{"title":"Temperature dependence of dielectric nonlinearity of BaTiO<sub>3</sub> ceramics","authors":"Ichiro Fujii, Susan Trolier-McKinstry","doi":"10.20517/microstructures.2023.43","DOIUrl":"https://doi.org/10.20517/microstructures.2023.43","url":null,"abstract":"In many commercially utilized ferroelectric materials, the motion of domain walls is an important contributor to the functional dielectric and piezoelectric responses. This paper compares the temperature dependence of domain wall motion for BaTiO3 ceramics with different grain sizes, point defect concentrations, and formulations. The grain boundaries act as significant pinning points for domain wall motion such that fine-grained materials show smaller extrinsic contributions to the properties below the Curie temperature and lower residual ferroelectric contributions immediately above the Curie temperature. Oxygen vacancy point defects make a modest change in the extrinsic contributions of undoped BaTiO3 ceramics. In formulated BaTiO3, extrinsic contributions to the dielectric response were suppressed over a wide temperature range. It is believed this is due to a combination of reduced grain size, the existence of a core-shell microstructure, and a reduction in domain wall continuity over the grain boundaries.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136227952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Influence of hydrogel and porous scaffold on the magnetic thermal property and anticancer effect of Fe<sub>3</sub>O<sub>4</sub> nanoparticles","authors":"Man Wang, Rui Sun, Huajian Chen, Xiaohan Liu, Toru Yoshitomi, Masaki Takeguchi, Naoki Kawazoe, Yingnan Yang, Guoping Chen","doi":"10.20517/microstructures.2023.46","DOIUrl":"https://doi.org/10.20517/microstructures.2023.46","url":null,"abstract":"Magnetic hyperthermia uses magnetic nanoparticles (MNPs) for conversion of magnetic energy into thermal energy under an alternating magnetic field (AMF) to increase local temperature for ablation of cancer cells. The magnetic thermal capacity of MNPs not only depends on the intrinsic properties of MNPs but is also affected by the microenvironmental matrices surrounding the MNPs. In this study, the influence of agarose hydrogels and gelatin porous scaffolds on the magnetic thermal property and anticancer effect of Fe3O4 nanoparticles (NPs) were investigated with a comparison to free Fe3O4 NPs. Flower-like Fe3O4 NPs were synthesized and embedded in agarose hydrogels and gelatin porous scaffolds. Under AMF irradiation, the free Fe3O4 NPs had the best magnetic thermal properties and the most efficiently increased the local temperature to ablate breast cancer cells. However, the Fe3O4 NPs embedded in agarose hydrogels and gelatin porous scaffolds showed reduced magnetic-thermal conversion capacity, and the local temperature change was decreased in comparison to free Fe3O4 NPs during AMF irradiation. The gelatin porous scaffolds showed a higher inhibitory influence than the agarose hydrogels. The inhibitory effect of agarose hydrogels and gelatin porous scaffolds on magnetic-thermal conversion capacity resulted in a decreased anticancer ablation capacity to breast cancer cells during AMF irradiation. The Fe3O4 NP-embedded gelatin scaffolds showed the lowest anticancer effect. The results suggested that the matrices used to deliver MNPs could affect their performance, and appropriate matrices should be designed to maximize their therapeutic effect for biomedical applications.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135584774","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Magnetic structures and correlated physical properties in antiperovskites","authors":"Sihao Deng, Hongde Wang, Lunhua He, Cong Wang","doi":"10.20517/microstructures.2023.42","DOIUrl":"https://doi.org/10.20517/microstructures.2023.42","url":null,"abstract":"Compounds with perovskite structures have become one of the focuses in both materials science and condensed matter physics because of their fascinating physical properties and potential functionalities correlated to magnetic structures. However, the understanding of the intriguing physical properties is still at an exploratory stage. Herein, owing to the magnetic frustration prompted by Mn6N or Mn6C octahedra, the abounding magnetic structures of antiperovskites, including collinear antiferromagnetic, collinear ferromagnetic, collinear ferrimagnetic, non-collinear magnetic, and non-coplanar magnetic spin configurations, are systematically introduced through the updated coverage. In addition, owing to the “spin-lattice-charge” coupling of antiperovskites, a large number of physical properties, such as anomalous thermal expansion, giant magnetoresistance, anomalous Hall effect, piezomagnetic/baromagnetic effects, magnetocaloric effect, barocaloric effect, etc ., are summarized by combining the discussions of the determined magnetic structures. This review aims to clarify the current research progress in this field, focusing on the relationship between the magnetic structures and the correlated physical properties, and provides the conclusion and outlook on further performance optimization and mechanism exploration in antiperovskites.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135634010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Cryogenic atom probe tomography and its applications: a review","authors":"Ziyang Zhou, Zhengquan Wang, Ranming Niu, Pang-Yu Liu, Chao Huang, Yi-Hsuan Sun, Xiutong Wang, Hung-Wei Yen, Julie M. Cairney, Yi-Sheng Chen","doi":"10.20517/microstructures.2023.38","DOIUrl":"https://doi.org/10.20517/microstructures.2023.38","url":null,"abstract":"Cryogenic atom probe tomography (cryo-APT) is a new microstructure characterization technique with the potential to address challenges across various research fields. In this review, we provide an overview of the development of cryo-APT and the associated instrumentation that transforms conventional APT into cryo-APT. We start by introducing the APT principle and the instrumentation involved in the cryo-APT workflow, emphasizing the key techniques that enable cryo-APT specimen preparation. Furthermore, we shed light on the research made possible by cryo-APT, presenting several recent outcomes to demonstrate its capabilities effectively. Finally, we discuss the limitations of cryo-APT and summarize the potential research areas that can further benefit from this cutting-edge microstructural characterization technique.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135684471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Scanning transmission electron microscopy for advanced characterization of ferroic materials","authors":"Matthew J. Cabral, Zibin Chen, Xiaozhou Liao","doi":"10.20517/microstructures.2023.39","DOIUrl":"https://doi.org/10.20517/microstructures.2023.39","url":null,"abstract":"Scanning Transmission electron microscopy (STEM) technologies have undergone significant advancements in the last two decades. Advancements in aberration-correction technology, ultra-high energy resolution monochromators, and state-of-the-art detectors/cameras have established STEM as an essential tool for investigating material chemistry and structure from the micro to the atomic scale. This characterization technique has been invaluable for understanding and characterizing the origins of ferroic material properties in next-generation advanced materials. Many unique properties of engineering materials, such as ferroelectricity, piezoelectricity, and ferromagnetism, are intricately linked to their atomic-scale composition and structure. STEM enables direct observation of these structural characteristics, establishing a link with macroscopic properties. In this perspective, we provide an overview of the application of advanced STEM techniques in investigating the origin of ferroic material properties, along with discussions on potential opportunities for further utilization of STEM techniques.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136114412","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ainiu L. Wang, Marcus H. Hansen, Yi-Cheng Lai, Jiaqi Dong, Kelvin Y. Xie
{"title":"Improving orientation mapping by enhancing the diffraction signal using Auto-CLAHE in precession electron diffraction data","authors":"Ainiu L. Wang, Marcus H. Hansen, Yi-Cheng Lai, Jiaqi Dong, Kelvin Y. Xie","doi":"10.20517/microstructures.2023.27","DOIUrl":"https://doi.org/10.20517/microstructures.2023.27","url":null,"abstract":"Precession electron diffraction (PED) is a powerful technique for revealing the crystallographic orientation of samples at the nanoscale. However, the quality of orientation indexing is strongly influenced by the quality of diffraction patterns. In this study, we have developed a novel algorithm called Auto-CLAHE (automatic contrast-limited adaptive histogram equalization), which automatically enhances low-intensity diffraction pattern signals using contrast-limited adaptive histogram equalization (CLAHE). The degree of enhancement is dynamically adjusted based on the overall intensity of the diffraction pattern, with greater enhancement applied to patterns with fewer spots (i.e., away from zone axes) and little or no enhancement applied to patterns with many spots (i.e., at a zone axis). By improving the visibility of low-intensity diffraction spots, Auto-CLAHE significantly improves the template matching between experimentally acquired and simulated diffraction patterns, leading to orientation maps with dramatically higher quality and lower noise. We anticipate that Auto-CLAHE provides an efficient and practical solution for preprocessing PED data, enabling higher-quality crystal orientation mapping to be routinely obtained.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135648210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hailan Qin, Jianwei Zhao, Xiaoxin Chen, Hongtian Li, Shenghao Wang, Yuxiao Du, Huanfu Zhou, Peifeng Li, Dawei Wang
{"title":"Investigation of BiFeO<sub>3</sub>-BaTiO<sub>3</sub> lead-free piezoelectric ceramics with nonstoichiometric bismuth","authors":"Hailan Qin, Jianwei Zhao, Xiaoxin Chen, Hongtian Li, Shenghao Wang, Yuxiao Du, Huanfu Zhou, Peifeng Li, Dawei Wang","doi":"10.20517/microstructures.2023.34","DOIUrl":"https://doi.org/10.20517/microstructures.2023.34","url":null,"abstract":"BiFeO3-BaTiO3 (BF-BT)-based lead-free ceramics are promising piezoelectric materials exhibiting high Curie temperatures and excellent electrochemical properties. In this study, 0.70Bi1+x FeO3-0.30BaTiO3 (B1+x F-BT, x = -0.01, 0.00, 0.01, 0.02, 0.03, 0.04) lead-free piezoelectric ceramics were successfully fabricated via the conventional solid-phase reaction process. Crystallographic structure, microstructure, dielectric, impedance, ferroelectric, and piezoelectric properties among different compositions were comprehensively investigated. The X-ray diffraction analysis confirmed that all compositions exhibited a typical perovskite structure with a cubic-rhombohedral phase mixture. The grain size of ceramics tends to increase as the Bi2O3 content rises. In particular, the backscattered electron images and energy dispersive analysis revealed prominent core-shell microstructure within grains. Notably, the BF-BT ceramic containing 1% excess Bi displayed the maximum d 33 ~217 pC/N and ~243 pm/V accompanied by a high Curie temperature of 515 °C. The findings demonstrate the potential feasibility of BF-BT ceramics in the field of lead-free piezoelectric ceramics.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135011372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Optimizing the energy storage performance of NaNbO3 ceramics by rare-earth-based composite perovskite Sm(Mg0.5Zr0.5)O3 modification","authors":"Mingzhao Xu, Dafu Zeng, Xiang Wang, Peng Nong, Yue Pan, Qinpeng Dong, Jiaming Wang, Huanfu Zhou, Xiuli Chen","doi":"10.20517/microstructures.2023.19","DOIUrl":"https://doi.org/10.20517/microstructures.2023.19","url":null,"abstract":"Researchers often improve the energy storage performance of NaNbO3 ceramics through doping with Bi-based composites. Recent studies have shown that rare-earth elements, such as La and Sm, can suppress remanent polarization. In this study, a (1-x )NaNbO3-x Sm(Mg0.5Zr0.5)O3 ceramic system was designed. Doping with Sm(Mg0.5Zr0.5)O3 (SMZ) increases the resistance, activation energy, and bandgap of NaNbO3 ceramics, improves the breakdown field strength, and optimizes the energy storage efficiency of NaNbO3 ceramics. In this study, 0.92NaNbO3-0.08 SMZ achieved an energy storage density of 4.3/cm3 and an energy storage efficiency of 85.6% at 560 kV/cm. When x = 0.15, the sample exhibited an ultrahigh breakdown field strength and energy storage efficiency (720 kV/cm and 91%, respectively). In addition, the 0.08 SMZ sample had an ultrafast release rate of t 0.9 (57 ns), high current density (777.1 A/cm2), and high power density (69.93 MW/cm3). It has practical application prospects in high-performance energy storage capacitors.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2023-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80550526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Liangshu He, Yan Li, D. Torrent, X. Zhuang, T. Rabczuk, Y. Jin
{"title":"Machine learning assisted intelligent design of meta structures: a review","authors":"Liangshu He, Yan Li, D. Torrent, X. Zhuang, T. Rabczuk, Y. Jin","doi":"10.20517/microstructures.2023.29","DOIUrl":"https://doi.org/10.20517/microstructures.2023.29","url":null,"abstract":"In recent years, the rapid development of machine learning (ML) based on data-driven or environment interaction has injected new vitality into the field of meta-structure design. As a supplement to the traditional analysis methods based on physical formulas and rules, the involvement of ML has greatly accelerated the pace of performance exploration and optimization for meta-structures. In this review, we focus on the latest progress of ML in acoustic, elastic, and mechanical meta-structures from the aspects of band structures, wave propagation characteristics, and static characteristics. We finally summarize and envisage some potential research directions of ML in the field of meta-structures.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2023-08-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84834077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuanyuan Guo, Yanhui Cao, Junda Lu, Xuerong Zheng, Yida Deng
{"title":"The concept, structure, and progress of seawater metal-air batteries","authors":"Yuanyuan Guo, Yanhui Cao, Junda Lu, Xuerong Zheng, Yida Deng","doi":"10.20517/microstructures.2023.30","DOIUrl":"https://doi.org/10.20517/microstructures.2023.30","url":null,"abstract":"Seawater metal-air batteries (SMABs) are promising energy storage technologies for their advantages of high energy density, intrinsic safety, and low cost. However, the presence of such chloride ions complex components in seawater inevitably has complex effects on the air electrode process, including oxygen reduction and oxygen evolution reactions (ORR and OER), which requires the development of highly-active chloride-resistant electrocatalysts. In this review, we first summarized the developing status of various types of SMABs, explaining their working principle and comparing the battery performance. Then, the reported chlorine-resistant electrocatalysts were classified. The composition and structural design strategies of high-efficient chlorine-resistant ORR/OER electrocatalysts in seawater electrolytes were comprehensively summarized. Finally, the main challenges to be overcome in the commercialization of SMABs were discussed.","PeriodicalId":22044,"journal":{"name":"Superlattices and Microstructures","volume":null,"pages":null},"PeriodicalIF":3.1,"publicationDate":"2023-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73398930","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}