Advanced Energy Materials最新文献_第4页

Homogeneously Blended Donor and Acceptor AgBiS2 Nanocrystal Inks Enable High-Performance Eco-Friendly Solar Cells with Enhanced Carrier Diffusion Length (Adv. Energy Mater. 12/2025)

IF 24.4 1区材料科学

Advanced Energy Materials Pub Date : 2025-03-24 DOI: 10.1002/aenm.202570062

Hae Jeong Kim, Jin Young Park, Ye-Jin Choi, Soo-Kwan Kim, Taeyeong Yong, Wonjong Lee, Gayoung Seo, Eon Ji Lee, Seongmin Choi, Hyung Ryul You, Won-Woo Park, Soojin Yoon, Wook Hyun Kim, Jongchul Lim, Younghoon Kim, Oh-Hoon Kwon, Jongmin Choi

引用次数: 0

Photothermal Catalysts, Light and Heat Management: From Materials Design to Performance Evaluation (Adv. Energy Mater. 12/2025)

IF 24.4 1区材料科学

Advanced Energy Materials Pub Date : 2025-03-24 DOI: 10.1002/aenm.202570059

Enrique V. Ramos-Fernandez, Alejandra Rendon-Patiño, Diego Mateo, Xinhuilan Wang, Pia Dally, Mengmeng Cui, Pedro Castaño, Jorge Gascon

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Ultralong-Life Aqueous Ammonium-Ion Batteries Enabled by Unlocking Inert-Site of Medium-Entropy Prussian Blue Analogs 通过释放中熵普鲁士蓝类似物的内位实现超长寿命水性铵离子电池

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-03-24 DOI: 10.1002/aenm.202500589

Chun-Yan Wei, Zhong-Hui Sun, Zhen-Yi Gu, Dong-Xue Han, Li Niu, Xing-Long Wu

{"title":"Ultralong-Life Aqueous Ammonium-Ion Batteries Enabled by Unlocking Inert-Site of Medium-Entropy Prussian Blue Analogs","authors":"Chun-Yan Wei, Zhong-Hui Sun, Zhen-Yi Gu, Dong-Xue Han, Li Niu, Xing-Long Wu","doi":"10.1002/aenm.202500589","DOIUrl":"https://doi.org/10.1002/aenm.202500589","url":null,"abstract":"Prussian blue analogs (PBAs) have been heralded as promising alternative cathodes for aqueous ammonium-ion batteries (AAIBs) owing to their chemical flexibility at the molecular level and eco-friendliness. However, the low capacity, irreversible phase, and structure transition are the enormous challenges toward practical application. Herein, an entropy-regulating strategy is proposed to boost both specific capacity and structural stability by introducing Cu, Ni, Co, Mn, and Fe at the 4b sites in PBAs (CNCMF-PBAs). The synergistic effect of randomly dispersed metal elements creates abundant redox centers and enhances structural durability. This inhibits the dissolution of transition metal elements and facilitates a highly reversible phase transition between cubic and tetragonal structures with minimal lattice strain (only 0.8%) for NH4+ (de)intercalation. Moreover, it is interesting to find that this gradually growing cathode capacity roots from the activation of Cu2+/Cu+, Mn3+/Mn2+, and Ni3+/Ni2+ pairs by entropy induction at low voltage region. As a result, the CNCMF-PBAs cathode achieves a high reversible specific capacity of 101.2 mAh g−1 without attenuation over 45 000 cycles (lasting over 180 days) at 20 C. This study provides a substantial advance on PBAs cathode materials with excellent NH4+ storage and rapid multi-electron transfer kinetics.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"18 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143695220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhanced Zinc Deposition and Dendrite Suppression in Aqueous Zinc-Ion Batteries Via Citric Acid-Aspartame Electrolyte Additives

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-03-24 DOI: 10.1002/aenm.202500674

Tao Xue, Yongbiao Mu, Zhengchu Zhang, Jinpeng Guan, Jianhui Qiu, Chao Yang, Limin Zang, Lin Zeng

{"title":"Enhanced Zinc Deposition and Dendrite Suppression in Aqueous Zinc-Ion Batteries Via Citric Acid-Aspartame Electrolyte Additives","authors":"Tao Xue, Yongbiao Mu, Zhengchu Zhang, Jinpeng Guan, Jianhui Qiu, Chao Yang, Limin Zang, Lin Zeng","doi":"10.1002/aenm.202500674","DOIUrl":"https://doi.org/10.1002/aenm.202500674","url":null,"abstract":"Despite the advantages of low cost, safety, and environmental friendliness, aqueous zinc-ion batteries (AZIBs) encounter challenges such as zinc dendrite formation, severe side reactions, and electrolyte instability. Many effective additives exhibit limited solubility in water, thus reducing their practical application potential. In this study, a dissolution-promoting strategy is proposed by introducing citric acid (CA) to enhance the dissolution of aspartame (APM), resulting in a zinc sulfate electrolyte. Simulations and experiments indicate that CA regulates both the solvation structure of Zn2+ and the pH of the electrolyte, while APM preferentially integrates into the electric double layer to form a solid electrolyte interphase with CA, thereby suppressing hydrogen evolution and side reactions. Consequently, the zinc-zinc symmetric cell exhibits an extended lifespan of over 4,500 h at 1.0 mA cm−2/1.0 mAh cm−2. As a result, the AZIBs with this electrolyte and commercial zinc foil and MnO2 exhibit enhanced rate capability and improved capacity retention (75.6%) after 2,000 cycles. This study presents a novel strategy for stabilizing zinc anodes and offers a comprehensive framework for addressing fundamental challenges in AZIBs, advancing their practical application in next-generation energy storage systems.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"21 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143678360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Customized Design of R-SO3H-Containing Binders for Durable Iodine-Loading Cathode of Zinc–Iodine Batteries 定制设计含 R-SO3H 的粘合剂，用于锌碘电池的耐用碘负荷阴极

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-03-24 DOI: 10.1002/aenm.202500673

Xiaoxiao Liang, Qinxi Dong, Shan Guo, Chaoyuan Zeng, Zhixiang Chen, Binjie Zhang, Chuancong Zhou, Jie Zhang, Zhenyue Xing, Xinlong Tian, Xiaodong Shi

{"title":"Customized Design of R-SO3H-Containing Binders for Durable Iodine-Loading Cathode of Zinc–Iodine Batteries","authors":"Xiaoxiao Liang, Qinxi Dong, Shan Guo, Chaoyuan Zeng, Zhixiang Chen, Binjie Zhang, Chuancong Zhou, Jie Zhang, Zhenyue Xing, Xinlong Tian, Xiaodong Shi","doi":"10.1002/aenm.202500673","DOIUrl":"https://doi.org/10.1002/aenm.202500673","url":null,"abstract":"The challenges of iodine dissolution and polyiodide shuttle behavior severely hinder the development of zinc–iodine batteries (ZIBs). Among the battery components, binders play a vital role in maintaining mechanical integrity and facilitating the iodine conversion reaction of the iodine-loading cathode in ZIBs. Herein, a series of polyimide-based polymers rich in the sulfonic acid group (R-SO3H) are elaborately designed as functional binders for iodine-loading cathodes. According to the spectroscopic characterization and theoretical calculation results, PI-4S binder with R-SO3H, hydroxyl and imide groups holds stronger chemisorption capability for I2/I−/I3− species, which effectively helps to block the polyiodide shuttle and the active iodine's dissolution behavior. As a result, the corresponding ZIBs with PI-4S as binders deliver a reversible capacity of 142.7 mAh g−1 over 600 cycles at 0.2 A g−1, a high capacity of 157.6 mAh g−1 over 500 cycles at 0.5 A g−1 at 50 °C, and durable cycling stability of 88 mAh g−1 over 15000 cycles at 4 A g−1. This work guides the autonomous design of multifunctional polymer binders for iodine-loading cathodes and facilitates the practical application of ZIBs.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"23 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143695218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Universal Measurement Protocol and Cell Designs for Liquid-Based Active Cooling by the Electrochemical Peltier Effect (Adv. Energy Mater. 12/2025)

IF 24.4 1区材料科学

Advanced Energy Materials Pub Date : 2025-03-24 DOI: 10.1002/aenm.202570061

Yusuke Wakayama, Hongyao Zhou, Fumitoshi Matoba, Teppei Yamada

引用次数: 0

Interfacial Polarization-Enhanced Ultrahigh Performance Liquid Droplet Nanogenerator

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-03-24 DOI: 10.1002/aenm.202406116

Xin Chen, Yongqiang Zhang, Yi Huang, Yanjun Zhao, Fayang Wang, Pengfan Wu, Zhong Lin Wang, Xiaojing Mu, Ya Yang

引用次数: 0

Reduction-Induced Oxygen Loss: the Hidden Surface Reconstruction Mechanism of Layered Oxide Cathodes in Lithium-Ion Batteries (Adv. Energy Mater. 12/2025)

IF 24.4 1区材料科学

Advanced Energy Materials Pub Date : 2025-03-24 DOI: 10.1002/aenm.202570058

Seungyun Jeon, Gukhyun Lim, Hoseok Lee, Hyunyoung Park, Min Kyung Cho, Chan Kim, YeEun Lee, Jaehoon Kim, Minhyung Kwon, Jung-Keun Yoo, Hyangsoo Jeong, Jinwoo Kim, Seung-Ho Yu, Minah Lee, Jongsoon Kim, Jihyun Hong

引用次数: 0

Synergistic Improvement of Structural Ordering and Interface Binding of Hole Transport Monolayer for Efficient Inverted Perovskite Solar Cells 协同改善空穴传输单层的结构有序性和界面结合，实现高效反相包晶石太阳能电池

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-03-24 DOI: 10.1002/aenm.202500572

Ziyang Zhang, Tianhao Wu, Zhenzhen Qin, Mengjiong Chen, Wenxiang Xiang, Zhenhua Chen, Yanbo Wang, Zhanglin Guo, Toshinori Matsushima, Liyuan Han

{"title":"Synergistic Improvement of Structural Ordering and Interface Binding of Hole Transport Monolayer for Efficient Inverted Perovskite Solar Cells","authors":"Ziyang Zhang, Tianhao Wu, Zhenzhen Qin, Mengjiong Chen, Wenxiang Xiang, Zhenhua Chen, Yanbo Wang, Zhanglin Guo, Toshinori Matsushima, Liyuan Han","doi":"10.1002/aenm.202500572","DOIUrl":"https://doi.org/10.1002/aenm.202500572","url":null,"abstract":"The widespread application of self-assembled monolayer (SAM) hole transport materials has driven rapid advancements in the performance of inverted perovskite solar cells (PSCs). However, the difficulty of achieving a highly ordered SAM for hole transport and the weak binding strength between SAM and the perovskite layer not only leads to defective bottom interface but also reduces the compatibility with the large-area device fabrication. In this work, a co-assembled molecule functionalized with a diamide terminal group is demonstrated that is able to form supramolecular interaction with popular carbazole-based SAMs for regulating their structural ordering, and to improve the chemical bonding with perovskite Pb-I frameworks synergistically, which enables efficient and long-term stable inverted PSCs. As a result, the target co-assembled SAM contributes to a champion small-area device with a power conversion efficiency (PCE) of 25.3% (certified 25.0%), and demonstrates good compatibility with large-area fabrication by achieving highly reproducible performances in 1.02 cm2 devices. The encapsulated devices exhibit good stability with 92.8% and 91.2% of initial PCE after 1500 hours of aging under 85 °C and maximum power point (MPP) tracking at 65 °C for 1500 hours, respectively.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"93 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143695216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Breaking the Upper Limit of Substitution Concentration in Li Argyrodite Solid Electrolytes Using a Single-Solvent-Mediated Approach

IF 27.8 1区材料科学

Advanced Energy Materials Pub Date : 2025-03-23 DOI: 10.1002/aenm.202500532

Ji Woong Choi, Woong-Ju Kim, Suk-Ho Hwang, Sung-Chul Kim, Yoonju Shin, Sangdoo Ahn, Young Joo Lee, Jin Gu Kang, Dong-Wan Kim

{"title":"Breaking the Upper Limit of Substitution Concentration in Li Argyrodite Solid Electrolytes Using a Single-Solvent-Mediated Approach","authors":"Ji Woong Choi, Woong-Ju Kim, Suk-Ho Hwang, Sung-Chul Kim, Yoonju Shin, Sangdoo Ahn, Young Joo Lee, Jin Gu Kang, Dong-Wan Kim","doi":"10.1002/aenm.202500532","DOIUrl":"https://doi.org/10.1002/aenm.202500532","url":null,"abstract":"Although raising the substitution concentration of aliovalent cations in Li argyrodite solid electrolytes could boost solid-state battery performance, surpassing the known substitution limit has not been attempted. In this study, the upper substitution limit of a Li6+xP1−xSixS5Br solid electrolyte is increased using a single-solvent-mediated approach. The limit attained through this method is ≈40%, whereas that achieved through solid-state ball milling is ≈30%. This result is validated by monitoring variations in the interplanar distance, Raman shift, and ionic conductivity with respect to the substitution level. The ionic conductivity of Li6.4P0.6Si0.4S5Br is as high as ≈3.1 mS cm−1, exceeding that accomplished through ball milling. The enhanced limit is ascribed to the reduced particle size, which leads to an increased surface-area-to-volume ratio of the particles. This interpretation is supported by a theoretical formalism developed based on substituent accumulation within the space-charge layers, which predicts how the technical limit depends on the surface-volume fraction. A Li// Li6.4P0.6Si0.4S5Br//Li symmetric cell demonstrates excellent Li plating and stripping over extended cycling. A full cell incorporating Li6.4P0.6Si0.4S5Br retains ≈67% (96 mAh g−1) of its initial capacity (143 mAh g−1) after 50 cycles at 0.2 C, and delivers 76 mAh g−1 at 1 C.","PeriodicalId":111,"journal":{"name":"Advanced Energy Materials","volume":"183 1","pages":""},"PeriodicalIF":27.8,"publicationDate":"2025-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143678328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0