Polymers最新文献

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Advanced Hybrid Strategies of GelMA Composite Hydrogels in Bone Defect Repair. GelMA 复合水凝胶在骨缺损修复中的先进混合策略。
IF 4.7 3区 工程技术
Polymers Pub Date : 2024-10-29 DOI: 10.3390/polym16213039
Han Yu, Xi Luo, Yanling Li, Lei Shao, Fang Yang, Qian Pang, Yabin Zhu, Ruixia Hou
{"title":"Advanced Hybrid Strategies of GelMA Composite Hydrogels in Bone Defect Repair.","authors":"Han Yu, Xi Luo, Yanling Li, Lei Shao, Fang Yang, Qian Pang, Yabin Zhu, Ruixia Hou","doi":"10.3390/polym16213039","DOIUrl":"10.3390/polym16213039","url":null,"abstract":"<p><p>To date, severe bone defects remain a significant challenge to the quality of life. All clinically used bone grafts have their limitations. Bone tissue engineering offers the promise of novel bone graft substitutes. Various biomaterial scaffolds are fabricated by mimicking the natural bone structure, mechanical properties, and biological properties. Among them, gelatin methacryloyl (GelMA), as a modified natural biomaterial, possesses a controllable chemical network, high cellular stability and viability, good biocompatibility and degradability, and holds the prospect of a wide range of applications. However, because they are hindered by their mechanical properties, degradation rate, and lack of osteogenic activity, GelMA hydrogels need to be combined with other materials to improve the properties of the composites and endow them with the ability for osteogenesis, vascularization, and neurogenesis. In this paper, we systematically review and summarize the research progress of GelMA composite hydrogel scaffolds in the field of bone defect repair, and discuss ways to improve the properties, which will provide ideas for the design and application of bionic bone substitutes.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"16 21","pages":""},"PeriodicalIF":4.7,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11548276/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142626670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of Probiotic Fermentation on the Physicochemical Properties of Hemp Seed Protein Gels. 益生菌发酵对大麻籽蛋白凝胶理化特性的影响
IF 4.7 3区 工程技术
Polymers Pub Date : 2024-10-29 DOI: 10.3390/polym16213032
Yipeng Liu, Yingxue Fei, Chen Li, Jianming Cheng, Feng Xue
{"title":"Impact of Probiotic Fermentation on the Physicochemical Properties of Hemp Seed Protein Gels.","authors":"Yipeng Liu, Yingxue Fei, Chen Li, Jianming Cheng, Feng Xue","doi":"10.3390/polym16213032","DOIUrl":"10.3390/polym16213032","url":null,"abstract":"<p><p>Hemp seed protein isolates (HPI) were used to produce a gel through probiotic fermentation. This study assessed how fermentation time (ranging from 0 to 16 h) affected the physicochemical properties of the HPI gel. The results indicated that gel formation began after 8 h of fermentation, as demonstrated by a pH decrease, an increase in particle size, and the development of aggregation observed through fluorescence and scanning electron microscopy. The gel produced after 16 h of fermentation showed the highest viscosity, storage modulus, and gel strength, attributed to stronger molecular interactions, including non-covalent and covalent crosslinking. However, the gel produced after 12 h of fermentation showed the highest water-holding capacity, and extending the fermentation beyond 12 h caused a decrease in water-holding capacity. Additionally, the subunits tended to form polymers after fermentation, suggesting that gel formation was influenced by both acidification and specific covalent crosslinking. These findings propose that HPI could serve as a viable alternative for developing plant-based gel products.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"16 21","pages":""},"PeriodicalIF":4.7,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11548347/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142626109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical Strength of Additive Manufactured and Standard Polymeric Components Joined Through Structural Adhesives. 通过结构粘合剂连接的添加剂制造和标准聚合物部件的机械强度。
IF 4.7 3区 工程技术
Polymers Pub Date : 2024-10-29 DOI: 10.3390/polym16213036
Andrea Spaggiari, Simone Orlandini
{"title":"Mechanical Strength of Additive Manufactured and Standard Polymeric Components Joined Through Structural Adhesives.","authors":"Andrea Spaggiari, Simone Orlandini","doi":"10.3390/polym16213036","DOIUrl":"10.3390/polym16213036","url":null,"abstract":"<p><p>The main aim of this work is to evaluate the mechanical properties of additive manufactured polymeric parts joined with standard plastic parts through structural adhesives. The primary advantage of this technique is its ability to significantly increase the size of the final assembly by using additive manufacturing (AM) for complex joints and inexpensive, reliable extruded plastic parts for load-bearing components. This hybrid assembly combines the flexibility and shape adaptability of AM with the structural strength and cost-effectiveness of extruded polymer parts, resulting in a final design that performs comparably to the base material. The materials used in the paper are rigid acrylic adhesive and toughened acrylic, both applicable with almost no surface preparation and fast curing. The 3D-printed parts are produced in ABS, while the standard parts are in PVC. First, the work is devoted to estimating the performance of the adhesives using pin-collar joints and a combined numerical and experimental methodology. The second section presents and discusses the results of two more realistic applications of adhesive bonding to hybrid complex joints. For the pin-collar joints, the results show failure mostly in the adhesive, with an average shear stress of 11.5 MPa and 5.22 MPa and a stiffness of 4449 N/mm and 3649 N/mm for the rigid and toughened adhesives, respectively. The results of the adhesive bonding of structural joints show that the adhesive is always capable of providing the load-carrying capacity required to achieve the strength of traditionally manufactured polymeric parts. The paper shows that adhesives are a feasible way to expand the potential of 3D-printed equipment to obtain larger hybrid parts partially realized with traditional technology, especially with inexpensive off-the-shelf bars and sections.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"16 21","pages":""},"PeriodicalIF":4.7,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11548706/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142626344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Current and Future Insights in Organic-Inorganic Hybrid Materials. 有机-无机杂化材料的现状与未来展望。
IF 4.7 3区 工程技术
Polymers Pub Date : 2024-10-29 DOI: 10.3390/polym16213043
Jesús-María García-Martínez, Emilia P Collar
{"title":"Current and Future Insights in Organic-Inorganic Hybrid Materials.","authors":"Jesús-María García-Martínez, Emilia P Collar","doi":"10.3390/polym16213043","DOIUrl":"10.3390/polym16213043","url":null,"abstract":"<p><p>The text below outlines some current and future possibilities for organic-inorganic hybrid materials [...].</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"16 21","pages":""},"PeriodicalIF":4.7,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11548524/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142626890","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Induced Electron Traps via the PCBM in P(VDF-HFP) Composites to Enhance Dielectric and Energy Storage Performance. 通过 P(VDF-HFP)复合材料中的 PCBM 诱导电子陷阱,提高介电和储能性能。
IF 4.7 3区 工程技术
Polymers Pub Date : 2024-10-29 DOI: 10.3390/polym16213030
Yantao Yang, Jingqi Qiao, Haiyu Sun, Wenhao Yang, Liangliang Wei, Xuetong Zhao
{"title":"Induced Electron Traps via the PCBM in P(VDF-HFP) Composites to Enhance Dielectric and Energy Storage Performance.","authors":"Yantao Yang, Jingqi Qiao, Haiyu Sun, Wenhao Yang, Liangliang Wei, Xuetong Zhao","doi":"10.3390/polym16213030","DOIUrl":"10.3390/polym16213030","url":null,"abstract":"<p><p>Polymer-based composites with excellent dielectric properties are essential for advanced energy storage applications. In this work, the [6,6]-phenyl-C<sub>61</sub>-butyric acid methyl ester (PCBM) as a filler was incorporated into the poly(vinylidene fluoride-co-hexafluoropropylene) (P(VDF-HFP)) composite to improve its dielectric performance. P(VDF-HFP) composite films with varying PCBM concentrations were prepared via solution casting and their dielectric, energy storage, and charge-discharge properties were characterized. It was found that the doped PCBM could introduce new charge traps with an energy level of 1.25 eV that modulate charge transport and energy storage characteristics of the polymer matrix. The dielectric constant of the composites was enhanced to the maximum of 10.87 as 0.2 vol% PCBM was added, while the breakdown strength reached 455 MV/m, achieving an energy density of 7.38 J/cm3, which is 33% higher than the pristine P(VDF-HFP) film. Furthermore, the charge-discharge efficiency of the composites was enhanced 66% under the electric field of 300 MV/m. These results demonstrate that PCBM significantly improves the dielectric and energy storage properties of P(VDF-HFP) composites, providing a promising approach for the development of high-performance dielectric materials in flexible energy storage devices.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"16 21","pages":""},"PeriodicalIF":4.7,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11548652/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142626113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of Crystallinity and Branched Chain on Thermal Degradation of Polyethylene: A SCC-DFTB Molecular Dynamics Study. 结晶度和支链对聚乙烯热降解的影响:SCC-DFTB 分子动力学研究。
IF 4.7 3区 工程技术
Polymers Pub Date : 2024-10-29 DOI: 10.3390/polym16213038
Shumao Zeng, Diannan Lu, Rui Yang
{"title":"Effects of Crystallinity and Branched Chain on Thermal Degradation of Polyethylene: A SCC-DFTB Molecular Dynamics Study.","authors":"Shumao Zeng, Diannan Lu, Rui Yang","doi":"10.3390/polym16213038","DOIUrl":"10.3390/polym16213038","url":null,"abstract":"<p><p>As a widely used plastic, the aging and degradation of polyethylene (PE) are inevitable problems, whether the goal is to prolong the life of PE products or address the issue of white pollution. Molecular simulation is a vital scientific tool in elucidating the mechanisms and processes of chemical reactions. To obtain the distribution and evolution process of PE's thermal oxidation products, this work employs the self-consistent charge-density functional tight binding (SCC-DFTB) method to perform molecular simulations of the thermal oxidation of PE with different crystallinity and branched structures. We discovered that crystallinity does not affect the thermal oxidation mechanism of PE, but higher crystallinity makes PE more susceptible to cross-linking and carbon chain growth, reducing the degree of PE carbon chain breakage. The branched structure of PE results in differences in free volumes between the carbon chains, with larger pores leading to a concentrated distribution of O<sub>2</sub> and chemical defects subsequently formed. The breakdown of PE is slowed down when chemical defects are localized in low-density regions of the carbon chain. The specifics and mechanism of PE's thermal oxidation are clearly revealed in this paper, which is essential for understanding the process in depth and for the development of anti-aging PE products.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"16 21","pages":""},"PeriodicalIF":4.7,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11548203/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142627055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of Isocyanate Structure on the Properties of Polyurethane: Synthesis, Performance, and Self-Healing Characteristics. 异氰酸酯结构对聚氨酯性能的影响:合成、性能和自愈特性。
IF 4.7 3区 工程技术
Polymers Pub Date : 2024-10-29 DOI: 10.3390/polym16213045
Hairui Wang, Lan Cao, Xiaolei Wang, Xiurui Lang, Wenwen Cong, Long Han, Hongyu Zhang, Huibin Zhou, Jujie Sun, Chengzhong Zong
{"title":"Effects of Isocyanate Structure on the Properties of Polyurethane: Synthesis, Performance, and Self-Healing Characteristics.","authors":"Hairui Wang, Lan Cao, Xiaolei Wang, Xiurui Lang, Wenwen Cong, Long Han, Hongyu Zhang, Huibin Zhou, Jujie Sun, Chengzhong Zong","doi":"10.3390/polym16213045","DOIUrl":"10.3390/polym16213045","url":null,"abstract":"<p><p>Polyurethane (PU) plays a critical role in elastomers, adhesives, and self-healing materials. We selected the most commonly used aromatic isocyanates, 4,4'-methylene diphenyl diisocyanate (MDI) and tolylene-2,4-diisocyanate (TDI), and the most commonly used aliphatic isocyanates, hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI), and dicyclohexylmethane-4,4'-diisocyanate (HMDI), as raw materials, combined with polytetramethylene ether glycol (PTMG) and 1,4-butanediol (BDO) to successfully synthesize five PU materials. The effects of isocyanate structure on polymerization rate, hydrogen bonding, thermal properties, phase separation, wettability, self-healing performance, adhesion, and mechanical properties were systematically investigated. The results show that isocyanates with higher symmetry facilitate hydrogen bonding, but excessive flexibility and crystallinity may inhibit its formation. MDI-based PU exhibits the highest hydrogen bonding index (HBI) of 4.10, along with the most distinct phase separation and the highest tensile strength of 23.4 MPa. HMDI-based PU demonstrates the best adhesion properties, with the highest lap shear strength of 7.9 MPa, and also exhibits excellent scratch healing ability. IPDI-based PU shows good self-healing performance, recovering 88.7% of its original tensile strength and 90.6% of its original lap shear strength after heating at 80 °C for 24 h. Furthermore, all the samples can be reprocessed by melt or solution methods, showing excellent recyclability.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"16 21","pages":""},"PeriodicalIF":4.7,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11548432/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142627056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on a Pseudo-Elastic Model for High-Damping Rubber. 高阻尼橡胶伪弹性模型研究
IF 4.7 3区 工程技术
Polymers Pub Date : 2024-10-29 DOI: 10.3390/polym16213042
Zhihao Guo, Tianbo Peng
{"title":"Study on a Pseudo-Elastic Model for High-Damping Rubber.","authors":"Zhihao Guo, Tianbo Peng","doi":"10.3390/polym16213042","DOIUrl":"10.3390/polym16213042","url":null,"abstract":"<p><p>With advancements in seismic isolation and damping technology, high-damping rubber (HDR) bearings are now widely used. However, significant gaps remain in HDR-analysis model research, with few studies integrating multiple factors, the Mullins effect, and stiffness hardening for more accurate practical predictions. This study classifies the effective behavior of HDR and examines the stress-strain relationships of different behavioral types using more appropriate equations. Mathematical models were established based on pseudo-elasticity theory, which is an extension of continuum mechanics. Subsequently, parameter functions were developed through parameter determination tests and regression analysis, leading to the completion of the pseudo-elastic model for HDR. Finally, the model's effectiveness was validated through validation tests. This study finds that behavior classification effectively examines phenomenological-based HDR stress-strain relationships, as distinct behavioral patterns are not adequately captured by a single approach. Incorporating tests to functionalize material parameters complements theoretical models. Additionally, accurately explaining HDR behavior requires considering the Mullins effect and stiffness hardening, influenced by the coupled effects of temperature, strain amplitude, and compressive stress. Consequently, this HDR pseudo-elastic model offers a comprehensive explanation of HDR behavior, including the Mullins effect and stiffness hardening, under various influencing factors based on clear mechanical principles and explicit computational procedures.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"16 21","pages":""},"PeriodicalIF":4.7,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11548339/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142626753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Highly Porous 3D Nanofibrous Scaffold of Polylactic Acid/Polyethylene Glycol/Calcium Phosphate for Bone Regeneration by a Two-Step Solution Blow Spinning (SBS) Facile Route. 采用两步法溶液吹塑纺丝 (SBS) 简易工艺制备用于骨再生的聚乳酸/聚乙二醇/磷酸钙高孔三维纳米纤维支架。
IF 4.7 3区 工程技术
Polymers Pub Date : 2024-10-29 DOI: 10.3390/polym16213041
Vanderlane Cavalcanti da Silva, Déborah Dos Santos Gomes, Eudes Leonan Gomes de Medeiros, Adillys Marcelo da Cunha Santos, Isabela Lemos de Lima, Taciane Pedrosa Rosa, Flaviana Soares Rocha, Leticia de Souza Castro Filice, Gelmires de Araújo Neves, Romualdo Rodrigues Menezes
{"title":"Highly Porous 3D Nanofibrous Scaffold of Polylactic Acid/Polyethylene Glycol/Calcium Phosphate for Bone Regeneration by a Two-Step Solution Blow Spinning (SBS) Facile Route.","authors":"Vanderlane Cavalcanti da Silva, Déborah Dos Santos Gomes, Eudes Leonan Gomes de Medeiros, Adillys Marcelo da Cunha Santos, Isabela Lemos de Lima, Taciane Pedrosa Rosa, Flaviana Soares Rocha, Leticia de Souza Castro Filice, Gelmires de Araújo Neves, Romualdo Rodrigues Menezes","doi":"10.3390/polym16213041","DOIUrl":"10.3390/polym16213041","url":null,"abstract":"<p><p>This work presents the successful production of highly porous 3D nanofibrous hybrid scaffolds of polylactic acid (PLA)/polyethylene glycol (PEG) blends with the incorporation of calcium phosphate (CaP) bioceramics by a facile two-step process using the solution blow spinning (SBS) technique. CaP nanofibers were obtained at two calcium/phosphorus (Ca/P) ratios, 1.67 and 1.1, by SBS and calcination at 1000 °C. They were incorporated in PLA/PEG blends by SBS at 10 and 20 wt% to form 3D hybrid cotton-wool-like scaffolds. Morphological analysis showed that the fibrous scaffolds obtained had a randomly interconnected and highly porous structure. Also, the mean fiber diameter ranged from 408 ± 141 nm to 893 ± 496 nm. Apatite deposited considerably within 14 days in a simulated body fluid (SBF) test for hybrid scaffolds containing a mix of hydroxyapatite (HAp) and tri-calcium phosphate-β (β-TCP) phases. The scaffolds with 20 wt% CaP and a Ca/P ration of 1.1 showed better in vitro bioactivity to induce calcium mineralization for bone regeneration. Cellular tests evidenced that the developed scaffolds can support the osteogenic differentiation and proliferation of pre-osteoblastic MC3T3-E1 cells into mature osteoblasts. The results showed that the developed 3D scaffolds have potential applications for bone tissue engineering.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"16 21","pages":""},"PeriodicalIF":4.7,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11548267/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142626006","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advanced Flexible Wearable Electronics from Hybrid Nanocomposites Based on Cellulose Nanofibers, PEDOT:PSS and Reduced Graphene Oxide. 基于纤维素纳米纤维、PEDOT:PSS 和还原石墨烯氧化物的混合纳米复合材料的先进柔性可穿戴电子设备。
IF 4.7 3区 工程技术
Polymers Pub Date : 2024-10-29 DOI: 10.3390/polym16213035
Ana Carrascosa, Jaime S Sánchez, María Guadalupe Morán-Aguilar, Gemma Gabriel, Fabiola Vilaseca
{"title":"Advanced Flexible Wearable Electronics from Hybrid Nanocomposites Based on Cellulose Nanofibers, PEDOT:PSS and Reduced Graphene Oxide.","authors":"Ana Carrascosa, Jaime S Sánchez, María Guadalupe Morán-Aguilar, Gemma Gabriel, Fabiola Vilaseca","doi":"10.3390/polym16213035","DOIUrl":"10.3390/polym16213035","url":null,"abstract":"<p><p>The need for responsible electronics is leading to great interest in the development of new bio-based devices that are environmentally friendly. This work presents a simple and efficient process for the creation of conductive nanocomposites using renewable materials such as cellulose nanofibers (CNF) from enzymatic pretreatment, poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS), and/or reduced graphene oxide (rGO). Different combinations of CNF, rGo, and PEDOT:PSS were considered to generate homogeneous binary and ternary nanocomposite formulations. These formulations were characterized through SEM, Raman spectroscopy, mechanical, electrical, and electrochemical analysis. The binary formulation containing 40 wt% of PEDOT:PSS resulted in nanocomposite formulations with tensile strength, Young's modulus, and a conductivity of 70.39 MPa, 3.87 GPa, and 0.35 S/cm, respectively. The binary formulation with 15 wt% of rGO reached 86.19 MPa, 4.41 GPa, and 13.88 S/cm of the same respective properties. A synergy effect was observed for the ternary formulations between both conductive elements; these nanocomposite formulations reached 42.11 S/cm of conductivity and kept their strength as nanocomposites. The 3D design strategy provided a highly conductive network maintaining the structural integrity of CNF, which generated homogenous nanocomposites with rGO and PEDOT:PSS. These formulations can be considered as greatly promising for the next generation of low-cost, eco-friendly, and energy storage devices, such as batteries or electrochemical capacitors.</p>","PeriodicalId":20416,"journal":{"name":"Polymers","volume":"16 21","pages":""},"PeriodicalIF":4.7,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11548421/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142626665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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