Advanced Materials最新文献_第2页

Durable Interphase Incorporating Cross‐Linked Polymer Enables Long‐Calendar‐Life Lithium Metal Batteries 结合交联聚合物的耐用界面使长日历寿命的锂金属电池成为可能

IF 29.4 1区材料科学

Advanced Materials Pub Date : 2026-10-19 DOI: 10.1002/adma.75435

Jia‐Lin Li, Jian‐Xin Tian, Xue‐Qiang Zhang, Yan‐Bin Gao, Dong‐Hao Zhan, Qian‐Kui Zhang, Zhao Zheng, Ya‐Nan Wang, Wen‐Jun Feng, Rui Wen, Jia‐Qi Huang

{"title":"Durable Interphase Incorporating Cross‐Linked Polymer Enables Long‐Calendar‐Life Lithium Metal Batteries","authors":"Jia‐Lin Li, Jian‐Xin Tian, Xue‐Qiang Zhang, Yan‐Bin Gao, Dong‐Hao Zhan, Qian‐Kui Zhang, Zhao Zheng, Ya‐Nan Wang, Wen‐Jun Feng, Rui Wen, Jia‐Qi Huang","doi":"10.1002/adma.75435","DOIUrl":"https://doi.org/10.1002/adma.75435","url":null,"abstract":"The practical deployment of lithium (Li) metal batteries is hindered by not only cycle life but also calendar life. The poor calendar life stems from both the repeated reconstruction of the solid‐electrolyte interphase (SEI) during cycles and, particularly, the continuous growth of SEI during storage. Herein, a durable SEI with high mechanical stability against volume fluctuations and superior passivation capability to suppress electrolyte permeation is demonstrated by integrating inorganics and a cross‐linked polymer into the SEI. Concretely, a cross‐linked polymer with high modulus and low swelling is in‐situ incorporated among the inorganics of an anion‐derived SEI. The elastic modulus of the SEI is significantly increased from 1.63 to 4.37 GPa, and the compactness of the SEI is also improved to suppress electrolyte permeation. Consequently, the cycle life and calendar life of Li metal coin cells are extended by 73% (from 190 to 329 cycles) and 129% (from 1553 to 3561 h), respectively. Furthermore, a prototype pouch cell (506 Wh kg −1 ) undergoes 124 cycles. This work establishes an effective strategy that concurrently improves the mechanical and passivation performance of the SEI, tackling the critical challenge of calendar life in Li metal batteries.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"11 1","pages":""},"PeriodicalIF":29.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149218772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Robust Dipicolinic Acid‐Anchored Self‐Assembled Monolayers for High‐Performance Wide‐Bandgap and Tandem Perovskite Photovoltaics 用于高性能宽禁带和串联钙钛矿光伏的坚固的二吡啶酸锚定自组装单层膜

IF 29.4 1区材料科学

Advanced Materials Pub Date : 2026-10-19 DOI: 10.1002/adma.75443

Yuxiao Guo, Yiren Gao, Daqing Zhang, Xu Li, Chong Zhang, Esmaeil Sheibani, Jinhai Huang, Tingwei He, Lars Kloo, Bo Xu

{"title":"Robust Dipicolinic Acid‐Anchored Self‐Assembled Monolayers for High‐Performance Wide‐Bandgap and Tandem Perovskite Photovoltaics","authors":"Yuxiao Guo, Yiren Gao, Daqing Zhang, Xu Li, Chong Zhang, Esmaeil Sheibani, Jinhai Huang, Tingwei He, Lars Kloo, Bo Xu","doi":"10.1002/adma.75443","DOIUrl":"https://doi.org/10.1002/adma.75443","url":null,"abstract":"The anchoring group of self‐assembled monolayer (SAM) hole‐transporting materials dictates both substrate binding and interfacial passivation, serving as a key lever for high‐performance perovskite photovoltaics. Herein, we report a novel SAM molecular material, denoted by XS21 , engineered with a multidentate dipicolinic acid (DPA) anchoring core to address conventional adhesion and degradation limitations. From an experimental perspective, the DPA anchor is found to promote molecular chemisorption onto the substrate, potentially originating from the dual‐action mechanism of pyridine–Ni coordination coupled with dicarboxylate‐metal interaction. Furthermore, XS21 imparts both low acid‐dissociation constants ( K a ) and superior ultraviolet (UV) photostability. Consequently, wide‐bandgap (1.79 eV) perovskite solar cells containing XS21 deliver a champion power conversion efficiency (PCE) of 21.54% with an exceptional open‐circuit voltage of 1.372 V. Crucially, integrating XS21 into monolithic all‐perovskite tandem solar cells yields a remarkable PCE of 29.62%, alongside an outstanding operational stability (retaining >90% of initial efficiency after 900 h of continuous operation). This work establishes multi‐dentate pyridine‐carboxylate anchoring as a vital paradigm for next‐generation efficient and stable perovskite photovoltaics.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"16 1","pages":""},"PeriodicalIF":29.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149218791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Closed Pores as Internal Stress‐Regulation Units for Practical Silicon–Carbon Anodes 封闭孔隙作为内应力调节单元的实用硅碳阳极

IF 29.4 1区材料科学

Advanced Materials Pub Date : 2026-10-19 DOI: 10.1002/adma.75427

Ziheng Li, Fengjun Ji, Guanglu Wei, Xueyi Nie, Rongshan Lan, Yalong Jia, Wei Zhai, Jingyu Lu, Qiyuan He, Jianzhong Jiang, Lijie Ci, Deping Li

{"title":"Closed Pores as Internal Stress‐Regulation Units for Practical Silicon–Carbon Anodes","authors":"Ziheng Li, Fengjun Ji, Guanglu Wei, Xueyi Nie, Rongshan Lan, Yalong Jia, Wei Zhai, Jingyu Lu, Qiyuan He, Jianzhong Jiang, Lijie Ci, Deping Li","doi":"10.1002/adma.75427","DOIUrl":"https://doi.org/10.1002/adma.75427","url":null,"abstract":"Silicon–carbon anodes are among the most promising candidates for high‐energy lithium‐ion batteries, yet their practical implementation remains constrained by lithiation‐induced outward deformation, electrode cracking, and persistent interphase degradation. Here, closed pores are introduced as internal stress‐regulation units to address the coupled mechanical and electrochemical instability of silicon–carbon anodes. Heteroatom‐doped carbon hosts are engineered to contain abundant closed nanopores, which redirect expansion‐induced stress toward the particle interior and suppress macroscopic electrode swelling. Meanwhile, heteroatom doping enlarges the carbon interlayer spacing and enhances electronic conductivity, enabling accelerated and more balanced Li + insertion/extraction kinetics. As a representative material, the nitrogen–doped silicon–carbon composite delivers a reversible capacity of 1756.5 mAh g − 1 , an initial Coulombic efficiency of 90.2%, and 868.4 mAh g −1 at 3 C, while reducing electrode thickness expansion from 38.4% to 13.1% after 50 cycles. The material is further produced in 6 kg batches and enables 2 Ah LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811) pouch cells with 80.0% capacity retention after 1200 cycles and only 8.4% thickness growth after 900 cycles. Machine–learning–guided phosphorus doping further validates the transferability of the closed‐pore design. This work establishes closed‐pore stress regulation as a scalable structural strategy for practical low‐expansion silicon–carbon anodes.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"73 1","pages":""},"PeriodicalIF":29.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149218748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Healable Thermoset Elastomeric Materials for Passive Radiative Cooling 用于被动辐射冷却的可愈合热固性弹性体材料

IF 29.4 1区材料科学

Advanced Materials Pub Date : 2026-10-19 DOI: 10.1002/adma.75417

Feifei Wang, Lengwan Li, Long Bai, Zhiyi Liu, Laijun Li, Zhi Li, Jiahao Ni, Kai Xu, Bin Zhao, Gang Pei, Qiaoqiang Gan, Alexei P. Sokolov, Ming Tian, Peng‐Fei Cao

{"title":"Healable Thermoset Elastomeric Materials for Passive Radiative Cooling","authors":"Feifei Wang, Lengwan Li, Long Bai, Zhiyi Liu, Laijun Li, Zhi Li, Jiahao Ni, Kai Xu, Bin Zhao, Gang Pei, Qiaoqiang Gan, Alexei P. Sokolov, Ming Tian, Peng‐Fei Cao","doi":"10.1002/adma.75417","DOIUrl":"https://doi.org/10.1002/adma.75417","url":null,"abstract":"Passive radiative cooling (PRC) technology with zero‐energy uptake is an efficient thermal management strategy for the development of sustainable society. Fabrication of PRC materials with intrinsic extensibility/dimensional stability and efficient healability that can adapt to irregular shapes with prolonged lifetime remains a significant challenge. The present study introduces a design principle for mechanically robust and healable PRC films based on a cross‐linked elastomeric network with combined physical interactions and dynamic covalent bonds, which can be readily modulated by inorganic coating and micro‐/nano‐porous hierarchical architectures while retaining extensibility and healability. Such thermosetting elastomeric PRC films are scalable with strong solar reflectance and long‐wave infrared emittance, realizing excellent cooling performance even after physical damage and healing process. It demonstrates excellent roof cooling ability in summer yet efficient ice‐sculpture preservation function in winter. The scalable synthesis of thermoset elastomeric PRC films opens up new pathways to realize flexible, stable and healable PRC materials, highly promising for practical applications.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"56 1","pages":""},"PeriodicalIF":29.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149218749","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synchronic Multilevel Assembly Toward Mesoporous Nanosized Intercalation‐Type Framework Anodes for Fast‐Charging Sodium‐Ion Batteries 用于快速充电钠离子电池的介孔纳米嵌入型框架阳极的同步多层组装

IF 29.4 1区材料科学

Advanced Materials Pub Date : 2026-10-19 DOI: 10.1002/adma.75455

Yanhua Wan, Ziqing Yin, Mohamed Ait Tamerd, Minghao Liu, Yan Hong, Yefei Li, Menghao Yang, Fei Wang, Dongyuan Zhao, Wei Li

{"title":"Synchronic Multilevel Assembly Toward Mesoporous Nanosized Intercalation‐Type Framework Anodes for Fast‐Charging Sodium‐Ion Batteries","authors":"Yanhua Wan, Ziqing Yin, Mohamed Ait Tamerd, Minghao Liu, Yan Hong, Yefei Li, Menghao Yang, Fei Wang, Dongyuan Zhao, Wei Li","doi":"10.1002/adma.75455","DOIUrl":"https://doi.org/10.1002/adma.75455","url":null,"abstract":"Intercalation‐type metal oxides are promising anodes for fast‐charging sodium‐ion batteries (SIBs). However, viable electrode candidates remain scarce, constituting a major bottleneck and motivating intensive research into diverse structural frameworks. Here, we report a synchronic multilevel assembly strategy for synthesizing mesoporous intercalation‐type metal oxide framework anodes. Atomic‐scale assembly of cations, combined with in situ formation of conductive carbon networks, enables the synthesis of structurally tunable nanosized sodium titanate and overcomes the challenges of preparing multimetal oxide nanocrystals under high temperatures. The M‐Na 4 Ti 5 O 12 /C composite delivers superior rate capability (∼115 mAh g −1 at 10 A g −1 ) and cycling stability (<0.023% capacity fade per cycle over 1000 cycles at 0.2 A g −1 ) for sodium storage. Its outstanding kinetics arise from ultrafast Na + diffusion through interconnected mesoporous channels and low‐barrier, nanoscale ion‐conduction pathways. A pouch cell delivers a power density of ∼4.7 kW kg −1 and cycles stably for 1200 cycles, outperforming hard carbon at high rates. This work establishes a rational design framework for developing high‐rate battery materials.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"412 1","pages":""},"PeriodicalIF":29.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149218751","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Emerging Lipid Nanoparticle Targeting Strategies for Extrahepatic Delivery of RNA Therapeutics 新兴的脂质纳米颗粒靶向策略用于肝外递送RNA治疗

IF 29.4 1区材料科学

Advanced Materials Pub Date : 2026-10-19 DOI: 10.1002/adma.75408

Jiaxin Li, Jianping Liu, Nan Wang, Keyi Zhang, Wen Zhang, Mengze Gao, Zhiguo Lu, Xiaoyuan Chen, Yan Li

{"title":"Emerging Lipid Nanoparticle Targeting Strategies for Extrahepatic Delivery of RNA Therapeutics","authors":"Jiaxin Li, Jianping Liu, Nan Wang, Keyi Zhang, Wen Zhang, Mengze Gao, Zhiguo Lu, Xiaoyuan Chen, Yan Li","doi":"10.1002/adma.75408","DOIUrl":"https://doi.org/10.1002/adma.75408","url":null,"abstract":"Lipid nanoparticles (LNPs) have transformed RNA therapeutics through their high delivery efficiency, scalable manufacturing, and favorable safety profiles, as demonstrated by COVID‐19 mRNA vaccines and clinically approved small interfering RNA (siRNA) therapeutics. However, extending RNA delivery beyond the liver to extrahepatic tissues, including the spleen, lungs, lymph nodes, brain, and tumors, remains challenging because of the intrinsic hepatotropism of conventional LNPs and their limited cell‐type specificity. Recent advances in lipid chemistry, particle engineering, surface functionalization, protein corona modulation, and route‐specific administration have enabled new strategies to redirect LNPs toward specific tissues and cell populations. This review systematically examines these approaches and highlights key determinants of LNP tropism, including formulation composition, surface properties, endogenous protein adsorption, and administration route. We further discuss the clinical translation of extrahepatic LNP delivery, covering clinically validated products, emerging therapeutic candidates, and gaps between preclinical models and human applications. Major challenges include cell‐resolved biodistribution, long‐term safety, repeated‐dose immunogenicity, cross‐study comparability, and standardized quantitative assessment. Finally, we explore how high‐throughput screening, machine learning, and data‐driven design can accelerate the rational optimization of next‐generation LNPs. These advances may facilitate precise tissue‐ and cell‐selective RNA delivery, expanding the therapeutic potential of RNA medicines beyond the liver.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"497 1","pages":""},"PeriodicalIF":29.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149218754","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Breaking the Boltzmann Limit: A Review of Emerging Ultralow‐Power Transistor Technologies 突破玻尔兹曼极限：新兴超低功率晶体管技术综述

IF 29.4 1区材料科学

Advanced Materials Pub Date : 2026-10-19 DOI: 10.1002/adma.75434

Xuezhou Ma, Xiyu Tan, Dehuan Meng, Lian‐Mao Peng, Chenguang Qiu

{"title":"Breaking the Boltzmann Limit: A Review of Emerging Ultralow‐Power Transistor Technologies","authors":"Xuezhou Ma, Xiyu Tan, Dehuan Meng, Lian‐Mao Peng, Chenguang Qiu","doi":"10.1002/adma.75434","DOIUrl":"https://doi.org/10.1002/adma.75434","url":null,"abstract":"As complementary metal‐oxide‐semiconductor (CMOS) technology scales down to the sub‐2 nm node, the dramatic surge in power density has emerged as a fundamental bottleneck. Conventional metal‐oxide‐semiconductor field‐effect transistors (MOSFETs) are constrained by the 60 mV/dec Boltzmann thermal limit, rendering further supply voltage reduction exceedingly challenging. To surmount this fundamental limit, various novel sub‐60 mV/dec steep‐switching devices have been proposed, including tunnel field‐effect transistors (TFETs), negative‐capacitance field‐effect transistors (NCFETs), and cold‐source field‐effect transistors (CSFETs). A comprehensive review of the evolution of sub‑60 mV/dec technologies is presented, with particular emphasis on the three mainstream approaches: TFETs, NCFETs, and CSFETs. The underlying physical principles, recent research advances, optimization strategies, and remaining challenges of these devices are thoroughly analyzed. Finally, prospective directions for future breakthroughs are discussed, encompassing novel materials exploration, the synergistic integration of multiple physical mechanisms, and the experimental verification of integration with advanced CMOS nodes.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"81 1","pages":""},"PeriodicalIF":29.4,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149218775","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Stress‐Resistant Plant Cell‐Wall Inspired Cell Armor Enables Red Blood Cell Lyophilization 抗胁迫植物细胞壁启发细胞装甲使红细胞冻干

IF 29.4 1区材料科学

Advanced Materials Pub Date : 2026-10-18 DOI: 10.1002/adma.75447

Xia Zheng, Lingqi Wang, Huimei Cao, Youhua Lu, Kun Tao, Xiaoran Chen, Zhang Liu, Jianjun Wang

{"title":"Stress‐Resistant Plant Cell‐Wall Inspired Cell Armor Enables Red Blood Cell Lyophilization","authors":"Xia Zheng, Lingqi Wang, Huimei Cao, Youhua Lu, Kun Tao, Xiaoran Chen, Zhang Liu, Jianjun Wang","doi":"10.1002/adma.75447","DOIUrl":"https://doi.org/10.1002/adma.75447","url":null,"abstract":"Lyophilization offers an attractive route for ambient‐temperature storage of biological systems by eliminating cold‐chain dependence and suppressing solution‐phase degradation. However, lyophilizing mammalian cells remains challenging due to their vulnerability to coupled stresses, including ice‐induced mechanical injury and membrane destabilization during freezing and dehydration. In nature, stress‐resistant plant cells survive extreme conditions through multifunctional cell walls. Inspired by their natural survival strategies, we engineer an artificial membrane armor (AMA) that enables efficient lyophilization of red blood cells (RBCs). This biomimetic AMA integrates a nanoporous zeolitic imidazolate framework (ZIF‐8) for mechanical support, a water‐retentive polymer matrix for hydration retention and colloidal stabilization, and Zn 2 + coordination preserves membrane fluidity and suppresses freeze‐ and dehydration‐driven membrane phase transitions. Through synergistic interfacial protection, the AMA effectively buffers coupled stresses associated with lyophilization, enabling ∼95% post‐rehydration recovery of RBCs using an ultra‐low protectant content (<5 wt%) together with an ambient shelf‐life of at least 3 months, unachievable with previous methods. Furthermore, the rehydrated RBCs preserve their native morphology, membrane mechanics, metabolic activity, oxygen transport capability, and in vivo circulation behavior. This work establishes a bioinspired interfacial engineering strategy for transferring desiccation tolerance from plants to mammalian cells, advancing ambient‐temperature biostorage of sensitive living systems.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"292 1","pages":""},"PeriodicalIF":29.4,"publicationDate":"2026-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149208490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Spatially Decoupled Charge Compensation Enables Versatile Cation–Anion Co‐Intercalation in Layered Metal Oxide Cathodes 空间去耦电荷补偿实现了层状金属氧化物阴极中阳离子-阴离子的多用途Co -插层

IF 29.4 1区材料科学

Advanced Materials Pub Date : 2026-10-17 DOI: 10.1002/adma.75440

Huabin Kong, Jianxin Ou, Lei Fang, Chuangchuang Duan, Xuanbing Chen, Yancheng Chen, Siying Chen, Le Yang, Xianji Qiao, Fuda Yu, Yanbin Shen, Liwei Chen, Hongwei Chen

{"title":"Spatially Decoupled Charge Compensation Enables Versatile Cation–Anion Co‐Intercalation in Layered Metal Oxide Cathodes","authors":"Huabin Kong, Jianxin Ou, Lei Fang, Chuangchuang Duan, Xuanbing Chen, Yancheng Chen, Siying Chen, Le Yang, Xianji Qiao, Fuda Yu, Yanbin Shen, Liwei Chen, Hongwei Chen","doi":"10.1002/adma.75440","DOIUrl":"https://doi.org/10.1002/adma.75440","url":null,"abstract":"Multivalent cation–anion co‐(de)intercalation offers a promising pathway to higher energy densities in multivalent ion batteries. However, its practical realization is challenged by lattice strain and the lack of effective dual charge‐compensation strategies. Here, we report a layered vanadium oxide cathode with pre‐intercalated melamine ligands (MeVO) that enables a spatially decoupled charge‐compensation mechanism—organic ligands serve as redox centers for anions, while metal sites accommodate multivalent cation redox. This design alleviates electrostatic crowding, promotes ion mobility, and preserves structural integrity. Using Mg 2 + ‐TFSI − as a representative system, MeVO delivers a record cycle life of over 36 000 cycles at a loading of approximately 3 mg cm − 2 and an areal capacity of 3.3 mAh cm − 2 at a higher loading of 16.4 mg cm − 2 , surpassing leading Mg‐ion cathodes. The hybrid structure also supports co‐(de)intercalation of various multivalent cations and anions, demonstrating its potential as a versatile intercalation platform for high‐performance energy storage.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"4 1","pages":""},"PeriodicalIF":29.4,"publicationDate":"2026-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149198986","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High-Entropy Ceramic-Enhanced Deformable Triboelectric Nanogenerator for Noncontact Biomechanical and Raindrop Energy Harvesting (Adv. Mater. 58/2026) 用于非接触生物力学和雨滴能量收集的高熵陶瓷增强可变形摩擦电纳米发电机（Adv. Mater. 58/2026）

IF 29.1 1区材料科学

Advanced Materials Pub Date : 2026-10-16 DOI: 10.1002/adma.75293

Shengyou Li, Wei-Chen Peng, Syun-Hong Chou, Zhi-Xian Yan, Jiann-Yeu Chen, Dun-Jie Jhan, Wei-Chun Yang, Shi-Hong Chen, Yi-Lin Huang, Cheng-Hung Tsai, Ming-Yen Lu, Heng-Jui Liu, Cheolmin Park, Ying-Chih Lai

{"title":"High-Entropy Ceramic-Enhanced Deformable Triboelectric Nanogenerator for Noncontact Biomechanical and Raindrop Energy Harvesting (Adv. Mater. 58/2026)","authors":"Shengyou Li, Wei-Chen Peng, Syun-Hong Chou, Zhi-Xian Yan, Jiann-Yeu Chen, Dun-Jie Jhan, Wei-Chun Yang, Shi-Hong Chen, Yi-Lin Huang, Cheng-Hung Tsai, Ming-Yen Lu, Heng-Jui Liu, Cheolmin Park, Ying-Chih Lai","doi":"10.1002/adma.75293","DOIUrl":"10.1002/adma.75293","url":null,"abstract":"<p><b>Noncontact Biomechanical and Raindrop Energy Harvesting</b></p><p>In their Research Article (DOI: 10.1002/adma.74157), Heng-Jui Liu, Cheolmin Park, Ying-Chih Lai, and co-workers report a large-area, fully deformable high-entropy ceramic particle-doped triboelectric nanogenerator (TENG). The high-entropy effect arising from multielement incorporation substantially enhances the triboelectric charge-trapping capability, while the carbonized fabric interlayer serves as a reservoir for storing triboelectric charges. The TENG demonstrates broad practical applicability, including contact/non-contact human biomechanical energy harvesting and large-area distributed raindrop energy harvesting.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"38 58","pages":""},"PeriodicalIF":29.1,"publicationDate":"2026-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adma.75293","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149198991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0