/Si thin films prepared by Chemical Beam Vapor Deposition 化学束气相沉积法制备的 TiN/Si 薄膜上的 TiO2:ZrO2 的光谱椭偏仪研究

IF 1.6 4区化学

Surface and Interface Analysis Pub Date : 2024-08-09 DOI: 10.1002/sia.7348

Pratiksha Agnihotri, Aman Verma, Anjali Saini, Rashmi Rani, W. Maudez, E. Wagner, G. Benvenuti, Chandan Banerjee, Mrinal Dutta, Radheshyam Rai

{"title":"A spectroscopic ellipsometry study of TiO2:ZrO2 on TiN/Si thin films prepared by Chemical Beam Vapor Deposition","authors":"Pratiksha Agnihotri, Aman Verma, Anjali Saini, Rashmi Rani, W. Maudez, E. Wagner, G. Benvenuti, Chandan Banerjee, Mrinal Dutta, Radheshyam Rai","doi":"10.1002/sia.7348","DOIUrl":"https://doi.org/10.1002/sia.7348","url":null,"abstract":"The application of variable angle spectroscopic ellipsometry (VASE) to the characterization of thin films is very important because it facilitates the understanding of their physical and optical properties. To prepare a series of film samples consisting of TiO2:ZrO2 on a TiN/Si substrate, we employed the SYBILLA P200 equipment (manufactured by ABCD Technology) through the process of Chemical Beam Vapor Deposition (CBVD). TiO2:ZrO2 on TiN/Si thin films is a composite material that has gained significant attention in various technological applications, particularly in the field of thin film coatings on semiconductor substrates like TiN/Si. TiO2:ZrO2 thin films exhibit excellent dielectric properties and good thermal stability, making them suitable for various electronic and semiconductor applications. From FESEM and EDX analysis, it is found that with increase of Ti/Zr atomic ratio, grain size increases. Ellipsometric analysis reveals increase in film thickness and refractive index with increase in Ti/Zr atomic ratio. As the film continues to grow, changes in its microstructural phase led to a transition from a monolayer physical ellipsometry model to a bilayer physical model. This transition is due to the appearance of inhomogeneity in the TiO2:ZrO2 thin film. Dynamic fits obtained using a two‐layer physical model and a Cauchy–Lorentz optical model show three distinct phases in the film growth phase: a nucleation phase, a fusion phase, and a continuous layer phase. Although our proposed model shows satisfactory performance in most cases, the determination of the refractive index can be problematic for very thin thicknesses. The developed VASE modeling process should be able to generate TiO2:ZrO2characterization on TiN/Si substrate films using comparable physical and optical modeling considerations.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":null,"pages":null},"PeriodicalIF":1.6,"publicationDate":"2024-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141922840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Three‐dimensional carbon nanotube framework enables low‐cost LiFe5O8 anode material for high‐performance lithium‐ion batteries 三维碳纳米管框架实现了用于高性能锂离子电池的低成本 LiFe5O8 负极材料

IF 1.7 4区化学

Surface and Interface Analysis Pub Date : 2024-08-06 DOI: 10.1002/sia.7347

Lei Li, Jinsheng Huo, Qiwen Ran, Xingquan Liu

{"title":"Three‐dimensional carbon nanotube framework enables low‐cost LiFe5O8 anode material for high‐performance lithium‐ion batteries","authors":"Lei Li, Jinsheng Huo, Qiwen Ran, Xingquan Liu","doi":"10.1002/sia.7347","DOIUrl":"https://doi.org/10.1002/sia.7347","url":null,"abstract":"LiFe5O8 is regarded as a promising material, which is used as anode for lithium‐ion batteries on account of its lower cost and higher theoretical capacity. However, its practical applications are hindered by the low electron transfer rate, poor cycling performance, and huge magnification of lattice volume. In this work, a LiFe5O8/carbon nanotubes (CNTs) composite anode is designed to realize the ideal anode for low‐cost lithium‐ion batteries, showing broad commercial application prospects. It is found that the three‐dimensional conductive network of CNTs is used to accelerate electron transfer rate within the LiFe5O8 particles, thereby significantly reducing the reversible reaction barrier (Fe/Fe3O4). In addition, it can also alleviate the volume change of electrode, which maintains a stable Li+ insertion/extraction behavior during long‐term cycles. As a consequence, there is still a high capacity (427.3 mAh g−1) of the LiFe5O8/CNTs 3% anode reserved after 50 cycles at 0.5 C whereas the bare LiFe5O8 anode only delivers a low capacity of 220.6 mAh g−1 along with a poor cycling stability. This work highlights the outstanding contribution of electronic conductivity toward the electrochemical performance of LiFe5O8 anode and provides a low‐cost and commercially applicable composite anode for developing lower cost lithium‐ion batteries.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-08-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141945020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Design and optimization of hexagonal tungsten ring metasurface perfect absorbers with circuit model 利用电路模型设计和优化六边形钨环元表面完美吸收器

IF 1.7 4区化学

Surface and Interface Analysis Pub Date : 2024-08-05 DOI: 10.1002/sia.7346

Ali Reza Sarikhani, Mohammad Reza Salehi, Seyedeh Leila Mortazavifar, Mojtaba Shahraki, Ebrahim Abiri

{"title":"Design and optimization of hexagonal tungsten ring metasurface perfect absorbers with circuit model","authors":"Ali Reza Sarikhani, Mohammad Reza Salehi, Seyedeh Leila Mortazavifar, Mojtaba Shahraki, Ebrahim Abiri","doi":"10.1002/sia.7346","DOIUrl":"https://doi.org/10.1002/sia.7346","url":null,"abstract":"In this paper, a perfect absorber (PA) based on tungsten is proposed to include hexagonal‐shaped metasurface absorbers with varying hole sizes ranging from quadrangular to circular, allowing them to cover a wide wavelength spectrum. The study investigates the effects of various parameters, including the number of sides of the inner hole, on the absorber's performance and identifies the most suitable absorber by introducing an equivalent circuit. The outcomes of full‐wave numerical simulations primarily based on the finite element method (FEM) highly correspond to the final results of the circuit model. Additionally, the circuit model significantly reduces computation time and requires less storage compared with full‐wave simulations. The results show that the hexagonal‐square metasurface absorber achieves exceptional absorption rates, with an average of 99.9% in the 431 to 532 nm wavelength range and over 90% in the 300 to 915 nm range. The hexagonal‐hexagonal metasurface absorber also exhibits high absorption rates, with an average of over 99% in the 431 to 518 nm and 700 to 780 nm ranges, and over 90% in the 300 to 940 nm range. The absorption performance of the proposed hexagonal‐circle metasurface absorber is also remarkable, with an absorption value of over 99% in the 670 to 771 nm range and above 90% in the 365 to 991 nm range. These models can be utilized to design and simulate other subwavelength absorbers in a broad frequency range, including terahertz and visible light, making them suitable for various applications.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141969366","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Influence of the base pressure in deposition of a‐SiCx interlayers for adhesion of Diamond‐Like Carbon on metallic alloy 基底压力对在金属合金上沉积 a-SiCx 夹层以粘附类金刚石碳的影响

IF 1.7 4区化学

Surface and Interface Analysis Pub Date : 2024-07-26 DOI: 10.1002/sia.7345

Jennifer Stefani Weber, Michael Cristian Goldbeck, Vanessa Piroli, Carla Daniela Boeira, Bruna Louise Perotti, Newton Kiyoshi Fukumasu, Fernando Alvarez, Alexandre Fassini Michels, Carlos Alejandro Figueroa

{"title":"Influence of the base pressure in deposition of a‐SiCx interlayers for adhesion of Diamond‐Like Carbon on metallic alloy","authors":"Jennifer Stefani Weber, Michael Cristian Goldbeck, Vanessa Piroli, Carla Daniela Boeira, Bruna Louise Perotti, Newton Kiyoshi Fukumasu, Fernando Alvarez, Alexandre Fassini Michels, Carlos Alejandro Figueroa","doi":"10.1002/sia.7345","DOIUrl":"https://doi.org/10.1002/sia.7345","url":null,"abstract":"Diamond‐like carbon (DLC) is an amorphous material widely used in industrial applications due to its chemical, mechanical, and tribological properties and, also, for decorative purposes. However, its low adhesion to ferrous alloys reduces its effectiveness in certain applications, necessitating the use of adhesion interlayers to reduce stresses at the interfaces and enhance the density of strong bonds. In this context, the factors that promote good adhesion in this system and specify the parameters must be understood in detail. Thus, the present study aims to assess the influence of the base pressure on the deposition of an amorphous silicon carbide adhesion interlayer between DLC coating and a ferrous alloy substrate. Microstructural, physicochemical, morphological, and mechanotribological analyses were conducted to understand the adhesion behavior in terms of structural and chemical aspects. In addition to the influence of the interlayer thickness, the elemental Si/C ratios and the relative oxygen content have an impact on the maximum load supported by the coatings, as well as the different delamination mechanisms generated in adhesion tests.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141784866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

X‐ray standing wave assisted XANES for depth dependent chemical state analysis of Cr in Cr2O3/Cr bilayer structure 利用 X 射线驻波辅助 XANES 对 Cr2O3/Cr 双层结构中的 Cr 进行深度依赖性化学态分析

IF 1.7 4区化学

Surface and Interface Analysis Pub Date : 2024-07-18 DOI: 10.1002/sia.7342

Ayushi Trivedi, Md. Akhlak Alam, Ajay Khooha, Rajnish Dhawan, Rajendra Kumar Sharma, Shilpa Tripathi, Manoj Kumar Tiwari

{"title":"X‐ray standing wave assisted XANES for depth dependent chemical state analysis of Cr in Cr2O3/Cr bilayer structure","authors":"Ayushi Trivedi, Md. Akhlak Alam, Ajay Khooha, Rajnish Dhawan, Rajendra Kumar Sharma, Shilpa Tripathi, Manoj Kumar Tiwari","doi":"10.1002/sia.7342","DOIUrl":"https://doi.org/10.1002/sia.7342","url":null,"abstract":"We report the detailed depth‐dependent structural and chemical analysis of the Cr2O3/Cr bilayer structure deposited on Si ˂100˃ substrate. The non‐destructive simultaneous X‐ray reflectivity and grazing incidence X‐ray fluorescence measurements were used for this purpose. Corresponding variation in the chemical state of Cr atoms as a function of depth has been studied using X‐ray standing wave (XSW) assisted X‐ray absorption near edge structure (XANES) measurements. Various oxidation states of Cr atoms present in the Cr2O3/Cr bilayer structure were determined using X‐ray photoelectron spectroscopy (XPS). Depth‐resolved XANES measurements confirmed the presence of chromium oxide (Cr2O3) and hydroxide (Cr (OH)3) at the top surface of the Cr2O3/Cr bilayer structure. The results also reveal the presence of metallic Cr along with its compounds Cr2O3 and Cr (OH)3 at the interface medium, showing significant mixing between the Cr2O3 and Cr layers. Our results clearly demonstrate that the XSW assisted XANES technique is extremely efficient for determining the variation of chemical states at the surface, interface, and different depths of a thin film structure. Such types of analysis are particularly useful for differentiating the presence of a metal from its own oxides, even at higher depths inside a thin film medium.","PeriodicalId":22062,"journal":{"name":"Surface and Interface Analysis","volume":null,"pages":null},"PeriodicalIF":1.7,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141745559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0