Yanfen Liu, Xiaotan Zhang, Shaaban M. Shaaban, Zhicheng Li, Dalal A. Alshammari, Xieyu Xu, Yan Tang, Zeinhom M. ElBahy, Bingan Lu, Yangyang Liu, Jiang Zhou
{"title":"Postpone Interfacial Impoverishment of Zn-Ions via Neodymium-Based Conversion Films for Stable Zn Metal Anodes","authors":"Yanfen Liu, Xiaotan Zhang, Shaaban M. Shaaban, Zhicheng Li, Dalal A. Alshammari, Xieyu Xu, Yan Tang, Zeinhom M. ElBahy, Bingan Lu, Yangyang Liu, Jiang Zhou","doi":"10.1002/aenm.202500962","DOIUrl":"https://doi.org/10.1002/aenm.202500962","url":null,"abstract":"The widespread adoption of aqueous zinc-ion batteries (AZIBs) is significantly limited by the diminished cycling stability and reduced lifetime caused by the formation of rampant dendrites and detrimental side reactions, resulting from over-fast depletion of Zn<sup>2+</sup> at the interface. In this contribution, a negatively charged neodymium-based film via in situ conversion (NCF-Zn) is presented that attracts Zn<sup>2+</sup> ions and repels OH<sup>−</sup> and SO<sub>4</sub><sup>2−</sup> anions. Thereby, a higher Zn<sup>2+</sup> concentration is mentioned to postpone the impoverishment of Zn<sup>2+</sup> due to the over-fast kinetics, lower the nucleation barrier, and thus uniform the electrodeposition. Meanwhile, the side reactions on the Zn anode can be suppressed due to the repelling of OH<sup>−</sup> and SO<sub>4</sub><sup>2−</sup> anions. Taking these synergetic advantages, the NCF-Zn anode enables ultra-stable cycles for more than 2500 h in Zn|Zn symmetric cells at a current density of 10 mA cm<sup>−2</sup> and impressive reversibility of 99.93% Coulombic efficiency in Zn|Cu asymmetric cells at a current density of 5 mA cm<sup>−2</sup>. Notably, the assembled MnO<sub>2</sub>|NCF-Zn full cell demonstrates remarkable long-term cycling stability, retaining 97.2% of its capacity at 1 A g<sup>−1</sup> after 1000 cycles. This work offers a straightforward yet effective strategy for constructing a stable protective layer, advancing the development of highly reversible AZIBs.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"3 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143608634","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Deep Eutectic Solvent Additive Induced Inorganic SEI and an Organic Buffer Layer Synergistic Protected Li Anode for Durable Li-CO2 Batteries","authors":"Mengmeng Yang, Junxiang Zhang, Xilin Wang, Ruixin Zheng, Pengyang Lei, Xiaorui Wang, Hao Li, Bin Wang, Jianli Cheng","doi":"10.1002/aenm.202405628","DOIUrl":"https://doi.org/10.1002/aenm.202405628","url":null,"abstract":"Interface instability and safety concerns related to lithium anodes are major barriers to the practical use of Li-CO<sub>2</sub> batteries. To address these challenges, an organic–inorganic dual-layer protective coating is developed to improve Li⁺ transport, provide electronic insulation, and isolate CO<sub>2</sub> and H<sub>2</sub>O. Deep eutectic solvents (DESs) are used as electrolyte additives to promote a stable, inorganic solid electrolyte interphase (SEI) composed of Li<sub>3</sub>N, LiF, and LiCl, which enhance ionic conductivity, lowers surface energy, and suppresses dendrite growth. Additionally, an elastic Li-Nafion buffer layer is incorporated to mitigate volume expansion during cycling. This dual protection system significantly improves cycling stability, extending the lifespan of Li||Li and Li-CO<sub>2</sub> batteries by 5.19 and 4.62 times, respectively, with a reversible cycle life of 4160 h. A pouch battery using this system also demonstrates exbatteryent stability, with 1400 h of cycling at 50 µA cm<sup>−2</sup> and a cut-off specific capacity of 250 µAh cm<sup>−2</sup>. These findings offer valuable insights for enhancing the stability and longevity of Li-CO<sub>2</sub> batteries.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"5 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143599561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jong Hun Sung, Un Hwan Lee, Jiwon Lee, Bo Yu, Muhammad Irfansyah Maulana, Seung-Tae Hong, Hyun Deog Yoo, Joonhee Kang, Jong-Sung Yu
{"title":"Dynamic Cycling of Ultrathin Li Metal Anode via Electrode–Electrolyte Interphase Comprising Lithiophilic Ag and Abundant LiF under Carbonate-Based Electrolyte","authors":"Jong Hun Sung, Un Hwan Lee, Jiwon Lee, Bo Yu, Muhammad Irfansyah Maulana, Seung-Tae Hong, Hyun Deog Yoo, Joonhee Kang, Jong-Sung Yu","doi":"10.1002/aenm.202500279","DOIUrl":"https://doi.org/10.1002/aenm.202500279","url":null,"abstract":"The use of ultrathin lithium (Li) metal anode in Li metal batteries (LMBs) has the potential to significantly improve the energy density in comparison to the conventional LMBs. However, they possess several challenges such as intrinsic dendrite growth and dead Li, leading to poor cyclability and coulombic efficiency (CE). In addition, the ultrathin Li metal can cause much faster degradation of performances than thicker one owing to the exhaustion of Li resource with less compensation. To address these problems, silver trifluoromethanesulfonate (AgCF<sub>3</sub>SO<sub>3</sub>, AgTFMS) is proposed as a functional electrolyte additive in carbonate-based electrolyte to buffer the dendritic Li growth and to provide enhanced cyclability. Interestingly, Ag metal derived from the AgTFMS exhibits lithiophilic properties through an alloying reaction with Li. Furthermore, the CF<sub>3</sub> functional group of AgTFMS generates a physically stable LiF-rich solid-electrolyte interphase (SEI), which further suppresses the Li dendrite growth. An LiNi<sub>0.8</sub>Mn<sub>0.1</sub>Co<sub>0.1</sub>O<sub>2</sub> (NMC811) full-cell comprising the ultrathin Li metal anode (20 µm) with AgTFMS additive reveals an excellent capacity retention of up to 88.2% over 200 cycles, as well as outstanding rate capability under harsh practical condition. As a result, the AgTFMS additive can pave a new dimension for the design of high energy density LMBs using the ultrathin Li metal anode.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"46 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143599680","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Biao Zhou, Xiang Wu, Zhengyan Jiang, Jinwook Kim, Zhaojin Wang, Jiayun Sun, Ming Guan, Kai Wang, Xiaochun Liu, Wallace C.H. Choy
{"title":"Foldable Inverted Perovskite Solar Cells Enabled by Region-Dependent Microscopic and Macroscopic Strain Relaxation","authors":"Biao Zhou, Xiang Wu, Zhengyan Jiang, Jinwook Kim, Zhaojin Wang, Jiayun Sun, Ming Guan, Kai Wang, Xiaochun Liu, Wallace C.H. Choy","doi":"10.1002/aenm.202405093","DOIUrl":"https://doi.org/10.1002/aenm.202405093","url":null,"abstract":"While foldable solar cells can advance the applications from emerging electronics like self-powered wearable optoelectronic devices, the poor mechanical durability of perovskite films due to the severe intrinsic strain, and the brittle nature of the flexible ITO electrode hinder foldable perovskite solar cells (F-PSCs) realization. Here, the strategy of region-dependent microscopic and macroscopic strain suppression is demonstrated to achieve efficient F-PSCs on silver nanowires (AgNWs) electrodes. Fundamentally, by introducing the region-dependent modification approach of functionalized polymer incorporation, the significant release of microscopic strain in perovskite film is demonstrated by effectively suppressing defects at places with crystallization orientation variation of perovskite surface/grain boundaries. Equally important, the gradient macroscopic strain is simultaneously eliminated by inhibiting the FA<sup>+</sup> (formamidinum) gradient distribution in perovskite film's depth direction. The two-strain relaxations greatly enhance the mechanical durability of perovskite film, while also improving phase stability and suppressing ion migration. Finally, efficient F-PSCs (23% PCE, the highest value among reported F-PSCs) is realized with remarkable foldability, with efficiency maintaining 94% of its initial value even after 2000 times multidirectional folding at 0.75 mm curvature radius, which far exceeds the mechanical durability of typical ITO-based flexible PSCs. This work aids in comprehending strain modulation role for F-PSCs realization.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"86 1 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143599560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Changfan Xu, Ping Hong, Yulian Dong, Marc Robert, Guosheng Shao, Yong Lei
{"title":"Toward Complete CO2 Electroconversion: Status, Challenges, and Perspectives","authors":"Changfan Xu, Ping Hong, Yulian Dong, Marc Robert, Guosheng Shao, Yong Lei","doi":"10.1002/aenm.202406146","DOIUrl":"https://doi.org/10.1002/aenm.202406146","url":null,"abstract":"Electrocatalytic conversion of carbon dioxide (CO<sub>2</sub>) into valuable carbon-based fuels and chemicals represents a promising approach to closing the carbon cycle and setting a circular economy. Nevertheless, for current electrocatalytic CO<sub>2</sub> reduction reaction (ECO<sub>2</sub>RR) systems, realizing 100% CO<sub>2</sub> conversion with simultaneously high overall CO<sub>2</sub> conversion rate (i.e., single-pass conversion) and high Faradaic efficiency (FE) remains a significant challenge. Enhancing CO<sub>2</sub> conversion rate often results in a decrease in FE, conversely, improving FE may limit the CO<sub>2</sub> conversion rate. Metal–CO<sub>2</sub> (M–CO<sub>2</sub>) batteries with CO<sub>2</sub> conversion functions face similar challenges, particularly for reversible M–CO<sub>2</sub> batteries, which do not accomplish net CO<sub>2</sub> reduction because nearly all of CO<sub>2</sub>RR products are reoxidized to CO<sub>2</sub> during subsequent charging process. Such electrocatalytic CO<sub>2</sub> conversion system for carbon neutrality poses substantial challenges. This perspective provides an in-depth analysis of state-of-the-art ECO<sub>2</sub>RR systems and M–CO<sub>2</sub> batteries, alongside the main strategies employed to address their respective challenges. The critical importance of achieving both a high CO<sub>2</sub> conversion rate and high Faradaic efficiency is underscored for practical applications and to effectively close the carbon cycle. Furthermore, a strategic roadmap that outlines future research directions is presented, thereby facilitating the advancement of comprehensive CO<sub>2</sub> electroconversion technologies.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"68 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143599559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiang Miao, Zhouhan Wu, Wei Hu, Lin Guo, Ce-Wen Nan
{"title":"Dual-Aspect Control of Lithium Nucleation and Growth with Hydroxyapatite and Liquid Crystal Polymers for High-Performance Lithium Metal Batteries","authors":"Xiang Miao, Zhouhan Wu, Wei Hu, Lin Guo, Ce-Wen Nan","doi":"10.1002/aenm.202500566","DOIUrl":"https://doi.org/10.1002/aenm.202500566","url":null,"abstract":"Lithium (Li) metal is a promising anode material for next-generation high-energy-density batteries. However, safety concerns and the limited lifespan due to Li dendrite formation hinder its practical application. The complex dendrite formation process involves nonuniform nucleation and radial growth, requiring a holistic strategy to simultaneously regulate both processes. In this work, a dual-aspect control strategy is developed by designing a protective layer composed of hydroxyapatite (HA) and a liquid crystal polymer (LCP). Electrochemical, microstructural, and computational analyses revealed that HA provides homogenous Li<sup>0</sup> adsorption sites, enhancing Li nucleation kinetics and uniformity. Meanwhile, the LCP self-assembles into cation-selective channels, promoting Li-ion diffusion and regulating growth direction. This dual-aspect control significantly improved Li plating kinetics and mitigated Li dendrite formation. Benefiting from this strategy, the symmetric cell achieved a critical current density of 5 mA cm<sup>−2</sup> and maintained a lifespan of 500 h at 3 mA cm<sup>−2</sup>. Furthermore, in Li–sulfur batteries, the cell exhibited exceptional high-rate cycling performance (>10 mA cm<sup>−2</sup>) with an average capacity decay rate of only 0.056% over 1000 cycles. These results highlight the effectiveness of dual-aspect control in suppressing Li dendrites and improving high-rate cycling stability.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"70 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143599558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiaoping Yi, Yang Yang, Kaishan Xiao, Sidong Zhang, Bitong Wang, Nan Wu, Bowei Cao, Kun Zhou, Xiaolong Zhao, Kee Wah Leong, Xuelong Wang, Wending Pan, Hong Li
{"title":"Achieving Balanced Performance and Safety for Manufacturing All-Solid-State Lithium Metal Batteries by Polymer Base Adjustment (Adv. Energy Mater. 10/2025)","authors":"Xiaoping Yi, Yang Yang, Kaishan Xiao, Sidong Zhang, Bitong Wang, Nan Wu, Bowei Cao, Kun Zhou, Xiaolong Zhao, Kee Wah Leong, Xuelong Wang, Wending Pan, Hong Li","doi":"10.1002/aenm.202570049","DOIUrl":"10.1002/aenm.202570049","url":null,"abstract":"<p><b>Lithium Metal Batteries</b></p><p>In article number 2404973, Wending Pan, Hong Li, and co-workers designed a rigid-flexible organic-inorganic composite solid electrolyte with large-scale manufacturing potential for all-solid-state lithium metal batteries. Lithium ions migrate fast via the synergy of polymer segments, inorganic fillers and plasticizers. The porous fiber support layer ensures the safe, stable operation of the batteries, promoting practical solid electrolyte development.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"15 10","pages":""},"PeriodicalIF":24.4,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202570049","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143590008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Stress-Induced Anomalous Lithiation Plateau of LiFeyMn1−yPO4 Over High-Rate Discharging (Adv. Energy Mater. 10/2025)","authors":"Enhao Xu, Tuan Wang, Jinxuan Chen, Jie Hu, Haijun Xia, Hao Wu, Wenlong Cai, Qianyu Zhang, Yun Zhang, Kaipeng Wu","doi":"10.1002/aenm.202570052","DOIUrl":"10.1002/aenm.202570052","url":null,"abstract":"<p><b>Cathode Materials</b></p><p>In article number 2404929, Kaipeng Wu and co-workers demonstrate that the anomalous lithiation plateau of LiFe<sub>y</sub>Mn<sub>1−y</sub>PO<sub>4</sub> originates from stress concentration occurring at the interface between particle surface and bulk during rapid lithium insertion. This stress alleviates the lattice distortion of MnO<sub>6</sub> octahedra, thereby enhancing the Li<sup>+</sup> diffusion kinetics and eventually unlocking the capacity of Mn<sup>3+</sup>.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"15 10","pages":""},"PeriodicalIF":24.4,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202570052","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143590180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lei Ji, Daotong Yang, Jiayi Xue, Minxun Jia, Tong Wu, Quan Zhuang, Yingying Zhang, Jinghai Liu, Yuegang Zhang
{"title":"Flexible Titanium Nitride-Based Membrane Reactor for S8/Li2S and Dendrite Regulation in Lithium-Sulfur Batteries (Adv. Energy Mater. 10/2025)","authors":"Lei Ji, Daotong Yang, Jiayi Xue, Minxun Jia, Tong Wu, Quan Zhuang, Yingying Zhang, Jinghai Liu, Yuegang Zhang","doi":"10.1002/aenm.202570048","DOIUrl":"https://doi.org/10.1002/aenm.202570048","url":null,"abstract":"<p><b>Li-S Batteries</b></p><p>The flexible titanium nitride-based nanofiber membrane, functioning as a membrane reactor with active sites of chemical confinement catalysis, enhances sulfur redox kinetics, activates the S<sub>8</sub>/Li<sub>2</sub>S solid conversion, and guides directional Li dendrite growth along the membrane interface, enabling high-performance Li-S batteries with high-areal capacity, fast-charging and stable-cycling features. More in article number 2404738, Quan Zhuang, Jinghai Liu, Yuegang Zhang, and co-workers.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"15 10","pages":""},"PeriodicalIF":24.4,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202570048","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143595183","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Penghui Cao, MengDi Wu, Can Chen, Chuanchang Li, Chucheng Luo, Huali Zhu, Juan Yang, Jiayi Ning, Shanshan Li
{"title":"Designing Antifreeze Electrolytes with Colloid-Like Structures for High-Rate Performance in Aqueous Zinc-Ion Batteries (Adv. Energy Mater. 10/2025)","authors":"Penghui Cao, MengDi Wu, Can Chen, Chuanchang Li, Chucheng Luo, Huali Zhu, Juan Yang, Jiayi Ning, Shanshan Li","doi":"10.1002/aenm.202570051","DOIUrl":"10.1002/aenm.202570051","url":null,"abstract":"<p><b>Aqueous Zinc-Ion Batteries</b></p><p>In article number 2304591, Penghui Cao, Huali Zhu, and co-workers introduce konjac glucomannan (KGM) as a dual-functional additive for aqueous zinc-ion batteries. KGM disrupts the hydrogen bond network and acts as a Zn<sup>2+</sup> coordinator, forming a colloid-like electrolyte. This innovative structure enhances antifreeze performance and cycling stability, enabling long-term operation under low temperatures and high-rate conditions.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"15 10","pages":""},"PeriodicalIF":24.4,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202570051","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143590179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}