Dimitar N. Petrov , J. Ćwik , H.N. Nhat , D.-H. Kim , T.L. Phan
{"title":"Magnetocaloric effect of LiErP4O12 single crystal exhibiting competing ferromagnetic and anti-ferromagnetic interactions","authors":"Dimitar N. Petrov , J. Ćwik , H.N. Nhat , D.-H. Kim , T.L. Phan","doi":"10.1016/j.cap.2024.10.004","DOIUrl":"10.1016/j.cap.2024.10.004","url":null,"abstract":"<div><div>In this paper, we discuss the magnetic behavior and magnetocaloric effect of lithium erbium tetraphosphate (LiErP<sub>4</sub>O<sub>12</sub>) single crystal in the temperature range 2–85 K under magnetic fields up to 50 kOe. Detailed investigation of the temperature-dependent magnetization <em>M</em>(<em>T</em>) proves an existence of magnetic ordering below <em>T</em><sub><em>m</em></sub>, which has been estimated as a minimum in the <em>dM</em>/<em>dT vs</em>. <em>T</em> dependence. Above <em>T</em><sub><em>m</em></sub>, LiErP<sub>4</sub>O<sub>12</sub> possesses paramagnetic behavior and its magnetic susceptibility follows the Curie-Weiss law giving a higher value of the effective magnetic moment of Er<sup>3+</sup> compared to the theoretical one. This could be due to the Kramers spin degeneracy and the Stark structure of multiplets. Under an applied field <em>H</em> = 50 kOe, the maximum value of the magnetic-entropy change at 2 K reaches about 15 J/kgK, corresponding to a relative-cooling-power value of ∼343 J/kg. Assessments of the magnetic ordering exponent <em>n</em> and <em>N</em>(<em>T</em>, <em>H</em>) data prove LiErP<sub>4</sub>O<sub>12</sub> exhibiting short-range magnetic order. Due to the absence of magnetic hysteresis and large magnetocaloric response, we believe that LiErP<sub>4</sub>O<sub>12</sub> could be a promising candidate for magnetic-cooling applications in liquefying hydrogen and <sup>3</sup>He isotope.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"68 ","pages":"Pages 224-229"},"PeriodicalIF":2.4,"publicationDate":"2024-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142427498","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enhanced Joule heat release at surface irregularities","authors":"G.Sh. Boltachev, P.A. Russkikh, S.A. Chaikovsky","doi":"10.1016/j.cap.2024.09.013","DOIUrl":"10.1016/j.cap.2024.09.013","url":null,"abstract":"<div><div>The heat release that occurs in a cylindrical conductor carrying an alternating current is analyzed for the cases when the conductor has axisymmetric surface irregularities of one of three types: local bumps, local pits, and sequences of alternating bumps and pits (wavy irregularities). The magnetic field and current density distributions over the conductor cross section have been simulated. The simulation parameters were chosen to match the conditions of experiments on the generation of strong magnetic fields. However, due to the analysis of the initial heating stage, the problem is solved neglecting the temperature dependence of the resistivity of the material. A multiple increase in heat release power in the vicinity of a surface irregularity has been revealed for the three types of irregularities.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"68 ","pages":"Pages 189-195"},"PeriodicalIF":2.4,"publicationDate":"2024-10-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142427491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Piezoelectric flexible generator based on Mn-doped ZnO/PVDF composite films for energy harvesting application","authors":"Aman Kumar, Richa Sharma","doi":"10.1016/j.cap.2024.09.012","DOIUrl":"10.1016/j.cap.2024.09.012","url":null,"abstract":"<div><div>A flexible piezoelectric energy harvesting device was manufactured using Mn-doped ZnO (MnZ)/poly (vinylidene fluoride) (PVDF) composite film of various proportions of MnZ particles (5 wt%, 10 wt%, 20 wt% and 30 wt%) within the PVDF matrix. The phase formation, crystallinity and morphological characteristics of the fabricated composite films were analysed with the help of Fourier transform infrared (FTIR), X-ray diffraction (XRD), and Scanning Electron Microscopy (SEM). The piezoelectric performance of the constructed piezoelectric generator (PEG) device was measured by applying force on its surface which produced a significantly high open-circuit voltage of 344V and power density of 4.53 mW/cm<sup>2</sup>. Besides, these lead-free composite devices demonstrated remarkable sensitivity for human body motion detection in punching, finger bending, and wrist bending. Furthermore, practical usage of the fabricated PEG device was shown by powering devices like wristwatches, digital thermometers and glowing 20 light-emitting diodes (LEDs) of different colours.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"68 ","pages":"Pages 159-168"},"PeriodicalIF":2.4,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142358583","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jonggu Han , Jihoon Kim , Woojin Park , Sang Jun Park , Song Yi Baek , Byeongsun Yoo , Chulhwan Choi , Se Youn Moon
{"title":"Spatially-resolved spectroscopic investigation of the inhomogeneous magnetic field effects on a low-pressure capacitively-coupled nitrogen plasma","authors":"Jonggu Han , Jihoon Kim , Woojin Park , Sang Jun Park , Song Yi Baek , Byeongsun Yoo , Chulhwan Choi , Se Youn Moon","doi":"10.1016/j.cap.2024.09.010","DOIUrl":"10.1016/j.cap.2024.09.010","url":null,"abstract":"<div><div>Although magnetized plasmas have been frequently used to enhance the process rate or improve the film quality via the control of ion flux as well as energy and plasma density in semiconductor processes, the inhomogeneous magnetic field—which leads to plasma non-uniformity—remains as a problem to be solved. To address this problem, it is essential to conduct a comprehensive assessment of the magnetic effect throughout the entire discharge. Therefore, in the present study, we investigated the magnetic field effects (B < 100 G) on a capacitively-coupled nitrogen plasma based on spectroscopic analyses. The spatially-resolved emission spectra were measured along the radial direction at various vertical positions under the pressures of 10 mTorr and 250 mTorr both with and without magnetic field. By analyzing emission spectra such as N<sub>2</sub> FPS, N<sub>2</sub> SPS, N<sub>2</sub><sup>+</sup> FNS, and N I, we were able to obtain the radial distributions of reactive species density, vibrational temperature, and excitation temperature. In low-pressure plasma, with the application of a magnetic field, maximum increases in vibrational temperature and excitation temperature of 462 K and 491 K, respectively, were observed within the bulk region beneath the magnet. This magnetic effect resulted in a significant increase in reactive species density along the radial direction. It was also found that the local enhancement of ion density by magnetic field was strongly related to the increase in excitation temperature and the density of the N<sub>2</sub><sup>+</sup>(B) state. From this result, it is suggested that introducing an asymmetric magnetic field could modulate the spatial distributions of the physical and chemical properties of the plasma.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"68 ","pages":"Pages 180-188"},"PeriodicalIF":2.4,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142427490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rahul Kumar Yadav, Neha Bisht, Parag R. Patil, Ho Jae Ki, Sang Won Lee, Yong Tae Kim, Pravin S. Pawar, Indu Sharma, Vishesh Manjunath, Jaeyeong Heo
{"title":"A comprehensive numerical study of bilayer SnSe/SnS absorber based solar cells","authors":"Rahul Kumar Yadav, Neha Bisht, Parag R. Patil, Ho Jae Ki, Sang Won Lee, Yong Tae Kim, Pravin S. Pawar, Indu Sharma, Vishesh Manjunath, Jaeyeong Heo","doi":"10.1016/j.cap.2024.09.011","DOIUrl":"10.1016/j.cap.2024.09.011","url":null,"abstract":"<div><div>Herein, we present the simulation (using the SCAPS-1D program), of a bilayer absorber solar cell. First, we numerically studied the bilayer model using our experimentally observed parameters and investigated the results. The results from the bilayer absorber (SnSe/SnS) numerical analysis were then compared with a single (SnS and SnSe) absorber modeling. The optimized device with a bilayer absorber exhibited the highest performance, with a photo conversion efficiency (PCE) of 22.35%. In comparison, the single SnS and SnSe absorbers achieved a PCE of 14.79% and 13.69%. Furthermore, we compared this numerical study with our previous study having the same configuration. Although there was a significant difference in performance between the simulated and experimental studies, the outcomes of the fabricated devices exhibited similar trends to the simulations. Finally, we attempted to determine the key parameters responsible for the reduced performance in the experimental study.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"68 ","pages":"Pages 169-179"},"PeriodicalIF":2.4,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142358584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Exploring interfacial stability for Zr-doped sulfide solid electrolyte with first-principle calculation","authors":"Junbo Zhang , Wenjin Gong , Nini Qian , Bingbing Chen , Jianqiu Zhou","doi":"10.1016/j.cap.2024.09.009","DOIUrl":"10.1016/j.cap.2024.09.009","url":null,"abstract":"<div><div>First-principles calculations are employed to investigate the interfacial properties on the Zr-doped sulfide solid electrolytes. Theoretical calculation results show that the PS<sub>4</sub> tetrahedral structure near the Li/Li<sub>3</sub>PS<sub>4</sub> interface is severely damaged, whereas the Zr-doped sulfide solid electrolyte interface structure has a slight deformation. The Li ions migration energy barrier on the Zr-doped sulfide solid electrolyte interface is relatively lower than that on the Li/Li<sub>3</sub>PS<sub>4</sub>. Moreover, the stress-strain analysis indicates that the Li/Li<sub>3</sub>PS<sub>4</sub> interface structure experiences a maximum strain of only 6 %, while the Zr-doped sulfide solid electrolyte interface structure experiences a maximum strain of 10 %. This may be attributed to the ability of Zr doping to prevent S<sup>2−</sup> diffusion into the lithium metal anode and stabilize the Li ion transport skeleton. Therefore, Zr doping can improve the interface structure stability. This study will provide a useful perspective for designing high performance of solid electrolytes for the application of all-solid-state batteries.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"68 ","pages":"Pages 144-150"},"PeriodicalIF":2.4,"publicationDate":"2024-09-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142327949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Electrical characterization of lead-modified bismuth borovanadate glasses","authors":"Asha Rani , Rajesh Parmar , R.S. Kundu","doi":"10.1016/j.cap.2024.09.008","DOIUrl":"10.1016/j.cap.2024.09.008","url":null,"abstract":"<div><div>Specifically, the study looks into dielectric characteristics (<span><math><mrow><msup><mi>ε</mi><mo>′</mo></msup><mtext>and</mtext><mspace></mspace><msup><mi>ε</mi><mo>″</mo></msup></mrow></math></span>) and complex modulus formulation and AC conductivity of lead-modified bismuth borovanadate glasses (50-x) V<sub>2</sub>O<sub>5</sub>-40 B<sub>2</sub>O<sub>3</sub>-10 Bi<sub>2</sub>O<sub>3</sub>-xPbO, where x = 5,10, 15, 20 and 25 mol% with sample ID's VPb1, VPb2, VPb3, VPb4 & VPb5 according to different compositions of lead and vanadate. When the PbO content rises, there is a decreasing tendency in both the alternating current conductivity and dielectric constants. In order to fit AC conductivity data, Almond West equation is used to extract parameters, including crossover frequency (<span><math><mrow><msub><mi>ω</mi><mi>H</mi></msub></mrow></math></span>), frequency exponent (s), and direct current conductivity (<span><math><mrow><msub><mi>σ</mi><mrow><mi>d</mi><mi>c</mi></mrow></msub><mo>)</mo></mrow></math></span>. Direct current conduction mechanism in all glass samples except VPb5 [Correlated Barriers Hopping (CBH) conduction at all frequencies] at lower frequencies might potentially be attributed to large-polaron quantum mechanical tunneling (LQMT). Similar to this, at high frequencies, small polaron quantum mechanical tunnelling is followed by VPb2 & VPb3 while LQMT is followed by VPb1 & VPb4. Activation energy of dc conduction (<span><math><mrow><msub><mi>E</mi><mtext>dc</mtext></msub></mrow></math></span>) at higher frequencies (0.373–0.476 eV) for samples having sample ID VPb1 to VPb4 and sample VPb5 at all frequencies with <span><math><mrow><msub><mi>E</mi><mtext>dc</mtext></msub></mrow></math></span> 0.686 eV and modulus activation energy <span><math><mrow><mo>(</mo><msub><mi>E</mi><mi>R</mi></msub><mo>)</mo></mrow></math></span> (0.382–0.534 eV) are found in good agreement. Dielectric studies reveal non-Debye-type behaviour.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"68 ","pages":"Pages 151-158"},"PeriodicalIF":2.4,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142358582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
See-eun Tae , Ahmed Yousef Mohamed , Kosuke Kitase , Takafumi Kitazawa , Deok-Yong Cho
{"title":"Understanding spin-dependent vibrational frequencies in Fe(II) metal organic coordination complexes","authors":"See-eun Tae , Ahmed Yousef Mohamed , Kosuke Kitase , Takafumi Kitazawa , Deok-Yong Cho","doi":"10.1016/j.cap.2024.09.007","DOIUrl":"10.1016/j.cap.2024.09.007","url":null,"abstract":"<div><p>We investigated the compositional and temperature (<em>T</em>) dependences of vibrational frequencies in Hofmann-type Fe(<em>L</em>)<sub>2</sub>[<em>M</em>(CN)<sub>4</sub>] spin-crossover (SCO) coordination polymers in which {<em>M</em> = Ni, Pd or Pt with <em>L</em> = pyridine (py)}, or {<em>L</em> = 3-Cl-py or 3-methylpy with <em>M</em> = Ni}, using Raman spectroscopy. The SCO-driven peak shifts (in wavenumber) ranged up to ∼170 cm<sup>−1</sup>, manifesting significant spin-dependent structural evolutions. Furthermore, there appear clear HS signatures even at <em>T</em> ≪ <em>T</em><sub>SCO</sub> for <em>L</em> = 3-Cl-py or 3-methylpy implying the steric effects of the organic ligands on the HS trapping. Meanwhile, for <em>L</em> = py, such HS trapping at the low temperature was not significant although some spectra taken under high laser fluence exhibit light-induced excited spin state trapping (LIESST) effect. The mechanism of the LIESST is discussed in detail in terms of the <em>M</em> d – C 2sp hybridization effects.</p></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"68 ","pages":"Pages 138-143"},"PeriodicalIF":2.4,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142243733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hanwool Seong , Won-Young Choi , Jongbum Choi , Duck-Ho Kim , Tae-Eon Park , Byoung-Chul Min , Heon-Jin Choi , Dong-Soo Han
{"title":"Magnetic properties of GdFeCo thin films tailored by sputtering conditions","authors":"Hanwool Seong , Won-Young Choi , Jongbum Choi , Duck-Ho Kim , Tae-Eon Park , Byoung-Chul Min , Heon-Jin Choi , Dong-Soo Han","doi":"10.1016/j.cap.2024.09.006","DOIUrl":"10.1016/j.cap.2024.09.006","url":null,"abstract":"<div><p>The unique properties of ferrimagnets including easy detection of their dynamic and static states, strong resistance to external disturbances, and rapid dynamic characteristics, have made them attractive in the spintronics community. Our study focuses on the engineering of these magnetic properties of ferrimagnets, particularly employing a GdFeCo alloy, a prominent ferrimagnetic material, by utilizing magnetron sputtering. A series of GdFeCo films are fabricated by altering their thicknesses and working pressure during the sputtering process. Our experimental results reveal that these sputtering parameters significantly influence a Gd composition within the films, which in turn affects critical properties of ferrimagnets such as magnetic anisotropy, and magnetic moment compensation temperature. By precisely controlling these sputtering parameters, we successfully tailored the magnetic properties of the GdFeCo thin films with desired properties, offering new possibilities for the creation of sophisticated magnetic materials tailored to specific technological needs.</p></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"68 ","pages":"Pages 131-137"},"PeriodicalIF":2.4,"publicationDate":"2024-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142227941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of bromine on the formation of δ-CsPbI3 in Cs0.22FA0.78Pb(I1-xBrx)3 perovskite solar cells","authors":"Muntae Hwang, Il-Wook Cho, Jaewon Oh, Hyunbok Lee, Mee-Yi Ryu","doi":"10.1016/j.cap.2024.09.005","DOIUrl":"10.1016/j.cap.2024.09.005","url":null,"abstract":"<div><p>Applying Cs<sub>x</sub>FA<sub>1-x</sub>PbI<sub>3</sub> perovskite is a useful strategy for synthesizing high-efficiency organic-inorganic lead halide perovskite solar cells because it improves the stability of the perovskite structure. High concentration of cesium (Cs) in CsFAPbI<sub>3</sub> synthesized under ambient conditions typically lead to phase separation due to <em>δ</em>-CsPbI<sub>3</sub> formation and moisture, thereby reducing light absorption and increasing non-radiative recombination. To counter this, we fabricated the mixed halide Cs<sub>0.22</sub>FA<sub>0.78</sub>Pb(I<sub>1-x</sub>Br<sub>x</sub>)<sub>3</sub> perovskite films. Introducing bromine (Br) content effectively reduced the <em>δ</em>-CsPbI<sub>3</sub> formation and grain boundaries, thus suppressing the non-radiative recombination between perovskite and charge transport layers. Employing this approach, our perovskite solar cells with a 10 % Br concentration achieved a power conversion efficiency of 15.81 %. This demonstrates the potential of Br incorporation in enhancing the stability and efficiency of perovskite solar cells.</p></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"68 ","pages":"Pages 108-112"},"PeriodicalIF":2.4,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142168889","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}