Advanced Energy Materials最新文献_第6页

Decoupling Membrane Electrode Assembly Materials Complexity from Fuel Cell Performance through Image-Based Multiphase and Multiphysics Modelling

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-04-10 DOI: 10.1002/aenm.202405179

Jianuo Chen, Wenjia Du, Zunmin Guo, Xuekun Lu, Matthew P. Tudball, Xiaochen Yang, Zeyu Zhou, Shangwei Zhou, Alexander Rack, Bratislav Lukic, Paul R. Shearing, Sarah J. Haigh, Stuart M. Holmes, Thomas S. Miller

{"title":"Decoupling Membrane Electrode Assembly Materials Complexity from Fuel Cell Performance through Image-Based Multiphase and Multiphysics Modelling","authors":"Jianuo Chen, Wenjia Du, Zunmin Guo, Xuekun Lu, Matthew P. Tudball, Xiaochen Yang, Zeyu Zhou, Shangwei Zhou, Alexander Rack, Bratislav Lukic, Paul R. Shearing, Sarah J. Haigh, Stuart M. Holmes, Thomas S. Miller","doi":"10.1002/aenm.202405179","DOIUrl":"https://doi.org/10.1002/aenm.202405179","url":null,"abstract":"Proton exchange membrane fuel cells (PEMFCs) are important clean energy technology, yet the material and structural complexity of their membrane electrode assemblies (MEAs) can hamper the development of next-generation structures, as even a subtle change to one component can have a significant impact on others. Mathematical modelling of PEMFC MEAs proves to be one of the few techniques able to decouple this complexity, but the available models are commonly based on over-simplified structures meaning they are less able to inform material design. In this study, an advanced image-based modelling approach is developed to reveal the interplay of material changes in PEMFC MEAs. Using high-temperature PEMFCs as an example system, advanced structural imaging techniques are used to produce a detailed 3D MEA reconstruction which forms the basis for the multiphase and multi-physics model. This allows both the prediction of cell performance and the decoupling the impact of changes to individual structures or components (such as membrane pores, catalyst cracks, and phase migration), on cell behaviour. These phenomena can then be selectively ‘re-coupled’ to deconvolute the interplay of different materials employed within operational cells. The resulting insights provide a mechanistic understanding of MEA performance, guiding the design and optimisation of future PEMFCs.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"357 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143814215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Thermoresponsive Mono-Solvent Electrolyte Inhibiting Parasitic Reactions for Safe Lithium Metal Batteries

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-04-10 DOI: 10.1002/aenm.202500703

Jia-Xin Guo, Chang Gao, Yun-Fei Du, Feng Jiang, Nai-Lu Shen, Wen-Bo Tang, Xin Shen, Xin-Bing Cheng, Yuping Wu

{"title":"Thermoresponsive Mono-Solvent Electrolyte Inhibiting Parasitic Reactions for Safe Lithium Metal Batteries","authors":"Jia-Xin Guo, Chang Gao, Yun-Fei Du, Feng Jiang, Nai-Lu Shen, Wen-Bo Tang, Xin Shen, Xin-Bing Cheng, Yuping Wu","doi":"10.1002/aenm.202500703","DOIUrl":"https://doi.org/10.1002/aenm.202500703","url":null,"abstract":"Solvents in liquid and gel polymer electrolytes are recognized for contributing to high ionic conductivity in high-energy-density lithium metal batteries. However, parasitic reactions involving solvents and lithium metal induce safety risks under thermal abuse conditions and poor lifespan during room-temperature cycles, which are rarely investigated. This study introduces a thermoresponsive mono-solvent electrolyte as a built-in safety switch. The mono-solvent electrolyte polymerizes at elevated temperatures, creating a passivate polymer network without residue solvents. The polymer exhibits high thermal stability with 91% mass retention at 200 °C and significantly suppresses side reactions between lithium metal and the electrolyte, reducing thermal runaway risks. Ah-level Li||LiNi0.8Co0.1Mn0.1O2 pouch batteries employing this electrolyte can efficiently improve the critical temperature of thermal runaway by 75 °C compared to the thermoresponsive gel polymer electrolyte. At ambient temperatures, the electrolyte promotes the formation of a stable solid electrolyte interphase (SEI) rich in LiF and Li2O, effectively reducing side reactions and dendrite growth on the lithium anode. Consequently, Li||LiNi0.5Co0.2Mn0.3O2 cells retain 91% capacity after 152 cycles, even under high-loading cathodes (19.7 mg cm−2, 3 mAh cm−2). This research offers valuable insights into inhibiting parasitic reactions during the electrochemical cycle and thermal runaway, enhancing the lifespan and safety of high-energy-density batteries.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"1 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143814213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cu-Based Tandem Architectures for CO2 Electrolysis to Multicarbon Products

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-04-10 DOI: 10.1002/aenm.202405964

Ruizhe Yang, Lu Xia, Wulyu Jiang, Yi Cheng, Kaiwen Wang, Tengyu Chen, Fei Li, Xiaoli Zhao, Bin Wang, Yingtang Zhou, F. Pelayo García de Arquer, Ming Huang

{"title":"Cu-Based Tandem Architectures for CO2 Electrolysis to Multicarbon Products","authors":"Ruizhe Yang, Lu Xia, Wulyu Jiang, Yi Cheng, Kaiwen Wang, Tengyu Chen, Fei Li, Xiaoli Zhao, Bin Wang, Yingtang Zhou, F. Pelayo García de Arquer, Ming Huang","doi":"10.1002/aenm.202405964","DOIUrl":"https://doi.org/10.1002/aenm.202405964","url":null,"abstract":"Carbon dioxide electroreduction reaction (CO2RR) offers a pathway to convert CO2 into valuable multicarbon products (C2+), potential clean energy, and chemical vectors, using renewable electricity. Copper catalysts are, so far, the most selective in this process, but still face challenges such as high overpotentials and insufficient selectivity and stability when used alone. One strategy to tackle these is the use of Cu-based tandem structures, which incorporate tailored reaction sites to drive a segment of the CO2RR reaction, in a more favorable way, within the same electrode. Recent examples have shown how Cu-tandem catalysts can lead to voltage savings and improvements in selectivity. This review analyses various Cu-based tandem catalysts, focusing on alloys, heterostructures (especially highlighting the role of polymer coatings in achieving tandem effects through environmental control), and metal–organic frameworks (MOFs). It covers synthetic strategies to achieve tandem-enabling configurations and their suggested impact on reaction mechanisms and performance improvement toward C2+ electrosynthesis. The review concludes by offering a roadmap toward the design of more efficient Cu-based tandem electrodes for CO₂RR and beyond.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"42 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143820020","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Green Synthesis of Cu3P to Achieve Low-Temperature and High Initial Coulombic Efficiency Sodium Ion Storage

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-04-10 DOI: 10.1002/aenm.202500723

Yiming Liu, Qingmin Hu, Qinhao Shi, Shengyu Zhao, Xinhong Hu, Wuliang Feng, Jiaqiang Xu, Jiujun Zhang, Yufeng Zhao

{"title":"Green Synthesis of Cu3P to Achieve Low-Temperature and High Initial Coulombic Efficiency Sodium Ion Storage","authors":"Yiming Liu, Qingmin Hu, Qinhao Shi, Shengyu Zhao, Xinhong Hu, Wuliang Feng, Jiaqiang Xu, Jiujun Zhang, Yufeng Zhao","doi":"10.1002/aenm.202500723","DOIUrl":"https://doi.org/10.1002/aenm.202500723","url":null,"abstract":"Conversion-type transition metal phosphides (TMPs) are competitive anode materials to overcome the volumetric energy density limits of hard carbon for sodium-ion batteries (SIBs). However, the application of TMPs is generally constrained by their low initial coulombic efficiency (ICE), unsatisfied cycling stability and poor low-temperature (LT) performance. Herein, a green synthesis method is reported to prepare carbon quantum dots modified Cu3P nanoparticles anchored on carbon fibers (CF@Cu3P-CQDs) as anode for high-energy and LT SIBs. It is disclosed that such a structure enables good interface contact between electrodes/electrolytes, thus prompting the formation of a uniformly fine solid electrolyte interphase and hence a record-high ICE of 93% with a volumetric capacity of 1343 mAh·cm−3. Distribution of relaxation time analysis unveils that the rapid Na+ transfer between electrode/electrolyte interfaces and Na+ diffusion ability in CF@Cu3P-CQDs underlies the main reason for its high-rate capability (369–101 mAh·g−1 @0.1-50 C) and LT performance (368/350 mAh·g−1 @ 0.1C under −20/−40 °C). Promisingly, the CF@Cu3P-CQDs are directly used toward three cathode materials (namely P2-type Na0.78Ni0.31Mn0.67Nb0.02O2, carbon coated Na3V2(PO4)3, and low-cost Na4Fe3(PO4)2P2O7) without pre-sodiation process to assemble full-cells. This work sheds light on the fundamental understanding of electron/ion transfer kinetics of TMPs during de/sodiation and lays a foundation for the practical application of TMPs.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"75 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143814214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Highly Efficient Bifacial Narrow Bandgap Ag-CuInSe2 Solar Cells on ITO ITO 上的高效双面窄带隙 Ag-CuInSe2 太阳能电池

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-04-10 DOI: 10.1002/aenm.202500899

Amanat Ali, Dong-Hwan Jeon, Wonjoon Kim, Van-Quy Hoang, Jaebaek Lee, Dae-Ho Son, Jin-Kyu Kang, Kee-Jeong Yang, Dae-Kue Hwang, Shi-Joon Sung, Dae-Hwan Kim

{"title":"Highly Efficient Bifacial Narrow Bandgap Ag-CuInSe2 Solar Cells on ITO","authors":"Amanat Ali, Dong-Hwan Jeon, Wonjoon Kim, Van-Quy Hoang, Jaebaek Lee, Dae-Ho Son, Jin-Kyu Kang, Kee-Jeong Yang, Dae-Kue Hwang, Shi-Joon Sung, Dae-Hwan Kim","doi":"10.1002/aenm.202500899","DOIUrl":"https://doi.org/10.1002/aenm.202500899","url":null,"abstract":"Bifacial CuInSe₂ (CISe) solar cells hold significant promise for various applications but are constrained by relatively low power conversion efficiencies. This study boosts performance through reducing CISe absorber deposition temperature and using low-Ga back grading for an optimum gallium-to-indium ratio (Ga/(Ga+In); GGI) profile. Low deposition temperatures reduced ITO back contact thermal degradation, while low Ga concentration reduced GaOX formation and CISe/ITO charge recombination. Ag incorporation significantly improved key photovoltaic parameters, including open-circuit voltage (VOC) and fill factor (FF), while reducing Cu2−XSe secondary phase formation. This approach enables high-quality CISe growth below 420 °C-substantially lower than conventional temperatures. The study achieves record efficiency in the narrow bandgap CISe category, with Ag-alloyed devices demonstrating a champion rear-side efficiency of 8.44% at 390 °C, and a front-side efficiency of 15.30% at 420 °C. Under the assumption of double-sided total 2.0 solar illumination in an albedo environment, a champion bifacial power generation density (BPGD) of 23.1 mWcm−2 is achieved. Results indicate that lower deposition temperatures enhance rear-side performance, highlighting the role of low-temperature processing, low Ga doping, and Ag alloying in suppressing carrier recombination losses in CISe solar cells.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"116 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143819949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Exceeding 2.2 V Open‐Circuit Voltage in Perovskite/Organic Tandem Solar Cells via Multi‐Functional Hole‐Selective Layer

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-04-09 DOI: 10.1002/aenm.202404092

Jung Geon Son, Shahid Ameen, Jina Roe, Sujung Park, Jongdeuk Seo, Jaehyeong Kim, Abdullah Bin Faheem, Ha‐eun Koo, Si On Oh, Yeowon Jo, Jae Won Kim, YeonJeong Lee, Yun Seop Shin, Hyungsu Jang, Dongmin Lee, SungHyun Hur, Kyung‐Koo Lee, Shinuk Cho, Dong Suk Kim, Jin Young Kim, BongSoo Kim

{"title":"Exceeding 2.2 V Open‐Circuit Voltage in Perovskite/Organic Tandem Solar Cells via Multi‐Functional Hole‐Selective Layer","authors":"Jung Geon Son, Shahid Ameen, Jina Roe, Sujung Park, Jongdeuk Seo, Jaehyeong Kim, Abdullah Bin Faheem, Ha‐eun Koo, Si On Oh, Yeowon Jo, Jae Won Kim, YeonJeong Lee, Yun Seop Shin, Hyungsu Jang, Dongmin Lee, SungHyun Hur, Kyung‐Koo Lee, Shinuk Cho, Dong Suk Kim, Jin Young Kim, BongSoo Kim","doi":"10.1002/aenm.202404092","DOIUrl":"https://doi.org/10.1002/aenm.202404092","url":null,"abstract":"Perovskite/organic tandem solar cells (POTSCs) are promising candidates for surpassing the Shockley‐Queisser limit through reduction of thermalization losses. However, wide bandgap perovskite solar cells (WBG PSCs), which function as top cells of POTSCs, still suffer from significant open‐circuit voltage (VOC) losses, limiting efficiency improvement of POTSCs. Here, a multi‐functional hole‐selective layer (mHSL) is reported via blending two functionalized self‐assembled monolayer (SAM) molecules: (4‐(3,6‐diiodo‐9H‐carbazol‐9‐yl)butyl)phosphonic acid (36ICzC4PA) and (4‐(3,6‐dimethoxy‐9H‐carbazol‐9‐yl)butyl)phosphonic acid (36MeOCzC4PA). The blending of the two molecules plays multiple roles: i) Suppressing micelle formation of SAM molecules, ii) optimizing energy level alignment with homogeneous and highly covered SAMs, iii) enhancing crystallinity and orientation of perovskite through interaction with SAM materials, and iv) suppressing both lattice strain and phase segregation. Implementing mHSL on WBG PSCs enables a power conversion efficiency (PCE) of 18.85% with a notable VOC of 1.366 V. When integrated into POTSCs, the PCE reached 24.73% (certified 24.19%) with record‐high VOC and fill factor (FF) of 2.216 V and 84.07%, respectively. Furthermore, POTSCs exhibit excellent photo‐ and thermal stabilities, retaining ≈80% of their initial PCEs after maximum power point (MPP) tracking under 1‐sun illumination in ambient conditions for 305 h or exposure to 65 °C in N2 conditions for 500 h.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"25 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143805876","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enabling Metal Fluorides Cathodes at Elevated Temperatures Using a Molten Salt Electrolyte

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-04-08 DOI: 10.1002/aenm.202500293

Yuxuan Zhang, Junyu Chen, Xuedong Zhang, Baiyu Guo, Zhihao Yan, Yali Liang, Yumeng Sun, Long Xie, Xin He, Hongxia Gu, Jianyu Huang, Qiao Huang

{"title":"Enabling Metal Fluorides Cathodes at Elevated Temperatures Using a Molten Salt Electrolyte","authors":"Yuxuan Zhang, Junyu Chen, Xuedong Zhang, Baiyu Guo, Zhihao Yan, Yali Liang, Yumeng Sun, Long Xie, Xin He, Hongxia Gu, Jianyu Huang, Qiao Huang","doi":"10.1002/aenm.202500293","DOIUrl":"https://doi.org/10.1002/aenm.202500293","url":null,"abstract":"Conversion-type metal fluorides (MFs) cathodes are promising candidates for high-energy lithium–ion batteries. However, their cycling performance is limited due to the decomposition of organic solvent electrolytes at the cathode/electrolyte interface and the dissolution of active materials during cycling, especially at elevated temperatures (above 60 °C). To address these challenges, a thermally stable, organic solvent-free electrolyte (OSFE) composed of three low melting alkali perfluorinated sulfonimide salts is developed, which helps to minimize the undesirable solvent decomposition. Additionally, chemical vapor deposition technology is employed to apply a conformal carbon coating to a representative MF, NiF2, effectively preventing the dissolution of active materials. The synergistic effect of OSFE and carbon coating enables a previously uncyclable NiF2 cathode, which exhibits a high reversible discharge capacity of 450 mAh g−1 after 160 cycles at 80 °C. Moreover, by incorporating 10 wt.% Li10GeP2S12 (LGPS) into the OSFE, the cycle number of NiF2 is extended to 300 cycles, maintaining an impressive discharge capacity of 350 mAh g−1 at 60 °C. These advancements highlight the potential for successful operation of MFs at elevated temperatures using OSFE, paving the way for their practical applications and future commercialization.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"37 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143798203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Unveiling a Cooperative Mechanism for the Alkaline Hydrogen Evolution Reaction: Role of Built-in Electric Field (Adv. Energy Mater. 14/2025) 揭示碱性氢气进化反应的合作机制：内置电场的作用（Adv. Energy Mater.）

IF 24.4 1区材料科学

Advanced Energy Materials Pub Date : 2025-04-08 DOI: 10.1002/aenm.202570069

Krishankant, Rohit Bisht, Alok Kumar, Deepak Upreti, Baljeet Kaur, Rajashri R. Urkude, Chandan Bera, Vivek Bagchi

引用次数: 0

Unveiling the Critical Influence of EDTA Additives on Modulating Solvation Structure and Solid Electrolyte Interphase Formation in Water-in-Salt Electrolytes for Aqueous Batteries

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-04-08 DOI: 10.1002/aenm.202404145

Yachao Zhu, Guoshen Yang, Ruiqing Li, Jie Deng, Clément Pechberty, Si Chen, Xianqi Xu, Rossukon Jommongkol, Xuanze Wang, Hang Zhou, Jiaxin Zheng, Frédéric Favier, Olivier Fontaine

{"title":"Unveiling the Critical Influence of EDTA Additives on Modulating Solvation Structure and Solid Electrolyte Interphase Formation in Water-in-Salt Electrolytes for Aqueous Batteries","authors":"Yachao Zhu, Guoshen Yang, Ruiqing Li, Jie Deng, Clément Pechberty, Si Chen, Xianqi Xu, Rossukon Jommongkol, Xuanze Wang, Hang Zhou, Jiaxin Zheng, Frédéric Favier, Olivier Fontaine","doi":"10.1002/aenm.202404145","DOIUrl":"https://doi.org/10.1002/aenm.202404145","url":null,"abstract":"Water-in-salt (WIS) electrolytes confer a wide voltage window to aqueous batteries. However, the dynamic solid electrolyte interphase (SEI) is adversely affected by LiTFSIprecipitation/dissolution and continuous reforming issues, causing electrolyte dryness. Here, the aminopolycarboxylic (Ethylenediaminetetraacetic acid, EDTA) additive is introduced to WIS electrolytes. An intriguing solvation phenomenon is observed wherein EDTA exhibited insolubility in a low-concentrated (7m) solution while achieving certain solubility in a high-concentrated (21m) one. The assembled full cell with EDTA exhibited good cycling stability at a low 0.5 C. To elucidate the unique solvation phenomenon and unravel the mechanism of SEI formation, experimental characterizations, and simulations are conducted. Molecular Dynamics (MD) and physical measurements disclosed that sufficient Li+ acts as a bridge connecting EDTA with TFSI−-H2O. The simulated electrode/electrolyte interface investigated the dynamics, showing the difference in the activity and density of molecules after adding EDTA. Density Functional Theory (DFT) calculations together with physical measurements discovered EDTA- species are prone to facile reduction during cycling, and the products facilitated the formation of a robust fluorine–oxygen–sulfur-based SEI, outstanding critical roles of EDTA in forming the interphase compared with the unstable dynamic SEI. This work directs an alternative way and clear formation mechanism of the interphase for building stable aqueous batteries.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"108 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143806012","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Carbon Mediated In Situ Cathode Interface Stabilization for High Rate and Highly Stable Operation of All-Solid-State Lithium Batteries (Adv. Energy Mater. 14/2025)

IF 24.4 1区材料科学

Advanced Energy Materials Pub Date : 2025-04-08 DOI: 10.1002/aenm.202570072

Abhirup Bhadra, Maxime Brunisholz, Jacob Otabil Bonsu, Dipan Kundu

引用次数: 0