Journal of Electron Spectroscopy and Related Phenomena最新文献_第10页

Ionic liquid functionalized tin halide perovskite investigated by STXM and spectro-ptychography 离子液体功能化卤化锡钙钛矿的STXM和光谱技术研究

IF 1.9 4区物理与天体物理

Journal of Electron Spectroscopy and Related Phenomena Pub Date : 2023-05-01 DOI: 10.1016/j.elspec.2023.147330

Tianxiao Sun , Shengnan Zuo , Bo He , Xinye Yuan , Guixiang Li , Jigang Zhou , Markus Weigand , Antonio Abate , Jian Wang

{"title":"Ionic liquid functionalized tin halide perovskite investigated by STXM and spectro-ptychography","authors":"Tianxiao Sun , Shengnan Zuo , Bo He , Xinye Yuan , Guixiang Li , Jigang Zhou , Markus Weigand , Antonio Abate , Jian Wang","doi":"10.1016/j.elspec.2023.147330","DOIUrl":"10.1016/j.elspec.2023.147330","url":null,"abstract":"<div>The structural and compositional properties of tin halide perovskites (CH(NH2)2SnI3, FASnI3) with and without an ionic liquid of 1-Ethyl-3-methylimidazolium bis(trifluormethylsulfonyl) imide (EMITFSI) were investigated using the scanning transmission soft X-ray microscopy (STXM) and spectro-ptychography techniques at the Sn M5,4-edge, I M5,4-edge, O K-edge, C K-edge, and N K-edge. The study offers a comprehensive interpretation of the spectral characteristics of main components (C, N, Sn, and I) in Sn-based perovskites through STXM-based techniques and further reveals differences between the perovskite samples with and without adding EMITFSI ionic liquid. The chemical imaging of Sn and I shows that the perovskite sample without ionic liquid has Sn-rich regions in iodine cavities, while the ionic liquid-treated sample exhibits a more homogeneous perovskite phase. Furthermore, the C and N K-edge XANES resonance features support the interaction between the non-volatile ionic liquid and FA+, thus playing a protective role in the formation and stabilization of perovskite phase.</div>","PeriodicalId":15726,"journal":{"name":"Journal of Electron Spectroscopy and Related Phenomena","volume":"265 ","pages":"Article 147330"},"PeriodicalIF":1.9,"publicationDate":"2023-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48977382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Search for the interatomic Auger effect in Nitrous Oxide 一氧化二氮原子间俄歇效应的研究

IF 1.9 4区物理与天体物理

Journal of Electron Spectroscopy and Related Phenomena Pub Date : 2023-05-01 DOI: 10.1016/j.elspec.2023.147333

M. Mailhiot , Y. Hikosaka , K. Jänkälä , A. Kivimäki , C. Küstner-Wetekam , J. Palaudoux , E. Pelimanni , F. Penent , C. Zindel , M. Patanen , P. Lablanquie , M. Huttula , A. Hans

引用次数: 0

Scanning photoelectron spectromicroscopy: From static to operando studies of functional materials 扫描光电子能谱显微镜：从静态到操作的功能材料研究

IF 1.9 4区物理与天体物理

Journal of Electron Spectroscopy and Related Phenomena Pub Date : 2023-05-01 DOI: 10.1016/j.elspec.2023.147336

M. Amati , Toma Susi , P. Jovičević-Klug , M. Jovičević-Klug , Tomasz Kosmala , Gaetano Granozzi , Stefano Agnoli , Pengfei Yang , Yanfeng Zhang , Mattia Scardamaglia , L. Gregoratti

{"title":"Scanning photoelectron spectromicroscopy: From static to operando studies of functional materials","authors":"M. Amati , Toma Susi , P. Jovičević-Klug , M. Jovičević-Klug , Tomasz Kosmala , Gaetano Granozzi , Stefano Agnoli , Pengfei Yang , Yanfeng Zhang , Mattia Scardamaglia , L. Gregoratti","doi":"10.1016/j.elspec.2023.147336","DOIUrl":"10.1016/j.elspec.2023.147336","url":null,"abstract":"<div>The scanning photoelectron microscope (SPEM), developed more than 30 years ago, has undergone numerous technical developments, providing an incredibly vast kind of feasible sample environments, which span from the traditional high spatial resolution core level based chemical analysis to insitu and operando complex experiments, including also electrochemical setups and operational electronic devices at various temperatures. Another important step ahead is overcoming the so-called pressure gap for operando studies, recently extended to near ambient values by building special environmental cells. Using recent results of conventional and unconventional experiments, obtained with SPEM at the ESCA Microscopy beamline at Elettra Sincrotrone Trieste the present review demonstrates the current potential of this type of photoelectron spectromicroscopy to explore the interfacial properties of functional materials with high spatial resolution.</div>","PeriodicalId":15726,"journal":{"name":"Journal of Electron Spectroscopy and Related Phenomena","volume":"265 ","pages":"Article 147336"},"PeriodicalIF":1.9,"publicationDate":"2023-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42233436","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Scanning transmission X-ray microscopy of hydrogen evolution electrocatalysts on reduction graphene oxide membranes 还原氧化石墨烯膜上析氢电催化剂的扫描透射X射线显微术

IF 1.9 4区物理与天体物理

Journal of Electron Spectroscopy and Related Phenomena Pub Date : 2023-05-01 DOI: 10.1016/j.elspec.2023.147332

C. O. M. Mariano, Julia Bella Rodriguez, R. Clemente, T. Ohigashi, H. Yuzawa, W. Hsu, J. Shiue, C. Chuang

引用次数: 0

Scanning transmission X-ray microscopy of hydrogen evolution electrocatalysts on reduction graphene oxide membranes 还原氧化石墨烯膜上析氢电催化剂的扫描透射x射线显微镜研究

IF 1.9 4区物理与天体物理

Journal of Electron Spectroscopy and Related Phenomena Pub Date : 2023-05-01 DOI: 10.1016/j.elspec.2023.147332

Carl Osby M. Mariano , Jan Sebastian Dominic Rodriguez , Russell Hizon Clemente , Takuji Ohigashi , Hayato Yuzawa , Wei-Hao Hsu , Jessie Shiue , Cheng-Hao Chuang

{"title":"Scanning transmission X-ray microscopy of hydrogen evolution electrocatalysts on reduction graphene oxide membranes","authors":"Carl Osby M. Mariano , Jan Sebastian Dominic Rodriguez , Russell Hizon Clemente , Takuji Ohigashi , Hayato Yuzawa , Wei-Hao Hsu , Jessie Shiue , Cheng-Hao Chuang","doi":"10.1016/j.elspec.2023.147332","DOIUrl":"https://doi.org/10.1016/j.elspec.2023.147332","url":null,"abstract":"<div>Cobalt is one of the promising metal catalysts for hydrogen evolution reaction, and its catalytic performance can be further improved by supporting on graphene oxide and reduced graphene oxide as an active interface to the substrate. Scanning transmission X-ray microscopy (STXM) identifies the position-dependent functional groups on the membranes and chemical structure evolution of the CoxOy. The in-situ mass spectrometer analysis shows the reduction current and H2 generation of the electrocatalyst enhanced by the addition of graphene oxide and reduced graphene oxide to CoxOy, as compared to the CoxOy on the bare substrate. The best hydrogen evolution reaction performance of CoxOy at − 2.5 V is correlated with the high Co3+ concentration existed on the reduced graphene oxide, as evidenced by the nano- and element-resolved capability of STXM. With the economical electro-reduction synthesis, this study provides brand-new insights into the critical role of substrate rGO and electrocatalyst CoxOy toward the design of high efficiency electrocatalyst.</div>","PeriodicalId":15726,"journal":{"name":"Journal of Electron Spectroscopy and Related Phenomena","volume":"265 ","pages":"Article 147332"},"PeriodicalIF":1.9,"publicationDate":"2023-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49867367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Electronic and optical properties of SWCNTs and spin-orbit coupling effect on their electronic structures: First-principle computing SWCNT的电子和光学性质及其电子结构的自旋轨道耦合效应：第一性原理计算

IF 1.9 4区物理与天体物理

Journal of Electron Spectroscopy and Related Phenomena Pub Date : 2023-05-01 DOI: 10.1016/j.elspec.2023.147321

Abdelhafid Najim , Omar Bajjou , Anass Bakour , Khalid Rahmani

{"title":"Electronic and optical properties of SWCNTs and spin-orbit coupling effect on their electronic structures: First-principle computing","authors":"Abdelhafid Najim , Omar Bajjou , Anass Bakour , Khalid Rahmani","doi":"10.1016/j.elspec.2023.147321","DOIUrl":"10.1016/j.elspec.2023.147321","url":null,"abstract":"<div>In this research, electronic and optical properties of armchair (7,7), zigzag (7,0), and chiral (4,2) configurations of Single-Walled Carbon Nanotubes (SWCNT) and the effect of spin-orbit coupling (SOC) on their electronic structures were studied with density functional theory (DFT) computing. The armchair, zigzag, and chiral SWCNT structures were built using the CASTEP software. Then, this code was used to calculate the band structures, density of states and optical properties of these systems. Electronic and optical properties of SWCNT material could be influenced by its configuration, such as the bandgap energy, total density of states (TDOS) and partial density of states (PDOS), absorption coefficient, dielectric function, optical conductivity, complex refractive index, and the loss function. In the absence or presence of SOC effect, armchair, zigzag and chiral nanotubes are semiconductors. SOC causes the bandgap energy to increase and the TDOS of \"armchair, zigzag, and chiral SWCNTs\" to alter. These results provide crucial physical information regarding the control of the electronic properties of SWCNTs using SOC.</div>","PeriodicalId":15726,"journal":{"name":"Journal of Electron Spectroscopy and Related Phenomena","volume":"265 ","pages":"Article 147321"},"PeriodicalIF":1.9,"publicationDate":"2023-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42512224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Scanning transmission X-ray spectromicroscopy: A nanotool to probe hematite nanorods for solar water splitting 扫描透射X射线光谱显微镜：一种用于探测太阳水分解赤铁矿纳米棒的纳米工具

IF 1.9 4区物理与天体物理

Journal of Electron Spectroscopy and Related Phenomena Pub Date : 2023-05-01 DOI: 10.1016/j.elspec.2023.147334

Stefan Stanescu , Dana Stanescu , Adam Hitchcock

引用次数: 0

SPADExp: A photoemission angular distribution simulator directly linked to first-principles calculations SPADExp:与第一性原理计算直接相关的光电发射角分布模拟器

IF 1.9 4区物理与天体物理

Journal of Electron Spectroscopy and Related Phenomena Pub Date : 2023-04-01 DOI: 10.1016/j.elspec.2023.147297

Hiroaki Tanaka , Kenta Kuroda , Tomohiro Matsushita

{"title":"SPADExp: A photoemission angular distribution simulator directly linked to first-principles calculations","authors":"Hiroaki Tanaka , Kenta Kuroda , Tomohiro Matsushita","doi":"10.1016/j.elspec.2023.147297","DOIUrl":"10.1016/j.elspec.2023.147297","url":null,"abstract":"<div>We develop a software package SPADExp (simulator of photoemission angular distribution for experiments) to calculate the photoemission angular distribution (PAD), which is the momentum dependence of spectrum intensity in angle-resolved photoemission spectroscopy (ARPES). The software can directly load the output of the first-principles software package OpenMX, so users do not need to construct tight-binding models as previous studies did for PAD calculations. As a result, we can calculate the PADs of large systems such as quasicrystals and slab systems. We calculate the PADs of sublattice systems (graphene and graphite) to reproduce characteristic intensity distributions, which ARPES has experimentally observed. After that, we investigate twisted bilayer graphene, a quasicrystal showing 12-fold rotational symmetric spectra in ARPES, and the surface states of the topological insulator <math><mrow><msub><mrow><mi>Bi</mi></mrow><mrow><mn>2</mn></mrow></msub><msub><mrow><mi>Se</mi></mrow><mrow><mn>3</mn></mrow></msub></mrow></math>. Our calculations show good agreement with previous ARPES measurements, showing the correctness of our calculation software and further potential to investigate the photoemission spectra of novel quantum materials.</div>","PeriodicalId":15726,"journal":{"name":"Journal of Electron Spectroscopy and Related Phenomena","volume":"264 ","pages":"Article 147297"},"PeriodicalIF":1.9,"publicationDate":"2023-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42273827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Near-edge X-ray absorption fine structure spectroscopy in studies of self-assembled monomolecular films 近边x射线吸收精细结构光谱在自组装单分子薄膜研究中的应用

IF 1.9 4区物理与天体物理

Journal of Electron Spectroscopy and Related Phenomena Pub Date : 2023-04-01 DOI: 10.1016/j.elspec.2023.147322

Michael Zharnikov

{"title":"Near-edge X-ray absorption fine structure spectroscopy in studies of self-assembled monomolecular films","authors":"Michael Zharnikov","doi":"10.1016/j.elspec.2023.147322","DOIUrl":"10.1016/j.elspec.2023.147322","url":null,"abstract":"<div>This article reviews the application of near-edge X-ray absorption fine structure (NEXAFS) spectroscopy to characterization of self-assembled monolayers (SAMs) which are an important part of modern nanotechnology, being particular useful in context of surface and interface engineering. NEXAFS spectroscopy provides information about the electronic structure of the SAMs, which allows to recognize specific functional groups and building blocks of the SAM-forming molecules. Due to the linear dichroism effects in X-ray absorption, this technique is also capable to give insight into orientational order and molecular orientation in the SAMs, both overall and building-block-specific. To illustrate the above points, a variety of representative examples for different classes of SAMs is provided, accompanied by the information about the general aspects of the technique and the description of suitable data evaluation procedures. Finally, it is shown that the application of NEXAFS spectroscopy to SAMs is not only limited by their characterization but is also useful to monitor chemical and physical processes involving these systems.</div>","PeriodicalId":15726,"journal":{"name":"Journal of Electron Spectroscopy and Related Phenomena","volume":"264 ","pages":"Article 147322"},"PeriodicalIF":1.9,"publicationDate":"2023-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45209929","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Multiple-site Ag doping in Bi2Se 多位点Ag掺杂Bi2Se<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" altimg="si30.svg"显示

IF 1.9 4区物理与天体物理

Journal of Electron Spectroscopy and Related Phenomena Pub Date : 2023-04-01 DOI: 10.1016/j.elspec.2023.147295

Fumihiko Matsui, H. Ota, R. Eguchi, H. Goto, K. Kobayashi, Jun Akimitsu, H. Ozaki, Takumi Nishioka, K. Kimura, K. Hayashi, T. Shimano, N. Happo, Y. Kubozono

引用次数: 0