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Strikingly wide refrigeration temperature span in Ni-Co-Mn-Ti Heusler-type alloy ribbons induced by Hf doping and heat treatment 经Hf掺杂和热处理制备的Ni-Co-Mn-Ti heusler型合金带具有显著的制冷温度跨度
IF 9.7 2区 材料科学
Materials Today Physics Pub Date : 2026-06-01 Epub Date: 2026-05-19 DOI: 10.1016/j.mtphys.2026.102130
Hanxiao Chen , Lei Xu , ZiYu Wu , Zihan Wang , Bangpo Shen , Zhishuo Zhang , Chunsheng Fang , Changcai Chen , Xiaohua Luo , Shengcan Ma
{"title":"Strikingly wide refrigeration temperature span in Ni-Co-Mn-Ti Heusler-type alloy ribbons induced by Hf doping and heat treatment","authors":"Hanxiao Chen ,&nbsp;Lei Xu ,&nbsp;ZiYu Wu ,&nbsp;Zihan Wang ,&nbsp;Bangpo Shen ,&nbsp;Zhishuo Zhang ,&nbsp;Chunsheng Fang ,&nbsp;Changcai Chen ,&nbsp;Xiaohua Luo ,&nbsp;Shengcan Ma","doi":"10.1016/j.mtphys.2026.102130","DOIUrl":"10.1016/j.mtphys.2026.102130","url":null,"abstract":"<div><div>The Hf-doped Ni<sub>37</sub>Co<sub>13</sub>Mn<sub>35</sub>Ti<sub>15-<em>x</em></sub>Hf<sub><em>x</em></sub> (<em>x</em> = 1, 2) Heusler alloys are successfully fabricated in this work. The regulation of microstructure, crystallographic structure, martensitic transformation (MT), and magnetocaloric properties by Hf doping and subsequent annealing treatments is systematically investigated. Firstly, the introduction of Hf increases the reverse MT temperature <em>T</em><sub>A</sub>. After annealing, the newly formed 4O martensite is preferentially grown at grain boundaries (GBs). For Hf1 ribbons, the isothermal magnetic entropy change peak value (Δ<em>S</em><sub>M,max</sub>) decreases after annealing, while for annealed Hf2 ribbons, Δ<em>S</em><sub>M,max</sub> changes little in contrast with melt-spun ones. The refrigeration temperature span (Δ<em>T</em><sub>FWHM</sub>) is significantly broadened in both cases after annealing at 850 °C. Under a magnetic-field change of <em>μ</em><sub>0</sub>Δ<em>H</em> = 0–5 T, the Δ<em>T</em><sub>FWHM</sub> values of the Hf1 @850 °C and Hf2 @850 °C ribbons are 22.3 K and 21.8 K, respectively. The effective refrigeration capacities (<em>RC</em><sub>eff</sub>) for both samples are 101.7 J kg<sup>−1</sup> and 125.8 J kg<sup>−1</sup>, respectively, approximately 2.5 and 3.1 times that of the Hf1 melt-spun ribbons. Strikingly, by combining the Δ<em>T</em><sub>FWHM</sub> values of the melt-spun and annealed Ni<sub>37</sub>Co<sub>13</sub>Mn<sub>35</sub>Ti<sub>13</sub>Hf<sub>2</sub> ribbons, a large Δ<em>T</em><sub>FWHM</sub> of ∼28.3 K (287.4 K–315.7 K) is achieved with a large <em>RC</em><sub>eff</sub>. By precisely matching magnetocaloric alloys with different <em>T</em><sub>A</sub> with their corresponding Δ<em>T</em><sub>FWHM</sub>, a high-precision magnetic refrigeration system is designed, which is suitable for room temperature (RT) or near RT operation.</div></div>","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":"65 ","pages":"Article 102130"},"PeriodicalIF":9.7,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148186556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Triple self-trapped exciton emission with nanosecond decay dynamics in a one-dimensional organic lead halide perovskite for X-ray imaging 一维有机卤化铅钙钛矿中具有纳秒衰减动力学的三重自捕获激子发射x射线成像
IF 9.7 2区 材料科学
Materials Today Physics Pub Date : 2026-06-01 Epub Date: 2026-05-29 DOI: 10.1016/j.mtphys.2026.102136
Liang Li , Man Xia , Jianzhong Xu , Mengjia Li , Xuefang Lu , Hao Chen , Xin Qian , Zewenhui Zhang , Xiwei Lai , Tianyu Xu , Feng Huang , Richeng Lin
{"title":"Triple self-trapped exciton emission with nanosecond decay dynamics in a one-dimensional organic lead halide perovskite for X-ray imaging","authors":"Liang Li ,&nbsp;Man Xia ,&nbsp;Jianzhong Xu ,&nbsp;Mengjia Li ,&nbsp;Xuefang Lu ,&nbsp;Hao Chen ,&nbsp;Xin Qian ,&nbsp;Zewenhui Zhang ,&nbsp;Xiwei Lai ,&nbsp;Tianyu Xu ,&nbsp;Feng Huang ,&nbsp;Richeng Lin","doi":"10.1016/j.mtphys.2026.102136","DOIUrl":"10.1016/j.mtphys.2026.102136","url":null,"abstract":"<div><div>Halide scintillators, featured for their low self-absorption and cost-effectiveness, are essential components in radiation detection for high-energy physics and medical imaging. However, halides demonstrating self-trapped exciton (STE) emission, while exhibiting superiority in minimizing self-absorption, typically exhibit scintillation decay times on the order of tens of nanoseconds. This inherent limitation impedes their advancement for fast radiation detection applications. Here, one-dimensional (1D) organic lead halide perovskite ETPPbBr<sub>3</sub> single crystals are synthesized via a universal solvent evaporation method and manifest nanosecond-scale decay dynamics. The large ETP<sup>+</sup> cations drive the formation of a 1D face-sharing arrangement of [PbBr<sub>6</sub>]<sup>4−</sup> octahedra, enabling temperature-activated triple STE emissions. The emission at 628 nm shows a large Stokes shift of up to 258 nm and a decay of 50.3 ns at room temperature. Notably, a new STE emission centered at 495 nm emerges below 185 K and exhibits an ultrafast decay of 3.32 ns at 50 K. Furthermore, the crystals achieve a low detection limit of 95.6 nGy s<sup>−1</sup>, and a scintillation film fabricated by incorporating ETPPbBr<sub>3</sub> powders into poly(dimethylsiloxane) enables high-definition X-ray imaging with a spatial resolution of 11.5 lp mm<sup>−1</sup>, demonstrating that ETPPbBr<sub>3</sub> is promising for next-generation X-ray detection and imaging applications.</div></div>","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":"65 ","pages":"Article 102136"},"PeriodicalIF":9.7,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148186555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MOF-derived porous aerogel for broadband electromagnetic wave absorption and concurrent noise reduction 用于宽带电磁波吸收和同时降噪的mof衍生多孔气凝胶
IF 9.7 2区 材料科学
Materials Today Physics Pub Date : 2026-06-01 DOI: 10.1016/j.mtphys.2026.102141
Ziang Xu , Jin Peng , Xu Cao , Jieyu Xue , Xuhong Yang , Yuanrong Ding , Jingwen Zhao , Yong Yang
{"title":"MOF-derived porous aerogel for broadband electromagnetic wave absorption and concurrent noise reduction","authors":"Ziang Xu ,&nbsp;Jin Peng ,&nbsp;Xu Cao ,&nbsp;Jieyu Xue ,&nbsp;Xuhong Yang ,&nbsp;Yuanrong Ding ,&nbsp;Jingwen Zhao ,&nbsp;Yong Yang","doi":"10.1016/j.mtphys.2026.102141","DOIUrl":"10.1016/j.mtphys.2026.102141","url":null,"abstract":"<div><div>With the development of modern 5G communication technology, there is an urgent need for a lightweight and efficient advanced electromagnetic wave absorbing material. Here, a ZIF-67/CNTs/PVA-derived aerogel with strong reflection loss and electromagnetic wave absorption was prepared by freeze-drying and gradient temperature carbonization. The optimum electromagnetic wave absorption performance can be achieved by controlling the amount of ZIF-67 and the carbonization temperature. At 120 mg ZIF-67 addition, the minimum reflection loss (RL <sub>min</sub>) of −39.17 dB was achieved at 2.5 mm thickness. To further investigate the electromagnetic wave absorption properties of the sample, gradient temperature carbonization was employed. A remarkable RL <sub>min</sub> of −46.94 dB and an ultra-wide effective absorption bandwidth (EAB) of 7.12 GHz were achieved at 800 °C. This EAB nearly spans the entire Ku-band frequency range. In addition, the aerogel has high sound absorption coefficients with 0.94 at 3150 Hz, providing a novel approach for the development of multi-purpose, multifunctional microwave-absorbing aerogel.</div></div>","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":"65 ","pages":"Article 102141"},"PeriodicalIF":9.7,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148186871","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical ordering and non-linear magnetic behavior: enhancing magnetocaloric effect in FeMnNiGeSi high-entropy materials 化学有序和非线性磁性行为:增强FeMnNiGeSi高熵材料的磁热效应
IF 9.7 2区 材料科学
Materials Today Physics Pub Date : 2026-06-01 Epub Date: 2026-05-21 DOI: 10.1016/j.mtphys.2026.102128
V. Fournée , G. Lengaigne , P. Boulet , S. Migot , J. Ledieu , J. Tobola , S. Semsari Parapari , S. Ražnjević , S. Šturm , L. Gallo , S. Fabbrici , F. Cugini , M. Solzi , F. Albertini
{"title":"Chemical ordering and non-linear magnetic behavior: enhancing magnetocaloric effect in FeMnNiGeSi high-entropy materials","authors":"V. Fournée ,&nbsp;G. Lengaigne ,&nbsp;P. Boulet ,&nbsp;S. Migot ,&nbsp;J. Ledieu ,&nbsp;J. Tobola ,&nbsp;S. Semsari Parapari ,&nbsp;S. Ražnjević ,&nbsp;S. Šturm ,&nbsp;L. Gallo ,&nbsp;S. Fabbrici ,&nbsp;F. Cugini ,&nbsp;M. Solzi ,&nbsp;F. Albertini","doi":"10.1016/j.mtphys.2026.102128","DOIUrl":"10.1016/j.mtphys.2026.102128","url":null,"abstract":"<div><div>High-entropy alloys (HEAs) offer opportunities to discover new functional materials with combination of properties not reached in other classes of materials. Here we report a detailed investigation of the structure, magnetic and magnetocaloric properties of some high entropy materials in the FeMnNiGeSi quinary system. Our findings indicate the persistence of partial chemical ordering, with transition metal atoms and metalloids preferentially occupying specific crystallographic sites. This ordering is further supported by <em>ab initio</em> total energy calculation. In turn, the magnetic moment - carried out mainly by Fe and Mn - exhibits a strong dependence on the crystallographic sites occupied by these magnetic atoms. By exploring the chemical landscape, we observed highly non-linear magnetic behavior upon Mn doping, resulting in an isothermal entropy change (Δ<em>Sm</em>) as high as 35 Jkg<sup>−1</sup>K<sup>−1</sup> in 5 T, while the transition temperature can be tuned in the range from 160 to 263 K, approaching room temperature. These outstanding performances suggest that rare-earth free high entropy materials can rival conventional magnetocaloric materials. Additionally, we find that the first-order magnetostructural transition can evolve into a second-order magnetic transition through chemical tuning. This opens the possibility of discovering similar materials near the boundary between first- and second-order transitions, with vanishing hysteresis - potentially addressing their mechanical instability issue.</div></div>","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":"65 ","pages":"Article 102128"},"PeriodicalIF":9.7,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148186558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Regulation of defect evolution and magneto-structural coupling in Ni-Co-Mn-Sn alloys by Co content and thermal history Co含量和热历史对Ni-Co-Mn-Sn合金缺陷演化和磁-结构耦合的调控
IF 9.7 2区 材料科学
Materials Today Physics Pub Date : 2026-06-01 DOI: 10.1016/j.mtphys.2026.102138
Yuchen Wang , Mingfang Qian , Xuexi Zhang , Zhao Yin , Shuo Qu , Xu Song , Lin Geng
{"title":"Regulation of defect evolution and magneto-structural coupling in Ni-Co-Mn-Sn alloys by Co content and thermal history","authors":"Yuchen Wang ,&nbsp;Mingfang Qian ,&nbsp;Xuexi Zhang ,&nbsp;Zhao Yin ,&nbsp;Shuo Qu ,&nbsp;Xu Song ,&nbsp;Lin Geng","doi":"10.1016/j.mtphys.2026.102138","DOIUrl":"10.1016/j.mtphys.2026.102138","url":null,"abstract":"<div><div>In this work, the martensitic transformation (MT) behavior, defect evolution, and magnetic properties and magnetocaloric effect (MCE) of Ni<sub>50-x</sub>Co<sub>x</sub>Mn<sub>39</sub>Sn<sub>11</sub> (x = 6, 8, 10, 12 at.%) alloys were systematically investigated under different Co contents and thermal histories. Using XRD, DSC, <em>M</em>-<em>T</em> and <em>M</em>-<em>H</em> analyses, the combined effects of compositional tuning and thermal treatment on point defects, internal stress fields, atomic ordering, and magnetic structures were elucidated. The results show that increasing Co content lowers the MT temperature and enhances the ferromagnetism of the austenite, leading to a progressive evolution from a reversible thermoelastic transformation to the kinetic arrest state and finally to the strain-glass-like state. This behavior is attributed to the Co-induced modification of electronic structure and magnetic exchange interactions, which alters the free-energy balance between martensite and austenite. In addition, thermal history further modulates the transformation temperatures and magnetic performance within a given composition: water-quenched samples exhibit higher MT temperature and lower Curie temperature (<em>T</em><sub>C</sub>) of austenite, while aging reduces MT temperature and raises <em>T</em><sub>C</sub>, yielding the widest ferromagnetic austenite stability range and the strongest magneto-structural coupling. Especially, WQ-WQ sample of Co6 alloy exhibits outstanding MCE with a maximum magnetic entropy change (Δ<em>S</em><sub>M</sub><sup>max</sup>) of 28.1 J/(kg·K), effective temperature window (Δ<em>T</em><sub>FWHM</sub>) of 16.4 K and refrigeration capacity (<em>RC</em>) of 405.4 J/kg. Further analysis reveals that WQ suppresses the ordering process and retains anti-site defects, whereas aging promotes vacancy diffusion and atomic rearrangement, resulting in higher chemical ordering degree and enhanced ferromagnetic exchange. The cooperative evolution of vacancies and anti-site defects governs the chemical ordering and magnetic exchange balance, enabling effective control of transformation behavior and magnetic properties. This study clarifies the intrinsic mechanism by which Co-doping and thermal history jointly modulate the magneto-structural coupling in Ni-Co-Mn-Sn alloys, providing theoretical guidance for the design and optimization of high-performance magnetocaloric materials.</div></div>","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":"65 ","pages":"Article 102138"},"PeriodicalIF":9.7,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148186553","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Architecture-enabled broadband electromagnetic attenuation and RF-to-DC conversion in 3D-printed CNT-Co honeycomb composites 3d打印碳纳米管-钴蜂窝复合材料中支持架构的宽带电磁衰减和rf到dc转换
IF 9.7 2区 材料科学
Materials Today Physics Pub Date : 2026-06-01 Epub Date: 2026-05-26 DOI: 10.1016/j.mtphys.2026.102134
Yi-Jen Huang , Yu-Cheng Kuo , Chih-Ming Yu
{"title":"Architecture-enabled broadband electromagnetic attenuation and RF-to-DC conversion in 3D-printed CNT-Co honeycomb composites","authors":"Yi-Jen Huang ,&nbsp;Yu-Cheng Kuo ,&nbsp;Chih-Ming Yu","doi":"10.1016/j.mtphys.2026.102134","DOIUrl":"10.1016/j.mtphys.2026.102134","url":null,"abstract":"<div><div>Magneto-dielectric composite architectures are a promising way to couple broadband electromagnetic (EM) interaction with functional radiofrequency (RF) energy conversion through combined materials and structural design. A 3D-printed carbon nanotube-cobalt (CNT-Co) honeycomb composite was developed as an RF receiving lattice architecture and integrated with an external impedance-matching network, a Schottky-diode voltage-multiplier rectifier, and an energy-storage module. The CNT-Co composite provides complementary dielectric and magnetic dissipation, while the honeycomb architecture promotes field redistribution, extended interaction pathways, and impedance modulation. As a result, the optimized lattice exhibits dual-band broadband attenuation spanning 2.68–3.47 GHz and 7.62–13.50 GHz. Slab-to-lattice comparison was performed using field-distribution simulations and geometric parameter analysis, which revealed that broadening of the RF interaction beyond the intrinsic material response arose from a combination of multiple cavity-assisted reflections, distributed current flow, and local field concentration. Under controlled anechoic-chamber excitation at a fixed transmitter–receiver (Tx-Rx) distance of 30 cm, the rectenna architecture exhibits a higher open-circuit rectified voltage and a broader spectral response than a commercial Wi-Fi antenna under identical rectifier and measurement conditions. In load-defined measurements at 2.45 GHz, the highest delivered direct current (DC) output in the tested resistor range occurred at 100 Ω, reaching 48 μW at 20 dBm, and the honeycomb receiver maintained 2.7–4.7 times higher output power than the commercial reference in the examined input-power range. Under ambient indoor Wi-Fi exposure, the storage-assisted system enables continuous energy accumulation and battery-free powering of representative low-power electronics. These results establish a materials-architecture strategy for coupling broadband EM attenuation with practical RF-to-DC conversion in lightweight composite architectures.</div></div>","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":"65 ","pages":"Article 102134"},"PeriodicalIF":9.7,"publicationDate":"2026-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148186870","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Dynamic-recrystallization-mediated suppression of donor-like effects in n-type Bi2(Te,Se)3 thermoelectrics via extreme hot extrusion ”[Mater. Today Phys. 59 (2025) 101911] 应改正的错误,
IF 9.7 2区 材料科学
Materials Today Physics Pub Date : 2026-05-01 Epub Date: 2026-04-17 DOI: 10.1016/j.mtphys.2026.102085
Xiaoming Hu , Xin Chen , Jiachang Shui , Peng Zhou , Zeyu Wang , Yawei Li , Matthew Barnett , Zhu He , Guangqiang Li , Xi'an Fan
{"title":"Corrigendum to “Dynamic-recrystallization-mediated suppression of donor-like effects in n-type Bi2(Te,Se)3 thermoelectrics via extreme hot extrusion ”[Mater. Today Phys. 59 (2025) 101911]","authors":"Xiaoming Hu ,&nbsp;Xin Chen ,&nbsp;Jiachang Shui ,&nbsp;Peng Zhou ,&nbsp;Zeyu Wang ,&nbsp;Yawei Li ,&nbsp;Matthew Barnett ,&nbsp;Zhu He ,&nbsp;Guangqiang Li ,&nbsp;Xi'an Fan","doi":"10.1016/j.mtphys.2026.102085","DOIUrl":"10.1016/j.mtphys.2026.102085","url":null,"abstract":"","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":"64 ","pages":"Article 102085"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147726411","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Direct evidence of mixed-phase induced anomalous thermal transport in hybrid perovskite single crystals 杂化钙钛矿单晶中混合相诱导异常热输运的直接证据
IF 9.7 2区 材料科学
Materials Today Physics Pub Date : 2026-05-01 Epub Date: 2026-04-21 DOI: 10.1016/j.mtphys.2026.102107
Yuting Yu , Gan Zhang , Zifeng He , Jing Tu , Ankit Jain , Jonathan A. Malen , Derya Baran , Yee Sin Ang , Shusheng Xiong , Dawei Di , Wee-Liat Ong
{"title":"Direct evidence of mixed-phase induced anomalous thermal transport in hybrid perovskite single crystals","authors":"Yuting Yu ,&nbsp;Gan Zhang ,&nbsp;Zifeng He ,&nbsp;Jing Tu ,&nbsp;Ankit Jain ,&nbsp;Jonathan A. Malen ,&nbsp;Derya Baran ,&nbsp;Yee Sin Ang ,&nbsp;Shusheng Xiong ,&nbsp;Dawei Di ,&nbsp;Wee-Liat Ong","doi":"10.1016/j.mtphys.2026.102107","DOIUrl":"10.1016/j.mtphys.2026.102107","url":null,"abstract":"<div><div>The thermal conductivity of crystalline semiconductors is critical for their optoelectronic performance and is commonly described by the classical phonon gas model. Here, we report a clear violation of this conventional behavior during the phase transition of methylammonium lead bromide (MAPbBr<sub>3</sub>) perovskite single crystals. Through transient frequency domain thermoreflectance experiments, an anomalous kink in thermal conductivity between 170 and 220 K is observed, disrupting the usual monotonic decrease with increasing temperature above the Debye temperature. Temperature-dependent X-ray diffraction (TDXRD) experiments reveal that a mixed orthorhombic-tetragonal phase exists in MAPbBr<sub>3</sub> from 140 K to 210 K. By combining TDXRD with phonon Wigner transport equation calculations, the origin of this anomalous thermal conductivity kink is attributed to two causes: the differences in the phonon properties between the tetragonal and orthorhombic phases and an increasing proportion of the tetragonal phase at increasing temperature. The notable differences in the phonon properties between these two phases, coupled with the potential differences in the properties of the charge carriers, can dramatically impact the optoelectronic performance of hybrid perovskites. Importantly, a similar kink is also observed within methylammonium lead chloride, suggesting such mixed-phase-induced thermal transport properties may be applicable to a broader class of perovskite semiconductors.</div></div>","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":"64 ","pages":"Article 102107"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147726408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrigendum to “Machine-learning potentials for quantum and anharmonic effects in superconducting Fm3‾m LaBeH8” [Mater. Today Phys. DOI: 10.1016/j.mtphys.2025.101939] “超导LaBeH8中量子和非调和效应的机器学习潜力”的勘误表[今日材料物理,DOI: 10.1016/j.m tph.2025 .101939]
IF 9.7 2区 材料科学
Materials Today Physics Pub Date : 2026-05-01 Epub Date: 2026-04-12 DOI: 10.1016/j.mtphys.2026.102098
Guiyan Dong , Tian Cui , Zihao Huo , Zhengtao Liu , Wenxuan Chen , Pugeng Hou , Yue-Wen Fang , Defang Duan
{"title":"Corrigendum to “Machine-learning potentials for quantum and anharmonic effects in superconducting Fm3‾m LaBeH8” [Mater. Today Phys. DOI: 10.1016/j.mtphys.2025.101939]","authors":"Guiyan Dong ,&nbsp;Tian Cui ,&nbsp;Zihao Huo ,&nbsp;Zhengtao Liu ,&nbsp;Wenxuan Chen ,&nbsp;Pugeng Hou ,&nbsp;Yue-Wen Fang ,&nbsp;Defang Duan","doi":"10.1016/j.mtphys.2026.102098","DOIUrl":"10.1016/j.mtphys.2026.102098","url":null,"abstract":"","PeriodicalId":18253,"journal":{"name":"Materials Today Physics","volume":"64 ","pages":"Article 102098"},"PeriodicalIF":9.7,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147681502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stress-mediated formation of mossy structure during zinc electrodeposition in alkaline electrolytes for zinc-air batteries 锌-空气电池碱性电解液中锌电沉积过程中应力介导的苔藓状结构形成
IF 9.7 2区 材料科学
Materials Today Physics Pub Date : 2026-05-01 Epub Date: 2026-04-18 DOI: 10.1016/j.mtphys.2026.102102
Yavuz Savsatli , Faizal Arifurrahman , Bongki Shin , Andrew Hitt , Fan Wang , Hua Guo , Zeyuan Li , Jun Lou , Yimo Han , Harsh Agarwal , Ryan Stephens , Ming Tang
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