Advanced Materials最新文献

{"title":"Terahertz In‐Sensor Computing Utilizing Photothermoelectric Thin Films","authors":"He Shao, Yuxuan Zhang, Zhengxun Lai, Jiachi Liao, Bowen Li, Weijun Wang, Pengshan Xie, Baojie Chen, Chi Hou Chan, You Meng, Johnny C. Ho","doi":"10.1002/adma.202505719","DOIUrl":"https://doi.org/10.1002/adma.202505719","url":null,"abstract":"Terahertz (THz) detection is pivotal for biomedical diagnostics and security screening, enabled by its non‐ionizing nature and characteristic “fingerprint” spectra. However, weak THz–matter interactions, energy‐intensive processing, and complex hardware integration hinder its practical use. To this aim, a layered bismuth selenide (Bi<jats:sub>2</jats:sub>Se<jats:sub>3</jats:sub>)‐based THz detection array is fabricated via low‐temperature pulse irradiation synthesis (PIS), exhibiting a tunable thermally coupled bidirectional response. The intrinsic photothermoelectric (PTE) effect enables adaptive in‐sensor THz signal processing, achieving 200 V W<jats:sup>−1</jats:sup> responsivity and &lt;5 ms response time at 0.3 THz in a self‐powered mode. Integrated in‐sensor computing enhances accuracy through real‐time noise suppression, edge detection, and feature extraction. The array also demonstrates high imaging performance, with a &gt;90% recall rate for concealed object detection. This work provides a scalable, high‐precision THz sensing platform with transformative potential for biomedical and security applications.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"115 1","pages":""},"PeriodicalIF":29.4,"publicationDate":"2025-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144678010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Biomimetic 3D‐Printed Adaptive Hydrogel Bioadhesives Featuring Superior Infection Resistance for Challenging Tissue Adhesion, Hemostasis, and Healthcare","authors":"Qi Wu, Meenakshi Chauhan, Bassma Khamaisi, Eid Nassar‐Marjiya, Shady Farah","doi":"10.1002/adma.202502850","DOIUrl":"https://doi.org/10.1002/adma.202502850","url":null,"abstract":"Conventional suturing and stapling cause additional trauma, pain, and cost for patients. As alternatives, existing bioadhesives suffer from imprecise fabrication, limited wet tissue adhesion, and insufficient biological functionalities for effective wound management. This work proposes biomimetic hydrogel bioadhesives composed of modified natural tannic acid (TA), hyperbranched polylysine (HPL), and acrylic acid (AA), abbreviated PTLAs, to offer solutions for tissue adhesion under challenging environments (underwater, body fluids, cold, pressure), and for enhanced healthcare. These PTLAs are fabricated via 3D printing, enabling the precise and controlled production of bioadhesives that are customized in a personalized manner with great reproducibility. Inspired by molluscs, developed PTLAs exhibit robust wet and underwater tissue adhesion, outperforming commercial and many recently reported bioadhesives. Ex vivo lamb and in vivo rat models demonstrate ultrafast (5 s) and efficient sealing and hemostasis. Exceptional freeze resistance and pressure resistance further expand their applicability to extreme environments. Meanwhile, coupled with superior infection resistance, PTLAs ensure enhanced wound healthcare while sealing and hemostasis. Further, their self‐gelling feature supports dry powder adhesion/sealing applications, practical packaging, and long‐term storage. Overall, adaptive tissue‐like PTLAs present transformative potential as bio‐tapes, bio‐bandages, bio‐sealants, bio‐carriers, etc., paving the way for next‐generation bioadhesives design and enhanced healthcare solutions.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"6 1","pages":""},"PeriodicalIF":29.4,"publicationDate":"2025-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144677842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High Rate Capability and Cycling Stability in Multi-Domain Nanocomposite LiNi_1- _xTi₃ _x _/4O₂ Positive Electrodes.","authors":"Jungwoo Lim, Manel Sonni, Luke M Daniels, Mounib Bahri, Marco Zanella, Ruiyong Chen, Zhao Li, Alex R Neale, Hongjun Niu, Nigel D Browning, Matthew S Dyer, John B Claridge, Laurence J Hardwick, Matthew J Rosseinsky","doi":"10.1002/adma.202417899","DOIUrl":"https://doi.org/10.1002/adma.202417899","url":null,"abstract":"<p><p>LiNiO₂ positive electrode materials for lithium-ion batteries have experienced a revival of interest due to increasing technological energy demands. Herein a specific Ti⁴⁺ substitution is targeted into LiNiO₂ to access new compositions by synthesizing the LiNi_1- _xTi₃ _x _/4O₂ solid solution with the aim of retaining Ni³⁺. Compositions in the range 0.025 ≤ x ≤ 0.2 form nanocomposites of compositionally homogeneous ordered R <math> <semantics><mover><mn>3</mn> <mo>¯</mo></mover> <annotation>$bar 3$</annotation></semantics> </math> m and disordered Fm <math> <semantics><mover><mn>3</mn> <mo>¯</mo></mover> <annotation>$bar 3$</annotation></semantics> </math> m rock salt domains as observed via X-ray and neutron diffraction, and STEM. The disordered rock salt domains stabilize the ordered structure to provide excellent structural reversibility via the formation of coherent interfaces during cycling and enable deep delithiation using a constant voltage charging step without structural degradation. The detrimental structural phase transitions associated with the poor cyclability of LiNiO₂ are suppressed to yield a low strain positive electrode material with high capacity retention that offers high-rate capability even under increased cell electrode mass loadings. The composition x = 0.075 (LiNi_0.925Ti_0.05625O₂) affords a 93% capacity retention after 100 cycles (100 mA g^-1) and demonstrates high reversible capacities of 125 mAh g^-1 even under rates of 3200 mA g^-1. LiNi_0.925Ti_0.05625O₂ exhibits exceptional performance at electrode mass loadings (13.6 mg cm^-2) comparable to those required for commercial cell applications.</p>","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":" ","pages":"e2417899"},"PeriodicalIF":27.4,"publicationDate":"2025-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144688437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Thiophene Expanded Self-Assembled Monolayer as Hole Transport Layer for Organic Solar Cells with Efficiency of 20.78.","authors":"Yuanpeng Xie,Jingfu Tian,Xiaxia Yang,Junbo Chen,Shan Yu,Dianyong Tang,Xiaotian Hu,Yanming Sun,Menglan Lv","doi":"10.1002/adma.202502485","DOIUrl":"https://doi.org/10.1002/adma.202502485","url":null,"abstract":"Carbazole-derived self-assembled monolayers (SAMs) as hole transport layers (HTLs) have achieved groundbreaking progress of device efficiency in perovskite and organic photovoltaics. Expanding the π-conjugation of carbazole is an effective approach to enhance the molecular dipole moment and facilitate charge extraction of SAMs. However, this strategy tends to cause poor solubility and excessive self-aggregation of SAMs. In this work, two highly efficient SAMs are developed by substituting a non-fused thiophene unit on 3,6-position of carbazole, namely (2-(3,6-di(thiophen-3-yl)-9H-carbazol-9-yl)ethyl)phosphonate (2PAThCz) and diethyl (4-(3,6-di(thiophen-3-yl)-9H-carbazol-9-yl)butyl)phosphonate (4PAThCz). The introduction of thiophene can completely alter the molecular packing behavior of SAM, promoting more compact π-π stacking and increasing dipole moment, which enhances hole transport. Furthermore, the long spacer length on 4PAThCz enable to help it achieves excellent solubility, inhibit self-aggregation, and strengthen the molecular orderliness. As a result, an impressive efficiency of 20.78% (certified as 20.45%) is achieved for single-junction organic solar cells.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"14 1","pages":"e02485"},"PeriodicalIF":29.4,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Energy-Saving Hydrogen Production via Small Molecules Electrooxidation-Assisted Hybrid Systems.","authors":"Bing Wu,Wenxiang Su,Peipei Zhu,Jiancong Xu,Kai Yuan,Longbin Li,Yiwang Chen","doi":"10.1002/adma.202507842","DOIUrl":"https://doi.org/10.1002/adma.202507842","url":null,"abstract":"To alleviate overdependence on traditional fossil resources, green hydrogen (H2) production from an electrochemical water splitting (EWS) system powered by renewable energy resources (i.e., tidal, wind, and solar energy) has garnered considerable attention for its environmental sustainability. Nevertheless, the H2 production efficiency of the EWS system is restricted by the sluggish four-electron transfer process of the anodic oxygen evolution reaction (OER), which inhibits its further large-scale applications. Herein, recent advances in the hybrid EWS systems that substitutes OER with the thermodynamically favorable small molecules electrooxidation reaction (SMEOR) to integrate with the hydrogen evolution reaction are reviewed. First, the catalytic mechanisms of electrocatalysts toward SMEOR, reactor configurations, and evaluation parameters are briefly summarized. Next, the advantages and characteristics of the hybrid systems of SMEOR integrated with hydrogen evolution reaction/oxygen reduction reaction are highlighted and discussed in detail, including pollutant degradation, waste plastic upgrading, production of value-added chemicals, bipolar H2 production, and electricity output. Subsequently, the optimization strategies for rationally engineering the catalysts of SMEOR are proposed. Last, the current obstacles and future expectations of the hybrid EWS systems are outlined. This review aims to stimulate the further evolution of green H2 production.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"14 1","pages":"e07842"},"PeriodicalIF":29.4,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669601","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Machine Learning-Enhanced Modular Ionic Skin for Broad-Spectrum Multimodal Discriminability in Bidirectional Human-Robot Interaction.","authors":"Qianqian Yang,Bingqiao Li,Mengke Wang,Gaoyang Pang,Yuyao Lu,Jiayan Li,Huayong Yang,Honghao Lyu,Kaichen Xu,Geng Yang","doi":"10.1002/adma.202508795","DOIUrl":"https://doi.org/10.1002/adma.202508795","url":null,"abstract":"Multimodal tactile perception systems that mimic the functionality of human skin are able to perceive complex external stimuli, facilitating advanced applications in human-machine interactions. However, current systems still struggle with limited sensing ranges and suboptimal decoupling strategies, restricting their effective multimodal sensing. To achieve broad-spectrum multimodal discriminability, a machine learning-enhanced modular ionic skin (MIS) is developed via a synergistic sensor-algorithm optimization strategy. From the sensing material perspective, process-controlled hard-segment modulation in the ionic gel enables the development of diverse ionic conductors with enhanced sensing properties: a minimum temperature coefficient of -4.00% °C⁻¹ (10-160 °C), a linear gauge factor of 2.95 (0-100%), and a maximum pressure sensitivity of 80.5 kPa⁻¹ (0-1.3 MPa). With respect to the decoupling algorithm, a data-driven decoupling model for the MIS is meticulously proposed and trained on a dedicated multi-stimuli dataset, achieving maximum decoupling ranges for temperature and pressure with prediction errors as low as 7.0%, while maintaining reliable strain detection despite temperature interference. The effectiveness and functionality of the system are demonstrated in a multimodal wearable hand kit for operator hand recognition and a robotic gripper kit for feedback, highlighting its potential in bidirectional human-robot interaction.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"36 1","pages":"e08795"},"PeriodicalIF":29.4,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fundamental Limits on the Electron-Phonon Coupling and Superconducting T_c.","authors":"Dmitrii V Semenok, Boris L Altshuler, Emil A Yuzbashyan","doi":"10.1002/adma.202507013","DOIUrl":"https://doi.org/10.1002/adma.202507013","url":null,"abstract":"<p><p>Fundamental upper bounds on the electron-phonon interaction strength and superconducting transition temperature T_c in metals are established based on the intrinsic instability of the equilibrium between electrons and the crystal lattice under strong interaction. This instability explains why observed electron-phonon coupling constants are limited to λ ≲ 4. The theory also accounts for the mechanism of metastable superconductivity with enhanced T_c, which emerges near the instability threshold. Based on theoretical analysis and comparison with experimental data, room-temperature phonon-mediated superconductivity is found to be feasible exclusively in hydrogen compounds.</p>","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":" ","pages":"e2507013"},"PeriodicalIF":27.4,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144673433","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"3D Ordered Macroporous Superstructures of High Entropy Hydroxide with Strong Orbital Coupling Enhancing Water/Seawater Oxidation.","authors":"Xiaofeng Tian,Ruotong Liu,Weizhou Wang,Qin Yang,Zheng Huang,Yu Yang,Jishu Han,Tian Dong,Yunmei Du,Jianping Lai,Hongdong Li,Lei Wang","doi":"10.1002/adma.202506068","DOIUrl":"https://doi.org/10.1002/adma.202506068","url":null,"abstract":"The water splitting performance is strongly influenced by intrinsic properties of the catalyst and the accessibility of the active center. Herein, high-entropy hydroxides (HEH) with 3D ordered macroporous (3DOM) structure are prepared by chemical etching method with rational design. The 3DOM structure can maximize the exposure of the active sites and also facilitates bubble transport. As demonstrated by finite element analysis, the 3DOM structure modifies the spatial curvature of the catalyst, resulting in the enrichment of OH-. Moreover, the strong orbital coupling of transition metals significantly regulates the electronic structure of the catalyst, selectively adsorbs OH- at Fe sites, and inhibits the adsorption of Cl-. Thanks to these characteristics, 3DOM-HEH-300 shows the best oxygen evolution reaction (OER) performance in 1 m KOH (182 mV@100 mA cm-2, 211 mV@500 mA cm-2), and stables operation of more than 400 h. Besides, in natural seawater, it also exhibits the best catalytic activity (245 mV@100 mA cm-2, 278 mV@500 mA cm-2), which is better than similar catalysts without 3DOM structure. This work verifies the great synergistic effect of high entropy and mass transfer on the performance of OER, which also provides a new idea for constructing high-performance electrodes.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"14 1","pages":"e06068"},"PeriodicalIF":29.4,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Terminations Determine Energy-Level Alignment of Perovskite Buried Interfaces.","authors":"Yang Li,Junnan Guo,Jihua Tan,Ping Man,Shiang Li,Zixin Zeng,Thuc Hue Ly,Sai-Wing Tsang,Xinhui Lu,Weikang Wu,Chun-Sing Lee,Zhiqiang Guan","doi":"10.1002/adma.202506747","DOIUrl":"https://doi.org/10.1002/adma.202506747","url":null,"abstract":"The \"substrate-effect\", where the semiconduction type of perovskite changes according to that of the substrate is a widely-reported, but so far not fully understood phenomenon in the field of perovskite. The main challenge lies in the difficulty of probing and comprehending the electronic properties of perovskite buried interfaces. Here, through broadly investigating 20 buried interfaces formed between different perovskites and organic hole or electron transport materials (HTMs or ETMs), it is revealed that the substrate-effect originates from the distinct energy-level alignments at HTM or ETM substrates. Experimental and theoretical studies reveal that this difference stems from varying proportions of two perovskite terminations, which are determined by the interaction between substrates and perovskite crystals. With such mechanism, the semiconduction type of perovskite by controlling the proportion of surface terminations is successfully tuned. These findings provide new insights into optimizing device performance through termination engineering.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"15 1","pages":"e06747"},"PeriodicalIF":29.4,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Amorphizing Iron Molybdate as a High-Capacity Cathode for Lithium Metal Batteries Enabled by Multiple Insertion Reactions in the Metastable Structure.","authors":"Xiangjun Pu,Jaehoon Heo,Jaekyun Yoo,Long Chen,Chong-Rui Dong,Zhongxue Chen,Yuliang Cao,Jiayue Peng,Renjie Li,Yuyang Yi,Kisuk Kang,Zheng-Long Xu","doi":"10.1002/adma.202507840","DOIUrl":"https://doi.org/10.1002/adma.202507840","url":null,"abstract":"The rising energy demand for electric vehicles and energy storage has revived interest in lithium-metal batteries (LMBs). However, present LMBs still mainly rely on conventional lithium-ion batteries (LIBs) cathodes (e.g., LiFePO4 and LiNi1/3Mn1/3Co1/3O2) with limited reversible capacity (≈150 to ≈190 mAh g-1 cathode), necessitating the paradigm to achieve a new host with abundant Li+ accommodation sites. Herein, it is proposed a high-capacity amorphizing iron molybdate cathode a-Fe2(MoO4)3 (a-FMO), which can reversibly unlock Fe3+/Fe2+ and Mo6+/Mo4+ redox insertion reactions in the metastable structure. Different from its parent crystal and stoichiometric oxides mixtures, a-FMO, with its inherent metastable structure, can not only augment the lithium storage capacities with fully activated redox centers, but also attenuate the lattice confinements for Li+ ion migration. Consequently, the in-situ generated a-FMO electrode exhibited a notable reversible capacity of 254 mAh g-1 with stable cycling over 500 cycles. It endowed a specific energy density of 597 Wh kg-1 and all-climate adaptability over 60 to -40 °C benefited from the amorphizing nature, as well as negligible capacity degradation when cycling at -30 °C. The identification of local structure evolutions and multiple-redox activations in amorphizing materials broadens the scope for designing high-energy-density cathodes.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"5 1","pages":"e07840"},"PeriodicalIF":29.4,"publicationDate":"2025-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144669529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}