Advanced Energy Materials最新文献_第5页

Additive Engineering of Sequentially Evaporated FAPbI3 Solar Cells 顺序蒸发FAPbI3太阳能电池的增材工程

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-07-11 DOI: 10.1002/aenm.202500963

Elena Siliavka, Thalia Pandelides, Vladimir V. Shilovskikh, Angelika Wrzesinska‐Lashkova, Zongbao Zhang, Ran Ji, Boris Rivkin, Yana Vaynzof

{"title":"Additive Engineering of Sequentially Evaporated FAPbI3 Solar Cells","authors":"Elena Siliavka, Thalia Pandelides, Vladimir V. Shilovskikh, Angelika Wrzesinska‐Lashkova, Zongbao Zhang, Ran Ji, Boris Rivkin, Yana Vaynzof","doi":"10.1002/aenm.202500963","DOIUrl":"https://doi.org/10.1002/aenm.202500963","url":null,"abstract":"Despite the tremendous progress made in the field of perovskite solar cells, their commercialization remains hindered by several challenges, including scalability, stability, and sustainability. Thermal evaporation is a solvent‐free, scalable, and industrially relevant method, yet despite its many advantages, this method is limited by the lack of additive engineering strategies for controlling the growth of perovskite layers. Here, a novel additive engineering strategy is reported that enables the complete conversion of precursors to a perovskite phase during the two‐step deposition of formamidinium lead triiodide (FAPbI3). The approach is based on the co‐evaporation of potassium‐containing additives (KI and KSCN) alongside PbI2 during the first deposition step, followed by the evaporation of formamidinium iodide. It is demonstrated that the absence of additives leads to an incomplete conversion with a substantial amount of unconverted PbI2 remaining at the buried interface. On the other hand, the co‐evaporation of the additives improves the conversion process, leading, in the case of KSCN, to phase‐pure α‐FAPbI3 with improved microstructure. The additive‐engineered p‐i‐n devices achieve efficiencies up to 18.34%, among the highest reported for evaporated FAPbI3 solar cells without interfacial passivation. This work highlights the great potential of additive engineering for controlling the film formation of thermally evaporated perovskites.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"4 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144603382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The Role and Mechanism of Separators in Aqueous Zinc Metal Batteries: a Critical Review 水锌金属电池中隔膜的作用和机理综述

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-07-11 DOI: 10.1002/aenm.202502652

Wen Gu, Kuan Wu, Jiawen Huang, Xianzhong Yang, Xianglong Huang, Zixing Dong, Shanchong Shen, Yun Bai, Hua‐Kun Liu, Shi‐Xue Dou, Chao Wu

{"title":"The Role and Mechanism of Separators in Aqueous Zinc Metal Batteries: a Critical Review","authors":"Wen Gu, Kuan Wu, Jiawen Huang, Xianzhong Yang, Xianglong Huang, Zixing Dong, Shanchong Shen, Yun Bai, Hua‐Kun Liu, Shi‐Xue Dou, Chao Wu","doi":"10.1002/aenm.202502652","DOIUrl":"https://doi.org/10.1002/aenm.202502652","url":null,"abstract":"Aqueous zinc metal batteries (AZMBs) have gained increasing attention in recent years as a promising energy storage system due to their high specific capacity, low cost, and eco‐friendliness. However, dendrite growth and side reactions of zinc anodes severely hinder their reversibility and sustainability. The separator, an indispensable component of battery devices, increasingly influences the overall performance of AZMBs, although research into separators for AZMBs is still in its infancy. Despite years of exploration and development, a clear and systematic understanding of the underlying mechanisms of various separators is still lacking in the field. Herein, this article reviews the research advances and development status of separator modification strategies for AZMBs, with a focus on their key roles and mechanisms. In principle, these mechanisms encompass electric field distribution, ion sieve effect, crystal orientation, and desolvation effect. The unique advantages and limitations of each mechanism in regulating zinc deposition are comprehensively discussed. Notably, this review also provides an analysis of the effectiveness evaluation of separators in AZMBs. Finally, the critical challenges and future trends of separator modification for AZMBs are discussed, with the aim of inspiring the development of high‐performance separators and advancing the progress of AZMBs.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"12 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-07-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144603381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

From Operando Investigations to Implementation of Ni‐MOF‐74 Oxygen Evolution Electrocatalysts 从Operando研究到Ni - MOF - 74析氧电催化剂的实现

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-07-10 DOI: 10.1002/aenm.202501401

Julia Linke, Thomas Rohrbach, Adam Hugh Clark, Michal Andrzejewski, Nicola Pietro Maria Casati, Fabian Luca Buchauer, Mikkel Rykær Kraglund, Christodoulos Chatzichristodoulou, Eibhlin Meade, Marco Ranocchiari, Thomas Justus Schmidt, Emiliana Fabbri

{"title":"From Operando Investigations to Implementation of Ni‐MOF‐74 Oxygen Evolution Electrocatalysts","authors":"Julia Linke, Thomas Rohrbach, Adam Hugh Clark, Michal Andrzejewski, Nicola Pietro Maria Casati, Fabian Luca Buchauer, Mikkel Rykær Kraglund, Christodoulos Chatzichristodoulou, Eibhlin Meade, Marco Ranocchiari, Thomas Justus Schmidt, Emiliana Fabbri","doi":"10.1002/aenm.202501401","DOIUrl":"https://doi.org/10.1002/aenm.202501401","url":null,"abstract":"Metal‐organic frameworks (MOFs) as electrocatalysts for the alkaline oxygen evolution reaction (OER) show promising catalytic activity by offering great variability and high surface areas, enabling performance optimization and mechanistic studies. However, their stability during reaction and the structure‐performance relationship defining the origin of the high OER activity, are still vigorously debated. Herein, operando X‐ray absorption spectroscopy and operando X‐ray diffraction are applied to unveil the structural and electronic transformations of Ni‐MOF‐74 during OER. The irreversible destruction of the MOF‐74 crystal into a highly OER active, amorphous NiOOH‐metal organic compound is identified. Based on these findings, an amorphous Ni metal organic compound (Ni‐MOC*) is proposed for achieving high current densities both in a three‐electrode cell (14 A gNi−1 at 1.5 VRHE) and in an anion exchange membrane water electrolyzer (AEM‐WE) with a stable AEM‐WE performance exceeding 100 h at 500 mA cm−2.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"39 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144594053","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Dual Plasmonic Fields Enable High‐Density Hot‐Electron Generation with Stepwise Charge Transfer Directed to Oxygen Reduction Sites for Enhanced Artificial Photosynthesis of H2O2 双等离子体场能够产生高密度热电子，并逐步向氧还原位点转移，以增强H2O2的人工光合作用

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-07-10 DOI: 10.1002/aenm.202502302

Xiaowen Ruan, Minghua Xu, Xinlei Zhang, Chunsheng Ding, Depeng Meng, Jing Leng, Wei Zhang, Sai Kishore Ravi, Xiaoqiang Cui

{"title":"Dual Plasmonic Fields Enable High‐Density Hot‐Electron Generation with Stepwise Charge Transfer Directed to Oxygen Reduction Sites for Enhanced Artificial Photosynthesis of H2O2","authors":"Xiaowen Ruan, Minghua Xu, Xinlei Zhang, Chunsheng Ding, Depeng Meng, Jing Leng, Wei Zhang, Sai Kishore Ravi, Xiaoqiang Cui","doi":"10.1002/aenm.202502302","DOIUrl":"https://doi.org/10.1002/aenm.202502302","url":null,"abstract":"Artificial H₂O₂ photosynthesis via plasmonic heterojunction photocatalysts represents a promising route for solar‐to‐chemical energy conversion. However, traditional systems are often limited by inefficient charge separation, inadequate utilization of hot electrons, and non‐specific reaction sites, resulting in suboptimal H₂O₂ production. Here, we present a catalyst architecture that achieves high‐density hot‐electron generation with stepwise charge transfer directed to oxygen reduction sites, boosting H₂O₂ photosynthesis. The catalyst comprises ZnIn₂S₄ (ZIS) nanosheets integrated with two non‐noble plasmonic semiconductors, W18O49 nanoneedles and MoO3‐X nanosheets. This configuration leverages dual sites for localized surface plasmon resonance (LSPR) to amplify hot‐electron production while enabling sequential charge migration through the double S‐scheme, guiding electrons to reduction sites while minimizing recombination. The optimized Dual‐LSPR‐Double‐S‐Scheme (DLDS) catalyst exhibits a superior H2O2 production rate of 51.3 µmol g⁻¹ min⁻¹ under UV–vis light and 13.6 µmol g⁻¹ min⁻¹ under visible light. Spectroscopic analyses (fs‐TA, XPS, in‐situ DRIFTS) confirm rapid carrier dynamics, efficient hot‐electron accumulation, and formation of reactive oxygen intermediates (*O₂⁻, *OOH) at targeted sites. Theoretical calculations reveal enhanced local electric fields from dual LSPR, corroborating accelerated hot‐electron migration. The produced H₂O₂ is further evaluated for practical applications, including the detoxification of poisoned plants and bacterial inactivation, demonstrating its potential in environmental remediation.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"74 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144594052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

H* Site‐Blocking Alleviated Through Collaborative Copper Alloying for Large‐Current Hydrogen Production 协同铜合金在大电流制氢中缓解H*位点阻塞

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-07-10 DOI: 10.1002/aenm.202501852

Yue Zhou, Lei Zhao, Guiyue Xu, Ning Wang, Xuemin Chen, Zelin Wang, Deyu Kong, Xin Yang, Chao Meng

{"title":"H* Site‐Blocking Alleviated Through Collaborative Copper Alloying for Large‐Current Hydrogen Production","authors":"Yue Zhou, Lei Zhao, Guiyue Xu, Ning Wang, Xuemin Chen, Zelin Wang, Deyu Kong, Xin Yang, Chao Meng","doi":"10.1002/aenm.202501852","DOIUrl":"https://doi.org/10.1002/aenm.202501852","url":null,"abstract":"Industrial alkaline water splitting requires cost‐effective hydrogen evolution reaction (HER) electrocatalysts that can balance the adsorption of H2O, H*, and OH*. Despite robust water adsorption/dissociation and moderate H* adsorption, NiMo alloys are plagued by competitive OH* adsorption, which induces H* site‐blocking, thereby impeding the Volmer step and necessitating large overpotentials. Here, an integrated electrode design is developed by incorporating NiMoCu catalysts onto a stainless‐steel mesh (SSM) through Cu alloying. The optimized NiMoCu achieves a current density of 500 mA cm−2 at only 175 mV overpotential, nearly 19.5 and 6.9 times higher than NiMo and Pt/C, respectively. In situ characterizations and theoretical calculations reveal that segregating H* and OH* adsorption sites (Ni─Cu for H* and Mo for OH*) effectively mitigates H* site‐blocking. This segregation optimizes the short‐range adsorption of various intermediates, thereby enhancing the kinetics from Volmer to Heyrovsky step. Moreover, the regular 3D micrometer‐scale structure of SSM support promotes long‐range mass transfer, further improving the overall performance. When paired with NiFe LDH for anion‐exchange‐membrane (AEM) water splitting, the NiMoCu(−)||NiFe LDH(+) electrolyzer delivers 2 A cm−2 at 1.98 V, with robust durability. This strategy is extendable to NiMoCo and NiMoZn catalysts, offering a universal approach for efficient hydrogen production.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"44 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144603383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advanced Liquid Electrolyte Design for High‐Voltage and High‐Safety Lithium Metal Batteries 高电压和高安全性锂金属电池的先进液体电解质设计

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-07-10 DOI: 10.1002/aenm.202502654

Junhua Zhou, Huimin Wang, Yongqiang Yang, Xinyan Li, Can Guo, Zhibo Li, Shujing Wen, Jiehua Cai, Zhaokun Wang, Yufei Zhang, Qiyao Huang, Zijian Zheng

{"title":"Advanced Liquid Electrolyte Design for High‐Voltage and High‐Safety Lithium Metal Batteries","authors":"Junhua Zhou, Huimin Wang, Yongqiang Yang, Xinyan Li, Can Guo, Zhibo Li, Shujing Wen, Jiehua Cai, Zhaokun Wang, Yufei Zhang, Qiyao Huang, Zijian Zheng","doi":"10.1002/aenm.202502654","DOIUrl":"https://doi.org/10.1002/aenm.202502654","url":null,"abstract":"High‐voltage lithium metal batteries (LMBs) represent a promising technology for next‐generation energy storage, yet their commercialization is impeded by rapid performance degradation and safety concerns. Key challenges include lithium dendrite growth, unstable solid electrolyte interphase (SEI) and cathode electrolyte interphase (CEI), aluminum current collector corrosion, electrolyte oxidative decomposition, and inherent electrolyte flammability. This review systematically discusses strategies to overcome these issues by designing advanced liquid electrolytes, including: 1) regulating Li+ solvation structures via highly concentrated electrolytes (HCEs) or localized HCEs to stabilize Li deposition and suppress dendrites; 2) designing weakly solvating electrolytes with tailored solvent molecules to enhance SEI/CEI robustness; 3) leveraging ionic liquids as nonflammable solvents with high electrochemical stability to mitigate electrolyte oxidation and Al corrosion; and 4) incorporating flame‐retardant phosphorus‐ or chlorine‐based solvents to improve electrolyte safety. Perspectives on future research directions emphasize developing advanced in situ and full‐cell‐based characterization techniques, optimizing interfacial engineering, and scaling up cost‐effective electrolyte formulations, to accelerate the practical development of high‐voltage, high‐safety LMBs for the next‐generation energy storage.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"704 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144603384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Locating Non‐Radiative Recombination Losses and Understanding Their Impact on the Stability of Perovskite Solar Cells During Photo‐Thermal Accelerated Ageing 定位非辐射复合损失并了解其对钙钛矿太阳能电池光热加速老化过程稳定性的影响

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-07-10 DOI: 10.1002/aenm.202502787

Zijian Peng, Jonas Wortmann, Jisu Hong, Shuyu Zhou, Andreas J. Bornschlegl, Julian Haffner‐Schirmer, Vincent M. Le Corre, Thomas Heumüller, Andres Osvet, Barry P. Rand, Larry Lüer, Christoph J. Brabec

{"title":"Locating Non‐Radiative Recombination Losses and Understanding Their Impact on the Stability of Perovskite Solar Cells During Photo‐Thermal Accelerated Ageing","authors":"Zijian Peng, Jonas Wortmann, Jisu Hong, Shuyu Zhou, Andreas J. Bornschlegl, Julian Haffner‐Schirmer, Vincent M. Le Corre, Thomas Heumüller, Andres Osvet, Barry P. Rand, Larry Lüer, Christoph J. Brabec","doi":"10.1002/aenm.202502787","DOIUrl":"https://doi.org/10.1002/aenm.202502787","url":null,"abstract":"Commercialization of perovskite solar cells (PSCs) requires further breakthroughs in stability, but the complex degradation mechanisms and the interplay of the underlying stress factors complicate insight‐driven improvement of long‐term stability. This study establishes a quantitative link between potential degradation—specifically open‐circuit voltage (VOC) and quasi‐Fermi level splitting (QFLS)—and the photo‐thermal stability of PSCs. It is highlighted that an increase in non‐radiative recombination losses induces the seemingly negligible decrease in VOC and QFLS, though it causes a significant decrease in fill factor (FF) and/or short circuit current (JSC) instead, leading to an overall performance decline. By combining non‐destructive photoluminescence imaging and drift‐diffusion simulations, it is revealed that during photo‐thermal ageing, unstable low‐dimensional passivation fails within tens of hours, generating bulk defects, while unstable hole‐transport‐layer contacts induce interface defects within hours. Building on these findings, a robust hole‐transport‐layer polymer interface is employed and enhanced perovskite crystal quality to suppress both interface and bulk defect generation during ageing, achieving a T80 lifetime exceeding 1000 h under accelerated ageing conditions (85 °C and two‐sun illumination).","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"12 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144593859","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Photocatalytic Hydrogen Evolution with Conjugated Polymers: Structure–Property Insights and Design Strategies 光催化析氢与共轭聚合物：结构-性质的见解和设计策略

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-07-10 DOI: 10.1002/aenm.202501600

Wooteak Jung, Jinhyuk Choi, Sanghyeok An, Siwon Yun, Dae Sung Chung, Hyojung Cha, Jongchul Lim, Taiho Park

{"title":"Photocatalytic Hydrogen Evolution with Conjugated Polymers: Structure–Property Insights and Design Strategies","authors":"Wooteak Jung, Jinhyuk Choi, Sanghyeok An, Siwon Yun, Dae Sung Chung, Hyojung Cha, Jongchul Lim, Taiho Park","doi":"10.1002/aenm.202501600","DOIUrl":"https://doi.org/10.1002/aenm.202501600","url":null,"abstract":"Semiconducting polymer‐based photocatalysts have emerged as a promising platform for solar‐driven hydrogen production, offering tunable optoelectronic properties and synthetic versatility. This review systematically categorizes these materials into single‐component, multicomponent, and hybrid systems that integrate synthetic and biological components, each with distinct structural and mechanistic considerations. In single‐component systems, the influence of molecular polarity, backbone modifications, and charge transport pathways on exciton dynamics and catalytic performance is focused. In contrast, multicomponent systems exploit the complex interplay between the donor and acceptor materials, where morphology control, interfacial tuning, and intermolecular interactions collectively govern charge transport, recombination suppression, and catalytic activity. Hybrid systems extend these concepts by integrating semiconducting polymers with biological components and combining polymeric light‐harvesting capabilities with biocatalytic precision. By establishing clear structure–property relationships across these categories, the current design constraints and performance bottlenecks in polymer‐based hydrogen catalysts are critically assessed. Furthermore, not only material design strategies but also the role of advanced optical analysis, morphology characterization, and computational calculations (including machine learning‐guided materials discovery) in accelerating the rational design of next‐generation photocatalysts are discussed. This review provides a comprehensive roadmap for the development of high‐performance polymeric systems for sustainable hydrogen production, bridging fundamental molecular design principles with practical applications.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"1 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144594110","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fast-Charging Lithium–Sulfur Batteries (Adv. Energy Mater. 26/2025) 快充锂硫电池（Adv. Energy Mater. 26/2025）

IF 24.4 1区材料科学

Advanced Energy Materials Pub Date : 2025-07-09 DOI: 10.1002/aenm.202570116

Jakob Offermann, Sheikh Najeeb Ul Haq, Kai-Xing Wang, Rainer Adelung, Shu-Hao Chang, Binson Babu, Mozaffar Abdollahifar

引用次数: 0

A Novel Ti12-Based Metal-Organic Framework for Photocatalytic Hydrogen Evolution (Adv. Energy Mater. 26/2025) 一种新型ti12基金属-有机骨架光催化析氢（Adv. Energy Mater. 26/2025）

IF 24.4 1区材料科学

Advanced Energy Materials Pub Date : 2025-07-09 DOI: 10.1002/aenm.202570112

Bingbing Chen, Asma Mansouri, Celia M. Rueda-Navarro, Iurii Dovgaliuk, Philippe Boullay, Arianna Melillo, Juan José Ramírez-Hernández, Beibei Xiao, Dong Fan, Lokuge Aravindani Fernando, Gilles Patriarche, Ieuan Cornu, Pierre Florian, Guillaume Maurin, Sergio Navalón, Hermenegildo Garcia, Georges Mouchaham, Christian Serre

{"title":"A Novel Ti12-Based Metal-Organic Framework for Photocatalytic Hydrogen Evolution (Adv. Energy Mater. 26/2025)","authors":"Bingbing Chen, Asma Mansouri, Celia M. Rueda-Navarro, Iurii Dovgaliuk, Philippe Boullay, Arianna Melillo, Juan José Ramírez-Hernández, Beibei Xiao, Dong Fan, Lokuge Aravindani Fernando, Gilles Patriarche, Ieuan Cornu, Pierre Florian, Guillaume Maurin, Sergio Navalón, Hermenegildo Garcia, Georges Mouchaham, Christian Serre","doi":"10.1002/aenm.202570112","DOIUrl":"https://doi.org/10.1002/aenm.202570112","url":null,"abstract":"Photocatalytic Hydrogen EvolutionMIP-209(Ti) is a new microporous metal-organic framework (MOF) built up from Ti12O15 clusters and substituted terephthalate linkers, enabling isoreticular chemistry and clusters tunability for photocatalytic applications. Cr3+ doping (≤5 at%) on Ti-oxoclusters enhances water stability and markedly boosts hydrogen production from water under simulated solar light irradiation. Significant photocatalytic activity is achieved without noble metals, paving the way for tunable Ti-MOF-based photocatalysts. More in article number 2500211, Georges Mouchaham, Christian Serre, and co-workers.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture>\u0000 </div>\u0000 </figure>","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"15 26","pages":""},"PeriodicalIF":24.4,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/aenm.202570112","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144582227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0