{"title":"Efficient nitrogen elimination and microbial community characteristics in a sulfur-based autotrophic bioreactor at high nitrate loading.","authors":"Yuan Gao, Jie Ying","doi":"10.1080/09593330.2026.2746058","DOIUrl":"https://doi.org/10.1080/09593330.2026.2746058","url":null,"abstract":"<p><p>This study systematically evaluated the nitrogen removal performance and microbial community characteristics of the sulfur-based autotrophic denitrification (SAD) process under various influent loads (15-140 mg N/L). After 22 days acclimation at 15 mg N/L, the system achieved >90% stable NO<sub>3</sub><sup>-</sup>-N removal. Notably, the system demonstrated exceptional stability at a high load of 140 mg N/L, with an average total nitrogen removal rate of 98% (peaking at 99%). This performance indicates a successful adaptation to elevated loading conditions. The high removal efficiency is attributed to the coordinated metabolic processes within the system. As the nitrate load increased, sulfur oxidation accelerated, releasing protons and causing a decline in pH. The ratio of sulfate production to nitrate removal (6.8-10 mg/mg) remained consistent with the theoretical value of 7.54 mg/mg, confirming the integrity of the sulfur metabolic pathway across various loading conditions. Furthermore, the nitrate load acted as a selective pressure, promoting the dominance of Pseudomonadota and <i>Thiobacillus</i> to establish a robust functional microbial ecosystem. In conclusion, this study confirms the viability of the SAD process for treating wastewater with medium to high nitrate concentrations. It also reveals the metabolic and community mechanisms that support performance stability under various load conditions.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"1-10"},"PeriodicalIF":2.2,"publicationDate":"2026-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149180184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Kinetic responses of enriched nitrifying systems to acute erythromycin and tetracycline exposure.","authors":"Tugce Katipoglu-Yazan, Emine Cokgor, Derin Orhon","doi":"10.1080/09593330.2026.2730318","DOIUrl":"https://doi.org/10.1080/09593330.2026.2730318","url":null,"abstract":"<p><p>This study investigated the acute inhibitory impacts of two widely used antibiotics, erythromycin (ERY) and tetracycline (TET), on ammonia-oxidizing bacteria (AOB) and nitrite-oxidizing bacteria (NOB) within an enriched nitrifying culture. For this purpose, a lab-scale wastewater treatment system sustaining enriched nitrifiers was exposed to antibiotic concentrations ranging from 25 to 100 mg L<sup>-1</sup>. Model evaluations of oxygen uptake rate (OUR) evolution, together with ammonia and nitrite oxidation profiles, revealed distinct metabolic disruptions. ERY severely impaired the system, dropping overall nitrification efficiency to as low as 25% and halving the growth rates for both AOB and NOB. In contrast, TET exposure largely maintained overall nitrification performance with slightly reduced NOB activity. Under TET stress, the half-saturation constants for ammonia (K<sub>NH</sub>) and nitrite (K<sub>NO</sub>) increased to 32 and 2 mg N L<sup>-</sup><sup>1</sup>, respectively, indicating competitive inhibition and decreased substrate affinity. Both antibiotics reduced heterotrophic activity - more severely with ERY-triggering the release and utilisation of hydrolyzable biomass fractions. The results demonstrate that acute antibiotic toxicity and inhibitory impacts are markedly less pronounced in enriched nitrifying systems compared to conventional mixed activated sludge systems.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"1-10"},"PeriodicalIF":2.2,"publicationDate":"2026-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149126991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Guoyu Zhang, Yiwen Ding, Shuyu Zhao, Yijun You, Yuanyuan Gao, Yixuan Yang, Haili Tan, Yi Ding, Jing Zhu, Zhipeng Li
{"title":"Utilizing the nucleation activity of filamentous cyanobacteria to construct photogranules: treatment performance, formation process and recycling phycobiliprotein.","authors":"Guoyu Zhang, Yiwen Ding, Shuyu Zhao, Yijun You, Yuanyuan Gao, Yixuan Yang, Haili Tan, Yi Ding, Jing Zhu, Zhipeng Li","doi":"10.1080/09593330.2026.2740060","DOIUrl":"https://doi.org/10.1080/09593330.2026.2740060","url":null,"abstract":"<p><p>This study characterizes the dynamic development process of photogranules, explores the role of related substances in their formation, and verifies the resource recovery potential in nitrogen and phosphorus removal from wastewater. The characteristics of photogranules were observed, and the nitrogen and phosphorus removal efficiency of the system was measured. The content of protein and polysaccharide in extracellular polymeric substances was determined over time. Excitation-emission matrix fluorescence was used to analyse the types and changes of substances in the system. Resource recovery assessments were conducted by adopting the method of freeze-thaw combined with trituration to extract phycocyanin and determine the content of phycobiliprotein. Photogranule development went through three sequential phases: initially, photogranules were under 1 mm in diameter, with peripheral filaments proliferating to create an irregular, meteorite-like surface; densification: loosely woven filaments contracted, increasing density and reducing surface pits, forming more compact structures; at maturation, granules reached approximately 1.3 mm and became spherical. The system achieved approximately 98% nitrogen and 56% phosphorus removal. Protein and polysaccharide content in extracellular polymeric substances increased slightly over time. Excitation-emission matrix fluorescence showed abundant humic-like substances in the early phase, while microbial byproducts and aromatic proteins remained stable later. The freeze-thaw combined with trituration yielded the highest concentration of phycocyanin (0.31 mg L<sup>-1</sup>), with phycobiliprotein content stable at about 50 mg L<sup>-1</sup>. This study describes photogranule growth characteristics, confirms the structural role of EPS, and demonstrates the dual functionality of photogranules in nutrient removal and resource recovery.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"1-15"},"PeriodicalIF":2.2,"publicationDate":"2026-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149106085","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Electron beam irradiation for enhanced dewatering of dairy wastewater air flotation sludge: unravelling the demulsification and floc aggregation mechanism.","authors":"Ge Tang, Jingyi Zhang, Jilai Lu, Liwei Mao","doi":"10.1080/09593330.2026.2740753","DOIUrl":"https://doi.org/10.1080/09593330.2026.2740753","url":null,"abstract":"<p><p>Dairy wastewater air flotation sludge (DWAFS) is resistant to conventional mechanical dewatering due to its high fat content and protein-stabilized emulsion structure. To address this challenge, this study employed electron beam (EB) irradiation as a pretreatment method. The effects of irradiation dose on sludge dewaterability were systematically investigated, and the multi-dimensional underlying mechanisms were elucidated through integrated multi-scale characterization. The results showed that EB irradiation significantly enhanced dewaterability, with 5 kGy identified as the optimal dose based on a combined evaluation of dewatering performance and specific energy consumption. EB irradiation was shown to efficiently disrupt the protein-stabilized emulsion, likely via water radiolysis-derived free radicals. This process is proposed to drive organic component transformation, surface charge neutralization, protein-lipid co-aggregation and floc reconstruction, ultimately contributing to the conversion of bound water to free water and enhanced dewaterability. These findings clarify the demulsification-dewatering coupling mechanism of EB irradiation on DWAFS and provide a theoretical basis for engineering application in high-fat oily sludge treatment.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"1-13"},"PeriodicalIF":2.2,"publicationDate":"2026-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149105947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Environmental TechnologyPub Date : 2026-10-01Epub Date: 2026-09-17DOI: 10.1080/09593330.2026.2729540
Rutu H Patel, Helina Patel
{"title":"Integrated lignocellulolytic enzyme production and pretreatment of wheat straw by fungal consortium.","authors":"Rutu H Patel, Helina Patel","doi":"10.1080/09593330.2026.2729540","DOIUrl":"10.1080/09593330.2026.2729540","url":null,"abstract":"<p><p>In nature, fungi play a leading role in the biodegradation of organic waste by secreting a broad spectrum of lignocellulolytic enzymes (cellulases, hemicellulases, and ligninases). Inspired by this natural ecological synergy, in the present study, two promising fungal isolates, <i>Trichoderma</i> sp. isolate HR27 and <i>Ganoderma</i> sp. isolate HR31, were isolated and assessed for biocompatibility. Subsequently, their consortium was utilized for single-factorial optimization of various parameters (inoculum size, incubation time, lignocellulosic substrate, temperature, moisture content, pH, surfactant, nitrogen source, co-substrate, and inducer) under solid-state fermentation (SSF) using lignocellulosic waste for enhanced lignocellulolytic enzyme production. The results revealed that a significant increase in enzyme yield was achieved by utilizing wheat straw as the substrate, supplemented with 1.5 g/L Tween 80 and 0.5 mM CuSO<sub>4</sub> in Asther's medium with an initial pH of 3.5 at 30˚C. Compared to unoptimized media, optimized media resulted in 5.99, 5.18, 1.13, 2.57, 4.97, and 2.68-fold increases in endoglucanase, exoglucanase, β-glucosidase, mannanase, xylanase, and laccase production, respectively, on the fourth day of fermentation. Compositional analysis revealed that enhanced enzyme production under optimized conditions resulted in 31.7% delignification of wheat straw; however, only 22.9% was observed under unoptimized conditions, compared to that of the raw substrate. The removal of lignin resulted in higher exposure of cellulose (43.25%) and hemicellulose (24.85%) contents in wheat straw under optimized conditions. These findings highlight the potential of the fungal consortium as an effective candidate for lignocellulolytic enzyme cocktail production for various industrial applications using agricultural waste with concurrent valorization of agro-waste.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"3257-3279"},"PeriodicalIF":2.2,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148988611","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Comparative speciation and multi-index risk assessment of heavy metals in drinking-water, municipal wastewater, and industrial wastewater treatment sludges: implications for sustainable reuse.","authors":"Ming-Huang Wang, Edrafel Claudeen Mallorca-Manoy, Chiu-Wen Chen, Cheng-Di Dong","doi":"10.1080/09593330.2026.2737838","DOIUrl":"10.1080/09593330.2026.2737838","url":null,"abstract":"<p><p>This study compared the concentrations, operationally defined chemical fractions, and screening-level environmental risks of Cu, Cr, Zn, Cd, Ni, and Pb in 20 dewatered sludge samples collected from drinking-water treatment plants (DWTPs; <i>n</i> = 3), municipal wastewater treatment plants (MWWTPs; <i>n</i> = 11), and industrial wastewater treatment plants (IWWTPs; <i>n</i> = 6) in Taiwan. A modified BCR sequential extraction procedure was used to separate acid-extractable (F1), reducible (F2), oxidizable (F3), and residual (F4) fractions. MWDWTP sludge contained comparatively high Zn and Cd concentrations, whereas several IWWTP samples showed elevated Cu, Cr, Ni, and Pb. Cu, Cr, Ni, and Pb were frequently associated with F3 and/or F4, while Zn and Cd showed substantial F2 contributions at several sites. Concentration-based indices identified marked enrichment at selected facilities, whereas fraction-based indices indicated that mobility depended on both metal and sludge category. High Igeo values therefore represent enrichment relative to background and do not necessarily indicate high immediate mobility when metals occur mainly in F3 or F4. These results support site-specific evaluation of total metal loads and chemical fractionation before sludge reuse, treatment, or disposal.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"3342-3353"},"PeriodicalIF":2.2,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149037367","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Environmental TechnologyPub Date : 2026-10-01Epub Date: 2026-09-15DOI: 10.1080/09593330.2026.2732107
Yao Yao, Yinan Wang, Junfeng Su, Xue Li, Yihan Bai, Xuan Li
{"title":"Manganese-modified corn silk composite mycelial pellets immobilized bioreactor for simultaneous removal of nitrate, zinc, and nickel.","authors":"Yao Yao, Yinan Wang, Junfeng Su, Xue Li, Yihan Bai, Xuan Li","doi":"10.1080/09593330.2026.2732107","DOIUrl":"10.1080/09593330.2026.2732107","url":null,"abstract":"<p><p>The non-compliant discharge of electroplating wastewater containing nitrate (NO<sub>3</sub><sup>-</sup>-N) and heavy metals (HMs) harms aquatic ecosystems and makes it more difficult to control water pollution. This study prepared manganese-modified corn silk (Mn/CS) composite mycelial pellets (Mn-CMP) by combining Mn/CS with the fungal strain <i>Alternaria</i> sp. YNX. These Mn-CMP were then used as novel immobilized carriers to immobilize the strain <i>Zoogloea</i> sp. ZY8 to construct a dual-species immobilized bioreactor. Under optimal conditions, with influent concentrations of 20.0 mg L<sup>-1</sup> NO<sub>3</sub><sup>-</sup>-N, 1.0 mg L<sup>-1</sup> Zinc(II) (Zn(II)), and 1.0 mg L<sup>-1</sup> nickel(II) (Ni(II)), the bioreactor achieved simultaneous removal of NO<sub>3</sub><sup>-</sup>-N at 97.50%, Zn(II) at 99.50%, and Ni(II) at 96.87%. During this process, manganese (Mn) oxides acted as electron shuttles and active sites to enhance electron transfer, while oxygen-containing functional groups promoted HMs adsorption, and bioprecipitation further facilitated HMs immobilization. Furthermore, high-throughput sequencing revealed core functional genes for nitrogen and energy metabolism, which microorganisms regulated to respond to environmental changes. This study provided a new perspective for using Mn-CMP to immobilize functional bacteria to treat industrial wastewater co-contaminated with NO<sub>3</sub><sup>-</sup>-N and HMs.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"3298-3311"},"PeriodicalIF":2.2,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148976339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Environmental TechnologyPub Date : 2026-10-01Epub Date: 2026-09-23DOI: 10.1080/09593330.2026.2735896
Mehak Puri, Kavita Gandhi, M Suresh Kumar
{"title":"Comparative experimental evaluation of sequential biological-UV/H₂O₂ treatment for endocrine-disrupting chemical mixtures under controlled batch conditions.","authors":"Mehak Puri, Kavita Gandhi, M Suresh Kumar","doi":"10.1080/09593330.2026.2735896","DOIUrl":"10.1080/09593330.2026.2735896","url":null,"abstract":"<p><p>The study evaluates the degradation of a mixture of frequently detected endocrine disrupting chemicals in municipal wastewater using six sequential biological-advanced oxidation treatment systems. The evaluated systems include UV, H<sub>2</sub>O<sub>2</sub>, and UV/H<sub>2</sub>O<sub>2</sub> applied before or after biological treatment. The performance of the conventional municipal treatment plant was compared with sequential processes under previously optimized operating conditions (pH ≈ 5 (AOP), 7 (bio), 450 W UV power, 2.0 mM H₂O₂, reaction time for AOP: 60 min, and bio process: 6 h). The conventional system achieved only 36.41 ± 0.53% to 55.11 ± 0.48% removal of the mixture of target EDCs, whereas the bio/UV/H<sub>2</sub>O<sub>2</sub> was the most effective, achieving complete diethyl phthalate removal and >90 ± 0.65% of butyl paraben and bisphenol A, with 90.5 ± 1.33% reduction in chemical oxygen demand. The pseudo-first-order kinetic analysis indicated an enhanced degradation efficiency, with a maximum rate constant of 0.0048 min<sup>-</sup>¹. The energy consumption ranged from 9.47 × 10² to 1.56 × 10⁴ kWh kg<sup>-</sup>¹ COD, with the operating cost primarily driven by electricity (≈0.16 USD L<sup>-</sup>¹). These findings provide mechanistic and comparative insight into hybrid treatment performance under controlled conditions; however, validation under environmentally relevant concentrations and continuous-flow systems is required before practical implementation.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"3326-3341"},"PeriodicalIF":2.2,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149029946","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Environmental TechnologyPub Date : 2026-10-01Epub Date: 2026-09-23DOI: 10.1080/09593330.2026.2735890
Maria Carolina Costa, Miguel Campos, Marco Silva, Aline Martins Pinheiro, M Salomé Duarte, João R Sousa, Carlos Afonso Teixeira
{"title":"Process-oriented screening of agro-industrial waste streams for co-digestion in WWTP anaerobic digesters.","authors":"Maria Carolina Costa, Miguel Campos, Marco Silva, Aline Martins Pinheiro, M Salomé Duarte, João R Sousa, Carlos Afonso Teixeira","doi":"10.1080/09593330.2026.2735890","DOIUrl":"10.1080/09593330.2026.2735890","url":null,"abstract":"<p><p>Wastewater utilities require a systematic method for screening agro-industrial co-substrates before testing them in sewage-sludge digesters. This study developed and applied a hierarchical preliminary screening framework based on physicochemical characterisation, biochemical methane potential assays, first-order kinetic modelling, and volumetric methane production. Seven waste streams were evaluated individually: a fat-rich fraction recovered from meat-processing wash water, four meat-processing wash waters, used cooking oil, and confectionery-production wash water. Eight fixed-ratio mixtures were then assessed using selected meat-processing streams, cheese whey, olive mill wastewater, and winery wastewater. Specific methane production of the individual waste streams ranged from 0.087 to 0.969 m³ CH₄ kg<sup>-</sup>¹ VS. Across the mixtures, final SMP ranged from 0.390 to 0.855 m³ CH₄ kg<sup>-</sup>¹ VS and t₉₀ from 9.0 to 23.3 d. TS, VS, and COD were associated with volumetric methane production at days 10 and 30 but not with final SMP, k, or t₉₀. The COD-VMP10 and TS-VMP30 models explained 87.5% and 86.0% of the variability, showing that volumetric methane output was influenced by feedstock concentration. Biochemical compatibility was classified using final SMP, t₉₀, and evidence of sustained methane suppression; VMP10 and VMP30 then refined priorities within each category. The cheese whey + meat-processing wash water R2 mixture (M1; 1:1 v/v) was prioritised because it combined high SMP (0.792 m³ CH₄ kg<sup>-</sup>¹ VS), rapid apparent conversion (t₉₀ = 11.8 d), and the highest volumetric relevance. The framework converts physicochemical and BMP-derived results into a traceable basis for selecting external co-substrates for subsequent controlled validation with municipal sludge.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"3312-3325"},"PeriodicalIF":2.2,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149030004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A sustainable approach to the treatment of textile reverse osmosis concentrate using the photo-Fenton process.","authors":"Gamze Canbakal, Öykü Nur Ersöz, Gülay Arslan Çene, Senem Yazici Guvenc, Emine Can-Güven, Gamze Varank","doi":"10.1080/09593330.2026.2730325","DOIUrl":"10.1080/09593330.2026.2730325","url":null,"abstract":"<p><p>Textile industry wastewater consists of colored wastewater containing high concentrations of organic matter, complex components, reactive dyes, and chemical residues. While reverse osmosis (RO) membrane systems are frequently used to sustainably manage high-volume wastewater streams, they also produce a concentrated, resistant, and nonbiodegradable effluent. In this study, the photo-Fenton process was applied and optimized using Box-Behnken Design (BBD) to treat RO concentrate containing high concentrations of toxic and pollutant species. H<sub>2</sub>O<sub>2</sub>/COD, Fe<sup>2+</sup>/H<sub>2</sub>O<sub>2</sub>, and reaction time were selected as operating parameters, while COD, color index (CI), ultraviolet absorbance at 254 nm (UV<sub>254</sub>), and ultraviolet absorbance at 280 nm (UV<sub>280</sub>) removal efficiencies were selected as model responses. Statistically, the model's fits were evaluated using variance analysis. Numerical analysis determined the optimum process conditions as H<sub>2</sub>O<sub>2</sub>/COD 2.0, Fe<sup>2+</sup>/H<sub>2</sub>O<sub>2</sub> 0.25, and reaction time 68.4 min at pH 3.0. Under optimum conditions, the validation experiments demonstrated that the photo-Fenton process achieved removal efficiencies of 78.5% for COD, 96.6% for CI, 82.5% for total suspended solids, 92.8% for UV<sub>254</sub>, and 85.0% for UV<sub>280</sub>. The calculated operating cost of the process was 14.3 €/m<sup>3</sup>. The obtained results showed that the applied photo-Fenton process effectively removed pollutants from RO concentrate, and that the BBD could be used to optimize its operating conditions.</p>","PeriodicalId":12009,"journal":{"name":"Environmental Technology","volume":" ","pages":"3280-3297"},"PeriodicalIF":2.2,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148988565","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}