Advanced Energy Materials最新文献

{"title":"Plasmon-Driven Nitrogen Photoreduction to Ammonia Using Silica-Encapsulated Au Nanostar/TiO2 Nanohybrids","authors":"Yoel Negrín-Montecelo, Ana Sousa-Castillo, Noel Cardeñoso-Garrido, Lucía Guillade, Lucas V. Besteiro, Margarita Vázquez-González, Ramón A. Alvarez-Puebla, Begoña Puértolas, Miguel A. Correa-Duarte","doi":"10.1002/aenm.202501526","DOIUrl":"https://doi.org/10.1002/aenm.202501526","url":null,"abstract":"Plasmon-induced photocatalysis has gained traction as a promising means to efficiently drive chemical reactions using light. In particular, photocatalytic N₂ reduction emerges as a sustainable route to produce ammonia, a key starting material in the manufacture of nitrogen-rich fertilizers and a potential energy vector. Here, various Au nanoparticle morphologies combined with a TiO₂ semiconductor are initially screened, and Au nanostar is identified as the most efficient morphology. Encasing this material within a mesoporous silica shell improved their stability and selectivity to ammonia formation, eliminating the need for hole scavengers. Advanced characterization including TEM and <i>operando</i> SERS spectroscopy together with the evaluation of the material in the presence of optical filters and probes reveal that the superior performance originates from the injection of excited “hot” charge carriers from the plasmonic material to the semiconductor, driving N₂ reduction to NH₃ under visible light. The wavelength-dependence experiments demonstrate a synergistic interaction between gold interband transitions and plasmonic effects, combined with the TiO₂ semiconductor, which enhances catalytic performance across the spectrum. Importantly, hot holes generated at the plasmonic sites oxidize water into oxygen and subsequently to nitrates, maintaining charge balance in the photocatalyst. This dual functionality ensures effective charge circulation and sustainable performance across multiple cycles.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"8 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144279036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-Efficiency Fabry-Pérot-Resonance-Based Color-Tunable Bifacial Perovskite Solar Cells for Building Integrated Photovoltaics","authors":"Wennan Ou, Jie Liang, Jinyan Guo, Guihao Wang, Yuxuan Liu, Yinke Wang, Yuan Gao, Jie Wen, Zhi Li, Jiajia Hong, Yijia Guo, Haowen Luo, Xuntian Zheng, Chenshuaiyu Liu, Hongfei Sun, Yuhong Zhang, Ludong Li, Wenchi Kong, Han Gao, Lin Zhou, Renxing Lin, Hairen Tan","doi":"10.1002/aenm.202502208","DOIUrl":"https://doi.org/10.1002/aenm.202502208","url":null,"abstract":"Perovskite solar cells (PSCs) are promising for building-integrated photovoltaics (BIPV) owing to their superior low-light response and tunable bandgap. However, the implementation of perovskite-based BIPV still faces critical challenges, primarily due to the inherent trade-off between achieving color tunability via bandgap engineering and maintaining high power conversion efficiency (PCE), as well as ensuring sufficient operational stability. Here, rear-side color vibrancy of bifacial perovskite solar cells (BPSCs) is enhanced by introducing a low-loss ultrathin metal (LLUM) layer at the high-loss SnO₂/indium zinc oxide (IZO) interface under the guidance of Fabry-Pérot (F-P) resonance, achieving 60% coverage of sRGB color gamut for 1.52 eV BPSCs. Furthermore, the incorporation of 4-methylphenethylammonium chloride (4M-P) and an in-situ substrate-heated-crystallization strategy enhances carrier diffusion lengths, allowing LLUM-based BPSCs with a 900-nm-thick absorber to achieve a PCE of 23.7% under front illumination. Under albedo conditions of 0.1 and 0.2 sun irradiation intensity, the bifacial PCEs are elevated to 24.9% and 27.4%, respectively. The replacement of metal electrodes with IZO counterparts effectively suppresses metal ion diffusion, enabling BPSC devices to retain 87% of their initial efficiency after 1000 h of thermal aging at 85 °C. These results demonstrate the potential of LLUM-based BPSCs for efficient, color-tunable, and stable BIPV.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"36 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144260647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Total Specific Pore Length as a Key Feature of Carbon Support for High-Performance Low-Catalyst-Loading Fuel Cells","authors":"Donglai Li, Zitao Chen, Yuanzhe Ma, Sha Zheng, Ziliang Deng, Jingbo Li, Xuedong Bai, Haibo Jin, Xuezeng Tian, Zipeng Zhao","doi":"10.1002/aenm.202501785","DOIUrl":"https://doi.org/10.1002/aenm.202501785","url":null,"abstract":"To simultaneously achieve high power density, stability, and low platinum group metal (PGM) loading in the proton exchange membrane fuel cells, porous carbon materials are generally used as supports to anchor the Pt-based catalysts. Despite substantial studies on improving fuel cell performance via carbon support engineering, quantitatively identifying the preferable 3D pore feature remains a challenge. Herein, electron tomography is used to obtain the nano-scale 3D structure of representative carbon supports, which allowed us to quantitatively analysis the pore structure. A descriptor “total specific pore length” is introduced, which is defined as the sum of the pore lengths divided by the volume of the carbon matrix. We find larger total specific pore length correlates with higher oxygen transport rate in the membrane electrode assembly (MEA) test. Moreover, it is demonstrated that interconnected porous carbon, which shows a large total specific pore length, enables the catalyst to deliver a state-of-the-art rated power of 17.0 kW g_PGM⁻¹, with all key features (catalyst mass activity, rated power, and stability) surpassing the target set by the U.S. Department of Energy. As a result, the PGM loading of the MEA can be reduced to an ultralow level of 0.060 mg cm⁻².","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"102 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144269348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Ultralong-Life Aqueous Ammonium-Ion Batteries Enabled by Unlocking Inert-Site of Medium-Entropy Prussian Blue Analogs (Adv. Energy Mater. 22/2025)","authors":"Chun-Yan Wei,&nbsp;Zhong-Hui Sun,&nbsp;Zhen-Yi Gu,&nbsp;Dong-Xue Han,&nbsp;Li Niu,&nbsp;Xing-Long Wu","doi":"10.1002/aenm.202570096","DOIUrl":"https://doi.org/10.1002/aenm.202570096","url":null,"abstract":"<p><b>Ammonium-Ion Batteries</b></p><p>In article number 2500589, Zhong-Hui Sun, Li Niu, Xing-Long Wu, and co-workers report a medium-entropy Prussian blue analogues (ME-PBAs) through an entropy-regulated strategy for ammonium ion battery. The ME-PBAs not only endows highly reversible phase transitions but also unlocks inert-site by entropy induction at low-voltage.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"15 22","pages":""},"PeriodicalIF":24.4,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202570096","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144255923","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Peroxide-Driven Nitrogen Fixation Reactions for Energy Storage Applications","authors":"James Ebenezer, Parthiban Velayudham, Alex Schechter","doi":"10.1002/aenm.202501583","DOIUrl":"https://doi.org/10.1002/aenm.202501583","url":null,"abstract":"Electrochemical nitrogen fixation offers a sustainable and environmentally friendly alternative to conventional ammonia synthesis, yet it currently faces significant challenges in terms of energy efficiency, catalytic activity, and economic feasibility. Here, this work presents a novel peroxide-mediated dual-step strategy designed to efficiently address these challenges using advanced energy materials. Ruthenium oxide and cobalt phthalocyanine catalysts facilitate simultaneous hydrogen peroxide formation and nitrogen oxidation to nitrate (&lt;span data-altimg=\"/cms/asset/35628d5a-a57d-4015-b477-0666333093a1/aenm202501583-math-0001.png\"&gt;&lt;/span&gt;&lt;mjx-container ctxtmenu_counter=\"60\" ctxtmenu_oldtabindex=\"1\" jax=\"CHTML\" role=\"application\" sre-explorer- style=\"font-size: 103%; position: relative;\" tabindex=\"0\"&gt;&lt;mjx-math aria-hidden=\"true\" location=\"graphic/aenm202501583-math-0001.png\"&gt;&lt;mjx-semantics&gt;&lt;mjx-msubsup data-semantic-children=\"0,1,2\" data-semantic-collapsed=\"(4 (3 0 1) 2)\" data-semantic- data-semantic-role=\"unknown\" data-semantic-speech=\"upper N upper O 3 Superscript minus\" data-semantic-type=\"subsup\"&gt;&lt;mjx-mi data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"4\" data-semantic-role=\"unknown\" data-semantic-type=\"identifier\"&gt;&lt;mjx-c&gt;&lt;/mjx-c&gt;&lt;mjx-c&gt;&lt;/mjx-c&gt;&lt;/mjx-mi&gt;&lt;mjx-script style=\"vertical-align: -0.276em; margin-left: 0px;\"&gt;&lt;mjx-mo data-semantic- data-semantic-parent=\"4\" data-semantic-role=\"subtraction\" data-semantic-type=\"operator\" size=\"s\"&gt;&lt;mjx-c&gt;&lt;/mjx-c&gt;&lt;/mjx-mo&gt;&lt;mjx-spacer style=\"margin-top: 0.18em;\"&gt;&lt;/mjx-spacer&gt;&lt;mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"4\" data-semantic-role=\"integer\" data-semantic-type=\"number\" size=\"s\"&gt;&lt;mjx-c&gt;&lt;/mjx-c&gt;&lt;/mjx-mn&gt;&lt;/mjx-script&gt;&lt;/mjx-msubsup&gt;&lt;/mjx-semantics&gt;&lt;/mjx-math&gt;&lt;mjx-assistive-mml display=\"inline\" unselectable=\"on\"&gt;&lt;math altimg=\"urn:x-wiley:16146832:media:aenm202501583:aenm202501583-math-0001\" display=\"inline\" location=\"graphic/aenm202501583-math-0001.png\" xmlns=\"http://www.w3.org/1998/Math/MathML\"&gt;&lt;semantics&gt;&lt;msubsup data-semantic-=\"\" data-semantic-children=\"0,1,2\" data-semantic-collapsed=\"(4 (3 0 1) 2)\" data-semantic-role=\"unknown\" data-semantic-speech=\"upper N upper O 3 Superscript minus\" data-semantic-type=\"subsup\"&gt;&lt;mi data-semantic-=\"\" data-semantic-font=\"normal\" data-semantic-parent=\"4\" data-semantic-role=\"unknown\" data-semantic-type=\"identifier\"&gt;NO&lt;/mi&gt;&lt;mn data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic-parent=\"4\" data-semantic-role=\"integer\" data-semantic-type=\"number\"&gt;3&lt;/mn&gt;&lt;mo data-semantic-=\"\" data-semantic-parent=\"4\" data-semantic-role=\"subtraction\" data-semantic-type=\"operator\"&gt;−&lt;/mo&gt;&lt;/msubsup&gt;$rm{NO}_{3}^{-}$&lt;/annotation&gt;&lt;/semantics&gt;&lt;/math&gt;&lt;/mjx-assistive-mml&gt;&lt;/mjx-container&gt;) at an exceptionally low potential of 0.1 V versus RHE, achieving a nitrate yield of 71.1 ± 4.2 µg h&lt;sup&gt;−&lt;/sup&gt;¹ cm&lt;sup&gt;−&lt;/sup&gt;&lt;sup&gt;2&lt;/sup&gt; and a Faradaic efficiency (FE) of 2","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"64 2 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144260646","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Interface Engineering with ZrS₂: Achieving 10000-Cycle Lifespan in High-Rate Sodium Metal Batteries","authors":"Mingze Ma, Ning Lu, Fangxin Ling, Junyi Dai, Jiaxin Jiang, Ruilin Bai, Zhen Li, Zhiwen Zhuo, Yu Shao, Yu Yao, Hanyu Huo, Yan Yu","doi":"10.1002/aenm.202502416","DOIUrl":"https://doi.org/10.1002/aenm.202502416","url":null,"abstract":"Sodium metal batteries (SMBs) have emerged as promising alternatives to lithium-ion batteries for low-cost, high-energy-density energy storage. However, their practical application is hindered by uncontrolled dendrite growth and unstable interfacial reactions. In this study, a ZrS₂-based interlayer is introduced to enable dendrite-free, high-capacity SMBs with exceptional long-term stability. The 2D ZrS₂ sheets form a tightly bonded interface with the Na metal, effectively suppressing parasitic reactions at the electrolyte|Na interface. Additionally, ZrS₂ offers strong Na⁺ adsorption and features confined 2D ion transport channels, which facilitate uniform, planar Na deposition decoupled from the desolvation process. Importantly, the ZrS₂ interlayer demonstrates high Na⁺ diffusivity and accommodates Na⁺ via a reversible intercalation mechanism, thereby maintaining structural integrity under high current densities and prolonged cycling. As a result, the ZrS₂-modified Na anode achieves a remarkable cycle life of 4800 h at 2 mA cm⁻² with an areal capacity of 10 mAh cm⁻² in symmetric cells. In full-cell configurations, it delivers outstanding cycling stability over 10000 cycles at an ultrahigh rate of 50 C. This work provides a new design paradigm for interfacial engineering in SMBs and demonstrates a practical route toward safe, high-performance SMBs with enhanced durability.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"2 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144260649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Current Status and Future Prospects of Solid-State Lithium–Sulfur Batteries: A Focus on Reaction and Interface Engineering","authors":"Ru Xiao, Zhuoyan Qu, Junxing Ren, Guoxiu Wang, Zhenhua Sun, Feng Li","doi":"10.1002/aenm.202501926","DOIUrl":"https://doi.org/10.1002/aenm.202501926","url":null,"abstract":"The burgeoning development of solid-state electrolytes significantly improves the safty and practicality of solid-state lithium–sulfur batteries (LSBs). Based on mature solid-state electrolytes, challenges in electrochemical performance remain, largely due to complex reactions and interfacial issues on both sulfur and lithium sides. This review comprehensively examines the fundamental challenges and recent progress from the perspectives of reaction and interface. From a reaction standpoint, it discusses the trade-off between shuttle effect and redox kinetics, as well as the irreversible accumulation of kinetically dead sulfur across different electrolytes, which were often overlooked. Regarding interfaces, it discusses the formation of interfacial dead sulfur within the cathode and strategies to enhance the across-interface transport of charge carriers. It also analyzes mechanisms underlying lithium dendrite formation and interface failure, along with current solutions to mitigate dead lithium and extend lithium anode lifespan. In pursuit of meeting commercial demands for solid-state LSBs, engineering parameters targeting high energy density are specified by formulations, and differences in parameter design principles among different electrolyte systems are systematically analyzed. Finally, to bridge fundamental insights with practical applications, future research directions are proposed, emphasizing reaction and interface engineering for high-performance solid-state LSBs.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"36 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144269349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Industrial Scalability of Zinc-Ion Batteries: Enhanced Electrochemical Performance with High Mass Loading Electrodes on Graphene-Coated Metal Current Collectors (Adv. Energy Mater. 22/2025)","authors":"Heeyeon Heo,&nbsp;Jaeyeon Lee,&nbsp;Yong-Ryun Jo,&nbsp;Geon-Hyoung An","doi":"10.1002/aenm.202570095","DOIUrl":"https://doi.org/10.1002/aenm.202570095","url":null,"abstract":"<p><b>Zinc-Ion Batteries</b></p><p>Zinc-ion batteries (ZIBs) have become an attractive energy storage solution due to their intrinsic safety, eco-friendly properties, and affordability. The cover image vividly represents the advancement of ZIB technology through a graphene-coated stainless steel current collector designed for roll-to-roll manufacturing processes. The innovative graphene coating, combined with heat treatment to remove surface oxides, significantly enhances electrical conductivity and corrosion resistance. This breakthrough addresses the scalability and mechanical shortcomings of conventional graphite foil collectors, paving the way for safer, cost-effective, and sustainable grid-scale energy storage systems. More in article number 2500261, Yong-Ryun Jo, Geon-Hyoung An, and co-workers.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"15 22","pages":""},"PeriodicalIF":24.4,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202570095","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144255922","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"In Situ Solid Electrolyte Ionic Pathway Formation in High Sulfur Loading Cathodes for High-Performance All-Solid-State Lithium–Sulfur Batteries (Adv. Energy Mater. 22/2025)","authors":"Yipeng Su,&nbsp;Shuaiyang Ren,&nbsp;Qiyuan Lin,&nbsp;Yi Su,&nbsp;Yitao Lin,&nbsp;Weining Jiang,&nbsp;Yuegang Zhang","doi":"10.1002/aenm.202570092","DOIUrl":"https://doi.org/10.1002/aenm.202570092","url":null,"abstract":"<p><b>Lithium–Sulfur Batteries</b></p><p>In article number 2500363, Yuegang Zhang and co-workers improved the performance of all-solid-state lithium-sulfur batteries (ASSLSB), by using a melt-infiltration method to introduce P₂S₅ into sulfur-carbon secondary particles, forming in-situ lithium phosphorus sulfide solid electrolyte during discharging process. This establishes the ionic pathways in the cathode and activates more active materials, enabling high capacity and stable cycling under high sulfur loading, highlighting its potential for advanced ASSLSBs.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"15 22","pages":""},"PeriodicalIF":24.4,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202570092","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144256029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Solvent-Phobic and Ionophilic Carboxylated Polythiophene Layer for Fluoride-Rich Cathode Electrolyte Interphase (Adv. Energy Mater. 22/2025)","authors":"Haoze Ren,&nbsp;Zeyuan Sun,&nbsp;Meng Wang,&nbsp;Mengting Sun,&nbsp;Han Li,&nbsp;Alexis Pace,&nbsp;Esther S. Takeuchi,&nbsp;Amy C. Marschilok,&nbsp;Shan Yan,&nbsp;Kenneth J. Takeuchi,&nbsp;Elsa Reichmanis","doi":"10.1002/aenm.202570093","DOIUrl":"https://doi.org/10.1002/aenm.202570093","url":null,"abstract":"<p><b>Cathode Electrolyte Interphases</b></p><p>In article number 2406019 Elsa Reichmanis and co-workers offer a comprehensive understanding of poly[3-(potassium-4-butanoate)thiophene-2,5-diyl] (P3KBT) solvent-phobic | ionophilic behavior. P3KBT solvent-phobicity arises from dispersive, polar, and hydrogen-bonding interactions between P3KBT and electrolyte solvent. The ionophilic nature is driven by electrostatic interactions and reversible electrochemical (de)doping. When serving as an active material coating, P3KBT induces a LiF-rich, Li₂CO₃-limited cathode electrolyte interphase, significantly improving half-cell life.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"15 22","pages":""},"PeriodicalIF":24.4,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202570093","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144256030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}